WO2012085539A1 - Composition de nettoyage et procédé - Google Patents

Composition de nettoyage et procédé Download PDF

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Publication number
WO2012085539A1
WO2012085539A1 PCT/GB2011/052480 GB2011052480W WO2012085539A1 WO 2012085539 A1 WO2012085539 A1 WO 2012085539A1 GB 2011052480 W GB2011052480 W GB 2011052480W WO 2012085539 A1 WO2012085539 A1 WO 2012085539A1
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WO
WIPO (PCT)
Prior art keywords
phase comprises
oil
oil phase
composition according
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2011/052480
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English (en)
Inventor
Tim DUNSTAN
Paul D. I. Fletcher
Lee GRIFFITHS
Malcolm Tom Mckechnie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt and Colman Overseas Ltd
Original Assignee
Reckitt and Colman Overseas Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reckitt and Colman Overseas Ltd filed Critical Reckitt and Colman Overseas Ltd
Priority to EP11807719.7A priority Critical patent/EP2655589A1/fr
Publication of WO2012085539A1 publication Critical patent/WO2012085539A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C11D3/184—Hydrocarbons unsaturated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/2017—Monohydric alcohols branched
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/24—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/24—Hydrocarbons
    • C11D7/244—Hydrocarbons unsaturated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/261—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50—Solvents
    • C11D7/5004—Organic solvents
    • C11D7/5027—Hydrocarbons

