WO2012117828A1 - Composition d'agent de nettoyage - Google Patents

Composition d'agent de nettoyage Download PDF

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Publication number
WO2012117828A1
WO2012117828A1 PCT/JP2012/053088 JP2012053088W WO2012117828A1 WO 2012117828 A1 WO2012117828 A1 WO 2012117828A1 JP 2012053088 W JP2012053088 W JP 2012053088W WO 2012117828 A1 WO2012117828 A1 WO 2012117828A1
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WIPO (PCT)
Prior art keywords
mass
cleaning composition
composition according
ether
viscosity
Prior art date
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Ceased
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PCT/JP2012/053088
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English (en)
Japanese (ja)
Inventor
青野　恵
利江 廣畠
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Lion Corp
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Lion Corp
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Publication date
Application filed by Lion Corp filed Critical Lion Corp
Priority to PH1/2013/501774A priority Critical patent/PH12013501774A1/en
Priority to KR1020137019873A priority patent/KR101858291B1/ko
Publication of WO2012117828A1 publication Critical patent/WO2012117828A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Definitions

  • the present invention relates to a cleaning composition particularly suitable for hair or skin.
  • a clean and refreshing cleaning agent has long been preferred by men.
  • a heat wave that has never existed in the past has continued, and there has been a greater demand for cleaners and cleaners for hair and skin.
  • the development of a cleaner with a refreshing feeling is required.
  • a refreshing agent such as menthol is blended, but the present inventors have a structural state created by active agents in the cleaning agent by blending a refreshing agent such as menthol. It has been found that there is a problem that the viscosity changes and the viscosity decreases, and that menthol precipitates at low temperatures and becomes unstable. For example, when the viscosity decreases, shampoo or body soap is taken into your hands and dripping down when applied to the hair or body, especially when considering use in an inverted container etc. Decrease in viscosity is a big problem.
  • the present invention has been made in view of the above circumstances, and even in a system containing a refreshing agent such as menthol, a decrease in viscosity (hereinafter referred to as viscosity reduction and suppression of viscosity reduction is due to the addition of a refreshing agent such as menthol. It is an object of the present invention to provide a detergent composition with good usability that can provide a refreshing feeling without causing poor stability at low temperatures.
  • (a-1) an anionic surfactant and (a-2) an amphoteric surfactant include (c) menthol and the like.
  • the above-mentioned specific problem that occurs when a specific amount of a refreshing agent is blended can be solved by blending a specific amount of a specific multi-chain nonionic surfactant (b), giving a sufficient refreshing feeling, and the viscosity of the composition
  • the inventors have found that a cleaning composition that suppresses the decrease and has excellent low-temperature stability can be obtained, and has led to the present invention.
  • the present invention provides the following cleaning composition.
  • A (a-1) an anionic surfactant, (A-2) amphoteric surfactant: the total amount of (a-1) and (a-2) is 4% by mass or more, (B) a multi-chain nonionic surfactant that is solid at room temperature: 0.01 to 5% by mass;
  • C Menthol, menthone, camphor, borneol, cineole menthone, methyl salicylate, menthyl malonate, glycosyl-monomenthyl-O-acetate, 3-l-menthoxypropane-1,2-diol, l-menthyl-3-hydroxy
  • a detergent composition comprising: a refreshing agent selected from the group consisting of butyrate, spearmint oil, peppermint oil, peppermint oil and eucalyptus oil: 0.01 to 5% by mass.
  • component (b) is selected from a two-chain to four-chain ether-based and ester-based nonionic surfactant.
  • Component (b) is composed of POE cetostearyl hydroxymyrstyrene ether, PEG glyceryl diisostearate, PEG distearate, PEG glyceryl triisostearate, PEG pentaerythrityl tetrastearate, POE sorbitol tetrastearate, and POE sorbitol hexastearate
  • the cleaning composition according to ⁇ 2> which is selected.
  • ⁇ 4> Any one of ⁇ 1> to ⁇ 3>, wherein the blending mass ratio of the anionic surfactant to the amphoteric surfactant represented by (a-1) / (a-2) is 50/1 to 1/5 The cleaning composition described in 1.
  • (C) The cleaning composition according to any one of ⁇ 1> to ⁇ 4>, wherein the component is menthol.
  • ⁇ 6> And (d) a pearlizing agent selected from the group consisting of ethylene glycol monofatty acid esters, ethylene glycol difatty acid esters, ethylene glycol monoalkyl ethers, and ethylene glycol dialkyl ethers.
