WO2012144101A1 - 燃焼装置及び燃焼方法と、それを用いた発電装置及び発電方法 - Google Patents
燃焼装置及び燃焼方法と、それを用いた発電装置及び発電方法 Download PDFInfo
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- WO2012144101A1 WO2012144101A1 PCT/JP2011/074723 JP2011074723W WO2012144101A1 WO 2012144101 A1 WO2012144101 A1 WO 2012144101A1 JP 2011074723 W JP2011074723 W JP 2011074723W WO 2012144101 A1 WO2012144101 A1 WO 2012144101A1
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- combustion
- air
- flame
- combustion chamber
- airflow
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N10/00—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects
- H10N10/10—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects
- H10N10/13—Thermoelectric devices comprising a junction of dissimilar materials, i.e. devices exhibiting Seebeck or Peltier effects operating with only the Peltier or Seebeck effects characterised by the heat-exchanging means at the junction
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23B—METHODS OR APPARATUS FOR COMBUSTION USING ONLY SOLID FUEL
- F23B10/00—Combustion apparatus characterised by the combination of two or more combustion chambers
- F23B10/02—Combustion apparatus characterised by the combination of two or more combustion chambers including separate secondary combustion chambers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D1/00—Burners for combustion of pulverulent fuel
- F23D1/02—Vortex burners, e.g. for cyclone-type combustion apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/04—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment drying
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
- F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/24—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a vertical, substantially cylindrical, combustion chamber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/32—Incineration of waste; Incinerator constructions; Details, accessories or control therefor the waste being subjected to a whirling movement, e.g. cyclonic incinerators
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/44—Details; Accessories
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/44—Details; Accessories
- F23G5/46—Recuperation of heat
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L9/00—Passages or apertures for delivering secondary air for completing combustion of fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L9/00—Passages or apertures for delivering secondary air for completing combustion of fuel
- F23L9/02—Passages or apertures for delivering secondary air for completing combustion of fuel by discharging the air above the fire
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2206/00—Waste heat recuperation
- F23G2206/20—Waste heat recuperation using the heat in association with another installation
- F23G2206/203—Waste heat recuperation using the heat in association with another installation with a power/heat generating installation
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/52—Heat recovery pumps, i.e. heat pump based systems or units able to transfer the thermal energy from one area of the premises or part of the facilities to a different one, improving the overall efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/12—Heat utilisation in combustion or incineration of waste
Definitions
- the present invention relates to a combustion apparatus and a combustion method, and a power generation apparatus and a power generation method using the combustion apparatus, and more particularly to a technique for improving combustion efficiency and power generation efficiency.
- thermoelectric power generation module having high temperature durability disclosed in Japanese Patent No. 4457215
- a power generation device in which a part or all of the combustion chamber is formed by the thermoelectric power generation module can be realized. It is possible to efficiently generate power using the same heat source by generating thermoelectric power without reducing the power and generating power with a steam turbine.
- the combustion chamber disclosed in Japanese Patent No. 3318748 is formed into a cylindrical shape, and the air is rotated so that the combustion air is continuously supplied to the flame from the outside of the flame according to the progression of the flame. By expanding in the direction, it is possible to prevent deterioration of the power generation module forming the combustion chamber due to partial overheating.
- exhaust gas from combustion equipment that uses flammable waste containing various materials as fuel is used as part of combustion air for combustion equipment that uses high-viscosity liquid fuel such as waste oil as fuel.
- high-viscosity liquid fuel such as waste oil as fuel.
- Combustion is possible, and waste oil with high viscosity can be used as fuel by using the exhaust heat of the combustion device that uses the combustible waste as fuel.
- a rotary combustion apparatus using liquid fuel is disclosed in Japanese Patent Publication No. Hei 11-83022, Japanese Patent Publication No. 2000-257834, Japanese Patent Publication No. 2001-141245, Japanese Patent Publication No. 2009-144938, and the like.
- the excellent combustion efficiency in the capacity test of the device disclosed in the -141245 is known.
- a power generation device that forms part or all of the combustion chamber by a thermoelectric power generation module having a high temperature durability as disclosed in Japanese Patent No. 4457215 is possible, and the same heat source By simultaneously performing thermoelectric power generation and power generation using thermal energy without reducing the thermal energy that uses heat, it is possible to generate power with high energy efficiency.
- Patent No. 138656 proposes countermeasures against smoke and harmful substance generation due to incomplete combustion in a naturally aspirated combustion device that uses waste oil such as paper products and wood products, and waste oil from automobiles, machinery and food processing as fuel.
- a circulation type in a waste oil combustion apparatus is proposed.
- a combustion apparatus is proposed which has a feature that promotes combustion by providing a combustion promoting plate in the furnace so that the air in the furnace stays at a high temperature for a long time
- Japanese Patent No. 3318748 a petroleum product rotary combustion stove has been proposed that has the feature of rotating and supplying air by a blower to cause rotary combustion and secondary combustion on the outer periphery of the furnace.
- Combustion equipment improves combustion efficiency, achieves energy savings, and increases furnace durability.
- conventional combustion for example, in the case of plastic, there may be a problem that a lot of smoke is emitted, but the cause is that combustion is not preferable. Therefore, if the combustion is good, it will be both smoke removal and you will get both.
- thermoelectric power generation using a temperature difference a method for generating power without reducing thermal energy due to a temperature difference between the inside and outside of the combustion chamber is provided by forming a part or all of the combustion chamber of the thermoelectric power generation device with a thermoelectric power generation module. To do.
- thermoelectric power generation using the same heat source in the combustion chamber and simultaneous power generation by a steam turbine.
- Combustible waste containing miscellaneous materials is used as fuel without separating garbage that lowers the combustion temperature of high moisture or petroleum products that require a large amount of air to burn, and the same as combustion
- a power generation system that recycles combustible waste by thermoelectric power generation and steam turbine power generation is provided.
- a combustion method for combusting a combustible in a combustion device the step of introducing the combustible into a combustion chamber of the combustion device, the step of igniting and combusting the combusted material, A process of supplying air or a combustion-supporting gas (hereinafter referred to as air) from the outside of the flame, a process of secondary combustion of the combusted material by the air, and a process of exhausting the flame associated with combustion It is characterized by having.
- air combustion-supporting gas
- a configuration may be included in which the combusted material containing at least a solid content is additionally charged into the combustion chamber during combustion of the combusted material in the combustion method.
- a configuration in which an induced air flow is generated in the combustion chamber may be employed.
- a configuration may be provided in which air or the like is supplied to the flame from the rear in the flame traveling direction.
- the process of supplying air or the like to the flame from the outside and the process of supplying air or the like to the flame from the rear in the flame traveling direction may be alternately repeated.
- the progress of the flame may be controlled by a partition having flame passing means for the flame that progresses.
- the combustion object containing at least solid content is dried before combustion, the step of transferring the combustion object to a deposition site, and the deposited combustion object from a lower part of the deposition site. It may be configured to have a process of transferring to the upper part of the deposition site, a step of drying the combusted material in the deposition site and the process of the transfer, and a step of collecting the dried combusted material and transferring it to the combustion chamber.
- the combusted material may be blown up with air or the like, and an induced air flow may be generated outside the air flow.
- the dried combusted material In the process of recovering the dried combusted material and transferring it to the combustion chamber, it may be recovered together with the exhaust gas and supplied to the combustion device as combustion air.
- thermoelectric power generation module uses any one of the combustion methods described above. You can also.
- a combustion chamber is formed in a cylindrical shape, a cylindrical air injection pipe having an air supply port on the inner side surface of the combustion chamber and having a hole on the side surface is provided in the direction of flame propagation.
- the structure provided along may be sufficient.
- a configuration provided with a partition provided with flame passing means inside the combustion chamber may be employed.
- a configuration may be adopted in which the combustion object inlet is configured with a pipe on the side surface of the combustion chamber, and an airflow injection nozzle is provided so as to generate an induced airflow on the inner wall of the pipe.
- It may be configured to include a cylindrical secondary combustion chamber provided with a hole in a side surface having a flame intake means connected to the combustion chamber.
- a configuration may be provided in which the secondary combustion chamber and means for taking in air or a combustible gas (hereinafter referred to as air or the like) from the rear in the flame traveling direction communicating with the secondary combustion chamber may be used.
- air or the like combustible gas
- the secondary combustion chamber may include at least two types of secondary combustion chambers having different diameters.
- the secondary combustion chamber may be provided with a cylindrical cover that covers the outside so as to form a space having a means for taking in air.
