WO2016193149A1 - Procédé et dispositif pour réaliser des processus d'échange de matière, des processus de séparation de matière et/ou des réactions faisant intervenir au moins une phase stationnaire et au moins une phase mobile - Google Patents

Procédé et dispositif pour réaliser des processus d'échange de matière, des processus de séparation de matière et/ou des réactions faisant intervenir au moins une phase stationnaire et au moins une phase mobile Download PDF

Info

Publication number
WO2016193149A1
WO2016193149A1 PCT/EP2016/062012 EP2016062012W WO2016193149A1 WO 2016193149 A1 WO2016193149 A1 WO 2016193149A1 EP 2016062012 W EP2016062012 W EP 2016062012W WO 2016193149 A1 WO2016193149 A1 WO 2016193149A1
Authority
WO
WIPO (PCT)
Prior art keywords
stationary phase
phase
mobile phase
stationary
transport
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2016/062012
Other languages
German (de)
English (en)
Inventor
Michael Benje
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp AG
ThyssenKrupp Industrial Solutions AG
Original Assignee
ThyssenKrupp AG
ThyssenKrupp Industrial Solutions AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ThyssenKrupp AG, ThyssenKrupp Industrial Solutions AG filed Critical ThyssenKrupp AG
Publication of WO2016193149A1 publication Critical patent/WO2016193149A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D33/00—Filters with filtering elements which move during the filtering operation
    • B01D33/044—Filters with filtering elements which move during the filtering operation with filtering bands or the like supported on cylinders which are pervious for filtering
    • B01D33/048—Filters with filtering elements which move during the filtering operation with filtering bands or the like supported on cylinders which are pervious for filtering with endless filtering bands