  • ⁇ 7> The cleaning composition according to any one of ⁇ 1> to ⁇ 6>, further comprising (e) a cationic polymer.
  • ⁇ 8> The cleaning composition according to any one of ⁇ 1> to ⁇ 7>, further comprising (f) a silicone compound.
  • ⁇ 9> The cleaning composition according to any one of ⁇ 1> to ⁇ 8>, wherein the viscosity is 0.5 to 50000 mPa ⁇ s.
  • ⁇ 10> The cleaning composition according to any one of ⁇ 1> to ⁇ 9>, which is for hair or skin.
  • a detergent containing a specific multi-chain nonionic surfactant which is excellent in reducing viscosity reduction and low-temperature stability, and also has a refreshing feeling due to the incorporation of a refreshing agent such as menthol.
  • a composition can be provided. Further, by further adding (d) a pearling agent, a decrease in the viscosity of the composition can be further suppressed.
  • the smoothness at the time of a rinse can be improved by mix
  • the subject of Claim 6 is providing smoothness of a finish to hair etc., the smoothness after drying can be improved by mix
  • the cleaning composition of the present invention comprises: (A) (a-1) an anionic surfactant, (A-2) amphoteric surfactant, (B) a multi-chain nonionic surfactant that is solid at room temperature; (C) It contains a cooling agent.
  • the component (a) is used to maintain the viscosity of the composition by providing foaming when cleaning dirt such as the head, and a refreshing feeling after cleaning.
  • the anionic surfactant include carboxylic acid type, sulfonic acid type, sulfuric acid type, and phosphoric acid type.
  • ⁇ -olefin sulfonates are preferred for the sulfonic acid type, and alkyl sulfates and polyoxyalkylene alkyl ether sulfates are preferred for the sulfate type. These may be used alone or in combination of two or more.
  • the ⁇ -olefin sulfonate is preferably an alkyl group having 10 to 18 carbon atoms, particularly tetradecene sulfonate having 14 carbon atoms.
  • alkyl sulfate salts those having an alkyl group having 10 to 18 carbon atoms are preferred, and those having an alkyl group having 12 to 14 carbon atoms are particularly preferred.
  • polyoxyalkylene alkyl ether sulfate ester salt an alkyl group having 10 to 18 carbon atoms is preferable, and an alkyl group having 10 to 14 carbon atoms is particularly preferable.
  • the alkylene group portion is preferably a polyoxyethylene group or a polyoxypropylene group, and particularly preferably a polyoxyethylene group.
  • the range of the total number of added moles of ethylene is preferably 1 to 5.
  • These counter ions include alkali metal salts such as sodium and potassium; alkaline earth metal salts such as calcium and magnesium; ammonium salts; alkanolamine salts such as monoethanolamine, diethanolamine and triethanolamine.
  • POE (1-5) sodium lauryl ether sulfate, fatty acid soap, lauroyl sarcosine sodium, lauroyl methyl taurine sodium and the like are preferably used.
  • the number in () shows the average added mole number of ethylene oxide.
  • the compounding amount of the anionic surfactant is 3.9 to 30% by mass, preferably 5 to 15% by mass, based on the whole composition, from the viewpoint of maintaining the viscosity of the composition, and providing foaming and refreshing feeling. If the amount is less than 3.9% by mass, the thickening effect and the refreshing feeling may be reduced and foaming may be deteriorated. If the amount exceeds 30% by mass, the low-temperature stability may be deteriorated.
  • amphoteric surfactant (a-2) component is used in combination with the (a-1) anionic surfactant to form a network of these surfactants and increase the viscosity of the composition. Further, as with the component (a-1), it is blended in order to give foaming when cleaning dirt such as the head and a refreshing feeling after cleaning.
  • amphoteric surfactant include surfactants such as carboxylic acid type including amino acid type and betaine type, sulfate ester type, sulfonic acid type, and phosphate ester type. Of these, betaine surfactants are preferred.
  • betaine type amphoteric surfactants include alkyl betaine type activator, amide betaine type activator, sulfobetaine type activator, hydroxysulfobetaine type activator, amide sulfobetaine type activator, phosphobetaine type activator, imidazolium betaine.
  • Type activators and the like include laurylaminoacetic acid betaine, 2-coconut oil fatty acid-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauric acid amidopropyl betaine, and coconut oil fatty acid amidopropyl betaine. Among these, lauric acid amidopropyl betaine and coconut oil fatty acid amidopropyl betaine are preferable.