Definitions

  • This invention relates; to cleaning compositions and cleaning methods, employing water- in-oil emulsions ,
  • Detergent formulator-s are faced wi ' tli the task of devising products to remove a broad spectrum ox soils and stains from fabrics.
  • Chemically and physieo -chemically the varieties of soils and stains range the spectrum from primarily oily, through proteinaceous and carbohydrate, to inorganic, and detergent compositions have become more complex as formula- tors attempt to provide products which handle ail types, concurrently.
  • protease enzymes are commonly used in detergents for blood and gravy stains; amylase enzymes are used for carbohydrate stains; nonionic surfactants are used for hydrocarbon oils; and anionic surfactants and builders are used for particulate soil.
  • Bleach is used to chemically degrade stains that are not amenable to removal by less rigorous treatment .
  • Cosmetics are typically manufactured with great care, such that the clay and color bodies are i the form of very fine particles . , and are very t horoughly and completely mixed with,, and coated by, the oily material, which may be a hydrocarbon oil, silicone, lipid, or complex, mixtures thereof. While op- timai from the standpoint of the cosmetic formulator , the modern cosmetic product causes ma or problems for the detergent formulator,. since cosmetics constitute a mix of widely divergent soil types ⁇ oily, particulate, clay) all in intimate admixture and often brightly colored. No single deter- gent ingredient can reasonably be expected to handle such a. cdm 1 x rai l eu .
  • solvents of the type employed in this invention as grease and oil removal ingredients in cleaners of various types is well-known.
  • the use of such solvent is not without its one set of difficulties. Many of. the solvents which can. find utility in addressing oil stains have no effect or even a detri- mental effect on non-oily stains, typically cussing smearing. In some cases the solvents used may remove a stain from a first area only to redepos.it it in. a second area or other the entir item being cleaned. Moreover some solvents can provide a barrier to a stai such that components of a detergen formulation, present in the aqueous phase thereof are unable to contact a stain.
  • a cleaning composition comprising a water -i -oil emulsion, wherein the oil phase comprises a solvent having a Hiidebrand parameter of from 12 - 20.
  • the solvent is immiscible with water .
  • the solvent is in liquid form at room temperature and pres- sure ,
  • the solvent preferably comprises a ⁇ 3 ⁇ 4.o-Q aikene or alkane (e . g;. dodecene, dod eane)- or 4-me hyl -2 -pentanol .
  • a cleaning composition comprising a water - in-oil emulsion, wherein the oil phase comprises a 3 ⁇ 4 .
  • 3-- ⁇ 4 aikene or alkane e.g. dodecene, dodeeane
  • -msthyl- 2- entanol e.g. dodecene, dodeeane
  • a bleaching agent is present .
  • a cleaning composi ion comprising a water- in-oil emulsion, wherein the aqueous phase comprises a bleaching agent and the oil phase comprises a solvent having a Hildebrand parameter of from 12 - 20..
  • the sol ent preferably comprises a G . o- '1 aikene or alkane (e.g. dodecene, dodeeane) or 4 -methyl - 2 -pentanol , It has been .found that the formulation of the : invention has surprising performance advantages. These advantages ' are shown, particularly on oily / greas stains such as lipstick stains / mo or oils stains / boot polish stains ⁇ on fabric surfaces ⁇ .
  • the 0 10 ⁇ 4 aikene or alkane or 4 ⁇ methyls 2- pentanol contacts the stain first (and enables the dissolution / disruption of any grease component of the stain) and then the aqueous part of the formulation (which may contain a bleaching agent or other detergent active such as an -enzyme or surfactant) contacts the stain.
  • the aqueous part of the formulation which may contain a bleaching agent or other detergent active such as an -enzyme or surfactant
  • the composition comprises two independent aqueous phases.
  • the composition is in the form of ah oil in water i oil emulsion !GWO) or a water in oil in water (WOW) emulsion .
  • the composition Comprises a bl.ea.cii activator.
  • the bleach activator may be present, in an aqueous phase or in an oil phase.
  • the bleach activator is segregated from the bleaching agent.
  • the bleach activator is possibly in particulate form.
