WO2014012575A1 - Lampe à décharge à haute intensité présentant une traversée étanchéifiée par du verre de soudure - Google Patents

Lampe à décharge à haute intensité présentant une traversée étanchéifiée par du verre de soudure Download PDF

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Publication number
WO2014012575A1
WO2014012575A1 PCT/EP2012/063919 EP2012063919W WO2014012575A1 WO 2014012575 A1 WO2014012575 A1 WO 2014012575A1 EP 2012063919 W EP2012063919 W EP 2012063919W WO 2014012575 A1 WO2014012575 A1 WO 2014012575A1
Authority
WO
WIPO (PCT)
Prior art keywords
discharge lamp
pressure discharge
lamp according
glass solder
solder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2012/063919
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German (de)
English (en)
Inventor
Paul Braun
Klaus Stockwald
Christina Wille
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Osram GmbH
Original Assignee
Osram GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Osram GmbH filed Critical Osram GmbH
Priority to PCT/EP2012/063919 priority Critical patent/WO2014012575A1/fr
Priority to DE201221000280 priority patent/DE212012000280U1/de
Publication of WO2014012575A1 publication Critical patent/WO2014012575A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00—Gas-discharge or vapour-discharge lamps
    • H01J61/02—Details
    • H01J61/36—Seals between parts of vessels; Seals for leading-in conductors; Leading-in conductors
    • H01J61/366—Seals for leading-in conductors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00—Gas-discharge or vapour-discharge lamps
    • H01J61/82—Lamps with high-pressure unconstricted discharge having a cold pressure > 400 Torr
    • H01J61/827—Metal halide arc lamps
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/24—Manufacture or joining of vessels, leading-in conductors or bases
    • H01J9/32—Sealing leading-in conductors
    • H01J9/323—Sealing leading-in conductors into a discharge lamp or a gas-filled discharge device

Definitions

  • the invention is based on a high-pressure discharge lamp GE measure the preamble of claim 1.
  • These are in particular metal halide lamps.
  • Such lamps are in particular high-pressure discharge lamps with a ceramic discharge vessel for general lighting.
  • EP 1 114 438 and WO 2006/077516 and WO 2008/075273 each disclose a high-pressure discharge lamp in which iridium is used for the sealing.
  • the feedthrough is a pin or wire of iridium, with the pin sintered directly into the end of the ceramic discharge vessel.
  • the wire is pushed as a helix on a core pin.
  • Nb-pin or a niobähnliches material This means a material whose thermal expansion coefficient in the range 6 to 9 * 10 ⁇ 6 1 / K and is high temperature stable.
  • Re and Ta instead of Nb or alloys based thereon is suitable.
  • the implementation is melted in a short capillary at the end of the discharge vessel by means of solder as known per se ⁇ .
  • the electrode which is forwardly ⁇ is where the implementation is based on a shaft made of W, as in itself be ⁇ known. It has a head which may have a ball or a helix, as also previously known.
  • the implementation comprises at least one short before ⁇ more complete part of the iridium-containing portion which is at least partially surrounded by a sleeve of ceramic material, preferably is alumina.
  • the passage is sealed by means of glass solder in the capillary.
  • iridium direct sintering has been used and, in addition, torch vessel mounted pump and fill tubes have been required for sealing and electrode delivery.
  • This method requires its own Ferti ⁇ supply lines and special manufacturing method of the ceramic burner vessel, which includes the electrodes fitted with a ⁇ .
  • Tm203 carries 30-95Gew-%, is preferably a range of 40-90 wt .-%, more preferably this proportion is 43-57 wt .-% Tm203.
  • HT high temperature
  • this implementation is a wire part or pencil made of iridium, pure or as Iridiumleg réelle or iridium cermet.
  • the sleeve of the bushing is made of ceramic, which is advantageously adapted to the material of the capillary, usually PCA, in terms of the thermal expansion coefficient.
  • the ceramic sleeve is a micro-capillary of high purity A1203.
  • Typical dimensions of the seal are:
  • Inner diameter ID of the capillary 0.1 to 0.4 mm, a typical value is 0.31 mm.
  • Outer diameter OD of the capillary range 0.25 to 1.5 mm, a typical value is 0.61 mm.
  • a typical length L of the sleeve is 2.5 mm, while L can move in a range of 0.1 to 5 mm.
