WO2017012613A3 - Verfahren zur abscheidung von quecksilber in verbrennungsabgasen - Google Patents

Verfahren zur abscheidung von quecksilber in verbrennungsabgasen Download PDF

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Publication number
WO2017012613A3
WO2017012613A3 PCT/DE2016/100333 DE2016100333W WO2017012613A3 WO 2017012613 A3 WO2017012613 A3 WO 2017012613A3 DE 2016100333 W DE2016100333 W DE 2016100333W WO 2017012613 A3 WO2017012613 A3 WO 2017012613A3
Authority
WO
WIPO (PCT)
Prior art keywords
mercury
furnace gases
oxidized
furnace
separating mercury
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/DE2016/100333
Other languages
English (en)
French (fr)
Other versions
WO2017012613A2 (de
Inventor
Jan Schütze
Ralf PAESLACK
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vpc GmbH
Original Assignee
Vpc GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vpc GmbH filed Critical Vpc GmbH
Priority to EP16766469.7A priority Critical patent/EP3319711A2/de
Priority to US15/746,445 priority patent/US20180200672A1/en
Priority to DE112016003318.4T priority patent/DE112016003318A5/de
Publication of WO2017012613A2 publication Critical patent/WO2017012613A2/de
Publication of WO2017012613A3 publication Critical patent/WO2017012613A3/de
Anticipated expiration legal-status Critical
Priority to ZA2018/00808A priority patent/ZA201800808B/en
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/83—Solid phase processes with moving reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8665—Removing heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/003—Arrangements of devices for treating smoke or fumes for supplying chemicals to fumes, e.g. using injection devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/2073—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20753—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20776—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20784—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20792—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/204—Inorganic halogen compounds
    • B01D2257/2045—Hydrochloric acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/60—Heavy metals; Compounds thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/10—Catalytic reduction devices

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zur Abscheidung von Quecksilber (Hg) in Abgasen von Verbrennungsanlagen, in welchem ein katalytisch aktives Material mit einem mittleren Korndurchmesser < 35 pm in das Verbrennungsabgas zudosiert wird, wobei das vorhandene elementare Quecksilber oxidiert und resultierendes oxidiertes Quecksilber im Prozess über Adsorptions und Absorptionsprozesse an bereits bestehender Anlagentechnik abgeschieden wird. Die verstärkte Bildung von oxidiertem Quecksilber wird dabei in einem Temperaturbereich < 500 °C durchgeführt wird.
PCT/DE2016/100333 2015-07-23 2016-07-25 Verfahren zur abscheidung von quecksilber in verbrennungsabgasen Ceased WO2017012613A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP16766469.7A EP3319711A2 (de) 2015-07-23 2016-07-25 Verfahren zur abscheidung von quecksilber in verbrennungsabgasen
US15/746,445 US20180200672A1 (en) 2015-07-23 2016-07-25 Method for separating mercury from flue gas
DE112016003318.4T DE112016003318A5 (de) 2015-07-23 2016-07-25 Verfahren zur abscheidung von quecksilber in verbrennungsabgasen
ZA2018/00808A ZA201800808B (en) 2015-07-23 2018-02-07 Method for separating mercury from furnace gases

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102015009343.6 2015-07-23
DE102015009343 2015-07-23

Publications (2)

Publication Number Publication Date
WO2017012613A2 WO2017012613A2 (de) 2017-01-26
WO2017012613A3 true WO2017012613A3 (de) 2017-03-16

Family

ID=56939826

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2016/100333 Ceased WO2017012613A2 (de) 2015-07-23 2016-07-25 Verfahren zur abscheidung von quecksilber in verbrennungsabgasen

Country Status (5)

