WO2014128171A2 - Composition cosmétique comprenant un polysaccharide extrudé - Google Patents

Composition cosmétique comprenant un polysaccharide extrudé Download PDF

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Publication number
WO2014128171A2
WO2014128171A2 PCT/EP2014/053248 EP2014053248W WO2014128171A2 WO 2014128171 A2 WO2014128171 A2 WO 2014128171A2 EP 2014053248 W EP2014053248 W EP 2014053248W WO 2014128171 A2 WO2014128171 A2 WO 2014128171A2
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WO
WIPO (PCT)
Prior art keywords
weight
ethanol
premix
acid
hair
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2014/053248
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English (en)
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WO2014128171A3 (fr
Inventor
Julien PORTAL
Franck Hernandez
Xavier Schultze
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LOreal SA
Original Assignee
LOreal SA
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Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Publication of WO2014128171A2 publication Critical patent/WO2014128171A2/fr
Publication of WO2014128171A3 publication Critical patent/WO2014128171A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • Cosmetic composition comprising an extruded polysaccharide
  • the invention relates to a cosmetic composition
  • a cosmetic composition comprising the water-soluble fraction of an extrudate comprising a polysaccharide, and also to a method for the treatment of the hair, in particular for its shaping, using such a composition
  • the consumer In the styling field, in particular for products intended for the shaping and/or form retention of the hairstyle, the consumer is looking for styling products exhibiting good fixing properties.
  • compositions essentially composed of a solution, generally an alcoholic or aqueous/alcoholic solution, and of film-forming polymers (fixing components), the role of which is to form joins between the keratinous fibers.
  • the quality of the spray greatly conditions the nature of the joins created between the hairs, the homogeneity of the depositions, the fixing properties and the feel.
  • Very few polymers of natural origin are sufficiently fixing and conveyable in water or a water/ethanol mixture to be able to be used in hair compositions for shaping the hair.
  • polysaccharides such as starch or gum arabic
  • starch or gum arabic are not soluble in ethanol and, when they are conveyed in water, they form excessively viscous gels inap-litiste for being packaged in the spray or aerosol lacquer form. Nevertheless, these polysaccharides exhibit advantageous hair fixing properties.
  • the aim of the present invention is thus to have available styling products exhibiting good hair fixing properties, based on polymer of natural origin, which are con- veyed in an aqueous medium or in a water/ethanol medium and which can be dispensed in the spray form.
  • a subject matter of the present invention is thus a process for the preparation of a cosmetic composition comprising the following stages:
  • polycarboxylic acid comprising from 4 to 8 carbon atoms or the anhydride of said acid
  • said premix is kneaded under shearing, at a temperature between 100°C and 250°C, in order to form an extrudate; c) cooling the extrudate to a temperature of less than 100°C; d) introducing the cooled extrudate into water or into a water/ethanol mixture comprising from 0% to 75% (or 0.1 % to 75%) by weight of ethanol; e) recovering the filtrate obtained.
  • composition thus obtained according to the preparation process comprises, in an aqueous or aqueous/alcoholic medium, the fraction soluble in water at ambient temperature (25°C) of the extrudate obtained according to stage b).
  • This water- soluble fraction corresponds to the isolated filtrate obtained according to stage e) of the preparation process.
  • Another subject matter of the invention is a cosmetic composition capable of being obtained according to the preparation process described above.
  • Another subject matter of the invention is a method for the cosmetic treatment of the hair, comprising the application to the hair of a cosmetic composition as described above.
  • the method is in particular a method for fixing and/or shaping the hair.
  • the premix also known as extrusion premix
  • ethanol-insoluble polysaccharide is understood to mean a polysaccharide for which the solubility in ethanol at 25°C is less than 1 % by weight.
  • the ethanol-insoluble polysaccharide can be chosen from starch, cellulose, guar gum, gum arabic (INCI name: acacia Senegal gum), alginic acid, alginate salts (in particular sodium, calcium and zinc salts) and carrageenans.
  • the ethanol-insoluble polysaccharide is chosen from starch or gum arabic.
  • the ethanol-insoluble polysaccharide is starch.
  • the ethanol-insoluble polysaccharide is a fixing polymer.
  • fixing polymer is understood to mean a polymer capable, by application to the hair, of conferring a shape on the head of hair or of making possible the form retention of a shape already acquired.
