WO2012134717A3 - Polymères d'oléfines supérieures à terminaison vinyle et leurs procédés de production - Google Patents

Polymères d'oléfines supérieures à terminaison vinyle et leurs procédés de production Download PDF

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Publication number
WO2012134717A3
WO2012134717A3 PCT/US2012/027682 US2012027682W WO2012134717A3 WO 2012134717 A3 WO2012134717 A3 WO 2012134717A3 US 2012027682 W US2012027682 W US 2012027682W WO 2012134717 A3 WO2012134717 A3 WO 2012134717A3
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WO
WIPO (PCT)
Prior art keywords
higher olefin
produce
methods
vinyl terminated
olefin polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2012/027682
Other languages
English (en)
Other versions
WO2012134717A2 (fr
Inventor
Donna J. Crowther
Matthew W. Holtcamp
John R. Hagadorn
Charles J. Ruff
George Rodriguez
Patrick Brant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/072,249 external-priority patent/US8399724B2/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to CN201280014747.1A priority Critical patent/CN103443144B/zh
Priority to JP2014501091A priority patent/JP5739054B2/ja
Priority to EP12763904.5A priority patent/EP2688926A4/fr
Publication of WO2012134717A2 publication Critical patent/WO2012134717A2/fr
Publication of WO2012134717A3 publication Critical patent/WO2012134717A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C10M107/10—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024—Propene
    • C10M2205/0245—Propene used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
    • C10M2205/0265—Butene used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/04—Molecular weight; Molecular weight distribution
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/071—Branched chain compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

L'invention concerne un copolymère d'oléfines supérieures à terminaison vinyle présentant un Mn supérieur ou égal à 300 g/mol (mesuré par 1H NMR) qui comprend : (i) entre environ 20 et environ 99,9 mol % d'au moins un monomère d'oléfines supérieures C5 à C40 ; et (ii) entre environ 0,1 et environ 80 mol % de propylène ; le copolymère d'oléfines supérieures possédant au moins 40 % d'extrémités de chaîne allyle. Le copolymère peut également présenter un rapport extrémité de chaîne isobutyle/extrémité de chaîne allyle inférieur à 0,7: 1 et/ou un rapport extrémité de chaîne allyle/extrémité de chaîne vinylidène supérieur à 2:1.
PCT/US2012/027682 2011-03-25 2012-03-05 Polymères d'oléfines supérieures à terminaison vinyle et leurs procédés de production Ceased WO2012134717A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201280014747.1A CN103443144B (zh) 2011-03-25 2012-03-05 乙烯基封端的高级烯烃共聚物及其制造方法
JP2014501091A JP5739054B2 (ja) 2011-03-25 2012-03-05 ビニル末端高級オレフィンコポリマーおよびその生成方法
EP12763904.5A EP2688926A4 (fr) 2011-03-25 2012-03-05 Polymères d'oléfines supérieures à terminaison vinyle et leurs procédés de production

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/072,249 US8399724B2 (en) 2011-03-25 2011-03-25 Vinyl terminated higher olefin copolymers and methods to produce thereof
US13/072,249 2011-03-25
EP11167059.2 2011-05-23
EP11167059 2011-05-23

Publications (2)

Publication Number Publication Date
WO2012134717A2 WO2012134717A2 (fr) 2012-10-04
WO2012134717A3 true WO2012134717A3 (fr) 2012-11-22

Family

ID=46932224

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/027682 Ceased WO2012134717A2 (fr) 2011-03-25 2012-03-05 Polymères d'oléfines supérieures à terminaison vinyle et leurs procédés de production

Country Status (4)

Country Link
EP (1) EP2688926A4 (fr)
JP (1) JP5739054B2 (fr)
CN (1) CN103443144B (fr)
WO (1) WO2012134717A2 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104661751B (zh) * 2012-09-24 2017-02-22 埃克森美孚化学专利公司 乙烯基封端的聚乙烯的生产
US20160160071A1 (en) 2014-12-04 2016-06-09 Exxonmobil Chemical Patents Inc. Water-Based Polyolefin Corrosion Inhibitors Based on Vinyl/Vinylidene Terminated Polyolefins
EP3387046B1 (fr) * 2015-12-09 2019-12-25 SABIC Global Technologies B.V. Procédé de préparation de copolymères greffés à base de polyoléfine fonctionnalisée comprenant un premier bloc de polyoléfine ramifié à chaîne courte et une ou plusieurs chaînes latérales de polymères

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6897261B1 (en) * 1999-07-26 2005-05-24 Idemitsu Kosan Co., Ltd. Branched olefinic macromonomer, olefin graft copolymer, and olefin resin composition
US20060052553A1 (en) * 2002-12-04 2006-03-09 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
US20080281060A1 (en) * 2004-03-12 2008-11-13 Basell Polyotefine Gmbh Process For Polymerizaing 1-Hexene or Higher Alpha-Olefins
US20090318647A1 (en) * 2008-06-20 2009-12-24 Hagadorn John R Olefin Functionalization By Metathesis Reaction
US20090318644A1 (en) * 2008-06-20 2009-12-24 Patrick Brant High Vinyl Terminated Propylene Based Oligomers

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995033779A1 (fr) * 1994-06-09 1995-12-14 Exxon Chemical Patents Inc. PROCEDE DE DILUTION UTILE POUR POLYMERISER DES HOMOPOLYMERES ET DES COPOLYMERES OLEFINES-α NON ETHYLENIQUES AU MOYEN DE SYSTEMES CATALYSEURS EN ALLIAGES ORGANOMETALLIQUES
US5811379A (en) * 1996-06-17 1998-09-22 Exxon Chemical Patents Inc. Polymers derived from olefins useful as lubricant and fuel oil additives, processes for preparation of such polymers and additives and use thereof (PT-1267)
GB9715317D0 (en) * 1997-07-22 1997-09-24 Bp Chem Int Ltd Polymerisation catalysts
WO2004046214A2 (fr) * 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Systeme catalyseur multiple pour la polymerisation d'olefines et polymeres ainsi produits

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6897261B1 (en) * 1999-07-26 2005-05-24 Idemitsu Kosan Co., Ltd. Branched olefinic macromonomer, olefin graft copolymer, and olefin resin composition
US20060052553A1 (en) * 2002-12-04 2006-03-09 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
US20080281060A1 (en) * 2004-03-12 2008-11-13 Basell Polyotefine Gmbh Process For Polymerizaing 1-Hexene or Higher Alpha-Olefins
US20090318647A1 (en) * 2008-06-20 2009-12-24 Hagadorn John R Olefin Functionalization By Metathesis Reaction
US20090318644A1 (en) * 2008-06-20 2009-12-24 Patrick Brant High Vinyl Terminated Propylene Based Oligomers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2688926A4 *

Also Published As

Publication number Publication date
CN103443144A (zh) 2013-12-11
JP2014511910A (ja) 2014-05-19
EP2688926A4 (fr) 2015-07-08
EP2688926A2 (fr) 2014-01-29
WO2012134717A2 (fr) 2012-10-04
CN103443144B (zh) 2016-07-06
JP5739054B2 (ja) 2015-06-24

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