WO2016148390A1 - Pluralité de matériaux hôtes et dispositif électroluminescent organique comprenant ces matériaux - Google Patents

Pluralité de matériaux hôtes et dispositif électroluminescent organique comprenant ces matériaux Download PDF

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WO2016148390A1
WO2016148390A1 PCT/KR2016/001102 KR2016001102W WO2016148390A1 WO 2016148390 A1 WO2016148390 A1 WO 2016148390A1 KR 2016001102 W KR2016001102 W KR 2016001102W WO 2016148390 A1 WO2016148390 A1 WO 2016148390A1
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substituted
group
unsubstituted
membered
alkyl
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Bitnari Kim
Sang-Hee Cho
Hee-Ryong Kang
Jin-Ri HONG
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DuPont Specialty Materials Korea Ltd
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Rohm and Haas Electronic Materials Korea Ltd
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Priority claimed from KR1020160006579A external-priority patent/KR102613166B1/ko
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Priority to CN201680014780.2A priority Critical patent/CN107406761B/zh
Priority to JP2017548093A priority patent/JP6782249B2/ja
Priority to EP16765146.2A priority patent/EP3268449B1/fr
Priority to US15/551,951 priority patent/US10749119B2/en
Publication of WO2016148390A1 publication Critical patent/WO2016148390A1/fr
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    • H10K85/342—Transition metal complexes, e.g. Ru(II)polypyridine complexes comprising iridium

Definitions

  • the present disclosure relates to a plurality of host materials and organic electroluminescent device comprising the same.
  • An electroluminescent (EL) device is a self-light-emitting device which has advantages in that it provides a wider viewing angle, a greater contrast ratio, and a faster response time.
  • An organic EL device was first developed by Eastman Kodak, by using small aromatic diamine molecules and aluminum complexes as materials to form a light-emitting layer [Appl. Phys. Lett. 51, 913, 1987].
  • OLED organic electroluminescent device
  • electricity is applied to an organic light-emitting material which converts electric energy to light.
  • OLED has a structure comprising an anode, a cathode, and an organic layer disposed between the two electrodes.
  • the organic layer of OLED may comprise a hole injection layer, a hole transport layer, an electron blocking layer, a light-emitting layer (comprising a host and dopant materials), an electron buffering layer, a hole blocking layer, an electron transport layer, an electron injection layer, etc.
  • a material for preparing the organic layer can be classified according to its function, as a hole injection material, a hole transport material, an electron blocking material, a light-emitting material, an electron buffering material, a hole blocking material, an electron transport material, an electron injection material, etc.
  • Holes and electrons are injected from an anode and a cathode, respectively, to the light-emitting layer by applying electricity to OLED; excitons having high energy are formed by recombinations between the holes and the electrons, which make organic light-emitting compounds be in an excited state, and the decay of the excited state results in a relaxation of the energy into a ground state, accompanied by light-emission.
  • the most important factor determining luminous efficiency in OLED is a light-emitting material.
  • the light-emitting material needs to have high quantum efficiency, high electron mobility, and high hole mobility.
  • the light-emitting layer formed by the light-emitting material needs to be uniform and stable. According to colors visualized by light-emission, the light-emitting material can be classified as a blue-, green-, or red-emitting material, and a yellow- or orange-emitting material can be additionally included therein. Furthermore, the light-emitting material can be classified according to its function, as a host material and a dopant material. Recently, the development of OLED providing high efficiency and long lifespan is urgent.
  • a host material which plays a role as a solvent in a solid state and transfers energy, should have high purity, and an appropriate molecular weight for being deposited under vacuum.
  • a host material should have high glass transition temperature and high thermal decomposition temperature to ensure thermal stability; high electrochemical stability to have long lifespan; ease of preparation for amorphous thin film; and good adhesion to materials of adjacent layers.
  • a host material should not move to an adjacent layer.
  • the light-emitting material can be prepared by combining a host with a dopant to improve color purity, luminous efficiency, and stability.
  • a device showing good EL performances comprises a light-emitting layer prepared by combining a host with a dopant.
  • the host material greatly influences the efficiency and lifespan of the EL device when using a host/dopant system, and thus its selection is important.
  • Korean Patent Application Laid-open No. 2008-0047210 discloses an organic light emitting device comprising a carbazole derivative compound as a dopant material.