  • th bleach activator is selected from tetraace- tylethylendiatr.ine (TAED) , acetylated trxa.zine derivatives, n par icular 1,5- Diacetyl-2 , -dioxohexahydro- 1,3,5 -triazine (DADHT) , acetylated glycoiuriles, in particular Tetraacetyl ⁇ glycolurile ⁇ TAC3U ⁇ , acylimides, in particular n- nonanoylsucciniiTiide (NOSI) , acetylated phenolsulfonates , in particular n-nonanoyloxi or n -lauroyloxibenaolsulfonate (NOBS and/or PRAISE), acetylated phenol carbonic acids, in particular nonanoyloxi or d.ecancyloxibenzoesaeure (NOSI
  • Bleaching catalysts may be present.
  • Preferred examples include complexes of manganese, iron, cobalt, ruthenium, molybdenum, ti fca.nlurn or vanadium.
  • manganese salts are in the oxidation state +2 or +3 preferentially, for example manganese haiides, whereby the chloride is preferential.
  • manganese sulfate, manganese salts of organic acids such as manganese acetates, acetyla.eet.ona.te , oxalates as well as manganese nitrates are suitable.
  • Metal complexes with, maeromolecul r ligands may be used, such as! , 4 f 7 • - ⁇ Trimetliyi ⁇ - 1,4 , 7 - triazacyclononane (me -TACK5 1,4,7- T iazacyclononane (TA N) , 1, 5 , 9 -Trimethyl - 1 , 5 , $- triazacyciododecane .(me-TACD) , 2 -Methyl -1 , 4 , 7 trimethyl-- .1,4, 7 -triazaeyclononane (MeMeTACM) and/or 2 - Methyl - 1 , 4 , 7 triaisacyclononane ( e TACS) or ligands suc as 1,-2 -bis (4,7- Dimethyl 1,4,7- triazacyclonono -1-yl ) ethane (Me4-DTNE ⁇ .
  • the bleaching agent is usually a source of active oxygen, e.g. tirea / hydrogen peroxide.
  • the bleaching agent may be based on alternative chemistry, e.g. chlorine based bleach- ing agents, such as hypochlorite bleaches.
  • bleaching agents such as phthalittddo -peroxy-hexanoic- acid (PAP) per -sal s such as perborate, percarfooxiate , persulphate; are substantially insoluble in water (e.g. having a solubility of less than. 0.6g/litre of demineral ised water at 25°C.
  • PAP phthalittddo -peroxy-hexanoic- acid
  • per -sal s such as perborate, percarfooxiate , persulphate
  • PAP phthalittddo -peroxy-hexanoic- acid
  • dodecene, dodecaneS or 4-methyl-2 -pentahol wherein a substantially water insoluble bleaching agent is suspended in an aqueous phase or an oil phase.
  • the bleaching agent is in particulate form generally it has a particle size of 0..0001 to 2mm, e.g. such as Imnr.
  • the aqueous phase comprises 70-90% fay weight of t e compos i tion .
  • the oil phase preferably comprises 10-30% by weight of the coraposi tion ,
  • compositions of the invention have substant ally no transport between the oil and water phases.
  • the composition of the present invention preferably further comprises up to 10% by weight of a surfactant, preferably up to 8%, more preferably up to 5%, preferably up to .3%, and most preferably up to 2% by weight of each phase. It is postulated that the surfactant forms a micelle type barriei * around the water particles present in the emulsion.
  • the aqueous phase composition comprises a least 0.1% by weight (cleaning) surfactant, preferably at least 0,5%, more preferably at least 1%. more preferably at. least 2% by weight, more preferably at least 5% by weight and most preferably at least 10% by weight.
  • the cleaning composition desirably includes at leas one surfactant selected from anionic, cationic, non- ionic or amphoteric -(zwxtterionic) surfactants.
  • surfactants are those formed by the reaction of succinic acid I or succinic anhydride II, with a polyol , a polyaraiiie or a hydroxylamine.
  • R is a hydrocarbon group having rom about 12 to .about 200 carbon atoms, preferably 12 to about 100 carbo atoms,, more preferably 12 to SO and most preferably IS to 30 carbon atoms ,
  • the hydrocarbon grou R in the above formulae ma be derived from an alpha -olefin o an alpha -olefin fraction.
  • the alpha- olefins include l-dodecene, 1- trideeene, 1 ⁇ tetradecene, 1 -pentadecene , ⁇ -- bexadecene,. 1 -hept-adecene, I-octadecene , 1- eicosene, 1-triconfene , and the like.
  • the alpha olefin factions that are useful include Q. 5 ..
  • R n the above formulae is a hydrocarbon group derived from an olefin oligomer or polymer.
  • the olefin oligomer or polymer may be derived from a olefin mono- mer of 2 to about 10 carbon atoms , and in one ernbadiment about 3 to about 6 carbon, atoms, and in one embodiment about 4 carbon atoms.
  • the monomers include ethylene; propylene; 1 -butane 2 -butane; sobutene; l-pentene; 1- heptene; 1 -octane? 1-nonen ' e ? 1-decene; 2 ⁇ pent-ene; or a mixture of two or more thereof.
  • B. in the above formulae is a olyisobu exie group.
