WO2014102980A1 - Composition désodorisante et antibactérienne, et tissu désodorisant et antibactérien - Google Patents

Composition désodorisante et antibactérienne, et tissu désodorisant et antibactérien Download PDF

Info

Publication number
WO2014102980A1
WO2014102980A1 PCT/JP2012/083942 JP2012083942W WO2014102980A1 WO 2014102980 A1 WO2014102980 A1 WO 2014102980A1 JP 2012083942 W JP2012083942 W JP 2012083942W WO 2014102980 A1 WO2014102980 A1 WO 2014102980A1
Authority
WO
WIPO (PCT)
Prior art keywords
deodorant
antibacterial
fabric
mass
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2012/083942
Other languages
English (en)
Japanese (ja)
Inventor
修一 源中
佳成 宮村
行徳 下村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suminoe Co Ltd
Original Assignee
Suminoe Textile Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suminoe Textile Co Ltd filed Critical Suminoe Textile Co Ltd
Priority to PCT/JP2012/083942 priority Critical patent/WO2014102980A1/fr
Priority to JP2014553974A priority patent/JPWO2014102980A1/ja
Publication of WO2014102980A1 publication Critical patent/WO2014102980A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Disinfection or sterilisation of materials or objects, in general; Accessories therefor
    • A61L2/16—Disinfection or sterilisation of materials or objects, in general; Accessories therefor using chemical substances
    • A61L2/23—Solid materials, e.g. granules, powders, blocks or tablets
    • A61L2/232—Solid materials, e.g. granules, powders, blocks or tablets layered or coated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71—Salts of phosphoric acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/72—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/332—Di- or polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/422—Hydrazides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/195—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds sulfated or sulfonated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic

Definitions

  • the present invention provides a deodorizing antibacterial composition having excellent deodorizing performance even after repeated washing, excellent antibacterial performance, and good storage stability by being applied to a fabric or the like, and repeated
  • the present invention relates to a deodorizing and antibacterial fabric that is excellent in deodorizing performance even after washing and also has excellent antibacterial performance.
  • the present applicant has deodorized containing an amine compound, an inorganic porous material, a metal oxide, a metal hydroxide, an anionic surfactant, and a nonionic surfactant. It has been proposed to prepare a composition and attach the deodorant composition to at least a part of the fabric (see Patent Document 1). Since the deodorizing composition containing an amine compound, an inorganic porous material, a metal oxide, and a metal hydroxide is attached to the fabric, excellent deodorizing performance against various odors can be obtained.
  • the viscosity of the deodorant composition liquid increases remarkably, which causes storage stability such as gelation or aggregation after long-term storage. Had the problem of being bad.
  • the present invention has been made in view of such technical background, and can exhibit excellent deodorizing performance even after repeated washing, has excellent antibacterial performance, and has excellent storage stability. It is an object of the present invention to provide an antibacterial composition and a deodorized antibacterial fabric that has excellent deodorizing performance even after repeated washing and also has excellent antibacterial performance.
  • the present invention provides the following means.
  • an amine compound An inorganic deodorant, A first salt comprising a metal phosphate; An inorganic antibacterial agent, At least one second salt selected from the group consisting of sulfonates and carboxylates; A deodorizing antibacterial composition comprising a binder resin.
  • a deodorant antibacterial fabric wherein the deodorant antibacterial composition according to any one of items 1 to 6 is fixed to at least a part of the fabric.
  • the deodorant antibacterial fabric according to item 7 which is used as an underwear fabric, clothing, wallpaper, chair upholstery, vehicle interior material, curtain, carpet, shoe interior material or shoe insole.
  • the deodorizing antibacterial composition contains a metal phosphate (first salt), the deodorizing performance after repeated washing can be remarkably improved. Furthermore, since the composition contains an inorganic antibacterial agent, sufficient antibacterial performance can be obtained. Furthermore, although it contains a metal phosphate (first salt), it contains at least one second salt selected from the group consisting of sulfonates and carboxylates, so that the liquid stability of the composition is markedly improved. Even when the composition is processed into a fabric after long-term storage, a deodorized and antibacterial fabric excellent in deodorizing performance and antibacterial performance can be stably produced. Moreover, since the composition contains a binder resin, the components are prevented from being detached from the fabric or the like when the deodorant antibacterial composition is fixed to the fabric or the like.
  • At least one salt selected from the group consisting of an alpha olefin sulfonate and a polycarboxylate is used as the second salt, so that the liquid stability of the composition is further improved. Can be increased.
  • the solid content concentration in the composition is 15% by mass to 35% by mass, the long-term storage stability of the deodorant antibacterial composition can be further improved and processed into a fabric or the like.
  • the sedimentation of the components (deodorant component, antibacterial component, etc.) in the diluted solution of the deodorant antibacterial composition can be sufficiently suppressed.
  • the deodorizing antibacterial composition according to the present invention is from the group consisting of an amine compound, an inorganic deodorant, a metal phosphate (first salt), an inorganic antibacterial agent, a sulfonate, and a carboxylate. It contains at least one selected second salt and a binder resin.
  • Examples of the amine compound include a hydrazine derivative or an inorganic silicon compound carrying a polyamine compound.
  • hydrazine derivative examples include those obtained by reacting a hydrazine compound with a long-chain aliphatic compound, or those obtained by reacting a hydrazine compound and an aromatic compound.
  • one or two compounds selected from the group consisting of hydrazine and semicarbazide, and a group consisting of monocarboxylic acid having 8 to 16 carbon atoms, dicarboxylic acid, aromatic monocarboxylic acid, and aromatic dicarboxylic acid are selected.
  • reaction product with one or more compounds, or one or two compounds selected from the group consisting of hydrazine and semicarbazide, and a group consisting of monoglycidyl derivatives and diglycidyl derivatives having 8 to 16 carbon atoms. Reaction products with one or more compounds are preferred.
  • a chemical reaction is caused with respect to aldehydes, and an excellent adsorbing action can be exhibited to ensure malodor removal performance.
  • the reaction product include sebacic acid dihydrazide, dodecanoic acid dihydrazide, isophthalic acid dihydrazide, and the like.
  • the solubility of such a hydrazine derivative in water is desirably 5 g / L or less at 25 ° C. If the solubility in water is within this range, the hydrazine derivative is prevented from dissolving and flowing out even if it comes into contact with water by washing or the like.