  • Korean Patent Application Laid-open No. 2010-0015581 discloses an organic electroluminescent device comprising the triazine compound linked with carbazole, etc., directly as a host material.
  • Japanese Patent No. 3139321 discloses an organic emitting device comprising a biscarbazole derivative as a hole transport material.
  • the above publications do not specifically disclose an organic electroluminescent device using a plurality of host materials of a combination of 7H-dibenzo[c,g]carbazole having linker triazine with a carbazole derivative.
  • the present inventors have tried to find an organic electroluminescent device that can provide superior efficiency and long lifespan, and have found that it could be using a plurality of host materials comprising 7H-dibenzo[c,g]carbazole having linker triazine, and a carbazole derivative compared to using the conventional sole host material for a light-emitting layer.
  • the objective of the present disclosure is to provide an organic electroluminescent device having long lifespan while maintaining high luminous efficiency.
  • an organic electroluminescent device comprising at least one light-emitting layer disposed between an anode and a cathode, wherein the light-emitting layer comprises a host and a phosphorescent dopant, wherein the host comprises a plurality of host compounds, wherein at least a first host compound of a plurality of host compounds is represented by the carbazole derivative of the following formula 1:
  • a 1 represents a substituted or unsubstituted (C6-C30)aryl group, or a substituted or unsubstituted (5- to 30-membered)heteroaryl group, and A 1 may be linked to X 1 or X 8 ;
  • L 1 represents a single bond, or a substituted or unsubstituted (C6-C30)arylene group
  • X 1 to X 8 each independently, represent hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, a substituted or unsubstituted (3- to 30-membered)heteroaryl group, -NR 5 R 6 , or -SiR 7 R 8 R 9 ; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or polycycl
  • R 5 to R 9 each independently, represent hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, or a substituted or unsubstituted (3- to 30-membered)heteroaryl group; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or polycyclic (C3-C30), alicyclic or aromatic ring, whose carbon atom
  • a second host compound of a plurality of host compounds is represented by the 7H-dibenzo[c,g]carbazole having linker triazine of the following formula 2:
  • X, Y and Z each independently, represent N or CR 10 ; provided that at least one of X, Y and Z represent N;
  • L 2 represents a substituted or unsubstituted (C6-C30)arylene group
  • R 1 to R 4 each independently, represent hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, a substituted or unsubstituted (3- to 30-membered)heteroaryl group, -NR 11 R 12 , or -SiR 13 R 14 R 15 ; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or polycyclic (
  • R 10 to R 15 each independently, represent hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, or a substituted or unsubstituted (3- to 30-membered)heteroaryl group;
  • k and m each independently, represent an inter of 1 to 5; and where k or m represents an integer of 2 or more, each of R 3 or R 4 may be the same or different; and
  • heteroaryl and the heterocycloalkyl each independently, contain at least one heteroatom selected from B, N, O, S, Si, and P.
  • an organic electroluminescent device having high efficiency and long lifespan is provided.
  • the organic electroluminescent device of the present disclosure can be used for the manufacture of a display system or a lighting system.
  • the organic electroluminescent device comprising the compounds of formulae 1 and 2 will be described in detail.
  • a 1 represents a substituted or unsubstituted (C6-C30)aryl group, or a substituted or unsubstituted (5- to 30-membered)heteroaryl group; preferably, a substituted or unsubstituted (C6-C25)aryl group, or a substituted or unsubstituted (6- to 25-membered)heteroaryl group; and more preferably, a substituted or unsubstituted (C6-C25)aryl group, or a substituted or unsubstituted (6- to 20-membered)heteroaryl group.
  • a 1 may be selected from the group consisting of a substituted or unsubstituted phenyl, an unsubstituted biphenyl, an unsubstituted terphenyl, an unsubstituted naphthyl, a substituted fluorenyl, an unsubstituted spirofluorenyl, an unsubstituted fluoranthenyl, an unsubstituted phenanthrenyl, a substituted triazinyl, a substituted quinoxalinyl, a substituted quinazolinyl, an unsubstituted triphenylsilyl, an unsubstituted triphenylaminyl, an unsubstituted triphenylenyl, an unsubstituted dibenzothiophenyl, an unsubstituted benzonaphthothiophenyl, a substituted or unsubstituted dibenzofuranyl
  • the substituent of A 1 may not be a nitrogen-containing heteroaryl.