  • the polyxsobutene group may be made by the polymari zat ion of a ⁇ irefinery stream having a but-ene content of about 35 to about 75% by weight and an xsobutene content of about 30 to about 60% by weight.
  • R in the above formulae is a polyisobu- tene group derived from a polyxsobutene having a high methylvinylidene isomer content,, that is, at least about 50% and in one embodiment at least about 70% fflethylvinylidenes .
  • Suitable high methylvinyi idenes" poiyisobutenes include those prepared using boron trifluoride catalysts. The preparation of such polyxsobutene in which the methylvinyl idene isomer comprises a high percentage of the total olefin composition is described in US Patents 4,152,499 and 4,605,808,- the dis- closure of: each of which are incorporated herein by reference .
  • Suitable polyols include: ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene- glycol , ⁇ dipropylene glycol, tripropylene glycol, dibutylene glycol, tribu ylene glycol, 1 - 2 -butanedoii , 2 , 3 -dimethyl- 2 , 3 -butanediol , 2,3 -butariediol , 2 , 3 - hexanediol , 1 , 2- cyclohexanediol , pe ' ntaerythritol , dipentaerythritol 1., 7- heptanediol , 2, 4-he tanediol , 1 ,
  • Suitable polyamines may be aliphatic, cycloaliphat ie , heterocyclic or aromatic. Examples include alkylene polyamines and heterocyclic poiyaraines . Suitable alkylene polyamines include ethylene polyamines , butyl ens polyamines, propylene polyamines, pentylene polyamines, etc. The higher homologies are related to heterocyclic amines such as piperazines and KF- amino alky1 - substituted piperazines are also included.
  • polyamines include ethylene: diamine, triethyl- ene te ramine , ⁇ t ris - (2 ⁇ aminoethyl ⁇ amine , propylene diamine , trime hy ane diamine tri ropyleiie tstraniine , tetmethylene entamine , hexaethylene ' hep amine, pentaethylene hexaraine or a mixture of two or more thereof .
  • the poiyaniine may also be selected from the heterocyclic polyandries, for example aziridines, aaetidines, azoiidines, tetra-- and dihyd opyridines , pyrroles, indoles, piperidin.es, imidazoles, di- and tetra -hydroimidazoles . , piperazines.
  • heterocyclic polyandries for example aziridines, aaetidines, azoiidines, tetra-- and dihyd opyridines , pyrroles, indoles, piperidin.es, imidazoles, di- and tetra -hydroimidazoles . , piperazines.
  • Useful heterocyclic amines are the saturated 5- and 6-membered heterocyclic amines containing only nitrogen, oxygen and/or sulfur in the hetero ring, especially the piper ' idines- , piperazines, thiomorpb.olin.es, raorpholines, and pyrrolidines .
  • Suitable compounds include piperidine, aminoalkyl- s bstit ted piper dines, piperasine, aminoalfcyl -substituted piperazines , mo pholine , aminoalkyt- substituted morpholilies ' , pyrrolidine., and - aminoalkyl - substituted pyrrolidines such as N- araino op Imopholine f N-aminoethylpiperazine, and ⁇ , ⁇ '- diaminoethylpiperazine ,
  • Suitable hydroxyamines may be a primary, secondary or terti- ary amine.
  • the hydroxyamine may be an N- (hydroxy1 ⁇ - substituted alkyl amine, a hydrox 1 ⁇ substituted polyalkoxy analogue thereof, or a mixture of such compounds.
  • the hydroxylarnine suitably contains from about 1 to about 40 carbon atoms, preferably 1 to 20 carbon atoms, more prefe - blv 1 to 10 carbon atoms.
  • Prima y,- secondary and tertiary hydroxyamines may be represented by the following formula :
  • each is independently an alkyl group of one to about e ght carbon atoms or hydroxy!- srtbstituted alkyl group of about two to about 18 carbon atoms.
  • each R is. a lower alkyl group of up to seven carbon atoms.
  • the grou -R.'-QH in such formulae represents the hydroxy! -substituted hydrocarbon group.
  • R' can be an acrylic, alicyclic or aromatic group.
  • R' is an acyclic straight or branched alkylene group such as an ethylene, 1 , 2-propylene , 1 , 2- b tylene , 1 , 2 - oct-adecylene etc , group ..
  • R groups When two R groups are present in the same molecule they can be joined b a di ect carbon- o- carbon bond or through a faeteroatOTO (e.g., oxygen, nitrogen or sulfur) to form a 5 ⁇ , 6 ⁇ , -7 or 8- members ring structure.
  • a faeteroatOTO e.g., oxygen, nitrogen or sulfur
  • heterocyclic amines included N- ⁇ hydroxy1 lower alkyl ⁇ - raorphol ines thiomorpholines , piperidines, osasolidines , thiazolidines arid the like.
  • the hydroxyamines may be either N- (hydroxy- substituted hy ⁇ drocarbyl) amines , These may foe. hydroxy!
  • N- ⁇ hydroxy1- substituted hydrocarbon amines may foe conveniently prepared by reaction of epoxides with afore -described amines.
  • alkoxylated alkylene polyarnines e.g. K, N- (diethanol ) - ethylene diamine