Definitions

  • the invention relates to a device for carrying out mass transfer processes, mass separation processes and / or reactions involving at least one stationary phase and at least one mobile phase which can be conducted in a flow direction.
  • the invention relates to a method for carrying out mass transfer processes, mass separation processes and / or reactions involving at least one stationary phase and at least one mobile phase which can be conducted in a flow direction.
  • a stationary phase is flowed through by a mobile phase
  • devices are usually used in which the stationary phase is kept in a fixed bed.
  • the mobile phase may be in gaseous or liquid form and is passed through the stationary phase in a predetermined flow direction.
  • the object is achieved by a device for carrying out
  • stationary phase and mobile phase in the following means that it is at least one stationary phase or at least one mobile phase.
  • mass transfer process or reaction in the following means that each is at least one mass transfer process or at least one reaction.
  • the stationary phase is moved transversely to the flow direction of the mobile phase, so that the mobile phase comes into contact with changing areas of the stationary phase.
  • the stationary phase By moving the stationary phase relative to the flow of the mobile phase, it is possible to continuously provide a regenerated and / or otherwise conditioned portion of the stationary phase in the interaction region in which the mobile phase interacts with the stationary phase put.
  • the corresponding portion of the stationary phase may be removed from the interaction region and subjected to and / or regenerated to another operation, such as adsorption, desorption or reaction.
  • the layer thickness of the stationary phase to be passed or wetted by the mobile phase can be very small compared to methods in which the stationary phase is present as a fixed bed in a container. Therefore, strongly swelling, gel-like, fine-grained or otherwise due to their physical behavior to high pressure losses over the fixed bed leading substances can be used as a stationary phase.
  • the device according to the invention is designed such that the stationary phase can be flowed through by the mobile phase.
  • the mobile phase can thus be conducted in the flow direction through the stationary phase.
  • the stationary phase is orthogonal to
  • Flow direction of the mobile phase vertically, in particular from top to bottom, and the stationary phase is moved in the horizontal direction, so that it is possible to supply the mobile phase of the stationary phase via a feeder and discharge via a vertically arranged below the feeder discharge device.
  • the mobile phase can be supplied via a feeding device, which in the manner of a
  • Spray device is formed.
  • the invention is not limited thereto.
  • Other suitable liquid distribution devices may be used.
  • the device may comprise a discharge device, which is designed as a vacuum-discharge device, so that the mobile phase via a
  • Vacuum can be sucked off.
  • the device comprises a transport device for moving the stationary phase, which has an endlessly circulating transport medium, in particular a conveyor belt and / or a transport drum.
  • the stationary phase can be moved linearly and / or along a circular arc. Due to the endless circulating transport medium, the transport device can be used continuously for transporting the stationary phase.
  • the transport device is preferably designed such that the stationary phase is continuously or stepwise movable.
  • Filtration medium in particular a filter cloth, is.
  • the mobile phase can be passed through the transport medium formed as a filtration medium. In this respect, it can be prevented that the mobile phase accumulates on the transport medium and / or flows off along the transport medium.
  • the filtration medium components can be retained, which are separated from the mobile phase. These separated components can be used together with the stationary phase over the
  • Transport medium are discharged.
  • a transport means for the stationary phase for example, a band filter or a drum filter, in particular a vacuum band filter or a vacuum drum filter or a pressure drum filter can be used.
  • the device according to the invention is designed such that the mobile phase can be applied to the stationary phase so that the stationary phase does not flow through the mobile phase, but is merely wetted by the latter.
  • the stationary phase is preferably completely wetted. full
  • wetting in the context of the invention means that the stationary phase is completely loaded with liquid, wherein the loading capacity of the stationary phase is equal to the sum of the resulting from the particle porosity and by the bulk porosity of the stationary phase liquid receiving capacities. It is also advantageous if below the transport medium a
  • liquid-impermeable medium for example a sheet or a polymer plate of defined length in the direction of the stationary phase is arranged so that from the wetted stationary phase little or no liquid can drain.
  • Running speed of the transport medium can be set a defined residence time of the mobile phase on the stationary phase before the mobile phase is removed by a vacuum or by gas pressure from the stationary phase.
  • the device has a feeding device for the task of stationary phase on the transport medium.
  • a regenerated and / or otherwise conditioned stationary phase can be applied to the transport medium.
  • the feed device is provided in a transport direction of the transport medium in front of the interaction region, in which the stationary phase interacts with the mobile phase, so that the stationary phase after their task on the conveyor belt in the
  • the loading device preferably has a storage container in which the stationary phase can be temporarily stored between the removal of the transport device and the re-application to the transport device.
  • the stationary phase is stored in the form of a suspension.
  • the device comprises a removal device for removing the stationary phase of the transport medium.
  • the stationary phase for conditioning and / or regeneration of the transport medium can be removed.
  • the removal device is arranged in the transport direction of the transport medium behind the interaction region, so that the stationary phase can be removed from the transport medium after it has interacted with the mobile phase.
  • the device is designed in such a way that the stationary phase can be traversed several times by the mobile phase, as a result of which the size of the interaction region can be increased.
  • the mobile phase may be cross-flow, cross-current or cross-countercurrent fed to the stationary phase.
  • the device has several
  • Feeders for supplying the mobile phase and a plurality of discharge means for discharging the mobile phase which are connected in particular in series.
  • the device has a plurality of feed devices for feeding different mobile phases, so that the stationary phase can be subjected to different mobile phases. Furthermore, a plurality of removal devices can be provided, via which different mobile phases can be removed from one another separately.
  • Transport device for transporting a first stationary phase, a second
  • Transport device for transporting a second stationary phase and a
  • Transport device can be brought to the second transport device and / or via which the second stationary phase of the second transport device to the first transport device can be brought.
  • the device may comprise a first transport device for transporting a first stationary phase, a second transport device for transporting a second stationary phase and a second transport device
  • Transfer means via which a mobile phase between the first and the second transport means is interchangeable.
  • Further preferred embodiments include the material interconnection of more than two transport devices according to the invention, wherein these can be interconnected in any desired manner with regard to the guidance of stationary and mobile phases.
  • Another object of the invention is a method for carrying out mass transfer operations, mass separation processes and / or reactions involving at least one stationary phase and at least one flowing in a flow direction mobile phase, wherein the stationary phase is moved transversely to the flow direction of the mobile phase.