  • the ethanol-insoluble polysaccharide has a weight-average molecular weight ranging from 10 000 to 2 000 000 g/mol.
  • the ethanol-insoluble polysaccharide can be present in the premix in a content ranging from 55% to 85% by weight, preferably ranging from 60% to 80% by weight, with respect to the total weight of the premix.
  • the premix also comprises an ethanol-soluble polymer.
  • ethanol-soluble polymer is understood to mean a polymer having a solubility of at least 5% by weight in ethanol at 25°C.
  • the ethanol-soluble polymer is a fixing polymer.
  • the ethanol-soluble polymer can be chosen from ethylcellulose, hydroxypropylcel- lulose, hydroxyethyl ethylcelluloses (for example Bermocoll E 481 FQ from Akzo Nobel), carboxymethylethylcelluloses and their sodium salts, carboxymethylhy- droxyethylcelluloses and their sodium salts, polyvinyl alcohol, poly(C2-C 4 hy- droxyalkyl (meth)acrylate)s, such as poly(2-hydroxyethyl methacrylate) or poly(2- hydroxyethyl acrylate), polyvinylpyrrolidone or poly(2-ethyl-2-oxazoline).
  • Hydroxypropylcellulose is preferably used.
  • the ethanol-soluble polymer has a weight-average molecular weight ranging from 10 000 to 2 000 000 g/mol.
  • the ethanol-soluble polymer can be present in the premix in a content ranging from 10% to 40% by weight, preferably ranging from 10% to 30% by weight, pref- erably ranging from 10% to 20% by weight, with respect to the total weight of the premix.
  • the presence of the ethanol-soluble polymer and in particular of hydroxypropylcellulose makes it possible to carry out the extrusion stage b) (kneading under shear- ing) at a temperature between 100°C and 250°C, as is shown in the comparative examples described below.
  • This stage would be impossible to carry out in the absence of this ethanol-soluble polymer and would require the use of a conventional plasticizing agent, such as glycerol or sorbitol, in order to be able to extrude the polysaccharide, in particular starch, under these conditions without bringing about its deterioration.
  • the premix also comprises a polycarboxylic acid comprising from 4 to 8 carbon atoms or the anhydride of said acid.
  • the polyacid can be a dicarboxylic acid or a tricarboxylic acid. Said polyacid can be hydroxylated.
  • the polycarbox- ylic acid comprises from 4 to 6 carbon atoms.
  • the polycarboxylic acid or its anhydride can be chosen from maleic acid, maleic anhydride, succinic acid, succinic anhydride, itaconic acid, itaconic anhydride, tartaric acid, phthalic acid, phthalic anhydride or citric acid.
  • the polycarboxylic acid is chosen from maleic acid, maleic anhydride or tartaric acid.
  • the polycarboxylic acid can be present in the premix in a content ranging from 0.1 % to 30% by weight and preferably ranging from 1 % to 20% by weight, with respect to the total weight of the premix.
  • the extrusion premix can comprise a plasticizing agent.
  • the plasticizing agent can be added during the kneading stage.
  • the plasticizing agent makes it possible to lower the melting point of the polysaccharide. It thus makes possible easy processing of the polysaccharide in the process for the preparation of the cosmetic composition according to the invention
  • the plasticizing agent is liquid at ambient temperature (25°C) or else is solid and, in this case, has a melting point of less than 100°C.
  • the plasticizing agent can be chosen from:
  • glycerol ethylene glycol, propylene glycol, 1 ,4-propanediol, 1 ,2-butanediol, 1 ,3- butanediol, 1 ,4-butanediol, 1 ,5-pentanediol, 1 ,5-hexanediol, 1 ,6-hexanediol, 1 ,2,6- hexanetriol, 1 ,3,5-hexanetriol, neopentyl glycol, polyethylene glycols having a molecular weight ranging from 200 to 1500 g/mol, polypropylene glycols having a molecular weight ranging from 200 to 1500 g/mol, sorbitol (solid), sorbitol monoace- tate, sorbitol diacetate, sorbitol monoethoxylate, sorbitol diethoxylate, sorbitol hex- aeth
  • the plasticizing agent can be present in the extrusion premix or added in the kneading stage in a content ranging from 0% (or 0.1 %) to 39.9% by weight, pref- erably ranging from 0% (or 0.1 %) to 30% by weight, preferably ranging from 1 % to 20% by weight and more preferably ranging from 2% to 15% by weight, with respect to the total weight of the premix.
  • the extrusion premix com- prises the extrusion premix com- prises:
  • the extrusion premix comprises:
  • the process can comprise a stage of addition of the plasticizing agent during the kneading stage b).
  • the plasticizing agent can be introduced during the kneading stage and not before the kneading stage.
  • the preparation process according to the invention can comprise a stage of grind- ing the extrudate obtained after the kneading stage.
  • the grinding can be carried out by any known means which makes it possible to convert the extrudate into a powder.
  • the kneading stage b) of the preparation process described above can be carried out using a screw mixer/extruder.
  • the premix is kneaded under shearing in order to create, in the body, regions of crushing the premix.
  • the kneading stage is carried out with a screw mixer/extruder.
