WO2012110193A4 - Härtbare polymere massen - Google Patents

Härtbare polymere massen Download PDF

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Publication number
WO2012110193A4
WO2012110193A4 PCT/EP2012/000313 EP2012000313W WO2012110193A4 WO 2012110193 A4 WO2012110193 A4 WO 2012110193A4 EP 2012000313 W EP2012000313 W EP 2012000313W WO 2012110193 A4 WO2012110193 A4 WO 2012110193A4
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WO
WIPO (PCT)
Prior art keywords
concentration
contained
polymer material
accelerator
stabilizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2012/000313
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English (en)
French (fr)
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WO2012110193A3 (de
WO2012110193A2 (de
Inventor
Dieter Rossberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Industrial Solutions AG
Original Assignee
ThyssenKrupp Uhde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ThyssenKrupp Uhde GmbH filed Critical ThyssenKrupp Uhde GmbH
Priority to JP2013553826A priority Critical patent/JP2014513199A/ja
Priority to CA2823064A priority patent/CA2823064A1/en
Priority to KR1020137024371A priority patent/KR20140037053A/ko
Priority to RU2013134620/05A priority patent/RU2013134620A/ru
Priority to CN201280005459XA priority patent/CN103380160A/zh
Priority to US14/000,022 priority patent/US20130324642A1/en
Priority to EP12707975.4A priority patent/EP2675846A2/de
Publication of WO2012110193A2 publication Critical patent/WO2012110193A2/de
Publication of WO2012110193A3 publication Critical patent/WO2012110193A3/de
Publication of WO2012110193A4 publication Critical patent/WO2012110193A4/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/01—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5033—Amines aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C08G59/1461—Unsaturated monoacids
    • C08G59/1466—Acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/04—Epoxynovolacs
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C08L63/10—Epoxy resins modified by unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10—Epoxy resins modified by unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C08L91/06—Waxes
    • C08L91/08—Mineral waxes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)
  • Reinforced Plastic Materials (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Die Erfindung betrifft eine härtbare Masse einer erfindungsgemäßen Rezeptur, ein Verfahren zum Herstellen eines Polymerwerkstoffes aus der härtbaren Masse, den daraus entstehenden Polymerwerkstoff, sowie Mittel, die aus dem erfindungsgemäßen Polymerwerkstoff gefertigt sind und deren Verwendung.

Claims

15 GEÄNDERTE ANSPRÜCHE beim Internationalen Büro eingegangen am 17. Dezember 2012 (17.12.2012) Ansprüche
1. Verwendung eines Polymerwerkstoffes umfassend die Inhaltsstoffe der
nachfolgenden härtbaren Massen:
ein Harz auf Basis von Epoxy-Novolac Vinylester, wobei das Harz in einer Konzentration von 96,3 bis 98,95 % enthalten ist, einen Katalysator, wobei der Katalysator in Form einer 6%igen
Kobaltlösung in einer Konzentration von 0,05 bis 0,1 % enthalten ist, einen Beschleuniger, wobei der Beschleuniger in Form von Dimethylanilin in einer Konzentration von 0 bis 0,1 % enthalten ist, einen Härter, wobei der Härter in Form von Cumolhydroperoxid in einer Konzentration von 1 bis 2 % enthalten ist,
einen UV-Stabilisator, wobei der UV-Stabilisator in einer Konzentration von 0 bis 0,5 % enthalten ist,
Paraffin, wobei das Paraffin in Form von Wachs in einer Konzentration von 0 bis 1 % enthalten ist
und sich die Konzentrationsangaben auf 100 % einer zu härtenden
Gesamtmasse beziehen oder ein Harz auf Basis von Epoxy-Novolac Vinylester, wobei das Harz in einer Konzentration von 94 bis 97,95 % enthalten ist,
einen Beschleuniger, wobei der Beschleuniger in Form von N,N-
Dimethylanilin in einer Konzentration von 0,05 bis 0,2 % enthalten ist, einen Härter, wobei der Härter in Form von Dibenzoylperoxid in einer
Konzentration von 2 bis 4 % enthalten ist,
einen Verzögerer, wobei der Verzögerer in Form von p-tert-
Butylcatechol in einer Konzentration von 0 bis 0,3 % enthalten ist einen UV-Stabilisator, wobei der UV-Stabilisator in einer Konzentration von 0 bis 0,5 % enthalten ist,
Paraffin, wobei das Paraffin in Form von Wachs in einer Konzentration von 0 bis 1 % enthalten ist,
und sich die Konzentrationsangaben auf 100 % einer zu härtenden
Gesamtmasse beziehen
GEÄNDERTES BLATT (ARTIKEL 19) 16
in Vorrichtungen eines Elektrolyse-Verfahrens, in dem alkalische Medien, in denen Chlor oder chlorhaltige Verbindungen in flüssigem oder gasförmigem Aggregatzustand hergestellt werden und/oder zugeführt werden.
2. Verwendung eines Polymerwerkstoff nach Anspruch 1 , dadurch
gekennzeichnet, dass in den Polymerwerkstoff weitere zusätzliche
Komponenten, wie Füllstoffe und/oder Fasermaterialien, insbesondere Glasfasern und/oder Glasvliese und/oder Synthetikvliese, eingebettet sind.
3. Verwendung eines Polymerwerkstoffes nach einem der Ansprüche 1 oder 2 dadurch gekennzeichnet, dass der Polymerwerkstoff durch ein Verfahren, umfassend die nachfolgenden Verfahrensschritte hergestellt wird:
a. Harz und Katalysator für eine Zeitdauer, die das Verfallsdatum des Harzes nicht überschreitet, einer Vorbeschleunigung unterzogen werden,
b. der Beschleuniger, Härter, Verzögerer, UV-Stabilisator in der angegebenen Reihenfolge zugefügt werden, und eine härtbare Masse generiert wird,
c. wobei je nach Rezeptur ein oder mehrere Bestandteile des Schrittes b) und/oder der Katalysator aus Schritt a) wegfallen,
d. die härtbare Masse über Standardverfahren in eine gewünschte Form gebracht wird, wodurch ein Werkstück hergestellt wird, e. optional Paraffin von außen auf das Werkstück aufgebracht wird, und das Werkstück für 8 Stunden bei 80°C einer Wärmebehandlung unterzogen wird und ein fertiger Polymerwerkstoff generiert wird.
GEÄNDERTES BLATT (ARTIKEL 19)
PCT/EP2012/000313 2011-02-17 2012-01-25 Härtbare polymere massen Ceased WO2012110193A2 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2013553826A JP2014513199A (ja) 2011-02-17 2012-01-25 硬化性ポリマー材料
CA2823064A CA2823064A1 (en) 2011-02-17 2012-01-25 Curable polymeric mass
KR1020137024371A KR20140037053A (ko) 2011-02-17 2012-01-25 경화성 중합체 재료
RU2013134620/05A RU2013134620A (ru) 2011-02-17 2012-01-25 Отверждаемая полимерная масса
CN201280005459XA CN103380160A (zh) 2011-02-17 2012-01-25 可固化聚合物块体
US14/000,022 US20130324642A1 (en) 2011-02-17 2012-01-25 Curable polymer materials
EP12707975.4A EP2675846A2 (de) 2011-02-17 2012-01-25 Härtbare polymere massen