  • the stationary phase is flowed through by the mobile phase.
  • the invention also includes a method in which the mobile phase is applied to the stationary phase so that the latter is not flowed through by the mobile phase, but merely wetted by it.
  • the stationary phase is completely wetted.
  • Complete wetting in the sense of the method according to the invention means that the stationary phase is completely loaded with liquid, the loading capacity of the stationary phase being equal to the sum of the liquid absorption capacities resulting from the particle porosity and the bulk porosity of the stationary phase.
  • the stationary phase comprises at least one of the following components, wherein the inventive method is not limited to the examples given: an adsorbent, in particular activated carbon, activated carbon, one or more metal hydroxides or a natural or synthetic zeolite, a catalyst , an ion exchanger, in particular an ion exchange resin, an immobilized enzyme or an immobilized antibody or a solid or immobilized on a suitable solid phase catalyst.
  • an adsorbent in particular activated carbon, activated carbon, one or more metal hydroxides or a natural or synthetic zeolite, a catalyst , an ion exchanger, in particular an ion exchange resin, an immobilized enzyme or an immobilized antibody or a solid or immobilized on a suitable solid phase catalyst.
  • About a stationary phase with one of the above ingredients or other equivalent components dissolved components can be separated by adsorption from a, in particular liquid, mobile phase and desorbed in a further step again.
  • one or more dissolved components may be chemically
  • a treatment step may include treatment with an acid and / or with a base.
  • a treatment step may include a thermal treatment.
  • a treatment step may include thermal desorption by means of steam and / or an inert gas.
  • a treatment step may include extraction, for example with a belt extractor, a screw extractor or a carousel extractor.
  • a treatment step may include a separation of fine-grained ingredients.
  • the stationary phase conducted in the circulation is withdrawn continuously or discontinuously, a partial stream and this partial stream is subjected to one or more treatment steps and mixed again the stationary phase.
  • the recirculating stationary phase is withdrawn continuously or discontinuously, a partial stream and this partial stream is subjected to one or more treatment steps and mixed again the stationary phase.
  • the recirculating stationary phase is withdrawn continuously or discontinuously, a partial stream and this partial stream is subjected to one or more treatment steps and mixed again the stationary phase.
  • the recirculating stationary phase is withdrawn continuously or discontinuously, a partial stream and this partial stream is subject
  • regeneration has an expanded meaning in the sense of the device according to the invention as well as of the method according to the invention:
  • the stationary phase is an ion exchanger
  • the regeneration of the ion exchanger can be effected by means of an acid or a base
  • Regeneration can likewise be carried out using a device according to the invention.Also, it is possible to use other devices for regeneration, for example a stirred vessel which is continuously flowed through.
  • the stationary phase is an adsorbent, the desorption of the component adsorbed from the mobile phase is under regeneration to understand
  • Desorption can also be carried out using a device according to the invention, wherein the desorption thermally or by exposure to a
  • Devices are used, e.g. continuous or semi-continuous extractors, in particular band extractors, screw extractors or
  • Carousel extractors or devices for thermal desorption in particular
  • Stripping containers or stripping columns Regeneration of the adsorbent is also understood to mean treatment steps which are suitable for removing unwanted substances which reduce the loading capacity of the adsorbent with respect to the material (s) to be separated.
  • the stationary phase is a catalyst, then it can also be treated, extractively, thermally or in another way, to maintain its activity, before it is recycled to the apparatus or the method according to the invention.
  • the stationary phase is moved continuously, so that the stationary phase is moved through the flow of the mobile phase and thereby
  • the movement of the stationary phase is particularly preferably carried out by means of a transport device which has an endlessly circulating transport medium, for example a conveyor belt or filter belt.
  • the stationary phase can be arranged in the manner of a continuous filter cake on the endless circulating transport medium.
  • the stationary phase can be moved stepwise, thereby enabling clocked process control.
  • the stationary phase is segmented onto the transport medium of the transport device, so that a segmented stationary phase is formed on the transport medium. At least two different stationary phases are preferred transversely to
  • the different stationary phases can be arranged successively or alternately on the transport medium.
  • the different stationary phases preferably have different constituents and / or compositions, so that a mobile phase, which in particular flows through the different stationary phases in succession, can interact with different constituents and / or different compositions.
  • a plurality of task devices for the separate task of the different stationary phases are present on the transport medium.
  • a plurality of removal devices are provided for the separate removal of the different stationary phases of the transport medium.
  • the task of the various stationary phases, as well as the task of the mobile phases is clocked, whereby a segmentation of the stationary phase layer can be achieved and a cross-mixing of stationary and mobile phases can be suppressed.
  • the advantageous features and configurations described in connection with the device according to the invention can also be used.
  • the invention relates to the use of a filtration device with an endless circulating filtration medium, in particular a filter cloth, in a method for carrying out a mass transfer process, substance separation process and / or a reaction involving a stationary phase and a mobile phase which can be conducted in a flow direction as a transport device for moving the stationary phase transverse to the flow direction of the mobile phase.
  • a filtration device with an endless circulating filtration medium, in particular a filter cloth, in a method for carrying out a mass transfer process, substance separation process and / or a reaction involving a stationary phase and a mobile phase which can be conducted in a flow direction as a transport device for moving the stationary phase transverse to the flow direction of the mobile phase.
  • filter devices or drum filters in particular vacuum band filters or vacuum drum filters or pressure drum filters can be used as filtration devices.
  • the invention further relates to a method in which using one or more devices according to the invention on a moving stationary phase
  • the invention further relates to a method in which using one or more devices according to the invention on a moving stationary phase
  • the invention further relates to a method in which, using one or more devices according to the invention on a moving stationary phase, first a chromatographic separation of at least two dissolved in the mobile phase
  • inventive devices are further separated by chromatography.
  • the invention further relates to a method in which using one or more devices according to the invention by means of suitable stationary phases organic
  • Compounds may be pollutants in industrial wastewater, in soil remediation or in groundwater.
  • the organic compounds may be biotechnologically produced valuable substances and the aqueous solutions may be fermentation broths.
  • the recyclables can, for example
  • the valuable substances can be obtained after completion of a fermentation process from the fermentation broth. Alternatively, the valuable substances can be obtained during a fermentation process running in a fermentation reactor from a partial stream of the fermentation broth taken from the fermentation reactor. The fermentation broth depleted in terms of valuable substances can be returned to the fermentation reactor after depletion.