  • a screw mixer/extruder Such a kneading process is described in particular in the document EP-A-0 667 146.
  • the screw of the mixer/extruder can rotate at a speed ranging from 1 to 1000 revolutions/minute, preferably ranging from 1 to 250 revolutions/minute.
  • extruders of twin-screw mixer/extruder type these extruders being composed of the following elements:
  • At least one or more barrels independently thermally regulated at a temperature ranging from 100°C to 300°C, - two corotating shafts composed of screw elements, each element having a shape which provides the desired mixing function in the corresponding temperature zone,
  • the extrudate formed is subsequently cooled to a temperature of less than 100°C.
  • the extrudate formed is cooled to ambient temperature (25°C).
  • the cosmetic composition obtained according to the preparation process described above comprises the portion of the extrudate soluble at ambient temperature (25°C) in water or in a water/ethanol mixture comprising from 0% to 75% by weight of ethanol (or comprising up to 75% by weight of ethanol, or comprising from 0.1 % to 75% by weight of ethanol), subsequently known as water-soluble fraction of the extrudate. It corresponds to the filtrate isolated after introduction of the extrudate into water or the water/ethanol mixture.
  • cosmetic composition is understood to mean a composition compatible with keratinous substances, which exhibits a pleasant color, odor and feel and which does not cause unacceptable discomfort (stinging, tautness or redness) liable to turn the consumer away from it.
  • keratinous substances is understood to mean the skin (body, face, outline of the eyes, scalp), head hair, eyelashes, eyebrows, non-head hairs, nails or lips.
  • the wa- ter-soluble fraction of the extrudate can be present in a content, as dry matter, ranging from 1 % to 10% by weight and preferably ranging from 2% to 7% by weight, with respect to the total weight of the composition.
  • composition according to the invention can comprise additional cosmetic in- gredients chosen in particular from preservatives, fragrances, sunscreens, oils, waxes, thickeners, film-forming polymers, moisturizing agents, vitamins, proteins, ceramides, surfactants, antioxidants, agents for combating free radicals, colorants, antidandruff agents, chelating agents, propellants or fillers.
  • additional cosmetic in- gredients chosen in particular from preservatives, fragrances, sunscreens, oils, waxes, thickeners, film-forming polymers, moisturizing agents, vitamins, proteins, ceramides, surfactants, antioxidants, agents for combating free radicals, colorants, antidandruff agents, chelating agents, propellants or fillers.
  • additional cosmetic in- gredients chosen in particular from preservatives, fragrances, sunscreens, oils, waxes, thickeners, film-forming polymers, moisturizing agents, vitamins, proteins, ceramides, surfactants, antioxidants,
  • the cosmetic composition according to the invention has a viscosity ranging from 0.001 to 3 Pa.s (1 to 3000 centipoises), preferably ranging from 0.01 to 1 Pa.s (10 to 1000 centipoises) and preferably ranging from 0.03 to 0.5 Pa.s (30 to 500 centipoises), measured using a Brookfield DV-I+ viscometer, at 25°C, with the SC4-31 spindle at the rotational speed of 25 revolutions/minute.
  • a viscosity ranging from 0.001 to 3 Pa.s (1 to 3000 centipoises), preferably ranging from 0.01 to 1 Pa.s (10 to 1000 centipoises) and preferably ranging from 0.03 to 0.5 Pa.s (30 to 500 centipoises), measured using a Brookfield DV-I+ viscometer, at 25°C, with the SC4-31 spindle at the rotational speed of 25 revolutions/minute.
  • Such a composition is suited to being packaged as
  • composition according to the invention can be in the form of a lacquer, spray, gel, foam, cream or lotion.
  • the composition can be packaged in an aerosol.
  • the propellant(s) are chosen from non-liquefied compressed gases, such as air, nitrogen, nitrous oxide, carbon dioxide or dimethyl ether, or else from liquefied gases, such as volatile C3-C5 hydrocarbons, for example n-butane, isobutane, propane, pentane and halogenated hydrocarbons, such as 1 ,1 -difluoroethane, and their mixtures.
  • the pro- pellant is chosen from dimethyl ether and a propane/n-butane/isobutane mixture.
  • the propellant can be present in the composition according to the invention in proportions preferably ranging from 0.1 % to 60% by weight, more preferably from 1 .5% to 50% by weight and better still from 2% to 30% by weight, with respect to the total weight of the composition.
  • the propellant when it is a volatile C3-C5 hydrocarbon, it can be present in the composition in proportions preferably ranging from 0.1 % to 60% by weight, more preferably from 0.5% to 30% by weight and better still from 0.5% to 8% by weight, with respect to the total weight of the composition.
  • the propellant when it is a gas partially soluble in the composition, such as dimethyl ether or 1 ,1 -difluoroethane, it can be present in the composition in proportions preferably ranging from 10% to 50% by weight, more preferably from 30% to 45% by weight, with respect to the total weight of the composition.