  • the compounding amount of the amphoteric surfactant is preferably from 0.1 to 15% by mass, more preferably from 3 to 10% by mass, from the viewpoint of the effect of suppressing the viscosity reduction when used in combination with the anionic surfactant, foaming and refreshing feeling. It is. If the content is less than 0.1% by mass, a sufficient viscosity-inhibiting effect may not be obtained. If the content exceeds 15% by mass, the low-temperature stability may be deteriorated.
  • the total amount of the components (a-1) and (a-2) is 4% by mass or more, preferably 40% by mass or less, more preferably 8% by mass or more and 30% by mass from the viewpoint of the thickening effect. Hereinafter, it is 25 mass% or less especially. If the amount is too small, the cleaning effect is low, so that a refreshing feeling is difficult to obtain, and the viscosity of the composition becomes low.
  • the upper limit is not particularly limited, but the stability at low temperature may be reduced in the range exceeding 40% by mass. Further, from the viewpoint of foaming and refreshing feeling, 4 to 40% by mass is preferable, and 10 to 30% by mass is more preferable. If it is less than 4% by mass, sufficient foaming may not be obtained after cleaning. In the range exceeding 40% by mass, even if the amount is increased, it may not be possible to improve the effect of foaming and a refreshing feeling after washing.
  • the viscosity of the detergent composition can be improved by the network structure of the both.
  • the mass ratio of the anionic surfactant / amphoteric surfactant represented by (a-1) / (a-2) is preferably 50/1 to 1/5, more preferably 10/1 to 1/5. More preferably, it is 5/1 to 1/3. If this ratio is too small or too large, viscosity is difficult to obtain and the usability is inferior, and the low-temperature stability may decrease.
  • the “multi-chain nonionic surfactant” used in the present invention has an ethylene glycol, propylene glycol, glycerin, sorbit or pentaerythritol skeleton, and an alkyl having 12 to 20 carbon atoms via an ethylene oxide group.
  • “normal temperature” is defined as 15 to 25 ° C.
  • “solid” is defined as a measurement time exceeding 90 seconds in a liquid confirmation test described later.
  • Examples of such a multi-chain nonionic surfactant include ether-based and ester-based surfactants, and examples thereof include 2-chain to 4-chain types represented by the following general formula. ⁇ Double-stranded type> ⁇ Ether type Wherein R 1 is a monovalent alkyl or alkenyl group having 12 to 20 carbon atoms, R 2 is a monovalent alkyl or alkenyl group having 12 to 20 carbon atoms, and n is 40 to 100 (It is an integer.)
  • X 1 to X 3 are —OH group or —OCOR 3
  • R 3 is a monovalent alkyl group or alkenyl group having 12 to 20 carbon atoms
  • two or more of X 1 to X 3 Is -OCOR 3.
  • the sum of m1 + m2 + m3 is an integer from 40 to 100, in particular from 45 to 70.
  • R 4 is a monovalent alkyl or alkenyl group having 12 to 20 carbon atoms
  • R 5 is a monovalent alkyl or alkenyl group having 12 to 20 carbon atoms
  • p is 1 to 3
  • An integer and q is an integer of 100 to 200.
  • R 8 is a monovalent alkyl group having 12 to 20 carbon atoms, and two or more of X 13 to X 16 , particularly 4 And -OCOR 8.
  • s is an integer of 2 to 5
  • the sum of t1 + t2 + t3 + t4 is an integer of 100 to 200, particularly 140 to 160.
  • Examples of such a multi-chain nonionic surfactant include POE cetostearyl hydroxymyristyl ether, PEG glyceryl diisostearate, PEG distearate, PEG glyceryl triisostearate, PEG pentaerythrityl tetrastearate, POE sorbitol tetrastearate, Examples include hexastearic acid POE sorbit, and these can be used alone or in combination of two or more.
  • POE cetostearyl hydroxymyristyl ether, PEG glyceryl triisostearate, and PEG pentaerythrityl tetrastearate are particularly preferred from the viewpoint of the effect of suppressing the decrease in viscosity and stability at low temperatures.
  • the blending amount of the component (b) is 0.01 to 5% by mass, preferably 0.05 to 1% by mass, based on the whole composition, from the viewpoint of the effect of suppressing the viscosity reduction of the composition and the low temperature stability. If it is less than 0.01% by mass, sufficient reduction in viscosity reduction and low-temperature stability cannot be obtained. On the other hand, in the range exceeding 5% by mass, improvement in low-temperature stability cannot be obtained even if the amount is increased, and the refreshing feeling is also lowered.