- the drying apparatus comprising a drying object intake, a circulation inlet, a drying object discharge port, a deposition tank having a dried material discharge port, and a means for circulating and transferring from the drying object discharge port to the circulation intake port
- the structure which connects a material discharge port with the combustible material intake port of the said combustion apparatus may be sufficient.
- a rotary shaft is provided in the drying tank of the drying device, an injection pipe having a hole for promoting stirring is provided in the vicinity of the drying tank of the rotary shaft, and a plate is provided so as to cover the hole from above the hole of the injection pipe And a means for supplying pressure air or the like to the injection pipe.
- the means for supplying the pressurized air may be provided with a blower blade driven by a rotating shaft and supplying air or the like pressurized by the blade to the injection pipe.
- the rotary shaft may be divided into an outer shaft and a middle shaft, and a stirring blade, an injection pipe and a plate may be provided on the outer shaft, and a blower blade may be provided on the middle shaft.
- the drying object discharge port and the circulation intake port are communicated with each other by a circulation duct having a blowing means, and the circulation duct has an intake port.
- a configuration may be adopted in which an airflow jet nozzle provided with a compressed air supply means is provided on the lower inner wall and the bent portion inner wall so as to generate an induced airflow outside the airflow.
- the heat which uses the exhaust heat of the steam exhausted from the steam turbine provided with the exhaust heat boiler which generates steam using the exhaust heat of the combustion chamber, and the steam turbine which operates with the steam generated with the exhaust heat boiler A configuration may be employed in which an exchanger is provided and hot air or hot air supplied from the heat exchanger is taken into the circulation duct.
- thermoelectric power generation module provided with the several thermoelectric conversion element which performs this may be sufficient.
- Combustion device equipped with combustible solid waste cutting machine, air flow drying device for combustible solid waste, secondary combustion device using combustible solid waste as fuel, and exhaust heat boiler and steam using exhaust heat of combustion device
- a power generation system including a turbine generator and a heat pump, in which part or all of a combustion apparatus is formed by a thermoelectric power generation module, and the same heat source is efficiently used by the thermoelectric power generation and the steam turbine generator. You can also.
- the present invention has the following effects.
- the air taken in from the small holes is continuously and naturally supplied from the lower side of the side, thereby eliminating the incomplete combustion due to air shortage.
- a vertical combustion furnace with a plurality of small holes arranged in a zigzag line around the side creates a spiral air flow that increases the contact efficiency between the combustion gas and air that rises outside with the flame.
- the combustion furnace having a diameter larger than that of the combustion furnace increases the combustion efficiency by supplying air from the lower outside to the combustion gas rotating around the outside of the flame.
- the high-temperature partition provided with a plurality of small holes inside the combustion furnace that is overheated by the rising flame has the effect of reducing incomplete combustion due to a decrease in the combustion temperature.
- An optimum combustion structure is constructed by alternately stacking a plurality of the above-mentioned combustion furnaces according to the fuel material, and the combustion area is expanded in the vertical direction by continuously acting the respective functions. Eliminates internal overheating and increases the durability of the furnace.
- the natural intake type has a feature that does not require new power, and is an effective combustion structure in various combustion devices having a structure with an air supply function by a blower.
- a plurality of combustion furnaces with small holes on the side for generating a spiral air flow and a small hole for taking air from below into the combustion gas that circulates inside and outside the furnace A combustion structure in which a plurality of combustion furnaces are stacked on the inner and outer sides of the furnace is effective regardless of the shape and form as long as it has the functions described above.
- the flame By exhausting the airflow that circulates in the furnace from the exhaust port provided on the side, the flame extends to the exhaust port even if the top surface is opened, so that it is possible to safely inject solid fuel.
- Safety is improved by providing a cyclone in the direction of the air flow around the exhaust port.
- the safety is further enhanced by forcibly exhausting.
- thermoelectric power generation that generates power without reducing heat energy by using a heat source obtained by a rotary combustion device that uses combustible waste as fuel.
- Thermoelectric power generation can be performed efficiently by utilizing the temperature difference between the inside and outside of the combustion chamber by forming part or all of the combustion chamber of the power generation device by the thermoelectric power generation module.
- thermoelectric power generation module By forming a part or all of the combustion chamber of the power generation device with a thermoelectric power generation module, the combustion heat of the combustion chamber is used to generate thermoelectric power without reducing the thermal energy and the combustion chamber is used to generate steam. By generating electricity with the turbine, the same heat source can be efficiently generated.
- thermoelectric power generation module In the combustion chamber, by supplying air from the outside of the flame by air circulating around the outside of the flame, a space is provided between the flame and the inner wall of the combustion chamber formed by the thermoelectric power generation module, and the progress of the flame By continuously supplying air along the line, it is possible to prevent partial overheating by expanding the combustion area in the flame traveling direction, and to increase the durability of the power generation device.
- the partition provided to control the flame that progresses into the combustion chamber is provided with a material that glows red, thereby preventing the combustion temperature from decreasing and promoting combustion of the combustion gas that proceeds with the flame.
- Providing with a pipe material having a power generation function makes it possible to generate power and generate steam.
- miscellaneous materials can be It can compensate for the shortage of air supply when burning combustible waste.
- an air jet nozzle that provides a wind direction plate, forms a solid fuel inlet with a pipe, and generates an induced air flow to the combustion chamber inside.
- the combustion temperature is prevented from decreasing and stable and efficient combustion and power generation are possible.
- the material to be dried is suspended while stirring the material to be dried in the drying tank, air is supplied from below, and the material to be dried is brought into contact with the air by repeatedly carrying the airflow from the lower part to the upper part of the drying tank. Dry efficiently with increasing opportunities and area.
- the object to be dried is provided by providing an air jet nozzle on the inner wall of the lower part of the inlet of the circulation duct and the inner wall of the bent part so as to generate an induced airflow outside the airflow that blows the object to be dried together with air. Circulate smoothly.
- the odor of combustible waste which is the material to be dried, is removed by using the exhaust gas from the airflow drying device as combustion air for the combustion device.
- the drying efficiency is increased by using the exhaust heat generated by the heat pump as circulation air, and the power generation efficiency is increased by supplying cold air or refrigerant to the outside of the combustion chamber.
- a power generation device that uses flammable waste formed by a thermoelectric power generation module as fuel, a boiler that generates steam using the combustion heat of the power generation device, and a steam turbine that operates by steam generated in the boiler to generate power
- a power generation system that uses combustible waste as a fuel, equipped with a power generation device and a combustible waste airflow drying device, it is possible to recycle combustible waste and use thermoelectric power generation using the same heat source. By simultaneously performing steam turbine power generation, efficient power generation becomes possible.
- FIG. 1 shows a schematic diagram of a power generation system according to an embodiment of the present invention.
- FIG. 1 shows a schematic diagram of a power generation system according to an embodiment of the present invention.
- FIG. 1 As an intake method in the combustion chamber, an embodiment in which forced supply air and natural intake are combined will be described. Another example is shown. Another example is shown.
- upper surface (plane side) of a combustion chamber is shown.
- the structure of the combustion apparatus which throws in a to-be-burned material from the side surface of a combustion chamber is shown.
- Another embodiment of a combustion apparatus for injecting combustibles from the side will be shown.
- upper surface (plane side) of a combustion chamber is shown. Another example is shown.
- FIG. 1 shows a combustion section (10), a secondary combustion chamber (20), a blower (110), a waste oil tank section (30), etc. in the combustion apparatus of the present invention.
- a combustion apparatus (10) performs a combustion process as FIG. 1 shows.
- a combustible material such as a solid material
- an air injection nozzle part (111) is provided adjacent to it and plays a role of attracting the combustible material into the combustion chamber (15).
- any auxiliary combustible gas can be used instead of air, but in the following examples, air is used as an example.
- a solid material can be charged completely and reliably by an outside air shut-off type charging device provided with a double door and a charging auxiliary chamber (not shown) outside the combustion chamber. That is, an air injection nozzle part (111) having lead in the flame traveling direction and having a hole in the side surface is provided, and air continuously circulating along the traveling direction from the outside of the flame to the flame by the air rotating around the flame. Supply. For this reason, since air is injected along the flame and solids such as dust are introduced, it does not interfere with the flame, and therefore allows continuous injection.
- the inlet (13) is on the upper side of the air injection nozzle (111) and lifts the solid matter from below, improving the fire.
- the cross-sectional shape of the combustion chamber (15) is preferably a circular shape as shown in FIG.
- the injection port is formed in a cylindrical shape so as to communicate with the combustion chamber, and an air injection nozzle (111) that generates an induced air flow to the combustion chamber is provided inside, thereby enabling continuous injection of solid matter.
