WO2012134152A3 - 젖산과 아이소소바이드가 공중합된 폴리에스테르 수지 및 그 제조방법 - Google Patents

젖산과 아이소소바이드가 공중합된 폴리에스테르 수지 및 그 제조방법 Download PDF

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Publication number
WO2012134152A3
WO2012134152A3 PCT/KR2012/002240 KR2012002240W WO2012134152A3 WO 2012134152 A3 WO2012134152 A3 WO 2012134152A3 KR 2012002240 W KR2012002240 W KR 2012002240W WO 2012134152 A3 WO2012134152 A3 WO 2012134152A3
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WO
WIPO (PCT)
Prior art keywords
polyester resin
lactic acid
copolymerisation
isosorbide
production method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2012/002240
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English (en)
French (fr)
Other versions
WO2012134152A2 (ko
Inventor
김동진
김종량
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SK Chemicals Co Ltd
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SK Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SK Chemicals Co Ltd filed Critical SK Chemicals Co Ltd
Priority to HK14102620.8A priority Critical patent/HK1189610B/xx
Priority to US14/006,167 priority patent/US20140011976A1/en
Priority to EP12763836.9A priority patent/EP2692763B1/en
Priority to CN201280015245.0A priority patent/CN103459457B/zh
Priority to JP2014502456A priority patent/JP5848435B2/ja
Publication of WO2012134152A2 publication Critical patent/WO2012134152A2/ko
Publication of WO2012134152A3 publication Critical patent/WO2012134152A3/ko
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

젖산 또는 그의 유래 화합물과 아이소소바이드가 공중합되어, 바이오 매스 유래 화합물의 함량이 높을 뿐만 아니라, 내열성과 색상이 우수한 폴리에스테르 수지 및 그 제조방법이 개시된다. 상기 폴리에스테르 수지는, 테레프탈산을 포함하는 이가산 성분; 전체 디올 성분에 대하여, 1 내지 60몰%의 아이소소바이드 및 1 내지 90몰%의 에틸렌글리콜을 포함하는 디올 성분; 및 전체 수지 중합 반응물에 대하여 1 내지 50중량%의 젖산 또는 그의 유래 화합물이 공중합되어, 상기 이가산 성분으로부터 유도된 이가산 부분, 상기 디올 성분으로부터 유도된 디올 부분 및 상기 젖산 또는 그의 유래 화합물로부터 유도된 히드록시 일가산 부분이 반복되는 구조를 가진다.
PCT/KR2012/002240 2011-03-29 2012-03-28 젖산과 아이소소바이드가 공중합된 폴리에스테르 수지 및 그 제조방법 Ceased WO2012134152A2 (ko)

Priority Applications (5)

Application Number Priority Date Filing Date Title
HK14102620.8A HK1189610B (en) 2011-03-29 2012-03-28 Polyester resin resulting from the copolymerisation of lactic acid and isosorbide, and a production method therefor
US14/006,167 US20140011976A1 (en) 2011-03-29 2012-03-28 Polyester resin resulting from the copolymerisation of lactic acid and isosorbide, and a production method therefor
EP12763836.9A EP2692763B1 (en) 2011-03-29 2012-03-28 Polyester resin resulting from the copolymerisation of lactic acid and isosorbide, and a production method therefor
CN201280015245.0A CN103459457B (zh) 2011-03-29 2012-03-28 来源于乳酸和异山梨醇共聚作用的聚酯树脂及其制备方法
JP2014502456A JP5848435B2 (ja) 2011-03-29 2012-03-28 乳酸とイソソルバイドの共重合から得られるポリエステル樹脂およびその製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020110028366A KR101769560B1 (ko) 2011-03-29 2011-03-29 젖산과 아이소소바이드가 공중합된 폴리에스테르 수지 및 그 제조방법
KR10-2011-0028366 2011-03-29

Publications (2)

Publication Number Publication Date
WO2012134152A2 WO2012134152A2 (ko) 2012-10-04
WO2012134152A3 true WO2012134152A3 (ko) 2012-12-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2012/002240 Ceased WO2012134152A2 (ko) 2011-03-29 2012-03-28 젖산과 아이소소바이드가 공중합된 폴리에스테르 수지 및 그 제조방법

Country Status (7)