  • the refreshing agent used in the present invention is blended in order to give a refreshing feeling during use.
  • Such refreshing agents include menthol, menthyl glyceryl ether, menthyl carboxamide, vanillyl butyl ether, menthone, camphor, borneol, cineole menthone, methyl salicylate, menthyl malonate, glycosyl-monomenthyl-O-acetate, 3-l-menthol Examples include xylpropane-1,2-diol, l-menthyl-3-hydroxybutyrate, spearmint oil, peppermint oil, mint oil and eucalyptus oil. These can be used individually by 1 type or in combination of 2 or more types.
  • menthol menthyl glyceryl ether, menthyl carboxamide, vanillyl butyl ether, camphor, spearmint oil, peppermint oil, peppermint oil and eucalyptus oil are preferable, and menthol and peppermint oil are more preferable from the point of refreshing feeling at the time of use. Menthol is more preferable.
  • the blending amount of the refreshing agent is 0.01 to 5% by mass, preferably 0.1 to 2% by mass, based on the entire composition. If it is less than 0.01% by mass, sufficient refreshing feeling cannot be obtained, and if it exceeds 5% by mass, the low temperature stability cannot be maintained.
  • the composition of the present invention preferably further comprises (d) a pearlizing agent in order to further enhance the effect of suppressing the decrease in viscosity and to impart a pearl appearance to the composition.
  • a pearlizing agent include ethylene glycol monofatty acid ester, ethylene glycol difatty acid ester, ethylene glycol monoalkyl ether and ethylene glycol dialkyl ether, and these may be used alone or in combination of two or more. Can be used. Of these, ethylene glycol monofatty acid ester and ethylene glycol difatty acid ester are particularly preferable.
  • More specific examples include ethylene glycol distearate, ethylene glycol monostearate, ethylene glycol monostearyl ether, and ethylene glycol distearyl ether. More preferred are ethylene glycol distearate and ethylene glycol monostearate from the viewpoints of viscosity-inhibiting effect and pearl appearance.
  • the blending amount of the pearlizing agent is preferably from 0.1 to 10% by mass, more preferably from 0.1 to 3% by mass, based on the whole composition, from the viewpoint of the effect of suppressing the decrease in viscosity and the appearance of pearl. If the amount is less than 0.1% by mass, a sufficient viscosity-inhibiting effect and imparting a pearl appearance may not be obtained. If the amount exceeds 10% by mass, low-temperature stability may not be maintained.
  • composition of the present invention may further contain (e) a cationic polymer in order to impart smoothness during rinsing to hair or the like.
  • Cationic polymers include cationized cellulose, cationized cellulose derivatives, cationized starch, cationized guar gum, cationized guar gum derivatives, homopolymers of diallyl quaternary ammonium salts, quaternized polyvinylpyrrolidone derivatives, polyglycol polyamines Condensate, dialkyldiallylammonium salt / acrylamide copolymer, vinylimidazolium trichloride / vinylpyrrolidone copolymer, hydroxyethylcellulose / dimethyldiallylammonium chloride copolymer, vinylpyrrolidone / quaternized dimethylaminoethyl methacrylate copolymer, Polyvinylpyrrolidone
  • dialkyl diallylammonium salt / acrylamide copolymer cationized cellulose, cationized cellulose derivative, cationized guar gum, and cationized guar gum derivative are particularly preferred from the viewpoint of smoothness during rinsing.
  • the weight average molecular weight is preferably 0.5 ⁇ 10 6 to 3 ⁇ 10 6 , particularly 1 ⁇ 10 6 to 2 ⁇ 10 6 from the viewpoint of smoothness at the time of rinsing.
  • the weight average molecular weight is measured by a gel permeation chromatograph / multi-angle laser light scattering detector (GPC-MALLS).
  • the degree of cationization is preferably in the range of 0.1 meq / g to 5.0 meq / g, more preferably 0.5 meq / g to 4.0 meq / g, from the viewpoint of smoothness during rinsing. If the degree of cationization is less than 0.1 meq / g, the finger passage when the foam is rinsed may be poor, and the hair after drying may feel dry. On the other hand, when the degree of cationization exceeds 5.0 meq / g, the detergent composition may have poor low-temperature stability.
  • copolymer of dialkyl diallylammonium salt and acrylamide examples include Marcoat 550, Marcoat S, Marcoat 2200, CG-600 (above, trade name, manufactured by ONDEO NALCO), Kayaacryl Resin MN, Kayaacryl Resin. M50-A (above, trade name, manufactured by Nippon Kayaku Co., Ltd.).