- the input port (13) also serves as an ignition, where solid fuel or the like is burned and input.
- the ignition burner may be permanently placed there, or the solid material may be thrown into the inlet (13) after ignition and burned. Since the charging port (13) and the air injection nozzle (111) are provided in parallel at an inclination, the solid material in the garbage can be smoothly input, and also in (2) of FIG. As can be seen, it is seen that a further layer is formed when arranged in a tangential direction so that a swirling flow is generated with respect to the combustion chamber (15), so that the swirling flow allows solids to also be introduced continuously. It can be done.
- the combustion chamber (15) provided in the combustion device (10) is configured so that the airflow can be rotated.
- the wind direction plate (140) is provided in the combustion chamber (15) so as to be inclined with respect to the outlet (130) so as to make several turns, for example.
- the room of the hole (130) of the air blow-out port that has entered from the input port (13) is surrounded by a square, but it may be a circular tube as shown in FIG.
- the wind direction plate (140) is provided at the corner of the combustion chamber (15). As shown in FIG. 2 (2), the flow entering from the inlet (13) is discharged from the hole (130), but the wind direction plate (140) is in the direction of discharge with respect to the direction of discharge. In this way, the combustion gas is deflected to give a swirling component, and a swirling airflow is generated toward the center of the combustion chamber (15).
- a fuel injection nozzle (320) that communicates from a fuel tank in a liquid combustion chamber (15) that is liquid.
- a fuel injection nozzle (320) that communicates from a fuel tank in a liquid combustion chamber (15) that is liquid.
- the fuel injection nozzle (320) in the inlet (13) and supplying liquid or gaseous fuel from the tangential direction to the flame, the rotating airflow is supplied to the flame from the outside of the flame. , Promoting further combustion.
- the fuel injection nozzle (320) is injected along the swirl flow (not at right angles), the fuel can be smoothly promoted without countering the swirl flow.
- the fuel injection nozzle can also be provided at the inlet (13), and in that case, the flame is injected from the outside of the solid material.
- combustion nozzle (321) at the lower end of the combustion chamber and burning it with liquid fuel, it is possible to burn the solid material thrown in from the inlet (13) instead of the solid fuel.
- the nozzle can also be provided along the swirl flow.
- a high-viscosity combustion dish such as waste oil, which will be described later, which causes liquid and gaseous fuel to be subjected to secondary combustion using an air injection nozzle or the like.
- Conceivable. Others may be preliminarily dried with an airflow drying device.
- each wind direction plate (140) is provided. As shown in (2) of FIG. 2, the wind direction plate (140) is. As shown in FIG. 2 (3), it can be seen that the respective wind directions are offset from each other, so that it is easy to turn.
- the corners can be cut diagonally to provide a balloon. In this case, manufacture becomes easier.
- a plurality of partition plates (12) can be provided as necessary, and the partition plate (12) has a plurality of small holes (121) as appropriate.
- These small holes (121) are provided so as to generate airflow in the same direction along the inner wall of the combustion chamber (15). Therefore, these small holes (121) will contribute further to the generation of the small holes (121) when inclined in the direction in which the airflow is generated.
- the cylinder is provided with a circular cross section. If the cross section is circular, a swirl flow can be formed more preferably.
- the partition plates (12) are staggered. Since the air injection pipe (160) passes into the combustion chamber (15), and the injection ports (161) are provided in the air in the axial direction along the plurality of pipes, the combustion air is sufficiently supplied.
- the direction of the injection pipe is provided so as to easily form a swirl flow in the circumferential direction, and it is understood that swirl is easier because the wind direction plate (140) is provided at the tip. Will.
- the air jet pipe (16) can also be supplied from the outside from a blower.
- the combustion chamber has a square cross section, but it may have a circular shape, a rectangular shape, or other shapes.
- a waste oil tank (30) is also provided outside and can be supplied through an oil supply pipe (301).
- combustion chamber (15) is further provided with a thermal lightning power generation element (310) around it, there is an advantage that power generation can be performed.
- a thermal lightning power generation element (310) around it, there is an advantage that power generation can be performed.
- the combustion air flow further rises and enters the secondary combustion chamber (20).
- a flame discharge node (210) which is a natural gas that uses the negative pressure of the air flow generated by the progression of the flame.
- the flare node (210) for supplying air alternately from the outside of the intake-type flame and from the rear in the flame traveling direction, incomplete combustion due to shortage of combustion air can be prevented. That is, the flame passage (210) is provided with holes (202) that are sucked by the rising airflow on the circumference of the side surface of the jump box (210), and complete combustion is achieved by sucking in air from the outside. It can be in a close state.
- the side surface is provided with holes (202) in the axial direction every 90 degrees and a plurality of holes (202) are formed so as to form a staggered row so that intake air does not interfere.
- a cover (2) is provided around the flame extinguishing node (210) and surrounds it. Therefore, the flow is smooth, and the air is efficiently sucked into the flame extinguishing node (210).
- Venomitis (2 The airflow from 10) rises and enters the combustion promoting section (40). Part of the air drawn from the air inlet (201) is sucked into the airflow through the hole (205) of the top plate (400), and fresh oxygen is supplied to the airflow in the flame tube (210). The air flow is sucked into the hole of the partition plate (401) on the hole (205) as it is, and the direction of the airflow is changed by 90 ° to the discharge port (405). In short, sufficient combustion time can be gained by meandering.
- the partition plate (401) When the partition plate (401) is provided in the flame extinguishing node (210), the increased air flow, which can further increase the combustion efficiency, is bent 90 ° by the partition plate (401) and flows, and the flame progresses.
- the combustion temperature is raised by controlling and retaining.
- the hole (205) of the top plate (400) and the hole (402) of the partition plate (401) do not coincide with each other.
- the secondary combustion chamber is equipped with a mechanism for complete combustion.
- thermoelectric power generation that generates power without reducing the thermal energy by the same heat source and power generation that rotates the steam coubin using thermal energy can be performed simultaneously. Is possible.
- FIG. 5 shows a vertically long cylindrical combustion furnace (501) made of a non-combustible material, and a combustion furnace (502) is provided on the upper part thereof.
- the combustion furnace (501) is provided with small holes (510), which are provided vertically and circumferentially and arranged in a staggered row.
- two holes are provided so as to face each other, and in the vertical direction, two small holes facing each other in the 180 degree direction are provided. Has been placed. Therefore, as shown in FIG. 5, as shown in the side view, they are staggered. These small holes are for sucking outside air, and the reason why they are arranged in a staggered manner is that it is preferable for creating a swirling flow.
- a combustion furnace (502) is continuously arranged in a vertically long cylindrical combustion furnace (501) in which a plurality of small holes (506) are arranged in a staggered row on the side peripheral surface.
- the combustion furnace (502) has a cylindrical shape with a wide inner diameter of the combustion furnace (501), and includes a partition plate (520) provided with a plurality of small holes in the vertical direction. (501) is in communication.
- the opening (540) of the combustion furnace (501) and the opening of the combustion furnace (502) are connected, and as shown in (1) of FIG. 5, the flame bends in the horizontal direction as it rises. Then, it detours through the opening (802) opened at the end of the partition plate (520), changes again in the direction of 180 degrees, flows in the horizontal direction, and goes to the opening (505) of the combustion furnace (501).
- the partition plate (3) may be provided with a slit on the side surface of the combustion furnace (2) so that the partition plate (3) can be removed or inserted as required.
- a small hole (801) is also provided in the bottom plate (530) in the combustion furnace (502).
- the position is preferably a position where external air can be supplied, but the opening (802) through which the flame rises may be sucked.
- a combustion furnace (503) is provided above (1) in FIG. 5 of the combustion furnace (501).
- An opening (801) is provided at the end of the bottom (530), and sucks outside air.
- the connection between the combustion furnace (501) and the combustion furnace (502) (503) can be performed by welding, and as shown in FIG. 5 (501), a joint (540) (541) is provided by insertion. It can be fixed easily.
- the combustion furnace is configured such that the combustion furnace (501) and the combustion furnace (502) are alternately overlapped or combined with the combustion furnace (503). That is, it is a cross-sectional view showing the structure of a combustion apparatus having an exhaust port (505) at the top and a flame port (504) at the bottom, in which the combustion furnace (501) and the combustion furnace (502) are alternately stacked.
- the small holes (510) are utilized by utilizing the negative pressure generated by the updraft against the flame that is ignited by various combustion devices and rises with the combustion gas through the flame opening (505).
