WO2016102873A1 - Textile pour la fabrication de vêtements de protection contre le feu - Google Patents

Textile pour la fabrication de vêtements de protection contre le feu Download PDF

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Publication number
WO2016102873A1
WO2016102873A1 PCT/FR2015/053699 FR2015053699W WO2016102873A1 WO 2016102873 A1 WO2016102873 A1 WO 2016102873A1 FR 2015053699 W FR2015053699 W FR 2015053699W WO 2016102873 A1 WO2016102873 A1 WO 2016102873A1
Authority
WO
WIPO (PCT)
Prior art keywords
type
layer
fibers
son
threads
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2015/053699
Other languages
English (en)
French (fr)
Inventor
Sébastien Chatard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Europrotect France SA
Original Assignee
Europrotect France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Europrotect France SA filed Critical Europrotect France SA
Priority to BR112017013578-7A priority Critical patent/BR112017013578B1/pt
Priority to JP2017533813A priority patent/JP7118643B2/ja
Priority to PL15832816T priority patent/PL3237659T3/pl
Priority to DK15832816.1T priority patent/DK3237659T3/da
Priority to CN201580070507.7A priority patent/CN107109719A/zh
Priority to SI201531702T priority patent/SI3237659T1/sl
Priority to ES15832816T priority patent/ES2887081T3/es
Priority to EP15832816.1A priority patent/EP3237659B1/fr
Publication of WO2016102873A1 publication Critical patent/WO2016102873A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00Double or multi-ply fabrics not otherwise provided for
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D13/00Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
    • D03D13/008Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/43Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads with differing diameters
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/10Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
    • D10B2321/101Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide modacrylic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/04Heat-responsive characteristics