  • the cationized cellulose is obtained by adding a cationic functional group to cellulose.
  • polyquaternium-10 which is O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride is preferred.
  • the degree of cationization of the cationized cellulose is preferably in the range of 0.1 meq / g to 3.0 meq / g, more preferably 0.5 meq / g to 1.7 meq / g, from the viewpoint of smoothness during rinsing. If the degree of cationization is less than 0.1 meq / g, the finger passage when the foam is rinsed may be poor, and the hair after drying may feel dry.
  • the detergent composition when the degree of cationization exceeds 3.0 meq / g, the detergent composition may be inferior in low-temperature stability.
  • the molecular weight of the cationized cellulose is preferably in the range of 100,000 to 3,000,000, more preferably 150,000 to 2,000,000 from the viewpoint of smoothness during rinsing. If it is less than 100,000, the finger passage when rinsing the foam may worsen, and the hair after drying may feel dry. On the other hand, if it exceeds 3 million, the low-temperature stability of the cleaning composition may be inferior, and dissolution in the cleaning composition may be difficult.
  • cationized cellulose Commercially available products can be used as such cationized cellulose. Specific examples include Leogard LP, GP, MGP, KGP, XE-511K (trade name, manufactured by Lion Corporation), UCARE LR-30M. , JR-400, JR-30M (trade name, manufactured by Dow Chemical Japan Co., Ltd.), Katchinal HC-100 (trade name, manufactured by Toho Chemical Industry Co., Ltd.), and the like.
  • the cationized guar gum is obtained by adding a cationic functional group to guar gum.
  • the degree of cationization of the cationized guar gum varies depending on the degree of addition of the cationic group.
  • the degree of cationization is preferably in the range of 0.1 meq / g to 3.0 meq / g, more preferably 0.5 meq / g to 3.0 meq / g, and still more preferably from the viewpoint of smoothness at the time of rinsing. 1.0 meq / g to 2.4 meq / g. If the degree of cationization is less than 0.1 meq / g, the finger passage when the foam is rinsed may be poor, and the hair after drying may feel dry.
  • the detergent composition when the degree of cationization exceeds 3.0 meq / g, the detergent composition may be inferior in low-temperature stability.
  • the molecular weight of the cationized guar gum is preferably in the range of 100,000 to 3,000,000, and more preferably in the range of 200,000 to 2,000,000 from the viewpoint of smoothness during rinsing. If it is less than 100,000, the finger passage when rinsing the foam may worsen, and the hair after drying may feel dry. On the other hand, if it exceeds 3 million, the low-temperature stability of the cleaning composition may be inferior, and dissolution in the cleaning composition may be difficult.
  • a commercially available product can be used, and specific examples thereof include Lapole gum CG-M, CG-M7, CG-M8M (trade name, manufactured by Dainippon Pharmaceutical Co., Ltd.), N- Examples include Hance 3000 (trade name, manufactured by Hercules Japan), JAGUAR C-13S, C-14S, C-17, EXCEL (trade name, manufactured by Rhodia), and the like.
  • raw materials obtained by evaporating water to form powders or granules can be used, and raw materials liquefied with a solvent such as water can also be used.
  • the degree of cationization of the cationic polymer can be easily calculated if the chemical structure is clear, but even if the structure such as the monomer ratio is unknown, the measured value of N content such as Kjeldahl method can be used. Can be calculated.
  • the degree of cationization used in the present invention is based on the Kjeldahl method. It is calculated based on the value measured by the nitrogen determination method No. 2 of the general test method of cosmetic raw material standards.
  • meq / g which is a unit of the degree of cationization indicates the number of milliequivalents of N cation groups per 1 g of a sample.
  • the molecular weight of the component can be measured by a method of comparison with a polymer having a known molecular weight by liquid chromatography using a general GPC column.
  • the molecular weight of the cationized polymer shown in the present invention is a value measured using GPC-MALLS, and a sample solution diluted with a mobile phase having a pure polymer concentration of about 1,000 ppm is prepared from a TSK-GELA column (Tosoh ( The wavelength of about 633 nm was measured with a multi-angle light scattering detector using a 0.5 mol / L sodium perchlorate solution as a mobile phase.
  • polyethylene glycol having a known molecular weight was used as a standard product.
