WO2012102411A3 - 飽和アルデヒドを選択的に低減させる触媒と、その製造方法 - Google Patents

飽和アルデヒドを選択的に低減させる触媒と、その製造方法 Download PDF

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Publication number
WO2012102411A3
WO2012102411A3 PCT/JP2012/052327 JP2012052327W WO2012102411A3 WO 2012102411 A3 WO2012102411 A3 WO 2012102411A3 JP 2012052327 W JP2012052327 W JP 2012052327W WO 2012102411 A3 WO2012102411 A3 WO 2012102411A3
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WIPO (PCT)
Prior art keywords
catalyst
propionaldehyde
selectively reducing
production method
method therefor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
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PCT/JP2012/052327
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English (en)
French (fr)
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WO2012102411A2 (ja
Inventor
公人 奥村
川口　徹
康志 小林
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Nippon Kayaku Co Ltd
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Nippon Kayaku Co Ltd
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Publication date
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Priority to EP12738891.6A priority Critical patent/EP2669008A2/en
Priority to CN201280015909.3A priority patent/CN103648641A/zh
Priority to US13/982,302 priority patent/US20140024861A1/en
Priority to JP2012554883A priority patent/JP5881620B2/ja
Publication of WO2012102411A2 publication Critical patent/WO2012102411A2/ja
Publication of WO2012102411A3 publication Critical patent/WO2012102411A3/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/85—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

［課題］低濃度のプロピオンアルデヒドおよび／またはプロピオン酸および／またはプロピオニトリルを含有するアクロレインおよび／またはアクリル酸および／またはアクリロニトリルおよび／またはメチルメルカプトプロピオンアルデヒドを製造するために、これらの原料となるアクロレインからプロピオンアルデヒドを選択的に低減するための新規な触媒。特に、プロピオンアルデヒドを含有するアクロレインから、プロピオンアルデヒドを選択的に低減するのに用いる触媒。［解決手段方法］Moを必須成分とし、P, Si, W, Ti, Zr, V, Nb, Ta, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, In, Tl, Sn, Ag, As, Ge, B, Bi, La, Ba, Sb, Te, Ce, Pb, Mg, K, Rb, CsおよびAlの中から、好ましくはP, Si, W, Ti, Cr, Mn, Fe, Co, Ni, Zn, Sn, Bi, Sb, Ce, Mg, CsおよびKの中から選択される少なくとも１種の元素を含有する、プロピオンアルデヒドを含有するアクロレインからプロピオンアルデヒドを選択的に低減するのに用いる触媒。　
PCT/JP2012/052327 2011-01-28 2012-01-26 飽和アルデヒドを選択的に低減させる触媒と、その製造方法 Ceased WO2012102411A2 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP12738891.6A EP2669008A2 (en) 2011-01-28 2012-01-26 Catalyst for selectively reducing saturated aldehyde, and production method therefor
CN201280015909.3A CN103648641A (zh) 2011-01-28 2012-01-26 选择性减少饱和醛的催化剂及其制备方法
US13/982,302 US20140024861A1 (en) 2011-01-28 2012-01-26 Catalyst For Reducing Selectively Saturated Aldehyde And A Process For Preparing The Catalyst
JP2012554883A JP5881620B2 (ja) 2011-01-28 2012-01-26 飽和アルデヒドを選択的に低減させる触媒と、その製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011016304 2011-01-28
JP2011-016304 2011-07-15

Publications (2)

Publication Number Publication Date
WO2012102411A2 WO2012102411A2 (ja) 2012-08-02
WO2012102411A3 true WO2012102411A3 (ja) 2012-10-26

Family

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PCT/JP2012/052327 Ceased WO2012102411A2 (ja) 2011-01-28 2012-01-26 飽和アルデヒドを選択的に低減させる触媒と、その製造方法

Country Status (5)

Country Link
US (1) US20140024861A1 (ja)
EP (1) EP2669008A2 (ja)
JP (1) JP5881620B2 (ja)
CN (1) CN103648641A (ja)
WO (1) WO2012102411A2 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108479851B (zh) * 2018-03-22 2020-09-11 南京阿莫尼智能科技有限公司 一种绿色低温脱硝催化剂及其制备方法

