WO2012011768A2 - Composition de nettoyant pour démaquiller la peau - Google Patents

Composition de nettoyant pour démaquiller la peau Download PDF

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Publication number
WO2012011768A2
WO2012011768A2 PCT/KR2011/005412 KR2011005412W WO2012011768A2 WO 2012011768 A2 WO2012011768 A2 WO 2012011768A2 KR 2011005412 W KR2011005412 W KR 2011005412W WO 2012011768 A2 WO2012011768 A2 WO 2012011768A2
Authority
WO
WIPO (PCT)
Prior art keywords
composition
makeup
peg
dimethicone
silicone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2011/005412
Other languages
English (en)
Korean (ko)
Other versions
WO2012011768A3 (fr
Inventor
정창조
김대경
이존환
김현나
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amorepacific Corp
Original Assignee
Amorepacific Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020100071147A external-priority patent/KR101829372B1/ko
Priority claimed from KR1020110005752A external-priority patent/KR101778273B1/ko
Application filed by Amorepacific Corp filed Critical Amorepacific Corp
Publication of WO2012011768A2 publication Critical patent/WO2012011768A2/fr
Publication of WO2012011768A3 publication Critical patent/WO2012011768A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up

Definitions

  • the present invention relates to a makeup detergent composition that effectively removes makeup and at the same time provides freshness after cleansing.
  • a silicone-based surfactant is used as a surfactant in a detergent composition, and when used with a specific polyol, the makeup may be well erased and the residue may be less refreshed after washing.
  • silicone-based surfactants in which PEG is added to both ends of the silicone can provide a bubble-type cleaner that has excellent bubble retention ability, excellent makeup removal effect, and cleansing.
  • the present invention is a silicone-based surfactant and poly It provides a makeup cleaner composition comprising a.
  • the present invention provides a detergent composition
  • a detergent composition comprising a silicone-based surfactant having a high hydrophilicity by adding PEG to both ends of the silicone and a surfactant having a foaming ability as an active ingredient.
  • Makeup makeup composition according to the present invention while the makeup is effectively removed, there is no residue can be a refreshing face wash and can eliminate the hassle of the double face wash.
  • Figure 1 shows the result after applying the lipstick to the bioskin and then removed using various silicone-based surfactants.
  • Figure 2 shows the result after removing the lipstick using various polyols after applying the lipstick to the bioskin.
  • Figure 3 shows the result after removing the makeup using Comparative Example 1 of the cleaning composition prepared by applying the lipstick to the bioskin and then the composition of Table 3.
  • 4 is a lipstick applied to a bioskin, and then a polyol is glyces_26 (M-Hydro).
  • FIG. 5 shows the application of lipstick to bioskin followed by polyol methyl glue-
  • FIG. 6 illustrates the application of a lipstick to a bioskin and then varying the content of PEG-dimethicone isostearate (Si 1 wax WD-IS) and glycerin -26 (M—Hydro EG), which are silicone surfactants. The result after removing make-up using the detergent composition prepared by prescription is shown.
  • PEG-dimethicone isostearate Si 1 wax WD-IS
  • M—Hydro EG glycerin -26
  • FIG. 8 is a graph showing the bubble power of the bubble foam type detergent composition according to the present invention.
  • FIG. 9 is a photograph showing the makeup removal power of the bubble product type cleaner composition according to the present invention.
  • the present invention is a cleansing clean through simultaneous cleansing with effective makeup removal This provides a possible makeup cleanser composition.
  • the present invention provides a makeup detergent composition comprising a silicone-based surfactant and a polyol.
  • the silicone-based surfactants included in the composition of the present invention may be dimethicone PEG-8 laurate, dimethicone PEG-8 succinate, PEG-12 dimethicone (PEG- 12 Dimethicone, PEG-10 Dimethicone, PEG7-Dimethicone Isostearate, Organomodified trimethyl ammonium chloride polydimethylsi 1 ixane, Silicon Quarter Si 1 ic le quaternium-8, silicon quaternium-20, Isopropyl phenyl Dimethicone, cetyl PEG / PPG-10 / 1 dimethicone (Cetyl PEG / PPG-10 / 1 Dimethicone) and lauryl PEG— 8 dimethicone may be one or more selected from the group consisting of, in particular, dimethicone page-7 isostearate It is preferable to use.
  • R is derived from C18 methyl branched isostearic acid, with a total of 18 carbon atoms.
  • the polyol included in the composition of the present invention is PEG.PPG.polybutylene glycol -8.5.3 glycerin (PEG.PPG.Polybutylene Glycol-8.5.3 Glycerin), methyl glutes- 20 (Methyl Gluceth-20), Glycereth-26 (Glycereth_26), Hexylene Glycol, Diglycerin / Methyl Gluces-10 / PEG150 / PPG30 / Eryoxy Diglycol / Glyceres-12 / Diethoxydi Glycol (Diglycerine / methyl g 1 ucet h-10 / PEG150 / PPG30 / Et hoxy
  • At least one selected from the group consisting of Diglycol / Glycereth-12 / Diethoxydiglycol, Glycerine, Butylene Glycol, Propylene Glycol, PEG-400 and Dipropyleneglycol In particular, it is preferable to use glycerin -26.
  • the content of the silicone-based surfactant and the polyol used in the present invention may be 12 to 50 weight 3 ⁇ 4 '' based on the total weight of the composition.
  • the content of the silicone surfactant used in the present invention is 2 to 30% by weight based on the total weight of the composition, preferably 10 to 30% by weight. This is to maximize the makeup efficacy and usability of the cleaning composition and to balance the component content with other components.
  • the added polyol, together with the silicone-based surfactant, serves to increase the make-up removal force.
  • composition of the present invention may further contain a fatty acid salt for a refreshing feeling.
  • the fatty acid salt may include laurate, myristic acid salt or a mixture thereof.
  • a soap component having a carboxyl group or a surfactant is used for the detergent used to give a refreshing feeling. This is because soap components or surfactants with a carboxyl group create a feeling of crispness by generating divalent ions and soap-soap in water when washing the face.
  • the fatty acid salt is contained in an amount of 5 to 40% by weight based on the total weight of the composition.
  • the present invention provides a makeup detergent composition comprising a silicone-based surfactant and a surfactant having a foam forming ability.
  • the silicone-based surfactant included in the composition of the present invention is a compound having high hydrophilicity by adding polyethylene glycol (PEG) to both ends of the silicone, and particularly, a bis-pG-18 having excellent cleansing and bubble retention. Preference is given to using dimethyl ether dimethicone (Bis-PEG-18 dimethyl ether dimethicone).
  • the foam-forming surfactant contained in the composition of the present invention Fatty acid soap, sodium lauryl sulfate, sodium laureth sulfate, ammonium lauryl sulfate, ammonium laureth sulfate, lauryl glucose carboxylate, potassium glycinate, lauryl glucoside, decyl glucoside, coco glucoside, cocamidoprofil It may be a surfactant capable of foaming in anionic, nonionic or amphoteric ions such as betaine and cocamidopropyl hydroxy sultaine.