  • the blending amount of the cationic polymer is preferably 0.01 to 3% by mass, more preferably 0.05 to 1% by mass of the whole composition from the viewpoint of imparting smoothness to hair and the like during rinsing. . If the amount is less than 0.01% by mass, sufficient smoothness at the time of rinsing may not be imparted, and even if the amount exceeds 3% by mass, the smoothness at the time of rinsing may not be improved.
  • the composition of the present invention can be blended with (f) a silicone compound from the viewpoint of imparting a smooth finish.
  • a silicone compound include dimethylpolysiloxane (including highly polymerized dimethylpolysiloxane and silicone rubber), amino-modified silicone, methylphenylpolysiloxane, polyether-modified silicone, polyamino-modified silicone, betaine-modified silicone, Alcohol-modified silicone, fluorine-modified silicone, epoxy-modified silicone, mercapto-modified silicone, carboxy-modified silicone, fatty acid-modified silicone, silicone graft polymer, cyclic silicone, alkyl-modified silicone, aminoglycol-modified silicone, polyoxyalkylene / amino-modified silicone, trimethylsilyl group And terminal dimethylpolysiloxane, silanol-terminated dimethylpolysiloxane, and the like.
  • dimethylpolysiloxane, polyether-modified silicone, and polyamino-modified silicone are particularly preferably used.
  • the silicone compound an emulsion obtained by emulsifying the silicone compound with a surfactant can be used.
  • dimethylpolysiloxane, amino-modified silicone, and polyoxyalkylene / amino-modified silicone having a kinematic viscosity of 100,000 cst / 25 ° C. or more can be preferably used.
  • the blending amount of the silicone compound is preferably from 0.1 to 5% by mass, more preferably from 0.3 to 3% by mass, based on the smoothness after drying and a refreshing feeling. If it is less than 0.1% by mass, sufficient smoothness after drying may not be obtained, and if it exceeds 5% by mass, the refreshing feeling after washing may be inhibited.
  • Nonionic surfactant other than component (b) and amphoteric surfactant other than component (a-2) in the present invention, a nonionic surfactant other than the component (b) can be blended in order to further improve the refreshing feeling.
  • nonionic surfactants include polyglycerin fatty acid ester, POE (polyoxyethylene) hydrogenated castor oil, sorbitan fatty acid ester, POE sorbitan fatty acid ester propylene glycol fatty acid ester, glycerin fatty acid ester, POE / POP alkyl ether, monostearin Polyethylene glycol fatty acid esters such as polyethylene glycol acid, liquid POE glycerin fatty acid ester, POE sorbite fatty acid ester, POE alkyl ether, POE ethylene glycol fatty acid ester, POE propylene glycol fatty acid ester, POE glycerin fatty acid ester, POE sorbit Examples thereof include fatty acid esters
  • amphoteric surfactants other than the component (a-2) include lauryl dimethylaminoacetic acid betaine, coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine, N-coconut oil fatty acid acyl-N-carboxymethyl-N-hydroxyethylethylenediamine sodium, And N-coconut oil fatty acid acyl-N-carboxymethyl-N-hydroxyethylethylenediamine / sodium lauryl sulfate.
  • polyglycerin fatty acid ester, POE (polyoxyethylene) hydrogenated castor oil, POE alkyl ether, and POE / POP alkyl ether are preferable. More specifically, polyglyceryl laurate, POE (10 to 60) hydrogenated castor oil, POE (30) POP (6) decyl tetradecyl ether and the like are preferable.
  • the blending amount of the surfactant is preferably 0.1 to 10% by mass, more preferably 0.1 to 5% by mass based on the total composition from the viewpoint of improving the refreshing feeling. If it is less than 0.1% by mass, a refreshing feeling may not be obtained, and if it exceeds 10% by mass, a refreshing effect may not be obtained.
  • components generally blended into the cleaning composition as desired for example, nonionic surfactants other than those described above, Other than the above, high molecular compounds, amino acids, protein hydrolysates, sequestering agents, thickeners, polyols, oils, UV absorbers, pH adjusters, antioxidants, oxidizing agents, reducing agents, alkaline agents, dyes , Antibacterial agents, propellants and the like.
  • the fragrance and the fragrance composition described in JP-A-2003-95895 are used.
  • the fragrance or the fragrance composition is blended in the cleaning composition of the present invention so as to be 0.00001 to 50% by mass with respect to the total amount of the cleaning composition of the present invention. More preferably, 0.0001 to 30% by mass is blended.