- ) (520) or the like is supplied spirally from the outside of the flame, and in the combustion furnace (502), the inner diameter of the combustion furnace (501) is larger than that of the combustion furnace (501).
- the air taken in from the small holes (510) arranged at equal intervals on the outermost outermost surface of the bottom surface of (502) and the entire length of the outer periphery is supplied from below to increase the combustion efficiency.
- the small hole (601) is inclined upward and opened.
- the small hole (602) is provided so as to be inclined downward in the opposite direction. In this hot spring, eddy currents are produced and the effect is brought about.
- the openings (701), (702), and (801) can be inclined.
- the combustion furnaces (502) and (503) can also be provided so as to be inclined in the direction of assisting the spiral flow.
- providing a spiral staircase around the combustion furnace (501) as a means for forming a spiral in order to promote a spiral flow can further help to form a spiral flow. As shown in FIGS. 6 (1) and (2), it is effective to form a spiral flow by providing a cover (507) around the combustion furnace (501).
- the small holes (510) are arranged in a staggered manner in this case, so that a spiral flow occurs, and the combustion efficiency is determined by the mixing.
- the air taken in from the intake port generates airflow between the inner wall of the combustion furnace (501) and the flame and between the outer wall of the combustion furnace (501) and the cover (507), thereby cooling the furnace. Increase the durability of the furnace.
- an air flow is generated in the apparatus by providing a cover provided with a plurality of intake ports (1201) on the side surface of the cylindrical body of the combustion furnace (501) that covers the outside so as to form a space by the cover (507).
- a cover provided with a plurality of intake ports (1201) on the side surface of the cylindrical body of the combustion furnace (501) that covers the outside so as to form a space by the cover (507).
- outside air is drawn from the intake port (1201). Due to the rising flame and combustion gas, a negative pressure is generated and sucked, and enters the combustion furnace (501) through the small hole (510). In this case, a spiral flow is formed by the arrangement of staggered small holes.
- a plurality of suction ports (1201) can be provided depending on the size of the combustion furnace (501), and a blower or the like can be connected to the suction port (1201).
- a spiral staircase is provided along the small hole (510) so as to guide the upper opening of the small hole.
- this spiral staircase is easily sucked downward, it is also effective to make the width of the staircase narrower toward the lower side and wider toward the upper side.
- the partition plate (520) is made of a material that is overheated by a rising flame and is red-hot to prevent a decrease in combustion temperature, and by providing a plurality of openings (701) outside the partition plate (520). While the flame rising in the center of the furnace is retained, combustion is promoted when the combustion gas passes through the small hole (701) having a high temperature.
- the shape of the combustion furnace (501) is not limited as long as it has a function of generating a spiral air flow so as to supply air from the outside of the flame using the negative pressure generated in the furnace. However, if the rejection is circular, it will be understood that a spiral flow is easily formed.
- the combustion furnace (502) is not limited to a circular shape, a square shape, a polygonal shape, or the like as long as it has a function of supplying air from below to the combustion gas rotating around the flame inside the furnace.
- the small holes can be provided with a shape, number, size, arrangement, etc. as necessary so as to be suitable for combustion.
- the naturally aspirated combustion apparatus of the present invention is not limited to the above embodiment, and various modifications can be made by those skilled in the art within the scope of the technical idea of the present invention.
- the shape, material, scale, arrangement, etc. of the combustion furnace, divider exhaust port, flame opening, small hole are design problems, and the technical idea of the present invention is also in other shapes, materials, scales, arrangement. It does not deviate within the range.
- thermoelectric generator having a cylindrical combustion chamber (601) having a part of a side surface formed by a thermoelectric generator module having an output terminal (601k) is configured.
- the air injection pipe (601e) is provided so as to follow the flame traveling direction.
- a wind direction plate (601f) is provided along the air injection pipe (601e) in the vicinity of the hole (601g) of the air injection pipe (601e) in order to rotate the air flow in the axial direction.
- a red hot plate (601i) having a plurality of holes (601j) was provided in the combustion chamber.
- Steam is generated by using a pipe-shaped inlet (601a) that also serves as an ignition port provided with an airflow injection nozzle (601b) for generating an induced airflow for taking fuel into the combustion chamber and exhaust heat of the combustion chamber.
- a flame exhaust cylinder (601d) communicating with the secondary combustion (603) through a boiler (604) for generating
- a cylindrical cover (602b) having an air supply port (602c) on the outside is provided.
- the boiler (604) communicates with the steam turbine power generator (605) by the steam pipe (604a), and the steam turbine (605) has a waste steam cylinder (606a) by the steam pipe (605a). And the heat exchanger (606) communicates with the duct (606b).
- the air flow nozzle (601b) communicates with the duct (608l), the conveying device (607a) communicates with the cutting machine (607), the heat exchanger (606) and the blower (608m) communicates with the duct (606b), and the discharge
- the circulation duct (608k) provided with an airflow injection nozzle (608i) so as to generate an induced airflow outside the airflow on the lower inner wall and the bent inner wall near the joint portion between the pipe (608h) and the circulation duct (608k).
- a drying tank (608) provided with a cyclone (608) communicating with the transfer device (607a), and an air jet pipe provided with a plurality of holes (608f) in the vicinity of the tank connected to the motor (608a) (608e) and a rotary outer shaft (608c) in which a plate (608g) is obliquely installed so as to cover the hole (608f) from above the hole (608f) of the air injection pipe (608e)
- an air flow drying device provided with a rotating central shaft (608d) having a blower blade (608b), and a path between the expansion valve (609d) and the heat absorption part (609b) of the heat pump (608) outside the combustion chamber (601).
- An air injection pipe (608e) provided with a plurality of holes (608f) in the vicinity of the tank that cuts solid fuel with a cutting machine (607) and is connected to a motor (608a) via a transfer device (607a),
- a rotary shaft (608) having a rotating outer shaft (608c) in which a plate (608g) is obliquely provided so as to cover the hole (608f) from above the hole (608f) of the air injection pipe (608e) ( 608d) is introduced into the airflow drying device, and the airflow is induced to the outside of the airflow on the lower inner wall and the inner wall of the bent portion in the vicinity of the junction between the drying tank (608), the discharge pipe (608h) and the circulation duct (608k).
- a heat exchanger (600) and a duct (606b) Therefore, it is possible to efficiently increase the area and area of contact with the dry air blown from the continuous blower (608m), and to efficiently dry the dried solid fuel through the duct (608l) by the air flow of the drying tank (608). It is transferred to a pipe-shaped inlet (601a) that also serves as an ignition port equipped with an airflow injection nozzle (601b) for generating an induced airflow to be introduced into the combustion chamber, and is injected into the combustion chamber from the inlet.
- thermoelectric power generation module (601c) In the combustion chamber (601), heat generated by burning the fuel is used to generate power in the thermoelectric power generation module (601c) due to a temperature difference between the inside and outside of the combustion chamber, and in a waste heat boiler (604) due to combustion.
- the steam generates power at the same time without substantially reducing thermal energy by power generation in the steam turbine power generation device (605). Further, the efficiency of thermoelectric power generation is improved by providing a path between the expansion valve (609d) and the heat absorption part (609b) of the heat pump (609) outside the combustion chamber (601).
- the heat of the steam discharged from the steam turbine (605) is taken into the airflow drying device by a heat exchanger and a blower to increase the drying efficiency.
- Combustion air is warmed by adjoining the heat dissipating part (609a) of the heat pump to the blower, thereby increasing the combustion efficiency.
- the combustion apparatus (800) of FIG. 9 is an embodiment in the case of combining forced air supply and natural intake as an intake method in the combustion chamber.
- a combustion dish (802) raised with a foot is disposed in the combustion chamber (801), and oil is supplied to the combustion dish through an oil supply pipe (803).
- a blower opening (804) is installed at the bottom of the combustion chamber (801), and air or the like is blown from below to the bottom side of the combustion dish (802).
- the air blow (800a) becomes a straight air flow that travels upward along the inner peripheral surface of the combustion chamber (801), and is supplied from the outside of the flame of the combustion dish (802). I can mind. Further, natural intake (800b) from the periphery is performed from the natural intake port (805) above the combustion chamber (801), and contributes to the supply of air from the outside of the flame in the same manner as the straight air flow.
- the straight air flow along the inner peripheral surface of the combustion chamber (801) extends the fire bed in the flame traveling direction and allows continuous air supply. The same effect is produced.
- the combustion apparatus (810) of FIG. 10 is also an embodiment in the case of combining forced air supply and natural intake as an intake method in the combustion chamber.