  • the composition of the present invention preferably uses fatty acid soap for fresh face wash, which refers to fatty acid salts produced by the neutralization reaction of fatty acids and alkali chemicals. More specifically, saturated fatty acids having 12 to 22 carbon atoms, which form fatty acid soaps from fatty acids, may be used. Specific examples thereof include lauric acid, mystic acid, palmitic acid, stearic acid and behenic. There is an acid.
  • the content of the silicone surfactant used in the present invention is 5 to 30% by weight based on the total weight of the composition. It is less than 5% by weight make-up removal power is lower, more than 30% by weight is difficult to formulate, it may cause eye irritation, so the content was limited as described above.
  • the content of the foam-forming surfactant used in the present invention is 5 to 30% by weight based on the total weight of the composition. If the content is less than 5% by weight, the detergency is poor, and if the content exceeds 30% by weight 3 ⁇ 4> it is not preferable because it can cause eye irritation when entering the eye and it is difficult to make a bubble product with a high viscosity.
  • composition of the present invention may further contain at least one polyol selected from the group consisting of glycerin, butylene glycol and propylene glycol to help bubble retention. This not only increases the makeup removal power additionally, but also drains the bubbles.
  • the content of the polyol is 5 to 20% by weight based on the total weight of the composition. At less than 5% by weight, the effect is insignificant, and at more than 20% by weight, since the foam formation decreases due to the increase in viscosity, the content is limited as described above.
  • At least one surfactant having a foaming ability based on the total weight of the composition 5 to 30% by weight, 5 to 30% by weight of a bis-P-E-18 dimethyl ether dimethicone, 5 to polyol It provides a bubble foam type detergent composition consisting of 20% by weight and 20 to 85% by weight of purified water.
  • the cleaning composition of the present invention is preferably a bubble article type that is discharged in the form of bubbles through a forming container (bubble article container).
  • silicone-based surfactants were considered in consideration of the selection of the surfactant.
  • the silicone surfactant was selected from 11 raw materials of SILTECH in consideration of compatibility with water and oil as shown in Table 1 below, and a makeup removal test was performed.
  • test method is the same as the method used for the silicon-based surfactant, the results are shown in FIG.
  • silicone-based surfactant and poly, fragrance, preservatives, etc. were prepared at around 40 ° C.
  • poly was fixed to methyl glueses 20 (GLUCAM E-20) and prepared by formulating a cleaning composition according to the type of silicone surfactant (unit: weight «.
  • the cleaning composition of Table 4 was prepared in the same manner as in Test Example 3, and the make-up removal effect was observed in the same manner as the method used in Test Example 1, and the results thereof are shown in FIG. It was.
  • Example Work Example 9 Example 10 Examination Example 11
  • Example 12 Water 12.43 43.2 43.2 43.2 Interest Rate Serine 10
  • 10 Oily Lauric Acid 3 3 3 3 3 Myristic Acid 7 7 7 7 Neutralization TEA 6.8 6.8 6.8 6.8 6.8
  • O-Hydro EG 28 25 20 0 Incense appropriate amount, 3 ⁇ 4 amount, Preservative phenoxyethanol amount, appropriate amount
  • Comparative Example 2 is a general bubble cleansing product composition
  • Comparative Example 3 is a bubble cleansing product composition containing a PHYG-7 dimethicone isostearate
  • Examples 17 to 19 are bis-PG-18 dimethyl of the present invention
  • compare Examples 2 to 3 and Example 17 are 20% by weight of the content of fatty acid soap relative to the total weight of the composition
  • Examples 18-19 reduce the fatty acid soap content to 10% by weight of half, instead to improve the foaming force
  • Cocamidopropyl hydroxy sulfane or polyloglycerin, butyleneglycol was used as a co-surfactant (unit: weight%).
  • the chelating agent was added to purified water, and fatty acid, polyol, and the like were added thereto, followed by heating and dissolving at about 70 ° C., neutralization by addition of alkali, followed by mixing and cooling with flavor and preservative. .
  • the chelating agent is added to purified water, and then, polyol and fatty acid are added thereto, heated and dissolved at about 70 ° C., neutralized by addition of alkali, and then bis-pizzy-18 dimethyl ether dimethicone or fiji. -7 dimethicone isostearate was added and dissolved. Subsequently, additives such as fragrance and preservatives were added to the mixture, followed by cooling.
  • Part Tester foam tester, SITA foam tester
  • Example 17 containing bis-pG-18 dimethyl ether dimethicone was similarly high as that of Comparative Example 2, which has a general foaming force.
  • Comparative Example 3 containing a sebum-7 dimethicone isostearate has a lower foaming force than Examples 17-19, and when applied to a bubble article because the viscosity is high, bubbles are not easily formed and it is easily broken off. It was found that the foam was not discharged well but quickly disappeared.
  • Example 18 reduces the content of fatty acid soap in half than that of Example 17, and instead improves the foaming force using the amphoteric surfactant cocamidopropyl hydroxy sulphate and polyolol to improve the foaming force similar to that of Example 17
  • the fatty acid soap was contained in an amount of 10% by weight based on the total weight of the composition, and the polyol mixture of glycerin and butylene glycol was further included in the same manner as in Example 18 to improve foaming power. Than foam was lower.
  • Example 18 and Example 19 although the content of fatty acid soap is lower than that of Example 17, it further contains an auxiliary surfactant and a polyol, thereby providing excellent foaming and cleansing power, and simultaneously removing makeup and washing the face. The effect was excellent as a possible bubble product.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne une composition de nettoyant pour démaquiller la peau. La composition de la présente invention comprend un tensio-actif à base de silicium et un polyol ou un tensio-actif à base de silicium, dans lequel PEG est ajouté aux deux terminaisons du silicium pour accroître le caractère hydrophile, et un tensio-actif possédant une capacité de génération de mousse pour démaquiller efficacement et procurer aux utilisateurs une sensation de fraîcheur après le lavage.
PCT/KR2011/005412 2010-07-23 2011-07-22 Composition de nettoyant pour démaquiller la peau Ceased WO2012011768A2 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR1020100071147A KR101829372B1 (ko) 2010-07-23 2010-07-23 메이크업 세정제 조성물
KR10-2010-0071147 2010-07-23
KR1020110005752A KR101778273B1 (ko) 2011-01-20 2011-01-20 메이크업 제거와 개운한 세안이 가능한 버블폼 타입 세안제
KR10-2011-0005752 2011-01-20