  • the viscosity of the composition of the present invention is not particularly limited, but is preferably 0.5 to 50000 mPa ⁇ s, more preferably 50 to 50000 mPa ⁇ s, still more preferably 3000 to 30000 mPa ⁇ s, and particularly preferably 10,000. ⁇ 30000 mPa ⁇ s. If the viscosity is too low, it may spill out from the hand during use, and the head and hands may not be cleaned sufficiently, and a clean feeling may not be obtained. If the viscosity is too high, the detergent solution will not spread well and cannot be applied uniformly. In some cases, it cannot be washed sufficiently and a refreshing feeling cannot be obtained.
  • the viscosity of the composition is a value measured with a BM viscometer at 25 ° C.
  • the pH (25 ° C.) of the composition of the present invention is not particularly limited, but is preferably 2.5 to 10.0, more preferably 3.0 to 7.0.
  • the measurement of pH is based on the method prescribed
  • the shape and dosage form of the composition of the present invention are not particularly limited, and can be prepared and used in various shapes and dosage forms such as liquid, cream, lotion, gel, foam, aerosol, etc. , And can be prepared according to conventional methods for each dosage form.
  • the present invention also provides a cleaning composition
  • a cleaning composition comprising (a) (a-1) an anionic surfactant and (a-2) an amphoteric surfactant and (c) a refreshing agent, and (b) at room temperature.
  • a solid nonionic surfactant By blending a solid nonionic surfactant, there is provided a method for suppressing a decrease in viscosity of the cleaning composition by blending the component (c).
  • specific examples and blending amounts of the components (a) to (c) can be the same as those described for the cleaning composition.
  • test article (component (b)) is liquid by the test procedure specified in (3) at the test site specified in (2) using the equipment specified in (1). It shall be confirmed whether or not.
  • (1) Apparatus a) Constant-temperature water tank It is equipped with a stirrer, a heater, a thermometer, and an automatic temperature controller (that can control the temperature at ⁇ 0.1 ° C.) and has a depth of 150 mm or more.
  • thermometer shall be one for freezing point measurement (SOP-58 scale range 20 to 50 ° C) as defined in JIS B 7410 (1982) “Petroleum test glass thermometer”.
  • Rubber stoppers shall fit the mouth of the test tube (two), one of which shall have a hole in the center of the stopper to support the thermometer.
  • Test place The test place shall be a place under atmospheric pressure with a temperature of 20 ⁇ 5 ° C.
  • test tube is sealed with a rubber plug (hereinafter referred to as a “liquid determination test tube”), and the other test tube is sealed with a rubber plug with a thermometer (hereinafter referred to as a “temperature measurement test tube”). ).
  • the thermometer is immersed 30 mm and is placed upright on the test tube.
  • test tube After 10 minutes, take the test tube for liquid judgment from the thermostatic bath in an upright position on a horizontal table and immediately lay it horizontally on the table. D) Measure the time from when the test tube is tilted down until the tip of the liquid surface of the test article passes through line B. E) The test article measured in step d) exceeding 90 seconds shall be solid at the confirmation temperature.

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Abstract

L'invention concerne une composition d'agent de nettoyage qui est plaisante à utiliser, par laquelle une sensation de propreté est obtenue sans une diminution en viscosité et sans stabilité médiocre à de basses températures même dans un système formulé avec du menthol ou un autre agent de rafraîchissement. Cette composition d'agent de nettoyage contient : (a) un agent tensio-actif anionique (a-1) et un agent tensio-actif amphotère (a-2), à 4 % en masse ou plus en termes du total de (a-1) et (a-2) ; (b) un agent tensio-actif non ionique à chaînes multiples, qui est solide à température ambiante, à 0,01-5 % en masse ; et (c) un agent de rafraîchissement choisi dans le groupe consistant en le menthol, la menthone, le camphre, le bornéol, la cinéol-menthone, le salicylate de menthyle, le malonate de menthyle, le glycosyl-monomenthyl-O-acétate, le 3-L-menthoxypropane-1,2-diol, le L-menthyl-3-hydroxybutyrate, l'essence de menthe verte, l'essence de menthe poivrée, l'essence d'eucalyptus et l'essence de menthe, à 0,01-5 % en masse.