Country Link
US (1) US20140011976A1 (ko)
EP (1) EP2692763B1 (ko)
JP (1) JP5848435B2 (ko)
KR (1) KR101769560B1 (ko)
CN (1) CN103459457B (ko)
TW (1) TWI545145B (ko)
WO (1) WO2012134152A2 (ko)

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KR101775620B1 (ko) * 2011-04-06 2017-09-07 에스케이케미칼주식회사 코팅용 폴리에스테르 바인더 수지 및 이를 함유하는 코팅 조성물
ITTO20130711A1 (it) 2013-09-02 2015-03-03 Biochemtex Spa Composizioni di glicole etilenico bioderivato per bottiglie di poliestere
KR102251210B1 (ko) * 2014-04-11 2021-05-11 에스케이케미칼 주식회사 다층 폴리에스테르 시트 및 그 성형품
KR101586458B1 (ko) * 2014-04-22 2016-01-18 롯데케미칼 주식회사 신규한 폴리에스테르 수지
CN105440268B (zh) * 2014-08-29 2018-02-13 中国科学院长春应用化学研究所 一种脂肪族‑芳香族‑聚乳酸多嵌段共聚物
FR3027906B1 (fr) * 2014-10-29 2017-01-06 Roquette Freres Procede de fabrication d'un polyester contenant au moins un motif 1,4 : 3,6-dianhydrohexitol a coloration amelioree
KR102210477B1 (ko) * 2014-10-31 2021-01-29 에스케이케미칼 주식회사 다층 플라스틱 카드
CN105419769B (zh) * 2015-11-05 2018-11-16 中国石油天然气股份有限公司 一种可降解纤维及含其的压裂液与该压裂液的制备方法
KR102568743B1 (ko) * 2017-05-31 2023-08-22 에스케이케미칼 주식회사 폴리에스테르 수지, 이의 제조 방법 및 이로부터 형성된 수지 성형품
KR102568693B1 (ko) 2017-06-02 2023-08-21 에스케이케미칼 주식회사 폴리에스테르 섬유, 이의 제조 방법 및 이로부터 형성된 성형체
JP7240333B2 (ja) 2017-06-22 2023-03-15 エスケー ケミカルズ カンパニー リミテッド ポリエステル容器およびその製造方法
KR102684863B1 (ko) * 2017-06-26 2024-07-15 에스케이케미칼 주식회사 폴리에스테르 필름 및 이의 제조 방법
CN114829740A (zh) * 2019-12-18 2022-07-29 索尔维特殊聚合物美国有限责任公司 包含支化聚(羟基酸)的井下工具构件
CN111087588B (zh) * 2019-12-18 2022-05-24 浙江恒澜科技有限公司 一种异山梨醇改性的高耐热生物降解聚酯及其制备方法
CN112341611A (zh) * 2020-11-20 2021-02-09 吉林大学 一种高耐热良好力学性能可降解改性聚酯及其制备方法

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WO2006010061A1 (en) * 2004-07-09 2006-01-26 E.I. Dupont De Nemours And Company Copolyetherester compositions containing hydroxyalkanoic acids and shaped articles produced therefrom
WO2008056136A1 (en) * 2006-11-08 2008-05-15 Tate & Lyle Public Limited Company Lactic acid polymers
JP2009242443A (ja) * 2008-03-28 2009-10-22 Toray Ind Inc ポリ乳酸ブロック共重合体、その製造方法および成形品
JP2010037463A (ja) * 2008-08-06 2010-02-18 Nitto Denko Corp ポリエステル、ポリエステル組成物、粘着剤組成物、粘着剤層及び粘着シート

Also Published As

Publication number Publication date
CN103459457B (zh) 2016-05-25
JP2014509676A (ja) 2014-04-21
TWI545145B (zh) 2016-08-11
EP2692763B1 (en) 2020-03-25
EP2692763A4 (en) 2014-10-15
EP2692763A2 (en) 2014-02-05
KR101769560B1 (ko) 2017-08-18
US20140011976A1 (en) 2014-01-09
CN103459457A (zh) 2013-12-18
WO2012134152A2 (ko) 2012-10-04
TW201241039A (en) 2012-10-16
KR20120110477A (ko) 2012-10-10
HK1189610A1 (zh) 2014-06-13
JP5848435B2 (ja) 2016-01-27

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