  • the end of the capillary and the glass solder filling of the gaps between the burner tube end and the sleeve outer wall have a typical dimension of 10 to 120 ym in the radial direction, typically 40 microns.
  • the axial extent is in the range of 100ym-5000ym. Preferably a value of 600 ym to 2500 ym.
  • the glass solder filling in the gap between the inner wall of the sleeve and the iridium-carrying part has a radial length of 10 to 120 ym, a typical value is 25 ym.
  • the axial length is in a range of 100 ym-5000 ym. a typical value is 600 ym.
  • a eutectic mixture is used based on an alumina thulium oxide mixture.
  • HT stands for high temperature.
  • a third component x may be admixed as an oxide, ie a mixture A1203 / Tm203 / X203. This makes it possible to achieve a particularly high purity of the burner interior.
  • ⁇ advantageous way should be included in the solder Tm203 in a range between 30 and 70 wt .-%.
  • x is an element from the group of rare earths (SE) Er, Y, Sc alone or in combination of at least two elements of the group.
  • SE rare earths
  • Minimum diameter MID of the feedthrough wire is typically 0.2 to 0.35 mm.
  • Maximum length of the feedthrough wire is typically 1 to 5 mm.
  • Outer diameter is typically 0.8-2.6 mm, typical value is 1, 8 mm. r
  • the length is typically 0.35-2.6 mm, a typical value is 1 mm.
  • the inner diameter ID of the capillary is preferably 0.3-1.5 mm, a typical value is 0.65 mm.
  • the bore of the Kurzkapillare is filled with the through ⁇ guide member, and preferably a eutectic solder mixture.
  • a preferred eutectic solder mixture is Tm203-A1203 with 53 wt% A1203.
  • a critical point for determining the parameters of the end construction is the thermal mass of the Endenkonstrukti ⁇ on.
  • the outer surface over the A ⁇ bed length should preferably be in a specific ratio V to the entire surface of the discharge vessel.
  • the embedment length should typically be about 0.8 mm to 2 mm. That behaves ⁇ V nis the total surface of the discharge vessel to the outer surface of the fused- ⁇ is preferably 50 to 150, into ⁇ particular 60 to 90, based on a seal.
  • the absolute value of the outer surface of the Einschmelz ⁇ length in the range 2 to 6 mm 2 .
  • a typical safe value for the total length of the discharge vessel is 15 to 25 mm.
  • the ratio V therefore plays a role because the total surface ⁇ the thermal losses of the discharge vessel prevails ⁇ .
  • the cooling effect should be more pronounced in the area of the embedding length.
  • the glass solder be relatively low viscosity, which is why the mentioned composition is advantageous. This ensures, in particular, that the glass solder wets the capillaries completely up to the lower edge. In this consensus As a result, any harmful dead volume in the area of the capillary is avoided. Furthermore, a defined thermal transition between capillary and discharge volume is ensured, so that no undesirable scattering of light-technical properties can occur.
  • a preferred inner contour of the burner end includes a From ⁇ set or a nose which acts as a brake for the during manufacture low-viscosity glass solder.
  • Multi-wire system with a corresponding ceramic support member for guiding a certain number of iridium wires are used with adapted to the support member dimensions.
  • Another advantageous feature is a filling that is un saturated ⁇ .
  • a typical filling of this type known per se can be used.
  • the closing of the discharge vessel or burner by means of laser or IR radiation can take place. Also heating spirals are possible.
  • TU 1.5 + - 1 ⁇ mol / mm 3 or 0.5 + -0.33 ⁇ g / mm 3 ;
  • CeJ3 0.1 + - 0.05 ⁇ mol / mm 3 or 0.053 + -0.026 ⁇ g / mm 3 ;
  • PrJ3 0.025 +/- 0.025 ⁇ mol / mm 3 or 0.013 + 0.013 yg / mm 3 ;
  • a typical molar concentration of metal halides for a filling achieving a color temperature of 4000 K is as follows, applied here as well to a power of 70W with an internal volume of the discharge vessel of 300 mm 3 : LiJ: 0.4 + - 0.15 ⁇ mol / mm 3 or 0.053 + - 0.02 yg / mm 3 ;
  • DyJ3 0.4 + - 0.15 ⁇ mol / mm 3 or 0.22 + -0.08 ⁇ g / mm 3 .
