WO2013124183A3 - Thermoschock- und korrosionsbeständiger keramikwerkstoff auf der basis von calciumzirkonat und verfahren zu seiner herstellung - Google Patents

Thermoschock- und korrosionsbeständiger keramikwerkstoff auf der basis von calciumzirkonat und verfahren zu seiner herstellung Download PDF

Info

Publication number
WO2013124183A3
WO2013124183A3 PCT/EP2013/052744 EP2013052744W WO2013124183A3 WO 2013124183 A3 WO2013124183 A3 WO 2013124183A3 EP 2013052744 W EP2013052744 W EP 2013052744W WO 2013124183 A3 WO2013124183 A3 WO 2013124183A3
Authority
WO
WIPO (PCT)
Prior art keywords
resistant
calcium zirconate
corrosion
ceramic material
thermal shock
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2013/052744
Other languages
English (en)
French (fr)
Other versions
WO2013124183A2 (de
Inventor
Christos Aneziris
Patrick Gehre
Stefan SCHAFFÖNER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bergakademie Freiberg
Original Assignee
Bergakademie Freiberg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bergakademie Freiberg filed Critical Bergakademie Freiberg
Publication of WO2013124183A2 publication Critical patent/WO2013124183A2/de
Publication of WO2013124183A3 publication Critical patent/WO2013124183A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/48Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
    • C04B35/482Refractories from grain sized mixtures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00Compounds of zirconium
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/6261Milling
    • C04B35/6262Milling of calcined, sintered clinker or ceramics
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62625Wet mixtures
    • C04B35/6263Wet mixtures characterised by their solids loadings, i.e. the percentage of solids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62645Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/62665Flame, plasma or melting treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C04B2235/3246Stabilised zirconias, e.g. YSZ or cerium stabilised zirconia
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C04B2235/3248Zirconates or hafnates, e.g. zircon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3279Nickel oxides, nickalates, or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/442Carbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5427Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5436Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5445Particle size related information expressed by the size of the particles or aggregates thereof submicron sized, i.e. from 0,1 to 1 micron
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5463Particle size distributions
    • C04B2235/5472Bimodal, multi-modal or multi-fraction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602Making the green bodies or pre-forms by moulding
    • C04B2235/6027Slip casting
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/76Crystal structural characteristics, e.g. symmetry
    • C04B2235/768Perovskite structure ABO3
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/80Phases present in the sintered or melt-cast ceramic products other than the main phase
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9669Resistance against chemicals, e.g. against molten glass or molten salts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Thermal Sciences (AREA)
  • Composite Materials (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

Die Erfindung betrifft einen thermoschock- und korrosionsbeständigen Keramikwerkstoff auf der Basis von Calciumzirkonat sowie ein Verfahren zur Herstellung des Werkstoffes. Aus dem Keramikwerkstoff können geformte oder ungeformte Erzeugnisse für die Energietechnik, die Metallurgie, die Automobilindustrie, die Glas- und Zementindustrie und die chemische Industrie hergestellt werden. Der Erfindung liegt die technische Aufgabe zugrunde, einen thermoschock- und korrosionsbeständigen Keramikwerkstoff zu entwickeln, aus dem großvolumige Voll- und Hohlbauteile herstellbar sind. Zur Gewährleistung einer hohen chemischen Beständigkeit soll die keramische Bindematrix in der Zusammensetzung der Werkstoffzusammensetzung weitgehend entsprechen. Erfindungsgemäß besteht das Gefüge des Werkstoffes aus vorsynthetisiertem calciumcirkonathaltigen Brechgranulat mit einem ZrO2/CaO-Verhältnis zwischen 1,6 : 1 und 1 : 1,5 und einer Korngröße von 150 μm bis 6 mm mit einem Anteil größer 50 Masse% und einer das Brechgranulat umgebenden bei > 1400 °C gesinterten Bindematrix aus feinkörnigem Calziumzirkonat und/oder Zirkonoxid mit Korngrößen zwischen 50 nm und 150 μm.
PCT/EP2013/052744 2012-02-21 2013-02-12 Thermoschock- und korrosionsbeständiger keramikwerkstoff auf der basis von calciumzirkonat und verfahren zu seiner herstellung Ceased WO2013124183A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE201210003483 DE102012003483B3 (de) 2012-02-21 2012-02-21 Thermoschock- und korrosionsbeständiger Keramikwerkstoff auf der Basis von Calciumzirkonat und Verfahren zu seiner Herstellung
DE102012003483.0 2012-02-21

Publications (2)

Publication Number Publication Date
WO2013124183A2 WO2013124183A2 (de) 2013-08-29
WO2013124183A3 true WO2013124183A3 (de) 2013-11-14

Family

ID=47625436

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2013/052744 Ceased WO2013124183A2 (de) 2012-02-21 2013-02-12 Thermoschock- und korrosionsbeständiger keramikwerkstoff auf der basis von calciumzirkonat und verfahren zu seiner herstellung

Country Status (2)