  • the substituent of the substituted aryl or the substituted heteroaryl may be at least one of (C1-C30)alkyl, (C6-C30)aryl, (5- to 30-membered)heteroaryl, and mono- or di-(C1-C30)alkyl(C6-C30)aryl; preferably, at least one of (C1-C6)alkyl, (C6-C18)aryl, and di(C1-C6)alkyl(C6-C18)aryl; and for example, at least one of methyl, phenyl, biphenyl, naphthyl, naphthylphenyl, and fluorenyl substituted with dimethyl.
  • a 1 may be linked to X 1 or X 8 ; and the linkage is preferably a single bond.
  • L 1 represents a single bond, or a substituted or unsubstituted (C6-C30)arylene group; preferably, a single bond, or a substituted or unsubstituted (C6-C18)arylene group; and more preferably, a single bond, or a substituted or unsubstituted (C6-C12)arylene group.
  • L 1 may be a single bond, a substituted or unsubstituted phenyl, or an unsubstituted naphthyl, wherein the substituent of a substituted phenyl may be a carbazolyl substituted with phenyl.
  • X 1 to X 8 each independently, represent hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, a substituted or unsubstituted (3- to 30-membered)heteroaryl group, -NR 5 R 6 , or -SiR 7 R 8 R 9 ; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono-
  • X 1 to X 8 may be hydrogen, a substituted or unsubsituted phenyl, a substituted biphenyl, a substituted naphthyl, a substituted fluorenyl, an unsubsituted triphenylaminyl, an unsubsituted dibenzothiophenyl, an unsubsituted dibenzofuranyl, a substituted carbazolyl, a substituted benzocarbazolyl, an unsubsituted dibenzocarbazolyl, a substituted pyrimidinyl, a substituted or unsubsituted 25-membered heteroaryl, an unsubsituted 29-membered heteroaryl, -NR 5 R 6 , or -SiR 7 R 8 R 9 ; or may be linked to an adjacent substituent(s) to form an unsubsituted benzene ring, a substituted indole ring, or
  • R 5 to R 9 each independently, represent hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, or a substituted or unsubstituted (3- to 30-membered)heteroaryl group; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or polycyclic (C3-C30), alicyclic or aromatic ring, whose
  • the compound of formula 1 may be represented by any one of the following formulae 3 to 5:
  • V and W represent a single bond or NR 16 ; provided that both V and W are not a single bond or NR 16 ; wherein R 16 represents hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, or a substituted or unsubstituted (3- to 30-membered)heteroaryl group; preferably, a substituted or unsubstituted (C6-C25)aryl
  • a 2 represents a substituted or unsubstituted (C6-C30)aryl group; preferably, an unsubstituted (C6-C25)aryl group; more preferably, an unsubstituted (C6-C18)aryl group; and for example, an unsubstituted phenyl, an unsubstituted biphenyl, or an unsubstituted naphthyl.
  • a 2 may be linked to X 14 or X 15 ; and the linkage is preferably a single bond.
  • L 3 and L 4 each independently, represent a single bond, or a substituted or unsubstituted (C6-C30)arylene group; preferably, each independently, a single bond, or an unsubstituted (C6-C25)arylene group; more preferably, each independently, a single bond, or an unsubstituted (C6-C18)arylene group; and for example, each independently, a single bond, an unsubstituted phenylene, an unsubstituted biphenylene, or an unsubstituted naphthylene.
  • X 9 to X 26 each independently, represent hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, a substituted or unsubstituted (3- to 30-membered)heteroaryl group, -NR 5 R 6 , or -SiR 7 R 8 R 9 ; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted (C1-C30
  • a 1 , L 1 , X 1 to X 4 , X 7 , X 8 , and R 5 to R 9 are as defined in formula 1.
  • X, Y and Z each independently, represent N or CR 10 ; provided that at least one of X, Y and Z represent N;
  • L 2 represents a substituted or unsubstituted (C6-C30)arylene group; preferably, a substituted or unsubstituted (C6-C18)arylene group; more preferably, an unsubstituted (C6-C12)arylene group; and for example, phenylene, naphthylene, or biphenylene.