  • Hg 15-22 yg / mm 3 used.
  • HgJ2 For setting an improved tungsten cycle, it may be advantageous to use HgJ2 as well.
  • a typical molar concentration is
  • HgJ2 0.3-1.5 g / mm 3 ; a typical value is 0.7 yg / mm 3 .
  • the typical mix used is the following mix of metal halides:
  • GaJ3 (typical 1.6) 0.5 to 4 yg / mm 3 ;
  • InJ (typically 0.5) 0.3 ... 3 yg / mm 3 ;
  • ZnJ2 (type 2) 0.5 to 4 yg / mm 3 .
  • the end part of the bushing which may be made of Nb or niobähnli-erhern material, and at least a portion the front section of Ir is sealed with a high temperature solder.
  • a high temperature solder This is a well- ⁇ tes se Lot, see for example WO 2005/124823 or in WO 2003/096377 disclosed iridium-containing solder.
  • preferred embodiment is a solder, the oxides of the
  • the bushing is welded to the electrode.
  • At least the part of the leadthrough facing the Nb pin is preferably covered with the solder or the frit.
  • solder can also cover a larger area of the front part.
  • the discharge vessel is preferably made of alumina such as PCA or the like. made, as known. It can have integral ends or separate plugs.
  • alumina such as PCA or the like. made, as known. It can have integral ends or separate plugs.
  • Nb it is also possible to use another similar behaving material, in particular Ta or Re or a material whose thermal expansion coefficient differs by less than 20% from that of the Nb, referred to a temperature of 1100 K. You can also use a cermet. These materials are collectively called Nb material.
  • Typical is a wattage of 70 to 150 W, the lamp shows high stability and good dimming properties.
  • An Ir wire as a front section has been sintered directly into the capillary. However, the so far reali ⁇ sized lifetimes for a commercial application are too short.
  • frits of the type When using an unsaturated Hg-free filling is frits of the type have proved successful alumina / thulium oxide / aluminate and aluminum ⁇ miniumoxid / yttria particularly good.
  • the melting is achieved, for example, by means of an IR laser or W helix heater.
  • the sleeve in conjunction with a special glass solder is the key to keeping a high-temperature seal tight for a long time, using temperatures of at least 1550 ° C.
  • the discharge vessel is preferably bulbous, oval, elliptical, barrel-shaped or similar to a rugby ball shaped and in particular has a high aspect ratio of at least 2.
  • Ty ⁇ pisch allows the novel sealing technique shortening the overall length of the discharge vessel compared to the usual capillary sealed by 30 bis 60%.
  • Typical fillings include NaJ, CaJ2, and rare earth metals such as in particular CeJ3 and optionally PrJ3 and ErJ3.
  • rare earth metals such as in particular CeJ3 and optionally PrJ3 and ErJ3.
  • Other halogens such as chlorine or bromine are suitable for the halides.
  • ZnJ2, Inj, TU, NaJ and SEJ3 are used in particular as a filling
  • SE stands for rare earth metal.
  • Xe is used as inert gas, in particular, alone or in combination with other noble gases, in particular argon.
  • an end face of the capillary is provided, which is arranged substantially transversely to the longitudinal axis of the discharge vessel. Preferably, it is 70-90 ° arranged thereto. In this case, this end face seen from the two ⁇ th outer gap should extend at least by a width D to the outside, the gap width S of the outer
  • D is at least 2S.
  • High-pressure discharge lamp designed with a discharge vessel enclosing a discharge volume in which a filling is accommodated in the discharge volume of the discharge vessel is provided with an end which is tubular in the ⁇ particular as a capillary, and wherein in the end of a bushing is sealed by means of glass solder, wherein on the implementation, an electrode is attached, which protrudes into the discharge volume, characterized in that the implementation of a front, facing the discharge portion has at least which is made essentially of iridium, at least a wesentli ⁇ cher part of the front section within the end ver ⁇ runs and is surrounded by a sleeve of ceramic material, wherein a first inner and a second outer gap between the end and sleeve on the one hand and sleeve and Ir section on the other hand filled with glass solder.
  • High-pressure discharge lamp according to proposal 1 characterized marked ⁇ characterized in that the Ir section and electrode are connected by butt welding.