  • alkoxylated alkylene polyarnines include - (2 -hydroxyethyl ) : ethylene diamine, N,N -fois ' (2- hydroxyethyl )- ethylene- diamine. . , 1- ⁇ 2 -hydroxyethyl ⁇ piperazine, mono (hydroxy-propyl ) -substituted diethylene tria- rivine, di (hydroxypropyl ⁇ -substituted tetraethylene pentamine, N- (3 -hydroxybutyl) tetramethylerie diamine, etc. Higher homo- logues are also useful.
  • N- ⁇ ⁇ hydroxy1 -substituted hydrocarbyl) amines examples include mono-, di-, and criethanolamine, diethylethstnola- mine, di ( 3 - hydroxyIpropyl ) amine-, JM- (3 -hydroxybu yl ) amine , Kf- ⁇ 4 - hydroxybutyl ) amine , N- ., N-di - ( 2 -hydroxypropyl ) amine , N- (2 -hydroxylethyl j raorphoiine and its thio analogue, N-(2- hydroxyethyl ) cyclohexylamine., N ⁇ 3 - hydroxy1 cyclopentyl amine, o- , m- and p- aminophenol., M- ihydroxylethyl) piperazine, hi, hT -di (hydroxylethyl) piperazine, and the like, Further hydroxy
  • hydroxy- substituted priiaai-y amines include 2 -amino- 1- butanoi , .2 -amino - 2 -methyl - 1 -propanol , p- (beta -hydrexyethyL) -aniline , 2-amino- 1- ' -propanol , 3 -amino- 1- propanol ., 2 -amino- 2 -methyl -1 , 3-propanediol 2 -amino ⁇ 2 -ethyl- 1 , 3 -propanediol ,KF - ibetahydroxypropyl.) -W - (beta-arainoethyl ⁇ - pipexaziiie, trls- (hydroxyroethyl) aminoethane (also known as trismethylolaminoraethane) , 2 - amino-1-but
  • Hydroxyalkyl alkylene ' polyaraines having one or more hy- droxyalkyl substituents: on the nitrogen atoms are also useful.
  • Examples include l ⁇ ' 2-hydroxyethyl) ethylene diamine , N, N-bis (2 -hydrox eth l) ethylene diamine, 1 - 2 (hydroxyethyl ) - pipera-zine, raohohydroxypropyl -substituted diethylene tria- mine, dihydroxypropyi -substituted tetraethylene pentamine, N- (3 -hydroxybutyl ) te-tratnethylene diamine, etc. Higher homoiogues are also usef l .
  • Suitable surfactants include span 85 (sorbital trioleate) which, has an HLB value of 1.8, oGtylphenoi - 1 - e yleneancy which has an HLB value of 4.0 and span 80 sorbite.! monocleate which has an HLB value of 4,3.
  • surfactants not particularly described above may also be used. Those having an HLB value of less than 10 are preferred. Such surfactants are described in McGutcheon' s Detergents and Emulsifiers , North American Edition, 1982; Kirk-Othmer Encyclopaedia of Chemical Technology, 3rd Ed. , Vol . 22 , pp 346-387.
  • the particles of TAED may be coated / may have been brought into contact with a surfactant to aid the dispersion of the TAED particles in the oil phase.
  • a surfactant to aid the dispersion of the TAED particles in the oil phase.
  • Preferred dispersants are certain nonionic surf ctants which act by s ' teric hindrance and are active only at the protectant solid/organic liquid interface and do not act as emulsifying agents .
  • Such dispersants are suitably made up of ; - ⁇ a ⁇ ' a polymeric chain having a strong affinity for the liq- uid , and
  • Examples of such dispersants are chose of the Hypermer and Atlox lines, available from, the ICI group of companies , including Hyperraer PSl, Hypermer PS2 , Kypermer PS3 , Atlo LPI, Atlox LP2 , Atlox LP4 , Atlox LPS, Atlox LPS , and Atlox 4912 and Agriiner polymers such as Ag rimer AL-216 and AL-220, available from GAF .
  • the oil and or water phase of the composit on may contai other detergent actives such as enzymes , builders, perfumes, optical hrighteners, sail suspending agents, dye transfer inhibition agents.
  • a cleaning composition comprising a water-in -oil emulsion, wherein the aqueous phase comprises a bleaching agent and the oil phase comprises a solvent having a Hildebrand .parameter of f om 12 ⁇ - 2Q in a cleaning opera- t io .
  • the oil phase comprises ⁇ 0 - Ci- 4 alkene o alkane (e.g.. dodscene , dodecane) or 4 -methyl ⁇ - ' 2-pentanol .
  • the us is preferably for cleaning hard surfaces e.g. in a. dishwashing or kitchen / bathroom / toile / sanitary ware cleaning operation.
  • the use may be associated with a washing machine and be fo mechanical laundry and / or dishwashing.
  • The: use may also be for hand washing e.g. manua1 laundry.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne une composition de nettoyage qui comprend une émulsion d'eau dans l'huile. La phase huileuse comprend un solvant ayant un paramètre de Hildebrand de 12 à 20.
PCT/GB2011/052480 2010-12-23 2011-12-15 Composition de nettoyage et procédé Ceased WO2012085539A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11807719.7A EP2655589A1 (fr) 2010-12-23 2011-12-15 Composition de nettoyage et procédé