  • R 1 to R 4 each independently, represent hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, a substituted or unsubstituted (3- to 30-membered)heteroaryl group, -NR 11 R 12 , or -SiR 13 R 14 R 15 ; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or poly
  • R 10 to R 15 each independently, represent hydrogen, deuterium, a halogen, a cyano group, a carboxyl group, a nitro group, a hydroxyl group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C3-C30)cycloalkenyl group, a substituted or unsubstituted (3- to 7-membered)heterocycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, or a substituted or unsubstituted (3- to 30-membered)heteroaryl group; preferably, each independently, hydrogen, or a substituted or unsubstituted (C6-C25)aryl group; more preferably, each independently, hydrogen, or a substituted or unsubstituted (
  • k and m each independently, represent an inter of 0 to 5; and preferably, each independently, an inter of 0 to 2, and where k or m represents an integer of 2 or more, each of R 3 or R 4 may be the same or different.
  • the heteroaryl and the heterocycloalkyl each independently, contain at least one heteroatom selected from B, N, O, S, Si, and P; and preferably, contain at least one heteroatom selected from N, O, S and Si.
  • L 2 may be represented by any one of the following formulae 7 to 19:
  • Xi to Xp each independently, represent hydrogen, deuterium, a halogen, a cyano group, a substituted or unsubstituted (C1-C30)alkyl group, a substituted or unsubstituted (C2-C30)alkenyl group, a substituted or unsubstituted (C2-C30)alkynyl group, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C6-C60)aryl group, a substituted or unsubstituted (3- to 30-membered)heteroaryl group, a substituted or unsubstituted tri(C1-C30)alkylsilyl group, a substituted or unsubstituted tri(C6-C30)arylsilyl group, a substituted or unsubstituted di(C1-C30)alkyl(C6-C30
  • (C1-C30)alkyl is meant to be a linear or branched alkyl having 1 to 30 carbon atoms constituting the chain, in which the number of carbon atoms is preferably 1 to 20, more preferably 1 to 10, and includes methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, etc.;
  • (C2-C30)alkenyl is meant to be a linear or branched alkenyl having 2 to 30 carbon atoms constituting the chain, in which the number of carbon atoms is preferably 2 to 20, more preferably 2 to 10, and includes vinyl, 1-propenyl, 2-propenyl, 1-butenyl, 2-butenyl, 3-butenyl, 2-methylbut-2-enyl, etc.
  • (C2-C30)alkynyl is meant to be a linear or branched alkynyl having 2 to 30 carbon atoms
  • halogen includes F, Cl, Br, and I.
  • substituted in the expression “substituted or unsubstituted” means that a hydrogen atom in a certain functional group is replaced with another atom or group, i.e. a substituent.
  • a 1 represents a substituted or unsubstituted (C6-C25)aryl group, or a substituted or unsubstituted (6- to 25-membered)heteroaryl group
  • L 1 represents a single bond, or a substituted or unsubstituted (C6-C18)arylene group
  • X 1 to X 8 each independently, represent hydrogen, a substituted or unsubstituted (C6-C25)aryl group, a substituted or unsubstituted (5- to 30-membered)heteroaryl group, -NR 5 R 6 , or -SiR 7 R 8 R 9 ; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or polycyclic (C5-C25), alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one heteroatom selected from nitrogen, oxygen, and sulfur; and R
  • a 1 represents a substituted or unsubstituted (C6-C25)aryl group, or a substituted or unsubstituted (6- to 20-membered)heteroaryl group
  • L 1 represents a single bond, or a substituted or unsubstituted (C6-C12)arylene group
  • X 1 to X 8 each independently, represent hydrogen, a substituted or unsubstituted (C6-C18)aryl group, a substituted or unsubstituted (6- to 30-membered)heteroaryl group, -NR 5 R 6 , or -SiR 7 R 8 R 9 ; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or polycyclic (C6-C18) aromatic ring, whose carbon atom(s) may be replaced with at least one nitrogen atom; and R 5 to R 9 , each independently, represent a
  • L 2 represents a substituted or unsubstituted (C6-C18)arylene group
  • R 1 to R 4 each independently, represent hydrogen, a substituted or unsubstituted (C6-C25)aryl group, or a substituted or unsubstituted (3- to 25-membered)heteroaryl group; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or polycyclic (C3-C25), alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one heteroatom selected from nitrogen, oxygen, and sulfur; and k and m, each independently, represent an inter of 0 to 2.