Publications (2)

Publication Number Publication Date
WO2012011768A2 true WO2012011768A2 (fr) 2012-01-26
WO2012011768A3 WO2012011768A3 (fr) 2012-05-31

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PCT/KR2011/005412 Ceased WO2012011768A2 (fr) 2010-07-23 2011-07-22 Composition de nettoyant pour démaquiller la peau

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220096357A1 (en) * 2020-09-30 2022-03-31 L'oreal Hydrating no-rinse composition for makeup removal
CN118021642A (zh) * 2024-02-04 2024-05-14 凡可生物技术(广州)有限公司 一种具有优异起泡性和卸妆力的洗卸二合一组合物及其应用、制品

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10298032A (ja) * 1997-04-30 1998-11-10 Shiseido Co Ltd メーキャップ除去料
FR2789307B1 (fr) * 1999-02-08 2001-03-09 Oreal Composition cosmetique de demaquillage et/ou de nettoyage sous forme d'emulsion eau-dans-huile
KR100377261B1 (ko) * 2000-11-13 2003-03-26 애경산업(주) 고분자 유화 타입의 오일-프리형 수중유 조성물
FR2881342B1 (fr) * 2005-01-31 2007-03-02 Oreal Composition demaquillante
KR101508398B1 (ko) * 2007-05-15 2015-04-06 가부시키가이샤 시세이도 베시클 함유 조성물과 그 제조 방법

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220096357A1 (en) * 2020-09-30 2022-03-31 L'oreal Hydrating no-rinse composition for makeup removal
CN118021642A (zh) * 2024-02-04 2024-05-14 凡可生物技术(广州)有限公司 一种具有优异起泡性和卸妆力的洗卸二合一组合物及其应用、制品

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Publication number Publication date
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