Country Link
US (1) US20180200672A1 (de)
EP (1) EP3319711A2 (de)
DE (2) DE102016113650A1 (de)
WO (1) WO2017012613A2 (de)
ZA (1) ZA201800808B (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108479389B (zh) * 2018-04-27 2021-03-26 华中科技大学 一种烟气协同脱硝脱汞系统及方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009017811A2 (en) * 2007-08-02 2009-02-05 The Benthamite Company, Llc Composition, production and use of sorbent particles for flue gas desulfurization
WO2015051363A1 (en) * 2013-10-04 2015-04-09 University Of Cincinnati Method and system for removing gaseous mercury in flue gases
WO2015085513A1 (zh) * 2013-12-11 2015-06-18 浙江大学 用于硝汞协同控制的催化剂及制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4403244A1 (de) * 1994-02-03 1995-08-10 Metallgesellschaft Ag Verfahren zur Reinigung von Verbrennungsabgasen
DE4437781A1 (de) 1994-10-25 1996-05-02 Steinmueller Gmbh L & C Verfahren zum Entfernen von Quecksilber aus einem quecksilberhaltigen Abgas
US6719828B1 (en) * 2001-04-30 2004-04-13 John S. Lovell High capacity regenerable sorbent for removal of mercury from flue gas
DE10233173B4 (de) 2002-07-22 2006-03-23 Bayer Industry Services Gmbh & Co. Ohg Verfahren zur Abscheidung von Quecksilber aus Rauchgasen
JP2004075441A (ja) * 2002-08-14 2004-03-11 Huzhou Daikyo Hari Seihin Yugenkoshi Ｌｉ２Ｏ−Ａｌ２Ｏ３−ＳｉＯ２系結晶性ガラス及び結晶化ガラス、ならびに該結晶性ガラス及び結晶化ガラスの製造方法
CA2512520A1 (en) * 2003-01-13 2004-07-29 Engineering Performance Solutions, Llc Magnetic activated carbon and the removal of contaminants from fluid streams
US20070092419A1 (en) * 2005-10-26 2007-04-26 Iowa State University Research Foundation, Inc. Method for removal of mercury in gas streams
JP4277226B2 (ja) 2006-02-09 2009-06-10 バブコック日立株式会社 金属水銀酸化用触媒及び金属水銀酸化用触媒を備えた排ガス浄化用触媒とその製造方法
US8057576B1 (en) * 2008-06-10 2011-11-15 Calgon Carbon Corporation Enhanced adsorbents and methods for mercury removal
CN101528343B (zh) 2006-09-22 2012-04-25 巴布考克日立株式会社 金属汞的氧化催化剂
JP5553966B2 (ja) 2008-03-19 2014-07-23 千代田化工建設株式会社 水銀吸着材およびその吸着材を用いた排煙処理方法
US8691722B2 (en) * 2008-07-03 2014-04-08 Corning Incorporated Sorbent comprising activated carbon particles, sulfur and metal catalyst
JP5636577B2 (ja) 2008-07-29 2014-12-10 バブコック日立株式会社 金属水銀を含む排ガスの浄化方法および排ガス中の金属水銀の酸化触媒
US20150336081A1 (en) * 2012-03-07 2015-11-26 Clear Carbon Innovations LLC Magnetic adsorbents, methods for manufacturing a magnetic adsorbent, and methods of removal of contaminants from fluid streams
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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009017811A2 (en) * 2007-08-02 2009-02-05 The Benthamite Company, Llc Composition, production and use of sorbent particles for flue gas desulfurization
WO2015051363A1 (en) * 2013-10-04 2015-04-09 University Of Cincinnati Method and system for removing gaseous mercury in flue gases
WO2015085513A1 (zh) * 2013-12-11 2015-06-18 浙江大学 用于硝汞协同控制的催化剂及制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EVAN J. GRANITE ET AL: "Novel Sorbents for Mercury Removal from Flue Gas", INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH., vol. 39, no. 4, 1 April 2000 (2000-04-01), US, pages 1020 - 1029, XP055320959, ISSN: 0888-5885, DOI: 10.1021/ie990758v *

Also Published As

Publication number Publication date
ZA201800808B (en) 2019-03-27
EP3319711A2 (de) 2018-05-16
DE112016003318A5 (de) 2018-04-19
DE102016113650A1 (de) 2017-01-26
WO2017012613A2 (de) 2017-01-26
US20180200672A1 (en) 2018-07-19

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