  • L 2 represents an unsubstituted (C6-C12)arylene group
  • R 1 to R 4 each independently, represent hydrogen, a substituted or unsubstituted (C6-C18)aryl group, or a substituted or unsubstituted (5- to 18-membered)heteroaryl group; or may be linked to an adjacent substituent(s) to form a substituted or unsubstituted mono- or polycyclic (C5-C18), alicyclic or aromatic ring, whose carbon atom(s) may be replaced with at least one heteroatom selected from nitrogen, oxygen, and sulfur; and k and m, each independently, represent an inter of 0 to 2.
  • the first host compound of formula 1 may be selected from the group consisting of the following compounds, but is not limited thereto:
  • the second host compound of formula 2 may be selected from the group consisting of the following compounds, but is not limited thereto:
  • the organic electroluminescent device of the present disclosure comprises an anode; a cathode; and at least one organic layer disposed between the anode and cathode, wherein the organic layer comprises one or more light-emitting layers; the light-emitting layer comprises a host and a phosphorescent dopant; the host comprises a plurality of host compounds; and at least a first host compound of a plurality of host compounds is represented by formula 1, and a second host compound is represented by formula 2.
  • the light-emitting layer indicates a layer from which light is emitted, and may be a single layer or a multiple layer deposited by two or more layers. It is preferable that a doping amount of the dopant compound is less than 20 wt% based on the total amount of the host compound and the dopant compound.
  • the organic layer may comprise a light-emitting layer, and may further comprise at least one layer selected from a hole injection layer, a hole transport layer, an electron transport layer, an electron injection layer, an electron buffering layer, an interlayer, a hole blocking layer, and an electron blocking layer.
  • the weight ratio in the light-emitting layer between the first host material and the second host material may be in the range of 1:99 to 99:1.
  • the dopant to be comprised in the organic electroluminescent device of the present disclosure is preferably at least one phosphorescent dopant.
  • the phosphorescent dopant material for the organic electroluminescent device of the present disclosure is not limited, but may be preferably selected from metallated complex compounds of iridium (Ir), osmium (Os), copper (Cu) and platinum (Pt), more preferably selected from ortho-metallated complex compounds of iridium (Ir), osmium (Os), copper (Cu) and platinum (Pt), and even more preferably ortho-metallated iridium complex compounds.
  • the phosphorescent dopant may be selected from the group consisting of compounds represented by the following formulae 101 to 103.
  • L is selected from the following structures:
  • R 100 represents hydrogen, a substituted or unsubstituted (C1-C30)alkyl group, or a substituted or unsubstituted (C3-C30)cycloalkyl group;
  • R 101 to R 109 , and R 111 to R 123 each independently, represent hydrogen, deuterium, a halogen, a (C1-C30)alkyl group unsubstituted or substituted with a halogen, a substituted or unsubstituted (C3-C30)cycloalkyl group, a substituted or unsubstituted (C6-C30)aryl group, a cyano group, or a substituted or unsubstituted (C1-C30)alkoxy group;
  • R 106 to R 109 may be linked to an adjacent substituent(s) to form a substituted or unsubstituted fused ring, for example, a fluorene unsubstituted or substituted with an alkyl, a dibenzothiophene unsubstituted or substituted with an alkyl, or a dibenzofuran unsubstituted or substituted with an alkyl group;
  • R 124 to R 127 each independently, represent hydrogen, deuterium, a halogen, a substituted or unsubstituted (C1-C30)alkyl group, or a substituted or unsubstituted (C6-C30)aryl group; and R 124 to R 127 may be linked to an adjacent substituent(s) to form a substituted or unsubstituted fused ring, for example, a fluorene unsubstituted or substituted with an alkyl group, a dibenzothiophene unsubstituted or substituted with an alkyl group, or a dibenzofuran unsubstituted or substituted with an alkyl group;
  • R 201 to R 211 each independently, represent hydrogen, deuterium, a halogen, a (C1-C30)alkyl group unsubstituted or substituted with a halogen, a substituted or unsubstituted (C3-C30)cycloalkyl group, or a substituted or unsubstituted (C6-C30)aryl group; and R 208 to R 211 may be linked to an adjacent substituent(s) to form a substituted or unsubstituted fused ring, for example, a fluorene unsubstituted or substituted with an alkyl, a dibenzothiophene unsubstituted or substituted with an alkyl group, or a dibenzofuran unsubstituted or substituted with an alkyl group;
  • f and g each independently, represent an integer of 1 to 3; where f or g is an integer of 2 or more, each of R 100 may be the same or different; and
  • n an integer of 1 to 3.