Country Link
DE (1) DE102012003483B3 (de)
WO (1) WO2013124183A2 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11603319B2 (en) 2017-12-01 2023-03-14 Refratechnik Holding Gmbh Synthesis method for producing a calcium zirconate-containing material and batch and coarse ceramic refractory product having a pre-synthesized calcium zirconate-containing granular material

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112017004823A5 (de) 2016-11-09 2019-06-13 Technische Universität Bergakademie Freiberg Verbundwerkstoff aus Metall und Keramik und Verfahren zu dessen Herstellung
DE102020006598A1 (de) 2020-10-27 2022-04-28 Technische Universität Bergakademie Freiberg, Körperschaft des öffentlichen Rechts Feuerfester Keramikwerkstoff auf der Basis von La2O3 und Verfahren zu seiner Herstellung
DE102022001073A1 (de) 2022-03-29 2023-10-05 Technische Universität Bergakademie Freiberg, Körperschaft des öffentlichen Rechts Werkstoffverbund mit verbesserten Thermoschock- und Korrosionseigenschaften für Hochtemperaturanwendungen in der Metallurgie, in der chemischen Industrie und in der Zementindustrie
DE102022001271A1 (de) 2022-04-13 2023-10-19 Technische Universität Bergakademie Freiberg, Körperschaft des öffentlichen Rechts Werkstoffverbund aus dichter Innen- und Außenschale mit porösen Zwischenräumen für Bauteile in der Metallurgie, in der chemischen Industrie, in der Energietechnik, im Ofenbau und in der Zementindustrie
DE102022122280A1 (de) 2022-09-02 2024-03-07 Technische Universität Bergakademie Freiberg, Körperschaft des öffentlichen Rechts Kombination elektrischer Heizelemente, enthalten einen Verbundwerkstoff, mit Mikrowellen-Plasmabrennern für Hochtemperaturanwendungen in der Metallurgie, in der chemischen Industrie und in der Zementindustrie
CN118878321A (zh) * 2024-08-15 2024-11-01 郑州大学 一种氧化锆-锆酸钙复合陶瓷及其制备方法与应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2210201A1 (de) * 1972-03-03 1973-09-20 Goldschmidt Ag Th Verwendung von baddeleyit zur herstellung von feuerfesten massen
SU833859A1 (ru) * 1979-06-04 1981-05-30 Ленинградский Ордена Октябрьскойреволюции И Ордена Трудового Kpac-Ного Знамени Технологический Институтим. Ленсовета Шихта дл изготовлени огне-упОРНОгО МАТЕРиАлА
US4849383A (en) * 1986-12-24 1989-07-18 Mino Yogyo Company, Ltd. Basic refractory composition
DE4003568A1 (de) * 1989-02-07 1990-08-09 Akechi Ceramics Kk Giessschnauze fuer erschmolzenen stahl
JPH04168160A (ja) * 1990-10-31 1992-06-16 Sekisui Chem Co Ltd ZrO↓2―CaO系コーティング組成物
KR940006431B1 (ko) * 1991-12-27 1994-07-20 포항종합제철 주식회사 칼슘 지르코네이트질 부정형 내화조성물
US5902511A (en) * 1997-08-07 1999-05-11 North American Refractories Co. Refractory composition for the prevention of alumina clogging

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL300250A (de) 1962-11-14
US3342616A (en) 1965-09-20 1967-09-19 Corhart Refractories Co Refractory with periclase-based stabilized solid solution
DE1771273C3 (de) * 1968-04-27 1978-10-05 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Verfahren zur Herstellung von Keramik-Teilen aus stabilisiertem Zirkonoxid
DE2459601B1 (de) 1974-12-13 1976-03-04 Mannesmann Ag Feuerfeste keramische masse
AT344218B (de) 1975-06-02 1978-07-10 Didier Werke Ag Verschleissteile, insbesondere fuer schieberverschluesse an metallschmelze enthaltenden behaeltern
JPS6054971A (ja) 1983-09-05 1985-03-29 新日本製鐵株式会社 CaΖrO↓3−Ca↓3Si↓2ΖrO↓9−CaΖr↓4O↓9系耐火物
US5316571A (en) 1991-04-16 1994-05-31 Shinagawa Refractories Co., Ltd. Alumina-spinel type monolithic refractories
DE10006939C1 (de) 2000-02-16 2001-03-08 Didier Werke Ag Ringförmiger Einsatz für eine Schieberplatte sowie zugehörige Schieberplatte
US7326477B2 (en) 2003-09-23 2008-02-05 Saint-Gobain Ceramics & Plastics, Inc. Spinel boules, wafers, and methods for fabricating same
DE102005036394B4 (de) * 2005-08-03 2008-07-24 Tu Bergakademie Freiberg Verfahren zur Herstellung eines thermoschock- und korrosionsbeständigen Keramikwerkstoffes auf der Basis eines zirkondioxidfreien feuerfesten Oxides
CN101759229B (zh) * 2010-01-27 2012-02-08 巩义通达中原耐火技术有限公司 锆酸钙以及利用锆酸钙制备的水泥窑用镁钙锆砖