  • the organic compounds may also be monosaccharides, disaccharides or oligosaccharides and in the aqueous solution by a chemical, microbiological, enzymatic or hydrothermal route or by any combination of these ways obtained cellulose, hemicellulose or
  • Lignocellulose hydrolyzate act. Furthermore, the valuable substances can be organic compounds in aqueous solution from industrial processes.
  • the valuable material may be, for example, propylene glycol from a predominantly aqueous stream in a plant for the production of propylene oxide.
  • the invention further relates to a process in which inorganic compounds are separated from aqueous solutions using one or more devices according to the invention.
  • the inorganic compounds may be sodium chloride and other solutes, especially in seawater.
  • the inorganic compound may be a phosphate or ammonium
  • the aqueous solution may be sewage, in particular municipal waste water or agricultural sewage.
  • Fig. 1 shows a first embodiment of an apparatus for performing a
  • FIG. 2 shows a second embodiment of an apparatus for carrying out a mass transfer process, a substance separation process and / or a reaction under Involving a stationary phase and a mobile phase which can be conducted in a flow direction.
  • Fig. 3 shows a third embodiment of a device for carrying out a
  • FIG. 4 shows a plant for obtaining a carboxylic acid with a device according to the invention.
  • FIG. 1 shows schematically a first exemplary embodiment of a device 100 according to the invention, which is set up to carry out a mass transfer process, a substance separation process and / or a reaction involving a stationary phase 4 and a mobile phase which can be conducted in a flow direction M.
  • the device 100 may comprise an adsorbent.
  • the adsorbent can be, for example, activated carbon, activated carbon, one or more metal hydroxides, a natural or synthetic zeolite or a natural or synthetic
  • the stationary phase 4 may comprise a solid or immobilized on a suitable solid substrate catalyst, an immobilized enzyme or an immobilized antibody.
  • the invention is not limited to the substances mentioned. According to the
  • Embodiment is the stationary phase 4 in the device 100 as slurried solid.
  • the stationary phase 4 can be flowed through by the mobile phase.
  • the stationary phase 4 is moved transversely, in particular orthogonal, to the flow direction M of the mobile phase by means of a transport device 101, such that the interaction region in which the stationary phase 4 interacts with the mobile phase is continuously a regenerated section of the stationary Phase 4 is supplied.
  • the transport device 101 has a transport medium 1 designed as a filter medium, so that the stationary phase 4 can be held on the transport medium 1 and the mobile phase can flow through the stationary phase and the transport medium 1.
  • the transport medium 1 may be formed, for example, as a filter cloth.
  • a trained as a vacuum belt filter filtration device is used with an endless circulating filtration medium 1 as a transport device 101 for moving the stationary phase 4 transversely to the flow direction M of the mobile phase.
  • the task of the stationary phase 4 on the transport device 101 via a feed device 102 which comprises a reservoir 2 for the present as a slurry stationary phase 4.
  • the slurry is introduced at a feed point from above onto the transport medium of the transport device 101.
  • the device 100 has a liquid withdrawal 3, via which the slurry is withdrawn, so that a liquid-reduced stationary phase remains on the transport medium 1 in the manner of a filter cake.
  • the stationary phase applied to the transport medium is conveyed continuously in the transport direction S of the transport device 101.
  • the device 100 In a position which is arranged along the transport direction S behind the feed station of the stationary phase 4, the device 100 has a plurality of feed devices 5, 6, 7, via which the mobile phase is fed transversely to the transport direction S of the stationary phase 4. Below the feeders 5, 6, 7 is a respective
  • Discharge device 8, 9, 10 is arranged, via which the transverse, in particular orthogonal, flowing through the stationary phase and the transport medium 1 mobile phase is discharged.
  • the discharge devices 8, 9, 10 can be designed, for example, as vacuum discharge devices which suck the mobile phase by means of negative pressure.
  • Feeding means 5, 6, 7 arranged discharge means 8, 9, 10 together form an interaction device which provides an interaction region in which the stationary phase 4 interacts with the mobile phase.
  • Interaction devices are arranged in series according to the embodiment, so that the mobile phase is brought into cross-counterflow with the stationary phase 4 in contact.
  • a washing device 11 may be provided in a position which is arranged along the transport direction S behind the interaction means. Via the washing device 1 1, a washing medium can be applied to the moving stationary phase 4.
  • the washing medium can be the stationary phase 4 and the
  • the device 100 In a position which is arranged along the transport direction S behind the interaction devices and optionally behind the washing device 1 1, the device 100 has a removal device 103, via which the stationary phase 4 of the
  • the removal device has a
  • Collection device 12 in which the removed from the transport medium stationary phase 4 is collected.
  • the apparatus 100 further comprises a regeneration device 13, by means of which the stationary phase 4 removed by the transport device 101 is regenerated. After the regeneration, the stationary phase 4 is fed to the collecting container 2 of the feeding device and can be reloaded onto the transport device 101. In this respect, the stationary phase 4 is continuously recycled.
  • FIG. 2 shows a second exemplary embodiment of a device 100 according to the invention.
  • the stationary phase 4 is moved stepwise in the device 100 shown in FIG. 2, so that a clocked process management is made possible.
  • Task device 102 is clocked, i. the stationary phase is applied segmented onto the transport device 101.
  • a stationary phase 4 is formed in the manner of a segmented filter cake, wherein individual segments of the stationary phase are separated by gaps. As a result, the cross-mixing of the mobile phase can be suppressed.
  • FIG. 3 shows a third embodiment of a device 100 according to the invention, in which the stationary phase 4 is also moved stepwise in the transport direction S.
  • the stationary phase 4 is also moved stepwise in the transport direction S.
  • Device 100 several, in particular three, feeding devices 102, 102 ', 102 "are provided, via which several, in particular three, stationary phases 4, 4', 4" with different composition on the common transport device 101 will give up.
  • Fig. 4 is a plant for recovering a carboxylic acid such as
  • the plant has a fermenter 104, to which a carboxylic acid-containing fermentation broth 105 is taken.
  • the carboxylic acid-containing fermentation broth 105 is supplied as a mobile phase to a device 100 according to the invention for carrying out a mass transfer process, mass separation process and / or a reaction involving a stationary phase 4 and a mobile phase which can be conducted in a flow direction.
  • the apparatus 100 has a transporting device 101, on which a stationary phase 4 is moved in a transporting direction S, which is formed as a weakly basic ion exchange resin. In a first zone, the stationary phase 4 is flowed through in cross-countercurrent transversely to the transport direction S of the mobile phase.
  • the stationary phase 4 adsorbs the carboxylic acid, so that from the first zone a fermentation broth 106 is withdrawn, which has a reduced proportion of carboxylic acid.
  • the fermentation broth 106 withdrawn from the first zone is returned to the fermenter 104.
  • the stationary phase 4 in cross-countercurrent with an extractant 107, for example, with hot water, applied.
  • the extracted from the second zone extractant 108 has an increased content of carboxylic acid.
  • the devices 100 described above are for performing a
  • Mass transfer operation, mass separation process and / or a reaction involving a stationary phase 4 and a mobile phase can be conducted in a flow direction and configured such that the stationary phase 4 can be traversed by the mobile phase and the stationary phase in a direction S transverse to the flow direction M the mobile phase is movable.
  • the devices 100 make it possible to