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1021822.0 2010-12-23
GBGB1021822.0A GB201021822D0 (en) 2010-12-23 2010-12-23 Cleaning composition and method

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Publication Number Publication Date
WO2012085539A1 true WO2012085539A1 (fr) 2012-06-28

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220403298A1 (en) * 2019-07-12 2022-12-22 Novozymes A/S Enzymatic emulsions for detergents

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0072488A1 (fr) * 1981-08-14 1983-02-23 S.C. Johnson & Son, Inc. Composition de pré-détachage du linge à faible teneur de solvant
EP0216355A2 (fr) * 1985-09-24 1987-04-01 S.C. Johnson & Son, Inc. Composition aqueuse pour détacher le linge
GB2194547A (en) * 1986-09-02 1988-03-09 Colgate Palmolive Co Laundry pre-spotter composition providing oily soil removal
WO1997020094A1 (fr) * 1995-11-27 1997-06-05 The Procter & Gamble Company Composition pour traiter des taches sur des textiles a laver et procede de traitement
WO2001021755A1 (fr) * 1999-09-23 2001-03-29 Henkel Kommanditgesellschaft Auf Aktien Detergent a plusieurs phases a action antimicrobienne
WO2001070923A1 (fr) * 2000-03-22 2001-09-27 Unilever Plc Systeme de nettoyage double compartiment
US20100168252A1 (en) * 2006-07-10 2010-07-01 Jerome Guilbot Sugar derivatives, method for preparation thereof, their use as surface-active agents

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0072488A1 (fr) * 1981-08-14 1983-02-23 S.C. Johnson & Son, Inc. Composition de pré-détachage du linge à faible teneur de solvant
EP0216355A2 (fr) * 1985-09-24 1987-04-01 S.C. Johnson & Son, Inc. Composition aqueuse pour détacher le linge
GB2194547A (en) * 1986-09-02 1988-03-09 Colgate Palmolive Co Laundry pre-spotter composition providing oily soil removal
WO1997020094A1 (fr) * 1995-11-27 1997-06-05 The Procter & Gamble Company Composition pour traiter des taches sur des textiles a laver et procede de traitement
WO2001021755A1 (fr) * 1999-09-23 2001-03-29 Henkel Kommanditgesellschaft Auf Aktien Detergent a plusieurs phases a action antimicrobienne
WO2001070923A1 (fr) * 2000-03-22 2001-09-27 Unilever Plc Systeme de nettoyage double compartiment
US20100168252A1 (en) * 2006-07-10 2010-07-01 Jerome Guilbot Sugar derivatives, method for preparation thereof, their use as surface-active agents

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ABBOUD J.-L. M. AND NOTARIO R.: "CRITICAL COMPILATION OF SCALES OF SOLVENTPARAMETERS. PART I. PURE, NON-HYDROGENBOND DONOR SOLVENTS", PURE APPLIED CHEMISTRY, vol. 71, no. 4, 1999, pages 645 - 718, XP002671378, Retrieved from the Internet <URL:www.jaun.chem.ethz.ch/oc8/Materials/IUPACabboud1999.pdf> [retrieved on 20120313] *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220403298A1 (en) * 2019-07-12 2022-12-22 Novozymes A/S Enzymatic emulsions for detergents

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