- a combustion dish (812) is disposed at the bottom of the combustion chamber (811), and an air blowing port (813) is provided at the lower end of the side surface of the combustion chamber (801), so that the inner periphery of the combustion chamber (801) is provided. Blow along the surface.
- a swirling airflow (810a) is generated in which air rotates between the combustion dish (812) and the combustion chamber (811), and air can be supplied from outside the flame of the combustion dish (812).
- natural intake (810b) from the periphery is performed from the natural intake port (814) above the combustion chamber (811), and contributes to the supply from the outside of the flame in the same manner as the rotating airflow.
- the present invention can achieve the same effects as described above.
- the combustion apparatus (820) of FIG. 11 is also an embodiment in the case of combining forced air supply and natural intake as an intake method in the combustion chamber.
- An air blowing port (822) is installed in the middle of the side surface of the combustion chamber (821), and the air flow is circulated in the air blowing port to generate a straight air flow (820a) with a stable air volume and direction of the inner circumferential surface of the combustion chamber (821). To blow along.
- natural intake (820b) from the periphery is performed from the lower and upper natural intake ports (823) and (824) of the combustion chamber (821), and contributes to the supply of air from the outside of the flame in the same manner as the rotating airflow. To do.
- the present invention can achieve the same effects as described above.
- the combustion apparatus and the drying apparatus can be used in combination, but various known systems can be used for the drying apparatus.
- a nozzle is arranged downstream of the air blowing from the blower, and the heat or hot air generated by the combustion device is taken into the duct.
- a nozzle is arranged at the subsequent stage to introduce the material to be dried.
- a rotary kiln-type drying device that heats while rotating the kiln may be used.
- the material to be dried is blown up and circulated from the lower part to the upper part of the kiln by the air blow in the duct. Remove the dried product by vacuuming it up.
- a fixed amount is supplied by using a function of mixing and moving by providing a rotating shaft and rotating blades in a cylindrical drying tank. And drying is promoted by the heating from a bottom face and a side face.
- an airflow in a specific direction is generated in the combustion chamber, and the negative pressure at the inlet is relatively weakened.
- FIG. 12 shows a side view (a) and a plan view (b) of a combustion apparatus (1210) for injecting combustibles from the top (planar side) of the combustion chamber, and a side view (c) of another embodiment.
- the tip nozzle (1212a) of the air injection pipe (1212) is disposed in the vicinity of the lower side surface of the combustion chamber (1211), and an exhaust port (1213) is provided on the upper side surface to supply air or the like from the outside of the flame.
- the air from the air injection pipe constitutes an air flow (1214) that rotates around the inner periphery of the combustion chamber (1211).
- the flame in the combustion chamber is always drawn to the exhaust port side by the rotating airflow from the tip of the air injection pipe to the exhaust port. Therefore, the combustion object is introduced by opening the input port (1215). However, there is no risk of flames spouting from the inlet side, and it is possible to safely input the combustible material containing solid content at any time.
- the combustible material input from the input port (1215) falls directly toward the flame from each discharge port (1216).
- a large-diameter portion (1217) is formed in the upper portion of the combustion chamber, and the swirling airflow (1214) from the tip of the air injection pipe (1212a) In the large-diameter portion (1217), the outer periphery is further rotated, so that the flame is also attracted to the outer periphery.
- FIG. 13 shows a side view (a) and a plan view (b) of a combustion apparatus (1300) for charging a combustible from the side of the combustion chamber.
- a tip nozzle (1302a) of the air injection pipe (1302) is disposed near the lower side surface of the combustion chamber (1301), and an exhaust port (1303) is provided on the upper top surface to supply air and the like from the outside of the flame.
- the air from the air injection pipe forms an air flow (1304) reaching the top surface after rotating around the inner periphery of the combustion chamber (1301).
- a charging port (1305) for charging the combustible material is installed in the middle of the outer peripheral side surface of the combustion chamber (1301). As shown in the plan view (b), since the discharge port (1306) is directed along the air flow from the air injection pipe (1302), the flame is not ejected from the input port (1305), which is safe. Can be charged. Further, by providing a wind direction plate (1307) that extends the discharge port (1306) along the air flow, the flame is not attracted to the input port.
- FIG. 14 shows another embodiment of the combustion apparatus (1400) for injecting combustibles from the side.
- the tip nozzle (1402a) of the air injection pipe (1402) is arranged near the lower side surface of the combustion chamber (1401), and the exhaust port (1403) is provided on the upper top surface, from the outside of the flame. Supply air.
- the air from the air injection pipe forms an air flow (1404) reaching the top surface after rotating around the inner circumference of the combustion chamber (1401).
- an inlet (1405) for injecting combustibles is installed in the middle of the outer peripheral side surface of the combustion chamber (1401), and an air injection nozzle (1407) is provided in the same opening. According to this configuration, the flame is not sucked into the discharge port (1406) by the swirling airflow from the air jet pipe and the wind pressure from the air jet nozzle (1407), and safe injection can be performed.
- FIG. 14B shows a combustion apparatus (1400 ') according to another embodiment, in which the input port (1405') is directed to the upper surface side. Similarly, in this configuration, the flame is not sucked into the discharge port (1406 ') by the wind pressure from the air injection nozzle (1407), and safe injection can be performed.
- FIG. 15 shows a configuration in which a secondary combustion device (1503) is attached to the combustion device (1500).
- the secondary combustion apparatus has the same configuration as that disclosed in FIG. Since the side surface of the combustion chamber (1501) is provided with a row of a large number of holes (1502), a spiral gas flow is generated in the furnace and the contact efficiency between the combustion gas and the air rising outside with the flame is increased. And the radius of convolution becomes larger at the upper large diameter portion (1501a).
- a combustible material can be safely fed into the large-diameter portion (1501a) from the top inlet (1504). That is, in this device, since it is strongly sucked toward the secondary combustion device, the injected combustibles are not injected from the input port (4), and the injected combustibles are in the combustion chamber (1501) and the secondary combustion device (1503). It is completely burned in the combustion furnace.
- An oil supply pipe (1505) for supplying fuel is provided at the lower end of the combustion chamber (1501).
- FIG. 16 shows another embodiment in which a secondary combustion device (1603) is attached to the combustion device (1600).
- the side surface of the combustion chamber (1601) is provided with a row of many holes (1602), so that a spiral air flow is generated in the furnace, and the combustion gas rising outside with the flames.
- the contact efficiency of air is increased, and the radius of convolution is increased in the upper large diameter portion (1601a).
- the secondary combustion device (1603) may be directly attached to the top surface of the large diameter portion (1601a). Since the airflow rotates around the outer periphery of the large diameter portion (1601a), the combustible can be safely input from the top surface inlet (1604).
- An oil supply pipe (1605) for supplying fuel is provided at the lower end of the combustion chamber (1601).