  • the inorganic silicon compound carrying a polyamine compound is not particularly limited, and examples thereof include porous silicon dioxide carrying a polyamine compound and aluminum silicate carrying a polyamine compound.
  • the polyamine compound is not particularly limited, and examples thereof include aliphatic polyamines, aromatic polyamines, and alicyclic polyamines. Specific examples include diethylenetriamine and tetraethylenepentamine.
  • the polyamine compound is particularly effective for deodorizing aldehyde gas, and the inorganic silicon compound is effective for deodorizing basic gas.
  • the inorganic deodorant is not particularly limited, but it is preferable to use an inorganic porous material, a metal hydroxide and a metal oxide in combination.
  • Various odors can be effectively deodorized by using an inorganic porous material, a metal hydroxide and a metal oxide in combination.
  • the inorganic porous material has a large surface area because of its porosity, and has an excellent malodor adsorption ability.
  • the inorganic porous material include porous silica, activated carbon, zeolite, silica gel, and barley stone. Among them, it is preferable to use a zeolite having an excellent adsorption ability for acetic acid, ammonia gas, and the like. Zeolite is preferred because it is white and has less influence on the color of the fabric than activated carbon when supported on fibers. Zeolite has a skeletal structure in which silicon and aluminum are three-dimensionally bonded through oxygen. In this skeleton, molecular-level holes (pores) are opened, and various molecules such as water and organic molecules are taken into the skeleton, so that it is very useful as an adsorbent.
  • the artificial zeolite MFI-type zeolite has two types of pores derived from the crystal structure that are three-dimensionally connected to each other. Odor performance can be further improved.
  • MFI-type zeolite When MFI-type zeolite is used as the zeolite, it exhibits excellent deodorizing performance with basic gases such as ammonia and trimethylamine, and adsorbs trace amounts of neutral gases such as aldehydes and 1-nonene (deodorization). Also has an excellent effect.
  • metal hydroxide examples include zirconium hydroxide, magnesium hydroxide, aluminum hydroxide, ferrous hydroxide, and copper hydroxide, but are not particularly limited to these examples.
  • the said metal hydroxide exhibits the effect excellent in decomposition
  • metal oxide examples include, but are not limited to, copper oxide, alumina, titanium oxide, zinc oxide, iron oxide, and zirconium oxide.
  • the metal oxide exhibits an excellent effect in the decomposition (deodorization) of basic gases such as ammonia and trimethylamine.
  • the metal phosphate (first salt) is not particularly limited, but is at least one selected from the group consisting of aluminum tripolyphosphate, zirconium phosphate, titanium phosphate, tin phosphate and cerium phosphate.
  • the metal phosphate is preferably used.
  • the inorganic antibacterial agent is not particularly limited, and examples thereof include silver-supported inorganic porous materials such as silver-supported zeolite and zinc-supported inorganic porous materials such as zinc-supported zeolite.
  • specific examples of inorganic porous materials (other than zeolite) as a carrier for an inorganic antibacterial agent include silica gel and alumina gel.
  • the second salt at least one salt selected from the group consisting of sulfonates and carboxylates is used.
  • the sulfonate is not particularly limited, but an alpha olefin sulfonate is preferably used. Although it does not specifically limit as said alpha olefin sulfonate, For example, alpha olefin sulfonate sodium etc. are mentioned.
  • the carboxylate is not particularly limited, but polycarboxylate is preferably used.
  • the polycarboxylate is not particularly limited.
  • a copolymer of an ester compound of methoxypolyethylene glycol and acrylic acid and a crotonic acid, an ether compound of styrene glycol and allyl alcohol, and fumaric acid examples include copolymers.
  • the binder resin is not particularly limited.
  • the deodorant antibacterial composition of the present invention preferably further contains a nonionic surfactant.
  • a nonionic surfactant for example, polyoxyalkylene alkyl ether, polyoxyalkylene alkyl phenyl ether, sorbitan fatty acid ester, etc. are mentioned.
  • the amine compound, the inorganic porous material, the metal hydroxide, the metal oxide, the metal phosphate, the inorganic antibacterial agent, etc. are usually not dissolved in the solvent.
  • the average particle size of these dispersoids is preferably 10 nm to 100 ⁇ m.
  • the average particle size of the dispersoid is preferably 10 nm to 10 ⁇ m, and particularly preferably 10 nm to 5 ⁇ m.
  • the solid content concentration in the deodorant antibacterial composition is preferably set to 15% by mass to 35% by mass. When it is 15% by mass or more, it is possible to sufficiently suppress sedimentation of the components contained in the diluted liquid of the deodorant antibacterial composition when it is processed into a fabric or the like, and when it is 35% by mass or less, the deodorant antibacterial The long-term storage stability of the composition liquid can be further improved.
  • the content ratio of each component is not particularly limited, but the amine compound is preferably set in a range of 4 to 40 parts by mass with respect to 100 parts by mass of the binder resin. .
  • the inorganic deodorant is preferably set in the range of 10 to 100 parts by mass with respect to 100 parts by mass of the binder resin.