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2210201A1 (de) * 1972-03-03 1973-09-20 Goldschmidt Ag Th Verwendung von baddeleyit zur herstellung von feuerfesten massen
SU833859A1 (ru) * 1979-06-04 1981-05-30 Ленинградский Ордена Октябрьскойреволюции И Ордена Трудового Kpac-Ного Знамени Технологический Институтим. Ленсовета Шихта дл изготовлени огне-упОРНОгО МАТЕРиАлА
US4849383A (en) * 1986-12-24 1989-07-18 Mino Yogyo Company, Ltd. Basic refractory composition
DE4003568A1 (de) * 1989-02-07 1990-08-09 Akechi Ceramics Kk Giessschnauze fuer erschmolzenen stahl
JPH04168160A (ja) * 1990-10-31 1992-06-16 Sekisui Chem Co Ltd ZrO↓2―CaO系コーティング組成物
KR940006431B1 (ko) * 1991-12-27 1994-07-20 포항종합제철 주식회사 칼슘 지르코네이트질 부정형 내화조성물
US5902511A (en) * 1997-08-07 1999-05-11 North American Refractories Co. Refractory composition for the prevention of alumina clogging

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 198213, Derwent World Patents Index; AN 1982-25698E, XP002694341 *
DATABASE WPI Week 199230, Derwent World Patents Index; AN 1992-247307, XP002712686 *
DATABASE WPI Week 199617, Derwent World Patents Index; AN 1996-169704, XP002712685 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11603319B2 (en) 2017-12-01 2023-03-14 Refratechnik Holding Gmbh Synthesis method for producing a calcium zirconate-containing material and batch and coarse ceramic refractory product having a pre-synthesized calcium zirconate-containing granular material

Also Published As

Publication number Publication date
DE102012003483B3 (de) 2013-02-21
WO2013124183A2 (de) 2013-08-29

Similar Documents

Publication Publication Date Title
Castaldelli et al. Use of slag/sugar cane bagasse ash (SCBA) blends in the production of alkali-activated materials
Rahhal et al. Complex characterization and behavior of waste fired brick powder-portland cement system
Kohout et al. Effect of filler type on the thermo-mechanical properties of metakaolinite-based geopolymer composites
RU2011117311A (ru) Композиция для получения огнеупорного материала, огнеупорное фасонное изделие и способ его получения
CN104150926A (zh) 镍铁回转窑出料口专用浇注料的制作方法
WO2009133194A3 (de) Keramischer werkstoff, verfahren zur herstellung des keramischen werkstoffs und bauelement mit dem keramischen werkstoff
CN106747523A (zh) 低铁莫来石砖及其制造方法
CN102584191B (zh) 用蛇纹石尾矿制备堇青石陶瓷的方法
CN106187218B (zh) 一种氧化铬耐火材料及其制备方法
CN103328383A (zh) β-2CaO·SiO2的制造方法
CL2011003071A1 (es) Procedimiento para producir un aglomerado mediante mezcla de material fino y un ligante mineral que contiene un material mineral arcilloso con una proporcion de granulos finos de granulometria de menos de 4 micrometros de al menos 20%, y de menos de 1 micrometro de al menos 10% en peso; premezcla.
CN104446361A (zh) 重结晶陶瓷泥料及用其制备陶瓷制品的方法
MY160102A (en) Amorphous siliceous powder, process for production thereof, resin composition, and semiconductor encapsulation material
CN106747512A (zh) 一种钛铝酸钙粉体及其制备方法
WO2008078706A1 (ja) 非晶質シリカ質粉末、その製造方法及び半導体封止材
CN104310417B (zh) 一种含锆堇青石复相材料及其制备方法
Bose et al. Introduction to ceramics: fabrication, characterizations, and applications
Liu et al. Efficient co-valorization of phosphogypsum and red mud for synthesis of alkali-activated materials
CN102432317A (zh) 一种微晶氧化铝耐磨陶瓷及其制备方法
CN106220193A (zh) 一种碳化硅砖
CN101585670B (zh) 高强水泥熟料及其生产方法
López-Perales et al. Fly Ash as a Secondary Raw Material Improving the Sustainable Characteristics of a Conventional Silicoaluminate Refractory Castable
WO2011012510A3 (fr) Procédé d'oxydo-réduction en boucle utilisant comme masse oxydo-réductrice une composition à base d'oxyde supporté de cérium ou de cérium, de zirconium et/ou de terre rare
Bai et al. Potential Utilization of Loess in Grouting Materials: Effects of Grinding Time and Calcination Temperature
CN106316125A (zh) 一种环保陶瓷釉料及其制备方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13703442

Country of ref document: EP

Kind code of ref document: A2

122 Ep: pct application non-entry in european phase

Ref document number: 13703442

Country of ref document: EP

Kind code of ref document: A2