Definitions

  • the present invention relates to the field of textiles used for the manufacture of fireproof and heat resistant clothing. It relates more specifically to textiles obtained from fibers known to have good properties of resistance to heat and / or flame. It relates more particularly to textiles obtained by the intimate bonding of two textile layers of distinct compositions having complementary properties. Such intimate binding of the two layers is generally achieved by means of warp or weft threads of one of the layers punctually making a binding loop around a warp or weft thread of the other layer of the textile.
  • textile materials sold in the form of fibers or multi-filaments with very high mechanical and / or thermal performance but which have major disadvantages when used on the outer face of clothing. We speak here of deterioration of the performances with the radiations notably UV or of deterioration of aspect with the use and the washings notably by fibrillation.
  • the applicant has described in EP 1 373 617 a particular structure of textiles used for the manufacture of protective clothing for fire-fighting personnel.
  • These textiles are generally composed of two types of yarns, namely on the one hand meta-aramid-based yarns known for their heat resistance and their good textile features, present on the locus face, and on the other hand para- aramid yarns, used for their better mechanical resistance, mainly present on the reverse side.
  • One of the objectives of the invention is to modify such an arrangement so as to make it possible to produce a double-layer textile, one of the layers of which is substantially closed, thereby guaranteeing good protection against the external aggressions of the textile thus formed, and in particular a good protection. to projections of chemicals in particular.
  • Another objective is to produce a double-layer textile whose face has a good textile behavior, that is to say optimum characteristics of resistance to abrasion, pilling, fibrillation and coloristic and mechanical resistance, radiation including UV, while retaining good textile properties and a color suitable for use.
  • this textile is characterized in that the inner layer comprises son of a third type, different from the son of the second type, these son of the third type having resistance properties to the degradation of their properties. aspect to use and washing greater than those of the son of the second type, said son of the third type also working with the outer face to ensure the binding of the two layers.
  • the invention relates more particularly to a double-layer textile having characteristics of fire resistance and heat in particular.
  • This first fire-resistant layer can thus be considered as non-flammable and thermostable, in particular according to the ISO 14116 standard for which a level 3 index can be reached. According to this test, after applying the flame, the fabric must not show flame spread, inflamed debris, hole formation and flame persistence longer than 2 seconds.
  • the invention therefore relates to a double-layer textile having a first flame retardant layer having good abrasion resistance, pilling and lubrication, a color suitable for use.
  • This layer is formed in warp and weft by weaving threads of a first composition.
  • This textile comprises a second layer formed on the one hand in a material having high mechanical and / or thermal performance and obtained by warp and weft weaving of yarns of a second composition distinct from the first composition, and other part of a third composition which is punctually linked with the son of the first layer to allow to intimately join together the first and second layers of the textile.
  • Such a double-layered textile thus has a face that is easy to decline at the coloristic level in particular and a reverse side comprising a material with high mechanical performance and advantageously thermal.
  • the material having high mechanical and / or thermal performance is present exclusively on one and only one layer, and more precisely the back side.
  • the number of threads per centimeter arranged in warp and / or weft of the first layer is greater than the number of threads per centimeter arranged in warp and / or weft of the second layer.
  • the density in number of threads of the first layer is greater than that of the second layer.
  • the rear face has two populations of son, namely first son high mechanical and / or thermal performance, used as background son, and second son used as bonding son of the two layers, and the characteristics are at least to present a coloration similar to the outer layer, good behavior in use, including coloristic behavior to UV radiation and washes and not to degrade the fire behavior and heat of the textile support .
  • the number of threads per centimeter arranged in a frame may be slightly less than the number of warp threads for the first and the second layer, respectively.
  • the first layer may have armor of the canvas, twill, satin or derived from these basic armor whose weight is between 150 and 250 g / m 2 .
  • the second layer is advantageously carried out by means of a weave in a linen or canvas-derived weave, weighing between 50 and 150 g / m 2 .
  • these yarns do not harm the fire and heat behavior of the overall textile support.
  • these binding yarns may be of the same composition, but with a lower titre than those of the first layer. They can also be of different composition and lower title.
  • the first composition, present on the outer face may be chosen from the group comprising meta-aramid fibers, polyamide-imide, modacrylic fibers, flame retarded cellulosic fibers and mixtures obtained from these fibers. .
  • the first composition of the son forming the first layer has good flame and heat resistance properties, making it possible to use such a textile under extreme conditions, and in particular to allow the production of clothing of people who may have to fight against fires, such as firefighters.
  • the choice of materials constituting this first composition allows the latter to obtain optimum characteristics of resistance to abrasion, pilling, fibrillation and coloristic and mechanical resistance to UV radiation, while retaining good textile properties and coloring suitable for use.
  • the son arranged in warp and weft of the first layer may be of the same nature.
  • the face of the double-layered textile has a visual uniformity in terms of appearance and / or color.
  • the second composition, present on the inner surface only may be chosen from the group comprising the fibers of para-aramid, polybenzimidazole, poly (p-phenylene-2,6-benzobisoxazole) and the mixtures obtained from these fibers.
  • the son of the inner layer are partly made of a material that guarantees excellent thermal properties including heat resistance and / or excellent mechanical performance.