  • the metal phosphate (first salt) is preferably set in the range of 8 to 80 parts by mass with respect to 100 parts by mass of the binder resin. By being 8 parts by mass or more, the deodorizing performance after repeated washing can be further improved, and by being 80 parts by mass or less, long-term storage stability can be further improved.
  • the inorganic antibacterial agent is preferably set in the range of 1 to 10 parts by mass with respect to 100 parts by mass of the binder resin. When it is 1 part by mass or more, sufficient antibacterial performance can be imparted, and when it is 10 parts by mass or less, long-term storage stability can be further improved.
  • the second salt (at least one salt selected from the group consisting of sulfonate and carboxylate) is set in a range of 0.4 to 40 parts by mass with respect to 100 parts by mass of the binder resin. It is preferable. Although it is 0.4 parts by mass or more, the storage stability of the liquid can be improved in spite of containing the metal phosphate, and the viscosity of the liquid is 40 parts by mass or less. The rise and gelation can be suppressed and long-term storage stability can be improved.
  • the nonionic surfactant is preferably set in the range of 0.8 to 40 parts by mass with respect to 100 parts by mass of the binder resin.
  • the carrying amount (fixed amount) of the deodorant antibacterial composition on the fabric is preferably 2 g / m 2 to 50 g / m 2 (dry weight; solid content). Sufficient deodorant antibacterial performance can be obtained when it is 2 g / m 2 or more, and it can be avoided that the cost is increased when it is 50 g / m 2 or less (also exceeding 50 g / m 2). There is no significant improvement in deodorizing performance).
  • a method for preparing the coating liquid for the deodorant antibacterial composition is not particularly limited.
  • the amine compound, the inorganic deodorant, the metal phosphate, and the inorganic antibacterial A coating solution is prepared which comprises an aqueous dispersion in which an agent, the second salt, the nonionic surfactant, and the binder resin are dispersed in water.
  • the amine compound, the inorganic deodorant, the metal phosphate, the inorganic antibacterial agent, the second salt, the nonionic surfactant, and the binder resin are sufficiently dispersed in water as much as possible. It is preferable.
  • an amine compound, an inorganic deodorant, a metal phosphate, an inorganic antibacterial agent, a second salt, and a nonionic surfactant are dispersed in water in advance. Then, it is more preferable to disperse the binder resin from the viewpoint of dispersing them more uniformly.
  • the coating solution comprising the deodorant antibacterial composition thus obtained is applied to fabrics such as underwear fabrics, clothing, wallpaper, chair upholstery, vehicle interior materials, curtains, carpets, shoe interior materials, shoe insoles and the like.
  • the method for applying is not particularly limited, and examples thereof include a spray method, a dipping method, a coating method, and a padding method.
  • the pile yarn, the base fabric, and the backing layer may be applied in a single state, or the coating liquid may be applied in the form of a skin layer in which the pile yarn is planted on the base fabric. Alternatively, it may be applied in a form in which the skin layer and the backing layer are bonded and integrated through the adhesive layer.
  • a sealing layer with a deodorizing antibacterial function by mixing a deodorizing antibacterial composition into the processing liquid of a sealing layer, and apply
  • a curtain it may be applied by a spraying method after sewing, or may be applied and dried by a dipping method, a coating method, a padding method or the like in a fabric state.
  • the heat treatment temperature is preferably 100 ° C. to 180 ° C.
  • the deodorant antibacterial fabric of the present invention is obtained by fixing the deodorant antibacterial composition to at least a part of the fabric.
  • the deodorant antibacterial fabric of the present invention is not particularly limited.
  • skin-wearing fabric, clothing, wallpaper, chair upholstery, vehicle interior material, curtain, carpet, shoe interior material, shoe insole In addition to fabrics such as (see FIG. 1), fabrics such as woven fabrics, knitted fabrics, non-woven fabrics, and moquettes can be used.
  • the fiber constituting the deodorant antibacterial fabric is not particularly limited.
  • polyester fiber, polyamide fiber, polypropylene fiber, acrylic fiber, rayon fiber and the like are preferably used.
  • Natural fibers such as wool are also used.
  • Example 1 Hydrazide compound (sebacate dihydrazide; average particle size 1 ⁇ m) 2 parts by mass, aluminum tripolyphosphate (average particle size 2 ⁇ m) 3 parts by mass, zeolite (average particle size 5 ⁇ m) 3 parts by mass, zirconium hydroxide (average particle size 1 ⁇ m) 1 2 parts by mass of zinc oxide (average particle size 15 ⁇ m), 2 parts by mass of silver-supporting inorganic porous material (silver-supported zeolite; average particle size 20 ⁇ m), 0.5 part by mass of sodium alpha olefin sulfonate, polyoxyalkylene alkyl After mixing 1 part by mass of ether with 73 parts by mass of water and stirring sufficiently, 12.5 parts by mass of a urethane resin is further mixed and stirred with a stirrer to obtain a dispersion (deodorant). An antibacterial composition liquid) was obtained.
  • a urethane resin is further mixed and stirred with a stirrer to
  • a polyester stitchbonded nonwoven fabric (weight per unit: 140 g / m 2 ) was immersed in the dispersion for 5 seconds, then taken out, squeezed with mangles, and dried at 130 ° C. for 15 minutes to remove the deodorant shown in FIG. An antibacterial fabric was obtained.
  • the solid content application amount of the deodorant antibacterial composition in the deodorant antibacterial fabric was 5.4 g / m 2 .