  • the phosphorescent dopant material includes the following:
  • the organic electroluminescent device of the present disclosure may further comprise at least one compound selected from the group consisting of arylamine-based compounds and styrylarylamine-based compounds at the organic layer.
  • the organic layer may further comprise at least one metal selected from the group consisting of metals of Group 1, metals of Group 2, transition metals of the 4 th period, transition metals of the 5 th period, lanthanides and organic metals of the d-transition elements of the Periodic Table, or at least one complex compound comprising the metal.
  • a surface layer may be placed on an inner surface(s) of one or both electrode(s), selected from a chalcogenide layer, a metal halide layer and a metal oxide layer.
  • a chalcogenide (includes oxides) layer of silicon or aluminum is preferably placed on an anode surface of an electroluminescent medium layer
  • a metal halide layer or a metal oxide layer is preferably placed on a cathode surface of an electroluminescent medium layer.
  • Such a surface layer provides operation stability for the organic electroluminescent device.
  • the chalcogenide includes SiO X (1 ⁇ X ⁇ 2), AlO X (1 ⁇ X ⁇ 1.5), SiON, SiAlON, etc.;
  • the metal halide includes LiF, MgF 2 , CaF 2 , a rare earth metal fluoride, etc.; and the metal oxide includes Cs 2 O, Li 2 O, MgO, SrO, BaO, CaO, etc.
  • a hole injection layer, a hole transport layer, an electron blocking layer, or a combination thereof may be disposed between the anode and the light-emitting layer.
  • the hole injection layer may be composed of two or more layers in order to lower an energy barrier for injecting holes from the anode to a hole transport layer or an electron blocking layer (or a voltage for injecting a hole). Each of the layers may comprise two or more compounds.
  • the hole transport layer or electron blocking layer may be composed of two or more layers.
  • An electron buffering layer, a hole blocking layer, an electron transport layer, an electron injection layer, or a combination thereof may be disposed between the light-emitting layer and the cathode.
  • the electron buffering layer may be composed of two or more layers in order to control the electron injection and improve characteristics of interface between the light-emitting layer and the electron injection layer.
  • Each of the layers may comprise two or more compounds.
  • the hole blocking layer or electron transport layer may be composed of two or more layers, and each of the layers may comprise two or more compounds.
  • a mixed region of an electron transport compound and a reductive dopant, or a mixed region of a hole transport compound and an oxidative dopant may be placed on at least one surface of a pair of electrodes.
  • the electron transport compound is reduced to an anion, and thus it becomes easier to inject and transport electrons from the mixed region to an electroluminescent medium.
  • the hole transport compound is oxidized to a cation, and thus it becomes easier to inject and transport holes from the mixed region to the electroluminescent medium.
  • the oxidative dopant includes various Lewis acids and acceptor compounds
  • the reductive dopant includes alkali metals, alkali metal compounds, alkaline earth metals, rare-earth metals, and mixtures thereof.
  • a reductive dopant layer may be employed as a charge generating layer to prepare an electroluminescent device having two or more light-emitting layers and emitting white light.
  • each layer of the organic electroluminescent device of the present disclosure dry film-forming methods such as vacuum evaporation, sputtering, plasma, ion plating methods, etc., or wet film-forming methods such as inkjet printing, nozzle printing, slot coating, spin coating, dip coating, flow coating methods, etc., can be used.
  • the first host compound and the second host compound may be film-formed by co-evaporaton or mixture-evaporaton.
  • a thin film can be formed by dissolving or diffusing materials forming each layer into any suitable solvent such as ethanol, chloroform, tetrahydrofuran, dioxane, etc.
  • the solvent can be any solvent where the materials forming each layer can be dissolved or diffused, and where there are no problems in film-formation capability.
  • a co-evaporation indicates a process for two or more materials to be deposited as a mixture, by introducing each of the two or more materials into respective crucible cells, and applying electric current to the cells for each of the materials to be evaporated.
  • a mixture-evaporation indicates a process for two or more materials to be deposited as a mixture, by mixing the two or more materials in one crucible cell before the deposition, and applying electric current to the cell for the mixture to be evaporated.
  • the organic electroluminescent device of the present disclosure can be used for the manufacture of a display system or a lighting system.
  • An OLED device comprising a plurality of host compounds of the present disclosure as follows.