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un dispositif pour la réalisation de processus d'échange de matière, des processus de séparation de matière et/ou des réactions faisant intervenir au moins une phase stationnaire (4, 4', 4") et au moins une phase mobile pouvant être guidée dans un sens d'écoulement (M), qui est conçu de manière telle que la phase stationnaire (4, 4', 4") peut être déplacée transversalement par rapport au sens d'écoulement (M) de la phase mobile. En outre, l'invention concerne un procédé pour la réalisation de processus d'échange de matière, de processus de séparation de matière et/ou de réactions faisant intervenir au moins une phase stationnaire (4, 4', 4") et au moins une phase mobile s'écoulant dans un sens d'écoulement (M), la phase stationnaire (4, 4', 4") étant déplacée transversalement par rapport au sens d'écoulement (M) de la phase mobile.
PCT/EP2016/062012 2015-06-03 2016-05-27 Procédé et dispositif pour réaliser des processus d'échange de matière, des processus de séparation de matière et/ou des réactions faisant intervenir au moins une phase stationnaire et au moins une phase mobile Ceased WO2016193149A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102015108860.6A DE102015108860A1 (de) 2015-06-03 2015-06-03 Verfahren und Vorrichtung zur Durchführung von Stoffaustauschvorgängen, Stofftrennvorgängen und/oder Reaktionen unter Beteiligung mindestens einer stationären und mindestens einer mobilen Phase
DE102015108860.6 2015-06-03