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Abstract
Description
回転装置で得られる燃焼エネルギーを利用し、特許第4457215号で開示されているような高温耐久性のある熱電発電モジュールによって燃焼室の一部又は全部を形成する発電装置が可能となり、同一の熱源を利用する熱エネルギーを減じることなく熱電発電と熱エネルギーを利用する発電を同時にすることで、エネルギー効率の良い発電が可能となる。
又、特許第3066066号では、炉内に燃焼促進板を設けることで、炉内の空気を高温で長く滞留させることによって、燃焼を促進する特徴を特つ燃焼装置が提案され、特許第3318748号では、送風機によって空気を回転させて供給することで、回転燃焼を生じさせて、炉内外周で二次燃焼をさせる特徴を特つ石油製品回転燃焼ストーブが提案されている。
(1)固形物を燃料とする、炎の外側から空気を供給する燃焼方法は、未だ提案されていない。
(2)炎の外側から空気を供給する燃焼方法において、固形物の連続的な投入の方法は提案されていない。
(3)炎の外側から空気を供給する燃焼方法において、燃焼温度の低い場合の排炎を浄化する方法は提案されていない。
(4)雑多な固形燃料を使用するために、空気不足による不完全燃焼を防止する方法が提案されていない。
(5)燃焼室の一部又は全部を熱電発電モジュールにより形成し、熱エネルギーを減じることなく燃焼室内外の温度差で発電する方法は提案されていない。
(6)同一の熱源を利川して熱エネルギーを減じることなく発電する熱電発電と熱エネルギーを利用する発電等の複合した発常方法は提案されていない。
燃焼に伴う上昇気流によって生じる負圧を利用して、小孔から取り入れられる空気を側の下方より継続的に自然に供給することによって空気不足による不完全燃焼を解消する。
図1には、本発明の燃焼装置における燃焼部(10)、二次燃焼室(20)、送風装置(110)、廃油タンク部(30)等が示される。
固形物等の被燃焼物の投入口(13)があって、隣接して空気噴射ノズル部(111)が設けられ、燃焼室(15)内へ被燃焼物を誘引する役割を果たす。
なお、本発明では空気に代えて任意の助燃性気体を用いることもできるが、以下の実施例では空気を例として用いる。
即ち、炎の進行方向に鉛って側面に孔を具えた空気噴射ノズル部(111)を設け、炎の外側を廻旋する空気によって炎の外側から炎に対し進行方向に沿って継続的に空気を供給する。
この為に、炎に沿って空気を噴射し、ごみ等の固形物が投入されるので、炎の妨害にはならず、従って、連続投入を可能とするのである。
又、燃焼室(15)の断面形状は、図4に示されるように円形状が流れ上好ましいのが理解される。
そして、投入口を燃焼室に連通するよう筒状に形成し、内部に燃焼室までの誘引気流
を生じる空気噴射ノズル(111)を設けることにより固形物の連続投入を可能にする。
点火バーナをそこに常置してもよく、又固形物に点火後投入口(13)へ投げ入れて燃焼させても構わない。
傾斜して投入口(13)と空気噴射ノズル(111)が並行して設けられているので、ごみの固形物の投入がスムーズに行くようになっていると共に、又図1の(2)に示されるように、燃焼室(15)に対し旋回流が生成されるように接線方向に配置されると一層形成されるのがわかり、この旋回流によって固形物は、又連続して投入できることができるのである。
その為に、風向板(140)が、例えば適宜数旋回を起こすように、燃焼室(15)内へ吹き出し口(130)に対し傾斜して設けられる。投入口(13)から入った空気の吹き出し口の孔(130)の部屋は四角に囲まれているが、図4に示されるように、円管であっても構わない。
図2の(2)に示される実施例では、風向板(140)は、燃焼室(15)内の角部に設けられているのが分かる。図2の(2)に示されるように、投入口(13)から入った流れは、孔(130)から排出されるが、その排出方向に対して、風向板(140)がその投入方向に対して傾斜しており、これによって、燃焼ガスは偏向されて旋回成分が与えられ、燃焼室(15)の中心に向かって旋回気流が起きるのである。
勿論、該燃料噴射ノズルは、投入口(13)に設けることもでき、その場合、固形物の外側から炎を噴射することになる。
その他は、予め気流乾燥装置により乾燥させておくこともよいであろう。
又4隅には、開口(122)があって、旋回流の上昇口となっている。旋回流形成の為にしかし必ず4ケ所でなくてもよいが、対称性からいえば4ケ所が製作上は好ましい。
なお、図2の(3)に示されるように、角は斜めに切って吹き出しを設けることもできる。この場合は、製作がより容易となる。
このことで、仕切版(12)は、暖められておかれるので、気流に対して、燃焼温度を低下させない効果がもたらされる。特に、赤熱する素材とすることで一層の効果が得られる。仕切板(12)に沿った流れは、角部か隅部に設けられた開口(122)より、上昇することになり、その間充分な燃焼時間が与えられる。
従って、これら小孔(121)は、気流が生成される方向に傾斜して穿つられると一層その生成に寄与することになる。
この例では、仕切板(12)は、互い違いとなっている。空気噴射管(160)が燃焼室(15)内へ通っており、空気に噴射口(161)が、複数管に沿って軸方向に設けられるので、燃焼用空気が充分に供給される。勿論、噴射管の方向は、円周方向に旋回流を形成し易いように設けられ、その先には風向板(140)が設けられているので、旋回はより容易となるのが理解されるであろう。空気噴射管(16)は、外部より送風機から、供給されることもできる。
外部には廃油タンク(30)も設けて、給油管(301)を通して供給することができる。
回転燃焼装置に熱エネルギーを利用する発電装置を具えることにより、同一熱源によって熱エネルギーを減じることなく発電する熱電発電と熱エネルギーを併用する発電を同時に行う事を可能する。
即ち、排炎節(210)には、上昇気流によって、吸引される孔(202)が跳箱(210)の側面の円周上に設けられており、外部からの空気を吸い込むことで完全燃焼に近い状態とすることができる。側面には、例えば、90度ずつに軸方向に孔(202)を設け、互いに千鳥の列をなすように複数の孔(202)を設けると吸気が干渉せず好ましい。
1 0)からの気流は上昇し、燃焼促進部(40)へ入る。
吸気口(201)から吸い込まれた一部は、天板(400)の孔(205)を通って、気流へ吸気を行い、排炎筒(210)内の気流に新鮮な酸素を供給する。気流はそのまま、該孔(205)上の仕切版(401)の孔へ吸い込まれて、又90°方向を変じて、排出口(405)へ向かう。
要するに、蛇行させることで、充分な燃焼時間を稼ぐことができる。
このように二次燃焼室は、完全な燃焼を行う機構が備わっているのが分かる。
上記の燃焼装置に加えて、二次燃焼装置として、次のような燃焼炉を用いることもできる。
図5に示されるように、燃焼室(15)上に、本発明の燃焼炉(501)~(503)が配置される。 図5は、不燃性の素材によって作られた、垂直に長い円筒状の燃焼炉(501)を設け、且つその上部には、燃焼炉(502)が設けられる。燃焼炉(501)には、小孔(510)が設けられており、垂直方向にそして円周方向に設けられ且つ互いに千鳥状の列をなすように配置される。
従って、図5に示されるように、その側面で判るように、互い違いになるようになっている。
これら小孔は、外気を吸引する為のものであり、千鳥状に配置したのは、旋回流を興すのに好ましいからである。
燃焼炉(502)は、前記燃焼炉(501)の内径が広い円筒状であって、内部には、垂直方向に複数の小孔を設けた仕切盤(520)を備えており、前記燃焼炉(501)とが連通している。
この仕切盤(3)は、必要に応じて、取り外し又は挿入できるように、燃焼炉(2)の側面にスリットを設けておき、出し入れができるようにすることも可能である。
燃焼炉(501)と燃焼炉(502)(503)との結合は、溶接でも可であり、又図5の(501)に示されるように、挿入によって、継ぎ手(540)(541)を設ければ簡単に固定することもできる。
即ち、燃焼炉(501)と燃焼炉(502)を交互に重ね合わせた、上部に排気口(505)と下部に通炎口(504)を備えた燃焼装置の構造を表す断面図である。
図1の(501)の下方に示されるように、小孔(601)は上方に傾斜して開けられている。これに対して、小孔(602)では、逆方向に下方向に傾斜して設けられている。この湯合には、渦流が起こり攬件効果がもたらされる。
同様に、燃焼炉(502)(503)でも、開口(701)(702)(801)も傾斜して設けることが可能である。図5の(2)の、燃焼炉(501)のA-A、B-B断面で示されるように、螺旋流の助勢が出来るよう傾斜している。勿論、燃焼炉(502)(503)でも螺旋流の助勢の方向に傾斜して設けることができる。
図6の(1)(2)に示されように、燃焼炉(501)の周囲にカバー(507)を設けることが螺旋流を形成する上で、有効である。
更に、回廊(570)の旅路にそって、絞り(1203)を設ければ、特に、小孔近くへ設置すれば、一層小孔(510)への流入を容易とする事が出来る。
又、この螺旋階段は、下方程吸い込まれ易いので、下方程階段の幅を狭くして、上方に行くに従い、広くすることも有効であろう。
熱電発電するための電気的絶縁性の素材で形成した容体の内側の対向面上に夫々連続的に形成されて両端に生ずる温度差で発電を行う複数個の熱伝変換素子(601c)と電気出力端子(601k)を備えた熱電発電モジュールによって側面の一部を形成した筒状の燃焼室(601)を有する熱電発電装置を構成する。
該燃焼室(601)内に気流を生成するために、該燃焼室(601)の内側面にブロワ(601m)とダクト(601l)によって連通した複数の孔(601g)を側面に具えた筒状の空気噴射管(601e)を炎の進行方向に沿うように設ける。
また、燃焼温度の低下を防ぐために、該燃焼室内部に複数の孔(601j)を具えた赤熱盤(601i)を設けた。燃料を該燃焼室内に取り入れるための誘引気流を生じさせるための気流噴射ノズル(601b)を備えた点火口を兼ねたパイプ状の投入口(601a)と前記燃焼室の排熱を利用して蒸気を生成するボイラ(604)を通して二次燃焼(603)に連通する排炎筒(601d)を備える。