  • the aerosol device used to package the composition of the invention can be composed of an aerosol can equipped with a dispensing valve and an actuator.
  • composition can also be packaged in a pump-action spray.
  • the examples below illustrate the invention without, however, limiting the scope thereof.
  • the extrusion premix was prepared by mixing all of the ingredients (one-stage process). In another alternative form of the preparation process, the plasticizing agent was added during the stage of kneading the extrusion premix (2-stage proc- ess).
  • extrudates were prepared using a twin-screw extruder (microextruder from DSM), at an extrusion speed of 80 revolutions/minute, at a temperature of 170°C, by applying an extrusion force of between 200 and 6000 newtons (force indicated by the extruding device).
  • the hair solution was packaged in a pump-action spray.
  • the quality of the spray obtained was subsequently determined as a function of the width of the dispensed spray.
  • the quality of the spray is regarded as good when the spray is broad and well covering the sprayed surface; it is poor when the spray is narrow, forms a highly directional jet and is not very covering.
  • the fixing qualities of the hair lotion were also determined by applying the spray 5 times to a lock of hair. After drying, it was evaluated whether the hair was or was not well fixed.
  • Extrudates of starch, hydroxypropylcellulose and maleic anhydride Compositions of the extrudates prepared (contents as percentage by weight):
  • Extrudates 1 to 3 confer good properties of spray quality and of fixing of the treated locks of hair.
  • compositions of the extrudates prepared:
  • Extrudates 4 to 9 confer good properties of spray quality and of fixing of the treated locks of hair.
  • Extrudate 5' is not 10% soluble in the 70/30 water/ethanol mixture and forms a precipitate. It does not make it possible to prepare a sprayable hair composition.
  • compositions of the extrudates prepared:
  • Extrudates 10 to 15 confer good properties of spray quality and of fixing of the treated locks of hair.
  • the aqueous/alcoholic solutions prepared with extrudates 16, 17 and 18 were filtered in order to obtain the hair lotion.
  • Extrudates 16 to 21 confer good properties of spray quality and of fixing of the treated locks of hair.
  • Extrudates of starch, hydroxypropylcellulose, tartaric acid and glycerol Compositions of the extrudates prepared: Hydroxy- Tartaric Extrusion
  • Extrudates 20 to 27 confer good properties of spray quality and of fixing of the treated locks of hair.
  • Composition of the extrudate 22' prepared:
  • Extrudate 22' is not 10% soluble in the 70/30 water/ethanol mixture and forms a precipitate. It does not make it possible to prepare a sprayable hair composition.
  • compositions of the extrudates prepared:
  • the aqueous/alcoholic solutions prepared with extrudates 28 to 30 were filtered in order to obtain the hair lotion.
  • Extrudates 28 to 30 confer good properties of spray quality and of fixing of the treated locks of hair.
  • Example 31 (outside the invention): non-extruded starch
  • the solubility properties of the non-extruded starch were evaluated in water and in a 70/30 water/ethanol mixture.
  • the 14% aqueous starch solution exists in the form of a viscous gel.
  • the 10% aqueous/alcoholic starch solution exists in the form of a white, unstable and non-filterable viscous solution; a significant white deposit is formed at the bottom of the flask.
  • the 2 solutions prepared, packaged in a pump-action spray, are not sprayable.
  • the 14% aqueous solution of the starch and hydroxypropylcellulose mixture exists in the form of a viscous gel.
  • the 10% aqueous/alcoholic solution of the starch and hydroxypropylcellulose mixture exists in the form of a white, unstable and non-filterable viscous solution; a significant white deposit is formed at the bottom of the flask.
  • Example 33 (outside the invention): extruded starch/hydroxypropylcellulose
  • a mixture formed of 80% by weight of starch and 20% by weight of hydroxypropylcellulose was extruded at 170°C with a speed of the screws of 80 rev/min and a recorded extrusion force of 4400 N .
  • the solubility properties of the extrudate obtained were evaluated: the 10% aqueous/alcoholic extrudate solution exists in the form of a heterogeneous solution; a solid phase settles out at the bottom of the flask.
  • the aqueous/alcoholic solution prepared with extrudate 34 was filtered in order to obtain the hair lotion.
  • Extrudate 34 confers good properties of spray quality and of fixing of the treated locks of hair.
  • the contents are expressed as percentage by weight.
  • the aerosol compositions were packaged in a pump-action spray.
  • Composition 35 pump-action spray
  • Composition 36 pump-action spray
  • Composition 37 pump-action spray
  • Compositions 35 to 38 are applied to dry hair at ambient temperature and without rinsing.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