Publications (1)

Publication Number Publication Date
WO2016193149A1 true WO2016193149A1 (fr) 2016-12-08

Family

ID=56137279

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2016/062012 Ceased WO2016193149A1 (fr) 2015-06-03 2016-05-27 Procédé et dispositif pour réaliser des processus d'échange de matière, des processus de séparation de matière et/ou des réactions faisant intervenir au moins une phase stationnaire et au moins une phase mobile

Country Status (2)

Country Link
DE (1) DE102015108860A1 (fr)
WO (1) WO2016193149A1 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5669202A (en) * 1979-11-12 1981-06-10 Ishikawajima Harima Heavy Ind Co Ltd Apparatus for separating sulfur from sulfur dioxide gas
US5004718A (en) * 1986-12-19 1991-04-02 Babcock-Hitachi Kabushiki Kaisha Process for calcining a denitrating catalyst
JPH03213919A (ja) * 1990-01-19 1991-09-19 Mitsubishi Electric Corp 空気調和機のフイルタ清掃装置
US20030146174A1 (en) * 2001-12-28 2003-08-07 Hansen Preben Boje Filtration method and apparatus
US20050153834A1 (en) * 2002-03-15 2005-07-14 Jens Weiguny Method for the production of a catalyst containing vanadium, phosphorus, and oxygen

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2165825A1 (fr) * 1993-11-02 1995-05-11 Bernhard Ulbrich Methode et dispositif pour la separation d'un melange
AT400309B (de) * 1994-05-27 1995-12-27 Alois Dr Jungbauer Kontinuierlich arbeitende trennanlage
AUPQ025599A0 (en) * 1999-05-10 1999-06-03 Uniquest Pty Limited Apparatus and method to at least partially separate components from a fluid feed stream