  • the adhering amount (dry state) of each component in the deodorant antibacterial fabric was as follows: carbodihydrazide: 0.4 g / m 2 , aluminum tripolyphosphate: 0.6 g / m 2 , zeolite: 0.6 g / m 2 , zirconium hydroxide : 0.2 g / m 2 , zinc oxide: 0.4 g / m 2 , silver-supporting inorganic porous material (silver-supported zeolite): 0.4 g / m 2 , sodium alpha olefin sulfonate: 0.1 g / m 2 , Polyoxyalkylene alkyl ether: 0.2 g / m 2 and urethane resin: 2.5 g / m 2 .
  • Examples 2 to 8 Comparative Examples 1 to 8> A deodorized antibacterial fabric was obtained in the same manner as in Example 1 except that the composition (formulation, blending ratio, etc.) was changed to the composition shown in Tables 1 and 2.
  • ⁇ Storage stability evaluation method of deodorant antibacterial composition liquid The deodorized antibacterial composition liquid was allowed to stand in a 45 ° C. constant temperature bath for 7 days, and then the taken out deodorized antibacterial composition liquid was visually observed and evaluated based on the following criteria. (Criteria) “ ⁇ ”: none of the solidification, sedimentation and separation of water was observed. “ ⁇ ”: at least one phenomenon of solidification, sedimentation and separation of water was observed. .
  • ⁇ Friction test method The deodorant antibacterial fabric was subjected to a friction test (friction frequency: 30 reciprocations) using a friction tester type II in accordance with JIS L0849, and evaluated based on the following criteria. “ ⁇ ”: Desorption of the deodorant antibacterial composition (component) was not observed “ ⁇ ”: Desorption of the deodorant antibacterial composition (component) was slightly observed “X”: Deodorant antibacterial composition ( A relatively large amount of component) was observed.
  • ⁇ Deodorization performance evaluation method> After putting a test piece (10 cm ⁇ 10 cm) of deodorant antibacterial fabric in a bag having an internal volume of 3 L, ammonia gas is injected so that the concentration is 200 ppm in the bag, and the remaining concentration of ammonia gas is measured after 20 minutes. The total amount from which ammonia gas was removed was calculated from the measured value, and the ammonia gas removal rate (deodorization rate) (%) was calculated therefrom. “ ⁇ ”: The removal rate is 80% or more “ ⁇ ”: The removal rate is 60% or more and less than 80% “X”: The removal rate is less than 60%.
  • the test was conducted according to JIS L1902-2008 (antibacterial test method and antibacterial effect of textile products).
  • the target test bacterium is S. aureus.
  • the bacteriostatic activity value was calculated by the following calculation formula and evaluated based on the following criteria.
  • Bacteriostatic activity value (Mb-Ma)-(Mc-Mo) Mb: Average value of common logarithmic values of bacteriostatic counts of 3 samples after 18 hours of culturing unprocessed standard fabric
  • Ma Average value of common logarithmic values of bacteriostatic counts of 3 samples immediately after inoculation of test bacteria on unprocessed standard fabric
  • Mc Average value of common logarithmic values of the number of bacteriostatics of three samples after 18 hours of culturing antibacterial fabrics
  • Mo Average value of common logarithmic values of the number of bacteriostatics of three samples immediately after inoculation of test bacteria on antibacterial fabrics (determination Standard)
  • ⁇ Bacteriostatic activity value is 2.2 or more.
  • ⁇ Bacteriostatic activity value is less than 2.2.
  • the fabric used for the deodorization performance evaluation method and the antibacterial performance evaluation method is the SEK mark fiber product laundry manual (JEC326) for each of the deodorization antibacterial fabrics of Examples 1 to 8 and Comparative Examples 1 to 8.
  • the cloth (washed cloth) after being washed according to the revision on April 1, 2012, in accordance with the Japan Fiber Evaluation Technology Council) was used. That is, in the washing, the washing machine uses a washing machine having a standard washing capacity and a standard amount of water with a centrifugal squeezing device conforming to the JIS C9606 standard defined in JIS L0217 washing method 103. A “standard detergent” was used.
  • the fabric after washing in this way was subjected to the above deodorant performance evaluation and antibacterial performance evaluation.
  • the deodorizing antibacterial compositions of Examples 1 to 8 according to the present invention are excellent in storage stability without gelation and aggregate formation over a long period of time, and therefore the deodorizing antibacterial composition of the present invention.
  • the composition liquid can stably provide a deodorized antibacterial fabric excellent in deodorizing performance and antibacterial performance even when the fabric is processed after long-term storage.
  • the deodorant antibacterial fabrics of Examples 1 to 8 according to the present invention did not release the deodorant antibacterial composition even when the friction test was performed, and were excellent in both the deodorant performance and the antibacterial performance.
  • the deodorant antibacterial composition according to the present invention is applied and fixed to, for example, a fabric and used to provide the fabric with excellent deodorant performance and antibacterial performance, but is particularly limited to such applications. It is not a thing.
  • the deodorant antibacterial fabric according to the present invention is not particularly limited, for example, underwear fabric, clothing, wallpaper, chair upholstery, vehicle interior material, curtain, carpet, shoe interior material, shoe insole Etc. are preferably used.