  • High-pressure discharge lamp according to claim 4 characterized marked ⁇ characterized in that the glass solder is at least up to a hemispherical portion of the front portion facing the rear portion.
  • High-pressure discharge lamp according to claim 1 characterized marked ⁇ characterized in that the glass solder is a high-temperature solder based on oxides of aluminum and Tm203 and possibly further
  • Oxides of Rare Earth Metals He, Y, Sc is.
  • High-pressure discharge lamp according to claim 1 characterized marked ⁇ characterized in that the filling comprises metal halides and in particular also comprises Hg.
  • High-pressure discharge lamp according to claim 7 characterized marked ⁇ characterized in that the filling is dosed unsaturated.
  • High-pressure discharge lamp according to claim 1 characterized ge ⁇ indicates that the implementation has a rear, facing away from the discharge second section, which is made of Nb or Ta or Re alone or in mixture.
  • FIG. 1 shows a high-pressure discharge lamp with discharge vessel
  • Outer bulb; 2 shows a first embodiment for the range of from ⁇ seal at one end.
  • Fig. 3 shows a second embodiment of the field of
  • Fig. 4 shows a third embodiment of the field of
  • FIG. 1 schematically shows a metal halide lamp 1. It consists of a discharge vessel 2 made of PCA into which two electrodes 3 are inserted.
  • the discharge vessel has a central part 5 and two ends. There are two at the ends
  • the lamp has a longitudinal axis A. ⁇
  • the discharge vessel 2 is surrounded by an outer bulb 7.
  • the discharge vessel 2 is in the outer bulb by means of an overall stells which supported a short and a long power supply 8a and 8b be ⁇ tains.
  • On the outer bulb sits a screw 9.
  • the discharge vessel contains a filling which typically comprises Hg (3 to 30 mg / cm 3 ) and 0.1 to 1 mg / cm 3 of metal halides.
  • a filling typically comprises Hg (3 to 30 mg / cm 3 ) and 0.1 to 1 mg / cm 3 of metal halides.
  • noble gas argon is typically used under a pressure of 30 to 300 hPa cold.
  • Figure 2 shows a first embodiment of the end of the ceramic discharge vessel for the region of the seal on a pipe piece or a capillary 6.
  • the electrode 3 with a head, which is formed as a helix 10, and a shaft 11 of W, is connected to a bushing 12 prepared from iridium and there butt-welded by laser (15).
  • a sleeve 16 made of aluminum oxide surrounds the pin 12 made of Ir in Be ⁇ rich short capillary 6 so that between the short capillary tube and a first gap 17 and between the sleeve and pin of Ir a second gap 18 remains.
  • a high-temperature solder 19 preferably a eutectic mixture of aluminum oxide and Tm 2 O 3, is introduced into the capillary 6. crowded. It extends from the outside to the front end of the capillary. Externally, it forms on the Ir pin a Me ⁇ niskus. The glass solder 19 also fills the first and second gaps 17, 18 out to the front end.
  • a stop 21 is attached to the Ir pin 12, so that the insertion depth of the pin is precisely defined.
  • the butt 15 is equal ⁇ time as a stop for the sleeve 16, before it is finally fixed by the glass solder.
  • the implementation may also be in two parts, wherein an outer portion may be made of Nb or wherein for this rear portion and another Nb-like material according to the following Tab. 1 can be used. There, four metals are compared to PCA, including Ir. Given is the thermal expansion coefficient TAK at an operating temperature of 1130 K and the percentage difference of the TAK to Nb.
  • the outer gap usually has a width of 10 to 150 ⁇ m, preferably 30 to 100 ⁇ m, and the inner gap has a width of 3 to 50 ⁇ m, preferably 10 to 40 ⁇ m.
  • the axial length of Ka ⁇ pillare is preferably 2.5 mm, the sleeve is as long and is flush with the capillary from.
  • the diameter of the Ir pin is at least 0.2 mm, preferably 0.25 to 0.4 mm.
  • FIG. 3 shows another embodiment in which the capillary 6 has on its inner wall in the vicinity of the opening to the discharge volume towards a nose 25 as a stopper for the glass solder 19.
  • FIG. 4 shows a similar exemplary embodiment with a stopper system for the glass solder.
  • the stopper system consists of a transverse to the longitudinal axis A running projection in the vicinity of the opening to the discharge volume.