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5669202A (en) * 1979-11-12 1981-06-10 Ishikawajima Harima Heavy Ind Co Ltd Apparatus for separating sulfur from sulfur dioxide gas
US5004718A (en) * 1986-12-19 1991-04-02 Babcock-Hitachi Kabushiki Kaisha Process for calcining a denitrating catalyst
JPH03213919A (ja) * 1990-01-19 1991-09-19 Mitsubishi Electric Corp 空気調和機のフイルタ清掃装置
US20030146174A1 (en) * 2001-12-28 2003-08-07 Hansen Preben Boje Filtration method and apparatus
US20050153834A1 (en) * 2002-03-15 2005-07-14 Jens Weiguny Method for the production of a catalyst containing vanadium, phosphorus, and oxygen

Also Published As

Publication number Publication date
DE102015108860A1 (de) 2016-12-08

Similar Documents

Publication Publication Date Title
DE69233679T2 (de) Verfahren zur Trennung von optischen Isomeren in einem simulierten Wanderbettsystem
DE4409487C2 (de) Verfahren und Anlage zur Vergärung von biogen-organischen Rohabfällen
DE2624943A1 (de) Vorrichtung und verfahren zur abtrennung und waschung eines feststoff- konzentrats aus einem feststoffhaltigen stroemungsmittel
CH616263A5 (fr)
WO2015096832A1 (fr) Procédé et dispositif de production de biogaz
DE102014106810A1 (de) Vorrichtung zur Aufbereitung von Abwasser
DE69803931T2 (de) Adsorption bzw. desorption gelöster bestandteile in flüssigkeiten und vorrichtung dafür
DE2445315C3 (fr)
DE2728469C2 (de) Verfahren und Einrichtung zur Behandlung von radioaktive Abfallstoffe enthaltenden Flüssigkeiten
DE3411998C2 (fr)
DE3812986A1 (de) Dekontaminationsverfahren fuer schwermetallverunreinigte boeden, speziell fuer quecksilber
WO2016193149A1 (fr) Procédé et dispositif pour réaliser des processus d'échange de matière, des processus de séparation de matière et/ou des réactions faisant intervenir au moins une phase stationnaire et au moins une phase mobile
EP2822673B1 (fr) Procédé et installation permettant de séparer du dioxyde de carbone de biogaz
EP3484846B1 (fr) Procédé de production catalytique d'acide formique et régénération du catalyseur utilisé à cet effet à pression positive réduite
EP4208282B1 (fr) Recirculation des matières valorisables de la purification de gaz d'échappement
EP3463699B3 (fr) Procédé et dispositif pour le nettoyage de pièces fabriquées industriellement
AT401048B (de) Verfahren und vorrichtung zur entfernung von ammonium-verbindungen aus abwässern
DE102009023627A1 (de) Mikrofluidischer Reaktor mit einem ringförmigen Reaktionsraum
DE102006038206A1 (de) Verfahren zur Entfernung von in gelöster Form vorliegenden Fremdstoffen aus Abwasser
DE4317338A1 (de) Verfahren zum Dekontaminieren von mit Schadstoffen verunreinigten Böden, Schlämmen, Aschen, Sedimenten oder dergleichen
DE2738120A1 (de) Einrichtung und verfahren zum thermischen regenerieren von massen in wasseraufbereitungs-anlagen
EP4154279B1 (fr) Procédé de décontamination liquide des objets contaminés radioactivement et retraitement d`eau du procédé
DE2832360A1 (de) Verfahren zur selektiven extraktion einer loeslichen komponente aus einem festen koernigen material, das eine anzahl loeslicher komponenten enthaelt
EP3653583B1 (fr) Procédé de traitement des matériaux biodégradables et dispositif de mise en uvre dudit procédé
EP0103674B1 (fr) Procédé et dispositif pour la séparation d'ammoniac libre et combiné à partir de solutions aqueuses renfermant les deux constituants

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16730269

Country of ref document: EP

Kind code of ref document: A1

122 Ep: pct application non-entry in european phase

Ref document number: 16730269

Country of ref document: EP

Kind code of ref document: A1