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Biochemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Veterinary Medicine (AREA)
  • Microbiology (AREA)
  • Public Health (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

L'invention fournit une composition désodorisante et antibactérienne qui tout en permettant de développer d'excellentes fonctions désodorisantes y compris après un lavage répété, est dotée d'excellentes fonctions antibactériennes, et d'une stabilité au stockage satisfaisante. La composition désodorisante et antibactérienne de l'invention est caractéristique en ce qu'elle comprend : un composé amine, un agent désodorisant inorganique, un premier sel constitué d'un phosphate de métal, un agent antibactérien inorganique, au moins une sorte de second sel choisie dans un groupe constitué d'un sulfonate et d'un carboxylate, et une résine de liant.
PCT/JP2012/083942 2012-12-27 2012-12-27 Composition désodorisante et antibactérienne, et tissu désodorisant et antibactérien Ceased WO2014102980A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/JP2012/083942 WO2014102980A1 (fr) 2012-12-27 2012-12-27 Composition désodorisante et antibactérienne, et tissu désodorisant et antibactérien
JP2014553974A JPWO2014102980A1 (ja) 2012-12-27 2012-12-27 消臭抗菌組成物及び消臭抗菌布帛

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2012/083942 WO2014102980A1 (fr) 2012-12-27 2012-12-27 Composition désodorisante et antibactérienne, et tissu désodorisant et antibactérien

Publications (1)

Publication Number Publication Date
WO2014102980A1 true WO2014102980A1 (fr) 2014-07-03

Family

ID=51020132

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2012/083942 Ceased WO2014102980A1 (fr) 2012-12-27 2012-12-27 Composition désodorisante et antibactérienne, et tissu désodorisant et antibactérien

Country Status (2)

Country Link
JP (1) JPWO2014102980A1 (fr)
WO (1) WO2014102980A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017070384A (ja) * 2015-10-06 2017-04-13 住江織物株式会社 消臭機能付き粘着不織布
JP2018143595A (ja) * 2017-03-07 2018-09-20 住江織物株式会社 消臭抗菌防水シート及び該消臭抗菌防水シートを用いた寝具用シート及びベッドパット
WO2018203536A1 (fr) * 2017-05-01 2018-11-08 大阪ガスケミカル株式会社 Agent d'absorption de substance odorante
JP2018187336A (ja) * 2017-05-01 2018-11-29 大阪ガスケミカル株式会社 臭気物質吸着剤
WO2021166417A1 (fr) * 2020-02-21 2021-08-26 パナソニックＩｐマネジメント株式会社 Composition de résine
JP2022158064A (ja) * 2021-04-01 2022-10-14 Ｔｂカワシマ株式会社 抗菌・抗ウイルス性シート
JP2024107560A (ja) * 2023-01-30 2024-08-09 本田技研工業株式会社 繊維製品及びその製造方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62231076A (ja) * 1986-03-28 1987-10-09 東海染工株式会社 セルロ−ス系繊維含有構造体の耐久性消臭加工法
JP2006336176A (ja) * 2005-06-06 2006-12-14 Nicca Chemical Co Ltd 消臭性繊維製品及びその製造方法
JP2008054705A (ja) * 2006-08-29 2008-03-13 Suminoe Textile Co Ltd 消臭ぬいぐるみ
JP2009090012A (ja) * 2007-10-11 2009-04-30 Nippon Zeon Co Ltd 消臭剤及びこの消臭剤を用いた繊維製品
JP2009106736A (ja) * 2007-10-11 2009-05-21 Nippon Zeon Co Ltd 消臭剤及びこの消臭剤を用いた繊維製品
WO2009110590A1 (fr) * 2008-03-07 2009-09-11 ライオン株式会社 Composition stérile/antibactérienne
JP2009285164A (ja) * 2008-05-29 2009-12-10 Suminoe Textile Co Ltd 消臭組成物及びその消臭組成物を付着した消臭布帛