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011011609A DE102011011609A1 (de) 2011-02-17 2011-02-17 Härtbare polymere Massen
DE102011011609.5 2011-02-17

Publications (3)

Publication Number Publication Date
WO2012110193A2 WO2012110193A2 (de) 2012-08-23
WO2012110193A3 WO2012110193A3 (de) 2013-01-10
WO2012110193A4 true WO2012110193A4 (de) 2013-03-07

Family

ID=45812744

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Application Number Title Priority Date Filing Date
PCT/EP2012/000313 Ceased WO2012110193A2 (de) 2011-02-17 2012-01-25 Härtbare polymere massen

Country Status (9)

Country Link
US (1) US20130324642A1 (de)
EP (1) EP2675846A2 (de)
JP (1) JP2014513199A (de)
KR (1) KR20140037053A (de)
CN (1) CN103380160A (de)
CA (1) CA2823064A1 (de)
DE (1) DE102011011609A1 (de)
RU (1) RU2013134620A (de)
WO (1) WO2012110193A2 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013003505B4 (de) * 2013-03-04 2021-08-12 Thyssenkrupp Uhde Chlorine Engineers Gmbh Verfahren zum Herstellen eines Rohres
WO2017121607A1 (de) 2016-01-12 2017-07-20 Thyssenkrupp Uhde Chlorine Engineers Gmbh Verbundmaterial

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4406646A1 (de) * 1994-03-01 1995-09-07 Basf Ag Eingedickte härtbare Formmassen aus einem Vinylester- oder Vinylesterurethanharz
US5486580A (en) * 1994-11-02 1996-01-23 The Dow Chemical Company Mesogenic novolacs and resins
CH691126A5 (de) * 1995-12-21 2001-04-30 Mbt Holding Ag Novolakvinylesterzusammensetzungen.
US6287992B1 (en) * 1998-04-20 2001-09-11 The Dow Chemical Company Polymer composite and a method for its preparation
US6774193B2 (en) * 2000-06-14 2004-08-10 Albemarle Corporation Stabilized unsaturated polymer resin compositions and methods of using the same
DE102008033577A1 (de) 2008-07-17 2010-01-21 Hobas Engineering Gmbh Faserverstärktes Kunststoffrohr

Also Published As

Publication number Publication date
WO2012110193A3 (de) 2013-01-10
CA2823064A1 (en) 2012-08-23
RU2013134620A (ru) 2015-04-10
JP2014513199A (ja) 2014-05-29
KR20140037053A (ko) 2014-03-26
WO2012110193A2 (de) 2012-08-23
DE102011011609A1 (de) 2012-08-23
CN103380160A (zh) 2013-10-30
US20130324642A1 (en) 2013-12-05
EP2675846A2 (de) 2013-12-25

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