  • a transparent electrode indium tin oxide (ITO) thin film (10 ⁇ /sq) on a glass substrate for an organic electroluminescent device (OLED) (Geomatec) was subjected to an ultrasonic washing with acetone, ethanol, and distilled water sequentially, and was then stored in isopropanol.
  • the ITO substrate was then mounted on a substrate holder of a vacuum vapor depositing apparatus.
  • N 4 ,N 4 ' -diphenyl-N 4 ,N 4 ' -bis(9-phenyl-9H-carbazol-3-yl)-[1,1'-biphenyl]-4,4'-diamine was introduced into a cell of the vacuum vapor depositing apparatus, and then the pressure in the chamber of the apparatus was controlled to 10 -6 torr, and evaporated by applying electric current to the cell, thereby forming a first hole injection layer having a thickness of 80 nm on the ITO substrate.
  • dipyrazino[2,3-f:2',3'-h]quinoxaline-2,3,6,7,10,11-hexacarbonitrile was then introduced into another cell of the vacuum vapor depositing apparatus, and evaporated by applying electric current to the cell, thereby forming a second hole injection layer having a thickness of 5 nm on the first hole injection layer.
  • N-([1,1'-biphenyl]-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fluorene-2-amine was introduced into one cell of the vacuum vapor depositing apparatus, and evaporated by applying electric current to the cell, thereby forming a first hole transport layer having a thickness of 10 nm on the second hole injection layer.
  • N-(4-(9,9-diphenyl-9H,9'H-[2,9'-bifluorene]-9'-yl)phenyl)-(9,9-dimethyl-N-phenyl-9H-fluorene-2-amine was then introduced into another cell of the vacuum vapor depositing apparatus, and evaporated by applying electric current to the cell, thereby forming a second hole transport layer having a thickness of 60 nm on the first hole transport layer.
  • a light-emitting layer was then deposited as follows.
  • a host material a first host compound and a second host compound shown in Table 1 below were introduced into two cells of the vacuum vapor depositing apparatus, respectively.
  • a compound D-96 was introduced into another cell as a dopant.
  • the two host compounds were evaporated at the same rate of 1:1, while the dopant was evaporated at a different rate from the host compounds, so that the dopant was deposited in a doping amount of 3 wt% based on the total amount of the host and dopant to form a light-emitting layer having a thickness of 40 nm on the hole transport layer.
  • An OLED device was produced in the same manner as in Device Examples 1-1 to 1-27, except that only a second host compound of Comparative Examples 1-1 to 1-4 shown in Table 1 was used as a sole host for a light-emitting layer.
  • An OLED device was produced in the same manner as in Device Examples 1-1 to 1-27, except that only a first host compound of Comparative Examples 2-1 to 2-4 shown in Table 1 was used as a sole host for a light-emitting layer.
  • OLED device was produced in the same manner as in Device Examples 1-2 and 1-14, except that only any one of Com-1 to Com-3 below, which are conventional organic electroluminescent compounds, was used as a second host for a light-emitting layer.
  • the driving voltage, the luminous efficiency and the color visualized by light-emission in Table 1 are based on a luminance of 1,000 nits of the organic electroluminescent devices, and the lifespan is the time taken to be 97% of the luminance when the early luminance at 5000 nits and a constant current is taken as 100% of the luminance.
  • an organic electroluminescent device comprising a plurality of host materials of the present disclosure has long lifespan while maintaining high luminous efficiency compared to conventional devices using only a sole host or a conventional organic electroluminescent compound.

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Abstract

La présente invention concerne une pluralité de matériaux hôtes et un dispositif électroluminescent organique comprenant ces matériaux. Comme il comprend une combinaison spécifique d'une pluralité de matériaux hôtes, le dispositif électroluminescent organique de la présente invention peut présenter une longue durée de vie tout en conservant une efficacité lumineuse élevée.
PCT/KR2016/001102 2015-03-13 2016-02-02 Pluralité de matériaux hôtes et dispositif électroluminescent organique comprenant ces matériaux Ceased WO2016148390A1 (fr)

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JP2017548093A JP6782249B2 (ja) 2015-03-13 2016-02-02 複数のホスト材料及びそれを含む有機電界発光デバイス
EP16765146.2A EP3268449B1 (fr) 2015-03-13 2016-02-02 Pluralité de matériaux hôtes et dispositif électroluminescent organique comprenant ces matériaux
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