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62231076A (ja) * 1986-03-28 1987-10-09 東海染工株式会社 セルロ−ス系繊維含有構造体の耐久性消臭加工法
JP2006336176A (ja) * 2005-06-06 2006-12-14 Nicca Chemical Co Ltd 消臭性繊維製品及びその製造方法
JP2008054705A (ja) * 2006-08-29 2008-03-13 Suminoe Textile Co Ltd 消臭ぬいぐるみ
JP2009090012A (ja) * 2007-10-11 2009-04-30 Nippon Zeon Co Ltd 消臭剤及びこの消臭剤を用いた繊維製品
JP2009106736A (ja) * 2007-10-11 2009-05-21 Nippon Zeon Co Ltd 消臭剤及びこの消臭剤を用いた繊維製品
WO2009110590A1 (fr) * 2008-03-07 2009-09-11 ライオン株式会社 Composition stérile/antibactérienne
JP2009285164A (ja) * 2008-05-29 2009-12-10 Suminoe Textile Co Ltd 消臭組成物及びその消臭組成物を付着した消臭布帛

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017070384A (ja) * 2015-10-06 2017-04-13 住江織物株式会社 消臭機能付き粘着不織布
JP2018143595A (ja) * 2017-03-07 2018-09-20 住江織物株式会社 消臭抗菌防水シート及び該消臭抗菌防水シートを用いた寝具用シート及びベッドパット
WO2018203536A1 (fr) * 2017-05-01 2018-11-08 大阪ガスケミカル株式会社 Agent d'absorption de substance odorante
JP2018187336A (ja) * 2017-05-01 2018-11-29 大阪ガスケミカル株式会社 臭気物質吸着剤
WO2021166417A1 (fr) * 2020-02-21 2021-08-26 パナソニックＩｐマネジメント株式会社 Composition de résine
JP2022158064A (ja) * 2021-04-01 2022-10-14 Ｔｂカワシマ株式会社 抗菌・抗ウイルス性シート
JP7545359B2 (ja) 2021-04-01 2024-09-04 Ｔｂカワシマ株式会社 抗菌・抗ウイルス性シート
JP2024107560A (ja) * 2023-01-30 2024-08-09 本田技研工業株式会社 繊維製品及びその製造方法
JP7614238B2 (ja) 2023-01-30 2025-01-15 本田技研工業株式会社 繊維製品及びその製造方法

Also Published As

Publication number Publication date
JPWO2014102980A1 (ja) 2017-01-12

Similar Documents

Publication Publication Date Title
JPWO2014102980A1 (ja) 消臭抗菌組成物及び消臭抗菌布帛
JP2009285164A (ja) 消臭組成物及びその消臭組成物を付着した消臭布帛
EP0287132A2 (fr) Substrat contenant un détergent pour le linge et enrobé avec un polymère anti-salissure
JP2014000292A (ja) 消臭組成物及び消臭布帛
JPS6393324A (ja) 防臭シ−ト
JP6146794B2 (ja) 消臭抗アレルゲン組成物が付着した繊維製品
JPS6342978A (ja) 洗濯物乾燥機における織物の状態調節用物品
WO2016158013A1 (fr) Composition désodorisante, tissu désodorisant, et produit fibreux
JP2008255507A (ja) 消臭布帛
TW201424780A (zh) 除臭抗菌組成物及除臭抗菌布帛
JP2013051993A (ja) 消臭組成物及びその消臭組成物を付着した消臭布帛
JP2016214618A (ja) 消臭水性液
US5004563A (en) Antistatic textile compositions and sol/gel/polymer compositions
JP2009221621A (ja) 消臭布帛及びその製造方法
JP5694000B2 (ja) 消臭組成物及びその消臭組成物を付着した消臭布帛
JP2017197884A (ja) 優れた消臭抗菌性能を有する衛生用品用繊維布帛
WO2017123637A1 (fr) Substrat traité par composé métallique amphotère et procédés de réduction des odeurs corporelles au moyen des substrats traités
JP2004300660A (ja) 繊維柔軟剤組成物
CN101146886A (zh) 变应原失活剂
JP2010163714A (ja) 繊維製品処理方法
JP2002069837A (ja) 消臭性布帛
US3981741A (en) Fibrous cleaning materials impregnated with a latex-mixture
JP2017070384A (ja) 消臭機能付き粘着不織布
JP4869635B2 (ja) 消臭性繊維製品及びその製造方法
JP2014042728A (ja) 消臭カーペットの製造方法及び消臭カーペット

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12890966

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2014553974

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12890966

Country of ref document: EP

Kind code of ref document: A1