また、該燃焼室(601)の外側にヒートポンプ(609)の膨張弁(609d)と吸熱部(609b)との経路を設けて熱電発電の効率を高める。
図9の燃焼装置(800)は、燃焼室における吸気方法として、強制給気と自然吸気を組み合わせる場合の実施例である。
燃焼室(801)内に足で底上げした燃焼皿(802)を配設し、燃焼皿には給油管(803)を通して給油する。燃焼室(801)の底部には、送風口(804)を設置して、燃焼皿(802)の底面側に下から空気等を送風する。
また、燃焼室(801)上方の自然吸気口(805)からは、周辺からの自然吸気(800b)が行われて、直進気流と同様に炎の外側からの給気に寄与する。
燃焼室(811)の底部には燃焼皿(812)を配設すると共に、燃焼室(801)の側面下端部には、送風口(813)を設置して、燃焼室(801)の内周面に沿うように送風する。
また、燃焼室(811)上方の自然吸気口(814)からは、周辺からの自然吸気(810b)が行われて、回旋気流と同様に炎の外側からの給気に寄与する。本発明も上記と同様の効果を得られる。
燃焼室(821)の側面中途部には、送風口(822)を設置し、送風口内で気流を回り込ませることにより安定した風量風向の直進気流(820a)を燃焼室(821)の内周面に沿うように送風する。
また、燃焼室(821)下方及び上方の自然吸気口(823)(824)からは、周辺からの自然吸気(820b)が行われて、回旋気流と同様に炎の外側からの給気に寄与する。本発明も上記と同様の効果を得られる。
例えば、サイクロンの下部から上部に被乾燥物をダクト内の送風で吹き上げて循環させる方法では、ブロワからの送風の下流にノズルを配置し、燃焼装置で発生した熱や熱風等をダクト内に取り込む。さらにその後段にノズルを配置して被乾燥物を導入する。これにより、燃焼装置で発生した温風や熱風を効率的に利用することができ、また、ブロワの後段で、ノズルを用いることによりモータの加熱も避けることが出来る。
燃焼室(1211)の下部側面近傍に空気噴射管(1212)の先端ノズル(1212a)を配置すると共に、上部側面に排気口(1213)を設け、炎の外側から空気等を供給する。このとき、空気噴射管からの空気は燃焼室(1211)内周を回旋する気流(1214)を構成する。
投入口(1215)から投入した被燃焼物は、各吐出口(1216)から炎に向けて直接落下する。
燃焼室(1301)の下部側面近傍に空気噴射管(1302)の先端ノズル(1302a)を配置すると共に、上部天面に排気口(1303)を設け、炎の外側から空気等を供給する。このとき、空気噴射管からの空気は燃焼室(1301)内周を回旋した後、天面に至る気流(1304)を構成する。
さらに、吐出口(1306)を気流に沿って延長する風向板(1307)を設けることで、火炎が投入口に誘引されないように構成している。
図14(a)において、燃焼室(1401)の下部側面近傍に空気噴射管(1402)の先端ノズル(1402a)を配置すると共に、上部天面に排気口(1403)を設け、炎の外側から空気等を供給する。このとき、空気噴射管からの空気は燃焼室(1401)内周を回旋した後、天面に至る気流(1404)を構成する。
本構成によれば、空気噴射管からの回旋気流と、空気噴射ノズル(1407)からの風圧により炎が吐出口(1406)に吸い込まれることはなく、安全な投入を行うことができる。
燃焼室(1501)の下端部には燃料を供給する給油管(1505)が設けられている。
燃焼室(1601)の下端部には燃料を供給する給油管(1605)が設けられている。
601a 投入口
601b 気流噴射ノズル
601c 熱電変換素子
601d 排煙筒
601e 空気噴射管
601f 風向板
601g 孔
601i 赤熱盤
601j 孔
601k 電気出力端子
601l ダクト
601m ブロワ
602 二次燃焼室
602a 孔
602b カバー
602c 給気口
603 広径な二次燃焼室
603a 赤熱盤
603b 孔
603c 排気管
604 ボイラ
604a 蒸気管
605 蒸気タービン発電装置
605a 蒸気管
606 熱交換機
606a 廃蒸気管
606b ダクト
607 裁断機
607a 搬送装置
608 気流乾燥装置
608a モーター
608b 送風羽根
608c 回転外軸
608d 回転中軸
608e 空気噴射管
608f 孔
608g プレート
608h 排出管
608i 気流噴射ノズル
608j サイクロン
608k 循環用ダクト
608l ダクト
608m ブロワ
609 ヒートポンプ
609a 放熱部
609b 吸熱部
609c 圧縮機
609d 膨張弁
Claims (28)
- 燃焼装置内で被燃焼物を燃焼する燃焼方法であって、
燃焼装置の燃焼室に該被燃焼物を投入する行程と、
該被燃焼物に点火して燃焼させる行程と、
該被燃焼物の燃焼に伴う炎に対し、炎の外側から空気又は助燃性気体(以下、空気等と呼ぶ)を供給する行程と、
該空気等により、被燃焼物を二次燃焼する行程と、
排煙する行程を有する
ことを特徴とする燃焼方法。 - 前記燃焼方法における前記被燃焼物の燃焼中に、
少なくとも固形分を含む該被燃焼物を前記燃焼室に追加投入する工程を有する
請求項1に記載の燃焼方法。 - 前記燃焼方法における被燃焼物を追加投入する工程において、
前記燃焼室に誘引気流を生じる
請求項2に記載の燃焼方法。 - 前記誘引気流が燃焼室内で回旋するように構成され、排煙する工程では気流の進行方向にサイクロン状に設けた排煙手段から排煙されるようにした
請求項3に記載の燃焼方法。 - 前記被燃焼物を二次燃焼する工程において、
炎の進行方向の後方から炎に対し空気等を供給する工程を有する
請求項1ないし4のいずれかに記載の燃焼方法。 - 前記燃焼方法において、
前記炎に対し空気等を外側から供給する行程と、炎に対して空気等を炎の進行方向の後方から供給する行程とを交互に繰り返す
請求項5のいずれかに記載の燃焼方法。 - 前記燃焼方法において、
進行してくる炎に対し通炎手段を有する仕切によって炎の進行を制御する
請求項1ないし6のいずれかに記載の燃焼方法。 - 前記燃焼方法において、少なくとも固形分を含む前記被燃焼物を燃焼前に乾燥する構成であって、
該被燃焼物を堆積場所に移送する行程と、
堆積した該被燃焼物を堆積場所の下部から堆積場所の上部へ移送する行程と、
堆積場所と該移送の過程とで被燃焼物を乾燥する工程、
乾燥した該被燃焼物を回収して燃焼室に移送する工程、
を有する請求項1ないし7のいずれかに記載の燃焼方法。 - 前記堆積場所の下部から上部へ移送する行程において、前記被燃焼物を空気等とともに吹き上げる構成であって、その吹き上げる気流の外側に誘引気流を生じるようにした
請求項8に記載の燃焼方法。 - 前記乾燥した前記被燃焼物を回収して燃焼室に移送する行程において、排気とともに回収し、その排気を燃焼装置に燃焼用空気として供給する
請求項8又は9に記載の燃焼方法。 - 請求項1ないし9のいずれかに記載の燃焼方法を用い、
前記燃焼装置を熱電発電モジュールで一部又は全部を形成することにより、燃焼行程において生じる該燃焼装置の内外の温度差を利用する発電方法。 - 被燃焼物を燃焼する燃焼装置において、
燃焼室を筒状に形成し、該燃焼室の内側面に給気口を備え、側面に孔を設けた筒状の空気噴射管を炎の進行方向に沿うように設けた
ことを特徴とする燃焼装置。 - 前記燃焼室内部に通炎手段を設けた仕切を備えた
請求項12に記載の燃焼装置。 - 前記燃焼室の側面に被燃焼物投入口をパイプで構成し、該パイプの内壁に誘引気流を生じるように気流噴射ノズルを設けた
請求項12又は13に記載の燃焼装置。 - 前記燃焼室に排煙手段を設け、該排煙手段を、廻旋する気流の進行方向にサイクロン状に設けた
請求項12ないし14のいずれかに記載の燃焼装置。 - 前記燃焼室に連なる炎の取り入れ手段を有する側面に孔を設けた筒状体の二次燃焼室を備えた
請求項12ないし15のいずれかに記載の燃焼装置。 - 前記二次燃焼室と、該二次燃焼室と連通している炎の進行方向の後方から空気又は助燃性気体(以下、空気等と呼ぶ)を取り入れる手段を設けた
請求項16に記載の燃焼装置。 - 前記二次燃焼室において、径の異なる少なくとも2種類の二次燃焼室を備えた
請求項16又は17に記載の燃焼装置。 - 前記二次燃焼室に、空気を取り入れる手段を有する空間を形成するよう外側にかぶせた筒状体のカバーを備えた
請求項16ないし19のいずれかに記載の燃焼装置。 - 被乾燥物取入口と循環用取入口と被乾燥物排出口と乾燥物排出口を有する堆積槽と、該被乾燥物排出口から循環用取入口に循環移送する手段を備える乾燥装置の該乾燥物排出口を前記燃焼装置の被燃焼物取入口とを接続した
請求項16ないし19のいずれかに記載の燃焼装置。 - 前記乾燥装置の乾燥槽に回転軸を設け、該回転軸の該乾燥槽近傍に攪拌を助長する孔を備えた噴射管を設け、該噴射管の該孔の上方から該孔を覆うようにプレートを斜設し、該噴射管には、圧力空気等を供給する手段を設けた
請求項20に記載の燃焼装置。 - 前記圧力空気を供給する手段は、回転軸によって駆動される送風羽根を設け、該羽根によって昇圧された空気等を前記噴射管へ供給することを特徴とする
請求項21に記載の燃焼装置。 - 前記回転軸は、外軸と中軸とに分かれ、外軸に攪拌羽根、噴射管及びプレートを設け、中軸には送風羽根を設けることを特徴とする
請求項22に記載の燃焼装置。 - 前記乾燥装置において、前記被乾燥物排出口と前記循環用取入口とを、送風手段を具えた循環用ダクトによって連通した構成であって、
該循環用ダクトにおいて、該循環用ダクトの取込口下部内壁及び曲折部内壁に、気流の外側に誘引気流を生じるように圧縮空気の供給手段を備えた気流噴射ノズルを設けた
請求項20ないし23のいずれかに記載の燃焼装置。 - 前記燃焼室外側にヒートポンプの膨張弁から吸熱部までの経路を設け、ヒートポンプの排熱をブロワによって該燃焼室の空気等の前記噴射管に供給する