  • the son forming the second layer may have low resistance to radiation including UV and / or washing, they are indeed protected and made invisible by the tight weaving son constituting the first layer.
  • the third composition may be chosen from the group comprising meta-aramid fibers, polyamide-imide fibers, modacrylic fibers, flame retarded or non-flame-resistant cellulosic fibers, polyester or flame-retarded polyamide fibers, and blends obtained from of these fibers
  • the warp son of the second layer may be different in nature from the weft son of the second layer.
  • the weft yarns and the warp yarns constituting the second layer may be of a different nature. They can also include aspects and / or colors distinct from each other. Such an embodiment is however not troublesome because these son are invisible at the face of the double-layer textile.
  • the invention relates to a double-layer textile formed by the weaving of two layers intimately bound together by binding points.
  • such a textile 1 thus comprises a first layer 2 formed by the weaving of son arranged both in warp and weft according to a first son composition. It also comprises a second layer 3 formed by the warp and weft weaving of son of compositions distinct from the first composition.
  • the section according to the figure can be made in particular in the warp direction of the textile, and consequently a binding yarn 4 of the chain makes it possible to bind the yarns 8, 9 of the second layer 3 with the threads of the first layer 2.
  • Such binding yarn 4 then forms a loop 5 around a weft yarn 6 of the first layer 2.
  • this loop 5 can be made beneath a warp 7 of the first layer 2. such This arrangement makes it possible to make the warp yarn 4 less visible at the level of the surface of the double-layer textile 1 corresponding to the outer face of the first layer 2.
  • the number of weft threads of the first layer 2 is greater than the number of weft threads of the second layer 3.
  • a double-layer textile may comprise a first layer formed by weaving in a weave derived from a 2/1 twill with a weight of 165 g / m 2 .
  • the density of the warp yarns of this first layer may be 32.4 threads per centimeter and the density of the weft threads may be equal to 22.5 threads per centimeter.
  • This first layer is advantageously composed exclusively of warp and weft of the same thread comprising 93% meta-aramid fibers dyed in the mass, 5% of para-aramid fibers dyed in the mass and 2% of antistatic fibers.
  • Such a yarn can be made by assembling several yarns of fibers joined or assembled by twisting.
  • this thread may be composed of two yarns whose metric number is 70. Such a yarn may therefore be qualified by a metric number Nm of a value of 70/2, ie 285 dtex.
  • the second layer may itself be formed by weaving a fabric in a plain weave weighing 85 g / m 2 .
  • the density of the yarns arranged in the warp direction of this second layer may be 16.2 threads per centimeter and the density of the yarns arranged in the weft direction may be 11.3 threads per centimeter.
  • Such a second layer may further comprise in the sense of the chain at least two kinds of son.
  • a first kind of warp yarn may be based on 100% para-aramid fibers, of metric number Nm 50/2, ie 400 dtex, and a second kind of warp yarn may be a mixture of 50% of fibers. of aramids with 50%> flame retarded viscose fibers having a metric number of Nm 45, or 222 dtex.
  • the son of the weft of this second layer may be son having 100% para-aramid fibers whose metric number is Nm 70/2, or 285 dtex.
  • the bonding or bonding between the two layers forming the double-layered textile is done during the weaving operation of the two layers, for example by means of the warp threads of the second layer and more specifically of the second kind of son, formed by the composition of the third type, based on a mixture of 50%> aramid fibers with 50%> flame retarded viscose fibers and having a metric number of Nm 45, or 222 dtex.
  • Such binding may be particularly advantageously combined with the armor of the first layer to reduce the visibility of the outside.
  • such a double-layered textile provides an outer surface at the level of the first layer, sufficiently closed to be used as an outer layer of firefighter's jacket, in particular to protect the wearer from chemical splashes.
  • the double-layer textile thus formed also has excellent mechanical properties and protection against heat and flame, and in particular it may have the following characteristics:
  • Such a fabric meets the requirements of ISO 14116 (Index 3), ISO 11612 (A, B1, C1, F1), EN 469.
  • such a fabric can be made in multiple colorations.
  • a double layer fabric may comprise a first layer formed by weaving in a 2/1 twill weave with a weight of 195 g / m 2 .
  • the density of the warp yarns of this first layer may be 35.3 threads per centimeter and the density of the weft threads may be 21.0 threads per centimeter.
  • This first layer is advantageously composed exclusively of warp and weft of the same yarn comprising 60% of modacrylic fibers and 40%> of cotton fibers.
  • Such a wire can be made by assembling several unitary yarns joined together or assembled by twisting.
  • this thread may be composed of two yarns whose metric number is 60. Such a yarn is therefore qualified by a metric number Nm of a value 60/2, ie 333 dtex.
  • the double-layer textile thus formed also has excellent mechanical properties and protection against heat and flame, and in particular it may have the following characteristics:
  • an artificial light fastness (ISO 105B02) of 5 or more for a fabric for a fabric of color other than "high visibility" colors.
  • Such a fabric meets all the requirements of IS014116 (Index 3), ISO 11612 (A, B1, C1, F1).
  • the fabric may have on its outer face a wide variety of shades of plain colors, high visibility, including yellow, orange or red, or printed patterns and colors used in camouflage for military applications.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
PCT/FR2015/053699 2014-12-23 2015-12-21 Textile pour la fabrication de vêtements de protection contre le feu Ceased WO2016102873A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
BR112017013578-7A BR112017013578B1 (pt) 2014-12-23 2015-12-21 Produto têxtil
JP2017533813A JP7118643B2 (ja) 2014-12-23 2015-12-21 防火用の衣服を製造するための布
PL15832816T PL3237659T3 (pl) 2014-12-23 2015-12-21 Tkanina do wytwarzania przeciwpożarowej odzieży ochronnej
DK15832816.1T DK3237659T3 (da) 2014-12-23 2015-12-21 Stof til fremstilling af beklædning til brandbeskyttelse
CN201580070507.7A CN107109719A (zh) 2014-12-23 2015-12-21 用于制造防火服装的织物
SI201531702T SI3237659T1 (sl) 2014-12-23 2015-12-21 Tekstil za izdelavo ognjevarnih oblačil
ES15832816T ES2887081T3 (es) 2014-12-23 2015-12-21 Textil para la fabricación de ropa de protección contra el fuego
EP15832816.1A EP3237659B1 (fr) 2014-12-23 2015-12-21 Textile pour la fabrication de vêtements de protection contre le feu