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WO2012101471A1 (en) * 2011-01-28 2012-08-02 Arkema France Improved process for manufacturing acrolein/acrylic acid
US9180427B2 (en) * 2011-02-18 2015-11-10 Asahi Kasei Chemicals Corporation Calcination apparatus, process for producing oxide catalyst, and process for producing unsaturated acid or unsaturated nitrile
JP2015034154A (ja) * 2013-08-09 2015-02-19 日本化薬株式会社 プロピオン酸を選択的に低減させる触媒の充填方法
CN104984752B (zh) * 2015-06-29 2017-03-22 中国人民大学 一种氮氧化物和汞协同氧化催化剂及其制备方法
CN110639536A (zh) * 2018-06-27 2020-01-03 中国石油化工股份有限公司 丙烯醛氧化制备丙烯酸催化剂
CN111068675A (zh) * 2018-10-18 2020-04-28 中国石油化工股份有限公司 丙烯醛制丙烯酸的负载型催化剂及其应用
CN111068700A (zh) * 2018-10-18 2020-04-28 中国石油化工股份有限公司 丙烯醛氧化合成丙烯酸的负载型催化剂及其应用
CN111068711A (zh) * 2018-10-18 2020-04-28 中国石油化工股份有限公司 丙烯酸催化剂及其应用
CN111068702A (zh) * 2018-10-18 2020-04-28 中国石油化工股份有限公司 用于制备丙烯酸的催化剂及其应用
CN111068701A (zh) * 2018-10-18 2020-04-28 中国石油化工股份有限公司 用于生产丙烯酸的催化剂及其应用
EP3962642A1 (en) * 2019-05-02 2022-03-09 Dow Global Technologies LLC Process for aldehyde byproduct reduction in acrylic acid production using highly active and selective catalysts
CN112619645B (zh) * 2019-09-24 2023-04-07 中国石油化工股份有限公司 用于制备丙烯酸的催化剂及其制备方法和应用
CN112547043B (zh) * 2019-09-25 2023-03-03 中国石油化工股份有限公司 丙烯醛合成丙烯酸用催化剂及其制备方法和应用
CN112547062B (zh) * 2019-09-25 2022-12-09 中国石油化工股份有限公司 丙烯醛制丙烯酸的催化剂及其制备方法和应用
CN114471530B (zh) * 2020-10-27 2023-09-29 中国石油化工股份有限公司 一种甲基丙烯酸制造用复合催化剂及其制备方法
CN112604701B (zh) 2020-12-29 2022-06-10 上海华谊新材料有限公司 复合氧化物催化剂及其制备方法和用途
CN112827496B (zh) * 2020-12-29 2022-04-12 上海华谊新材料有限公司 负载型复合氧化物催化剂及其制备和应用
JPWO2022163727A1 (ja) * 2021-01-27 2022-08-04
KR20230159843A (ko) * 2021-03-24 2023-11-22 미쯔비시 케미컬 주식회사 촉매, 촉매의 제조 방법, 및 α,β-불포화 알데하이드, α,β-불포화 카복실산, 및 α,β-불포화 카복실산 에스터의 제조 방법
CN113134362B (zh) * 2021-04-28 2022-10-04 陕西延长石油（集团）有限责任公司 一种用于乙醛与合成气无配体氢甲酰化制备乳醛的多相催化剂及其制备方法与应用
CN117943038A (zh) * 2022-10-27 2024-04-30 中国石油化工股份有限公司 氧化催化剂及其制备方法和应用和c3-c4烯酸的制备方法

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Publication number Priority date Publication date Assignee Title
CN108479851B (zh) * 2018-03-22 2020-09-11 南京阿莫尼智能科技有限公司 一种绿色低温脱硝催化剂及其制备方法

Also Published As

Publication number Publication date
JP5881620B2 (ja) 2016-03-09
US20140024861A1 (en) 2014-01-23
WO2012102411A2 (ja) 2012-08-02
CN103648641A (zh) 2014-03-19
EP2669008A2 (en) 2013-12-04
JPWO2012102411A1 (ja) 2014-07-03

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