  • the projection may be mounted either on the side of the capillary 26, or on the side of Sleeve Shirt ⁇ se, 27, or on both sides.
  • the length of the melting zone AX ie the axial region in which the solder extends at least into the capillary, is typically 0.8 to 4 mm.
  • a typical value for a 100 W lamp is 1.5 to 2.5 mm.
  • the frits typically consist of mixtures of various rare earth oxides such as Tm203 together with aluminum oxide, where ⁇ can be mixed with other SE oxides.
  • the presented sealing technique is suitable for both Hg-containing and Hg-free fillings.
  • the filling typically contains iodides of Na, Ce, Tm, Dy
  • the lead-through system with the iridium-containing front section is particularly well suited, in particular for wattages of 150 to 1000 W.
  • a particular advantage of the new closure technology is that it can be introduced on standard manufacturing machines.
  • the sealing is done by closing by laser radiation.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)
PCT/EP2012/063919 2012-07-16 2012-07-16 Lampe à décharge à haute intensité présentant une traversée étanchéifiée par du verre de soudure Ceased WO2014012575A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/EP2012/063919 WO2014012575A1 (fr) 2012-07-16 2012-07-16 Lampe à décharge à haute intensité présentant une traversée étanchéifiée par du verre de soudure
DE201221000280 DE212012000280U1 (de) 2012-07-16 2012-07-16 Hochdruckentladungslampe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2012/063919 WO2014012575A1 (fr) 2012-07-16 2012-07-16 Lampe à décharge à haute intensité présentant une traversée étanchéifiée par du verre de soudure

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WO2014012575A1 true WO2014012575A1 (fr) 2014-01-23

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4242123A1 (de) 1992-12-14 1994-06-16 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Hochdruckentladungslampe mit einem keramischen Entladungsgefäß
US5424609A (en) * 1992-09-08 1995-06-13 U.S. Philips Corporation High-pressure discharge lamp
EP1114438A1 (fr) 1999-07-20 2001-07-11 W. C. Heraeus GmbH & Co. KG Lampe a decharge a haute pression
US20020190653A1 (en) * 2000-03-08 2002-12-19 Yasaburo Takeji Discharge lamp
WO2003096377A1 (fr) 2002-05-10 2003-11-20 Koninklijke Philips Electronics N.V. Joint pour lampe a decharge
WO2005124823A1 (fr) 2004-06-14 2005-12-29 Koninklijke Philips Electronics N.V. Lampe a decharge a halogenure de metal ceramique
WO2006077516A2 (fr) 2005-01-19 2006-07-27 Koninklijke Philips Electronics N.V. Lampe a decharge haute pression
DE102006024238A1 (de) * 2006-05-23 2007-11-29 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Hochdruckentladungslampe
WO2008075273A1 (fr) 2006-12-18 2008-06-26 Koninklijke Philips Electronics N.V. Lampe à décharge haute pression ayant une chambre de décharge en céramique

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5424609A (en) * 1992-09-08 1995-06-13 U.S. Philips Corporation High-pressure discharge lamp
DE4242123A1 (de) 1992-12-14 1994-06-16 Patent Treuhand Ges Fuer Elektrische Gluehlampen Mbh Hochdruckentladungslampe mit einem keramischen Entladungsgefäß
EP1114438A1 (fr) 1999-07-20 2001-07-11 W. C. Heraeus GmbH & Co. KG Lampe a decharge a haute pression
US20020190653A1 (en) * 2000-03-08 2002-12-19 Yasaburo Takeji Discharge lamp
WO2003096377A1 (fr) 2002-05-10 2003-11-20 Koninklijke Philips Electronics N.V. Joint pour lampe a decharge
WO2005124823A1 (fr) 2004-06-14 2005-12-29 Koninklijke Philips Electronics N.V. Lampe a decharge a halogenure de metal ceramique
WO2006077516A2 (fr) 2005-01-19 2006-07-27 Koninklijke Philips Electronics N.V. Lampe a decharge haute pression
DE102006024238A1 (de) * 2006-05-23 2007-11-29 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Hochdruckentladungslampe
WO2008075273A1 (fr) 2006-12-18 2008-06-26 Koninklijke Philips Electronics N.V. Lampe à décharge haute pression ayant une chambre de décharge en céramique

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