請求項21ないし24のいずれかに記載の燃焼装置。 - 前記燃焼室の排熱を利用して蒸気を発生させる排熱ボイラと該排熱ボイラで生成される蒸気によって作動する蒸気タービンを備え、
該蒸気タービンから排出される蒸気の排熱を利用する熱交換機を設け、該熱交換機から供給される温風又は熱風を、前記循環用ダクトに取り込む
請求項24又は25に記載の燃焼装置。 - 前記請求項12ないし26のいずれかに記載の燃焼装置を用い、電気的絶縁性の素材で形成した容体の内側の対向面上に夫々連続的に形成されてされ、両端に生ずる温度差で発電を行う複数個の熱伝変換素子を備えた熱電発電モジュールによって一部又は全部を形成したことを特徴とする発電装置。
- 可燃性固形廃棄物裁断機と可燃性固形廃棄物の気流乾燥装置と可燃性固形廃棄物を燃料とする二次燃焼装置を備えた燃焼装置と燃焼装置の排熱を利用する排熱ボイラと蒸気タービン発電機とヒートポンプを備えた発電装置において、燃焼装置の一部又は全部を熱電発電モジュールで形成し、熱電発電と蒸気タービン発電機とによって同一の熱源を効率よく利用する発電システム。
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013510844A JP6037173B2 (ja) | 2011-04-19 | 2011-10-26 | 燃焼装置及び燃焼方法と、それを用いた発電装置及び発電方法 |
| US14/112,803 US20140083478A1 (en) | 2011-04-19 | 2011-10-26 | Combustion Device, Combustion Method, and Electric Power-Generating Device and Electric Power-Generating Method Using Same |
| RU2013150959/03A RU2561636C2 (ru) | 2011-04-19 | 2011-10-26 | Камера сгорания, способ сжигания, устройство производства электроэнергии и способ производства электроэнергии на таком устройстве |
| SG2013083126A SG194874A1 (en) | 2011-04-19 | 2011-10-26 | Combustion device, combustion method, and electric power-generating device and electric power-generating method using same |
| EP11863760.2A EP2703715A4 (en) | 2011-04-19 | 2011-10-26 | COMBUSTION APPARATUS, COMBUSTION METHOD AND DEVICE FOR GENERATING ENERGY, AND THEREOF USE METHOD FOR GENERATING ENERGY |
| KR1020137029533A KR20140029437A (ko) | 2011-04-19 | 2011-10-26 | 연소장치 및 연소방법과, 그것을 이용한 발전장치 및 발전방법 |
| CN201180071683.4A CN103688110B (zh) | 2011-04-19 | 2011-10-26 | 燃烧装置及燃烧方法、使用了它们的发电装置及发电方法 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011092979A JP2011242121A (ja) | 2010-04-20 | 2011-04-19 | 自然吸気型燃焼煙装置 |
| JP2011-092979 | 2011-04-19 | ||
| JP2011-155280 | 2011-07-13 | ||
| JP2011155280 | 2011-07-13 |
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| WO2012144101A1 true WO2012144101A1 (ja) | 2012-10-26 |
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| PCT/JP2011/074723 Ceased WO2012144101A1 (ja) | 2011-04-19 | 2011-10-26 | 燃焼装置及び燃焼方法と、それを用いた発電装置及び発電方法 |
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| Country | Link |
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| US (1) | US20140083478A1 (ja) |
| EP (1) | EP2703715A4 (ja) |
| JP (1) | JP6037173B2 (ja) |
| KR (1) | KR20140029437A (ja) |
| CN (1) | CN103688110B (ja) |
| RU (1) | RU2561636C2 (ja) |
| SG (1) | SG194874A1 (ja) |
| WO (1) | WO2012144101A1 (ja) |
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| WO2019130929A1 (ja) * | 2017-12-27 | 2019-07-04 | 株式会社Kelk | 熱電発電装置 |
| CN110513996A (zh) * | 2019-09-26 | 2019-11-29 | 中国电力工程顾问集团西北电力设计院有限公司 | 一种垃圾焚烧发电厂用垃圾干燥装置 |
| CN112469943A (zh) * | 2019-04-17 | 2021-03-09 | 生物能源株式会社 | 燃烧器装置和燃烧装置 |
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| EP2140932A1 (en) * | 2008-07-04 | 2010-01-06 | Ammonia Casale S.A. | A process and a reactor for oxidation of a hydrocarbon |
| RU2609918C2 (ru) * | 2014-12-02 | 2017-02-07 | Петр Прокофьевич Ковтун | Горелочное устройство для производства тепловой и электрической энергии |
| RU2611700C1 (ru) * | 2015-10-22 | 2017-02-28 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Юго-Западный государственный университет" (ЮЗГУ) | Автономная тепловая пушка |
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| CN107906523A (zh) * | 2017-12-06 | 2018-04-13 | 朴龙哲 | 一种垃圾焚烧炉 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019130929A1 (ja) * | 2017-12-27 | 2019-07-04 | 株式会社Kelk | 熱電発電装置 |
| GB2581730A (en) * | 2017-12-27 | 2020-08-26 | Kelk Ltd | Thermoelectric generator |
| GB2581730B (en) * | 2017-12-27 | 2022-02-23 | Kelk Ltd | Thermoelectric generation device |
| CN112469943A (zh) * | 2019-04-17 | 2021-03-09 | 生物能源株式会社 | 燃烧器装置和燃烧装置 |
| CN112469943B (zh) * | 2019-04-17 | 2024-06-07 | 生物能源株式会社 | 燃烧器装置和燃烧装置 |
| CN110513996A (zh) * | 2019-09-26 | 2019-11-29 | 中国电力工程顾问集团西北电力设计院有限公司 | 一种垃圾焚烧发电厂用垃圾干燥装置 |
| CN110513996B (zh) * | 2019-09-26 | 2023-12-08 | 中国电力工程顾问集团西北电力设计院有限公司 | 一种垃圾焚烧发电厂用垃圾干燥装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6037173B2 (ja) | 2016-11-30 |
| RU2013150959A (ru) | 2015-05-27 |
| JPWO2012144101A1 (ja) | 2014-07-28 |
| RU2561636C2 (ru) | 2015-08-27 |
| EP2703715A1 (en) | 2014-03-05 |
| CN103688110A (zh) | 2014-03-26 |
| US20140083478A1 (en) | 2014-03-27 |
| KR20140029437A (ko) | 2014-03-10 |
| SG194874A1 (en) | 2013-12-30 |
| CN103688110B (zh) | 2016-10-05 |
| EP2703715A4 (en) | 2015-04-29 |
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