WO2012102544A3 - 신규한 유기염료 및 이의 제조방법 - Google Patents

신규한 유기염료 및 이의 제조방법 Download PDF

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Publication number
WO2012102544A3
WO2012102544A3 PCT/KR2012/000587 KR2012000587W WO2012102544A3 WO 2012102544 A3 WO2012102544 A3 WO 2012102544A3 KR 2012000587 W KR2012000587 W KR 2012000587W WO 2012102544 A3 WO2012102544 A3 WO 2012102544A3
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WO
WIPO (PCT)
Prior art keywords
production method
method therefor
novel organic
organic dye
dye
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2012/000587
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English (en)
French (fr)
Other versions
WO2012102544A2 (ko
Inventor
안현철
정희정
배호기
박찬석
이춘영
마이클그레이트젤
케이나제루딘 엠디
첸이이
델캄 자레드히스
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Dongjin Semichem Co Ltd
Original Assignee
Dongjin Semichem Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongjin Semichem Co Ltd filed Critical Dongjin Semichem Co Ltd
Publication of WO2012102544A2 publication Critical patent/WO2012102544A2/ko
Publication of WO2012102544A3 publication Critical patent/WO2012102544A3/ko
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B59/00—Artificial dyes of unknown constitution
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B57/00—Other synthetic dyes of known constitution
    • C09B57/008—Triarylamine dyes containing no other chromophores
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B57/00—Other synthetic dyes of known constitution
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/631—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
    • H10K85/636—Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine comprising heteroaromatic hydrocarbons as substituents on the nitrogen atom
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2004—Light-sensitive devices characterised by the electrolyte, e.g. comprising an organic electrolyte
    • H01G9/2018—Light-sensitive devices characterised by the electrolyte, e.g. comprising an organic electrolyte characterised by the ionic charge transport species, e.g. redox shuttles
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
    • H01G9/20—Light-sensitive devices
    • H01G9/2027—Light-sensitive devices comprising an oxide semiconductor electrode
    • H01G9/2031—Light-sensitive devices comprising an oxide semiconductor electrode comprising titanium oxide, e.g. TiO2
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/30—Coordination compounds
    • H10K85/331—Metal complexes comprising an iron-series metal, e.g. Fe, Co, Ni
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/649—Aromatic compounds comprising a hetero atom
    • H10K85/657—Polycyclic condensed heteroaromatic hydrocarbons
    • H10K85/6576—Polycyclic condensed heteroaromatic hydrocarbons comprising only sulfur in the heteroaromatic polycondensed ring system, e.g. benzothiophene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/542—Dye sensitized solar cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/549—Organic PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Electromagnetism (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Hybrid Cells (AREA)
  • Photovoltaic Devices (AREA)

Abstract

본 발명은 신규한 유기염료 및 이의 제조방법에 관한 것으로, 전자 공여체로서 특정 지방족 화합물을, 중간 연결부분(스페이서(spacer))에 특정 유닛을 갖는 본 발명의 염료 화합물은 염료감응태양전지(dye-sensitized solar cell, DSSC)에 사용되어 종래의 염료보다 향상된 몰흡광계수, Jsc(단회로 광전류 밀도) 및 광전기 변환효율을 나타내며, 특히 [Co(Ⅱ)(bpy)3](B(CN)4)2와 [Co(Ⅲ)(bpy)3](B(CN)4)3의 레독스 커플을 포함하는 전해질 시스템과 병행사용하여 태양전지의 효율을 크게 향상시킬 수 있다.
PCT/KR2012/000587 2011-01-28 2012-01-25 신규한 유기염료 및 이의 제조방법 Ceased WO2012102544A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2011-0008702 2011-01-28
KR1020110008702A KR101985184B1 (ko) 2011-01-28 2011-01-28 신규한 유기염료 및 이의 제조방법

Publications (2)

Publication Number Publication Date
WO2012102544A2 WO2012102544A2 (ko) 2012-08-02
WO2012102544A3 true WO2012102544A3 (ko) 2012-12-13

Family

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PCT/KR2012/000587 Ceased WO2012102544A2 (ko) 2011-01-28 2012-01-25 신규한 유기염료 및 이의 제조방법

Country Status (2)

Country Link
KR (1) KR101985184B1 (ko)
WO (1) WO2012102544A2 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10786494B2 (en) 2013-12-02 2020-09-29 Chemocentryx, Inc. CCR6 compounds

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102898859B (zh) * 2012-10-19 2013-11-27 中国科学院长春应用化学研究所 有机染料及在染料敏化太阳电池中的应用
CN102898854B (zh) * 2012-10-19 2013-11-27 中国科学院长春应用化学研究所 以含烷氧基取代芴单元的三芳胺为给体的有机染料及在染料敏化太阳电池中的应用
ITMI20130208A1 (it) * 2013-02-14 2014-08-15 Eni Spa Colorante organico per una cella solare sensibilizzata da colorante
KR101469570B1 (ko) * 2013-05-31 2014-12-23 한국화학연구원 신규한 벤조퀴노리지노아크리딘 유도체, 이를 포함하는 염료감응 태양전지
KR102052565B1 (ko) * 2013-07-24 2019-12-06 덕산네오룩스 주식회사 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
CN103554100B (zh) * 2013-10-21 2016-06-08 南京邮电大学 一种有机太阳能电池材料的制备方法及其应用
CN103554957A (zh) * 2013-11-08 2014-02-05 天津理工大学 一种三苯胺-噻吩类有机染料及其制备方法和应用
WO2015087837A1 (ja) * 2013-12-09 2015-06-18 独立行政法人産業技術総合研究所 かさ高い置換基を持つトリフェニルアミンを電子供与性基とした有機色素化合物及びそれを用いた半導体薄膜電極、光電変換素子、光電気化学太陽電池
CN105315700A (zh) * 2014-07-14 2016-02-10 国家纳米技术与工程研究院 一种有机染料及其在染料敏化太阳电池中的应用
CN107663384B (zh) * 2016-07-20 2020-05-12 上海高驰资产管理有限公司 一种荧光染料及其制备方法和用途
US11613653B2 (en) 2017-07-26 2023-03-28 University Of Mississippi Dyes, dye-sensitized solar cells, and methods of making and using the same
US11421110B2 (en) 2017-07-26 2022-08-23 University Of Mississippi Dyes, dye-sensitized solar cells, and methods of making and using the same
JPWO2024262486A1 (ko) 2023-06-22 2024-12-26

Non-Patent Citations (3)

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Title
AYERS, T. ET AL.: "Redox and spin state control of Co(II) and Fe(II) N-hetero cyclic complexes", INORGANICA CHIMICA ACTA, vol. 307, 11 September 2000 (2000-09-11), pages 7 - 12 *
CAMERONA, P.J. ET AL.: "Electrochemical studies of the Co(III)/Co(II)(dbbip)2 redox coupleas a mediator for dye-sensitized nanocrystalline solar cells", COORDINATION CHEM. REV., vol. 248, 9 April 2004 (2004-04-09), pages 1447 - 1453 *
FELDT, S.M. ET AL.: "Design of organic dyes and cobalt polypyridine redox mediators for high- effciency dye-sensitized solar cells", J. AMER. CHEM. SOC., vol. 132, 24 November 2010 (2010-11-24), pages 16714 - 16724 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10786494B2 (en) 2013-12-02 2020-09-29 Chemocentryx, Inc. CCR6 compounds

Also Published As

Publication number Publication date
KR20120087485A (ko) 2012-08-07
WO2012102544A2 (ko) 2012-08-02
KR101985184B1 (ko) 2019-06-03

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