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1463264A FR3030583B1 (fr) 2014-12-23 2014-12-23 Textile pour la fabrication de vetements de protection contre le feu
FR1463264 2014-12-23

Publications (1)

Publication Number Publication Date
WO2016102873A1 true WO2016102873A1 (fr) 2016-06-30

Family

ID=52737278

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2015/053699 Ceased WO2016102873A1 (fr) 2014-12-23 2015-12-21 Textile pour la fabrication de vêtements de protection contre le feu

Country Status (12)

Country Link
EP (1) EP3237659B1 (da)
JP (1) JP7118643B2 (da)
CN (1) CN107109719A (da)
BR (1) BR112017013578B1 (da)
DK (1) DK3237659T3 (da)
ES (1) ES2887081T3 (da)
FR (1) FR3030583B1 (da)
HU (1) HUE055598T2 (da)
PL (1) PL3237659T3 (da)
PT (1) PT3237659T (da)
SI (1) SI3237659T1 (da)
WO (1) WO2016102873A1 (da)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3540108A1 (de) * 2018-03-13 2019-09-18 IBENA Textilwerke GmbH Doppelgewebe aus flammhemmenden fasern
US12152320B2 (en) 2019-07-12 2024-11-26 Aw Hainsworth And Sons Limited Fire resistant textile material

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6873683B2 (ja) * 2016-12-16 2021-05-19 帝人株式会社 三層構造織編物および繊維製品
DE202018101168U1 (de) * 2018-03-02 2018-03-09 Certoplast Technische Klebebänder Gmbh Klebeband
WO2021085097A1 (ja) * 2019-10-31 2021-05-06 東レ株式会社 多層構造繊維構造体、衣料品および作業服
FR3150819B1 (fr) 2023-07-06 2025-10-03 Tricots Saint James Etoffe tridimensionnelle réalisée par tricotage, vêtement réalisé à partir d’une telle étoffe, équipement comprenant un tel vêtement et procédé de tricotage d’une telle étoffe

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6110850A (en) * 1996-09-18 2000-08-29 Tiroler Loden Gmbh Fabric
WO2001064985A2 (en) 2000-03-02 2001-09-07 Marcanada Inc. Outer shell fabric for fire protective garments for firefighters and for workers exposed to risk of flash fire or electric arc
EP1373617A2 (fr) 2001-03-29 2004-01-02 Europrotect France Sa Tissu renforce
EP1479323A1 (de) 2003-05-19 2004-11-24 Sedac-Mecobel S.A. Sitz-Bett-Faltgestell
EP1880620A2 (en) * 2006-07-18 2008-01-23 Tejidos Estambril, S.A. Thermal protection fabric
WO2008114285A1 (en) * 2007-03-16 2008-09-25 Area 52 S.R.L. Fire-proof fabric

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2686868B2 (ja) * 1991-11-13 1997-12-08 東レ株式会社 防水性防護布帛および作業衣ならびにライダースーツ
JP2001348754A (ja) * 2000-03-31 2001-12-21 Unitica Fibers Ltd 高密度織物
ES2603840T3 (es) 2005-08-09 2017-03-01 Teijin Limited Tejido de estructura de dos capas y prenda de protección resistente al calor que comprende el mismo
EP2689055B1 (en) * 2011-03-22 2016-11-02 Barrday, Inc. Multilayer fabric for flame and thermal protection

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6110850A (en) * 1996-09-18 2000-08-29 Tiroler Loden Gmbh Fabric
WO2001064985A2 (en) 2000-03-02 2001-09-07 Marcanada Inc. Outer shell fabric for fire protective garments for firefighters and for workers exposed to risk of flash fire or electric arc
EP1373617A2 (fr) 2001-03-29 2004-01-02 Europrotect France Sa Tissu renforce
EP1479323A1 (de) 2003-05-19 2004-11-24 Sedac-Mecobel S.A. Sitz-Bett-Faltgestell
EP1880620A2 (en) * 2006-07-18 2008-01-23 Tejidos Estambril, S.A. Thermal protection fabric
WO2008114285A1 (en) * 2007-03-16 2008-09-25 Area 52 S.R.L. Fire-proof fabric

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3540108A1 (de) * 2018-03-13 2019-09-18 IBENA Textilwerke GmbH Doppelgewebe aus flammhemmenden fasern
US12152320B2 (en) 2019-07-12 2024-11-26 Aw Hainsworth And Sons Limited Fire resistant textile material

Also Published As

Publication number Publication date
DK3237659T3 (da) 2021-09-20
CN107109719A (zh) 2017-08-29
SI3237659T1 (sl) 2021-11-30
JP7118643B2 (ja) 2022-08-16
FR3030583B1 (fr) 2017-06-16
BR112017013578B1 (pt) 2022-01-04
FR3030583A1 (fr) 2016-06-24
JP2018500477A (ja) 2018-01-11
EP3237659B1 (fr) 2021-09-08
ES2887081T3 (es) 2021-12-21
HUE055598T2 (hu) 2021-12-28
PT3237659T (pt) 2021-09-16
EP3237659A1 (fr) 2017-11-01
PL3237659T3 (pl) 2021-12-13
BR112017013578A2 (pt) 2018-06-19

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