PCT/JP2012/053088 2011-02-28 2012-02-10 Composition d'agent de nettoyage Ceased WO2012117828A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PH1/2013/501774A PH12013501774A1 (en) 2011-02-28 2012-02-10 Cleaning agent composition
KR1020137019873A KR101858291B1 (ko) 2011-02-28 2012-02-10 세정제 조성물

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011-042004 2011-02-28
JP2011042004A JP5703840B2 (ja) 2011-02-28 2011-02-28 洗浄剤組成物

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WO2012117828A1 true WO2012117828A1 (fr) 2012-09-07

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JP (1) JP5703840B2 (fr)
KR (1) KR101858291B1 (fr)
MY (1) MY162460A (fr)
PH (1) PH12013501774A1 (fr)
WO (1) WO2012117828A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2014148245A1 (ja) * 2013-03-21 2017-02-16 ライオン株式会社 シャンプー組成物
WO2020044956A1 (fr) * 2018-08-29 2020-03-05 株式会社 資生堂 Produit cosmétique et nettoyant
JP2022504965A (ja) * 2018-10-25 2022-01-13 ザ プロクター アンド ギャンブル カンパニー 界面活性剤可溶性抗ふけ剤の付着を増強した組成物
CN115397387A (zh) * 2020-04-14 2022-11-25 东洋美妆株式会社 身体清洁剂
JP2023095290A (ja) * 2021-12-24 2023-07-06 株式会社 資生堂 洗浄料

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014128922A1 (fr) * 2013-02-22 2014-08-28 株式会社コーセー Composition visqueuse de détergent
CN103110557B (zh) * 2013-03-21 2015-03-25 白继良 具有清爽止汗作用的洗浴搓茶及其制备方法
WO2015134829A1 (fr) * 2014-03-07 2015-09-11 The Procter & Gamble Company Compositions comprenant un agent piquant
JP6602119B2 (ja) * 2015-09-04 2019-11-06 株式会社マンダム 皮膚洗浄剤
JP6649910B2 (ja) * 2017-03-02 2020-02-19 花王株式会社 皮膚洗浄剤組成物
JP7406235B2 (ja) * 2019-12-06 2023-12-27 株式会社ダリヤ カラーシャンプー組成物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10310790A (ja) * 1997-05-09 1998-11-24 Kose Corp 洗浄剤組成物
JP2005213209A (ja) * 2004-01-30 2005-08-11 Kawaken Fine Chem Co Ltd 染色毛髪用シャンプー組成物
JP2009035520A (ja) * 2007-08-03 2009-02-19 Kao Corp 洗浄剤組成物
JP2010138105A (ja) * 2008-12-11 2010-06-24 Sunstar Inc 透明洗浄剤組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10310790A (ja) * 1997-05-09 1998-11-24 Kose Corp 洗浄剤組成物
JP2005213209A (ja) * 2004-01-30 2005-08-11 Kawaken Fine Chem Co Ltd 染色毛髪用シャンプー組成物
JP2009035520A (ja) * 2007-08-03 2009-02-19 Kao Corp 洗浄剤組成物
JP2010138105A (ja) * 2008-12-11 2010-06-24 Sunstar Inc 透明洗浄剤組成物

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2014148245A1 (ja) * 2013-03-21 2017-02-16 ライオン株式会社 シャンプー組成物
WO2020044956A1 (fr) * 2018-08-29 2020-03-05 株式会社 資生堂 Produit cosmétique et nettoyant
JP2020033297A (ja) * 2018-08-29 2020-03-05 株式会社 資生堂 化粧料および洗浄料
CN112638355A (zh) * 2018-08-29 2021-04-09 株式会社资生堂 化妆品和清洁品
JP7191593B2 (ja) 2018-08-29 2022-12-19 株式会社 資生堂 化粧料および洗浄料
JP2022504965A (ja) * 2018-10-25 2022-01-13 ザ プロクター アンド ギャンブル カンパニー 界面活性剤可溶性抗ふけ剤の付着を増強した組成物
US12226505B2 (en) 2018-10-25 2025-02-18 The Procter & Gamble Company Compositions having enhanced deposition of surfactant-soluble anti-dandruff agents
JP7758567B2 (ja) 2018-10-25 2025-10-22 ザ プロクター アンド ギャンブル カンパニー 界面活性剤可溶性抗ふけ剤の付着を増強した組成物
CN115397387A (zh) * 2020-04-14 2022-11-25 东洋美妆株式会社 身体清洁剂
JP2023095290A (ja) * 2021-12-24 2023-07-06 株式会社 資生堂 洗浄料
JP7793363B2 (ja) 2021-12-24 2026-01-05 株式会社 資生堂 洗浄料

Also Published As

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PH12013501774A1 (en) 2013-10-14
JP5703840B2 (ja) 2015-04-22
JP2012180384A (ja) 2012-09-20
KR20130141654A (ko) 2013-12-26
KR101858291B1 (ko) 2018-05-15

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