Cette invention concerne un procédé de préparation d'une composition cosmétique obtenue par malaxage, à une température comprise entre 100 et 250°C, d'un prémélange comprenant un polysaccharide insoluble dans l'éthanol, un polymère soluble dans l'éthanol et un acide polycarboxylique comprenant de 4 à 8 atomes de carbone, puis introduction de l'extrudat formé, refroidi au préalable, dans l'eau ou un mélange eau/éthanol, et récupération du filtrat. La composition cosmétique selon l'invention est appliquée au traitement cosmétique des cheveux, en particulier pour la fixation ou la mise en forme des cheveux.
PCT/EP2014/053248 2013-02-22 2014-02-19 Composition cosmétique comprenant un polysaccharide extrudé Ceased WO2014128171A2 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR1351548 2013-02-22
FR1351548A FR3002445B1 (fr) 2013-02-22 2013-02-22 Composition cosmetique comprenant un polysaccharide extrude
US201361773198P 2013-03-06 2013-03-06
US61/773,198 2013-03-06

Publications (2)

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WO2014128171A2 true WO2014128171A2 (fr) 2014-08-28
WO2014128171A3 WO2014128171A3 (fr) 2014-10-30

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WO (1) WO2014128171A2 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180103958A (ko) * 2016-01-19 2018-09-19 노바몬트 에스.피.에이. 연마재 및/또는 구조화제로서의, 복합 형태인 분해 전분을 포함하는 조성물의 용도
EP3405171A1 (fr) * 2016-01-19 2018-11-28 Novamont S.p.A. Utilisation d'amidon déstructuré comme agent épaississant et composition contenant celui-ci
CN109549864A (zh) * 2019-01-18 2019-04-02 花安堂生物科技集团有限公司 一种乳化型祛斑化妆品及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0667146A1 (fr) 1994-01-25 1995-08-16 L'oreal Composition cosmétique ou dermopharmaceutique sous forme de pâte souple et procédé de préparation

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2209813T3 (es) * 1999-01-25 2004-07-01 Ecosynthetix Inc. Nanoparticulas de biopolimeros.
US20110212145A1 (en) * 2010-03-01 2011-09-01 Honeywell International Inc. Hair fixatives comprising cross linked starches

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0667146A1 (fr) 1994-01-25 1995-08-16 L'oreal Composition cosmétique ou dermopharmaceutique sous forme de pâte souple et procédé de préparation

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180103958A (ko) * 2016-01-19 2018-09-19 노바몬트 에스.피.에이. 연마재 및/또는 구조화제로서의, 복합 형태인 분해 전분을 포함하는 조성물의 용도
EP3405171A1 (fr) * 2016-01-19 2018-11-28 Novamont S.p.A. Utilisation d'amidon déstructuré comme agent épaississant et composition contenant celui-ci
JP2019506388A (ja) * 2016-01-19 2019-03-07 ノバモント・ソシエタ・ペル・アチオニＮｏｖａｍｏｎｔ Ｓｏｃｉｅｔａ Ｐｅｒ Ａｚｉｏｎｉ 研磨剤および／または構造化剤としての複合体化された形態の破壊澱粉を含む組成物の使用
KR102786038B1 (ko) * 2016-01-19 2025-03-24 노바몬트 에스.피.에이. 연마재 및/또는 구조화제로서의, 복합 형태인 분해 전분을 포함하는 조성물의 용도
CN109549864A (zh) * 2019-01-18 2019-04-02 花安堂生物科技集团有限公司 一种乳化型祛斑化妆品及其制备方法

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FR3002445B1 (fr) 2015-03-06
FR3002445A1 (fr) 2014-08-29
WO2014128171A3 (fr) 2014-10-30

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