WO2017122964A1 - Fibre de polyester, procédé de préparation pour celle-ci, et câble pour pneu la comportant - Google Patents

Fibre de polyester, procédé de préparation pour celle-ci, et câble pour pneu la comportant Download PDF

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Publication number
WO2017122964A1
WO2017122964A1 PCT/KR2017/000146 KR2017000146W WO2017122964A1 WO 2017122964 A1 WO2017122964 A1 WO 2017122964A1 KR 2017000146 W KR2017000146 W KR 2017000146W WO 2017122964 A1 WO2017122964 A1 WO 2017122964A1
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WIPO (PCT)
Prior art keywords
polyester fiber
treatment liquid
fiber
tire cord
polyester
Prior art date
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Ceased
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PCT/KR2017/000146
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English (en)
Korean (ko)
Inventor
한석종
안덕중
박진경
유성중
박두진
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Hyosung Corp
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Hyosung Corp
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Publication date
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Priority to CN201780005345.8A priority Critical patent/CN108431328B/zh
Priority to TR2018/07702T priority patent/TR201807702T1/tr
Publication of WO2017122964A1 publication Critical patent/WO2017122964A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44—Yarns or threads characterised by the purpose for which they are designed
    • D02G3/48—Tyre cords
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00—Heating or cooling textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/395—Isocyanates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/41—Phenol-aldehyde or phenol-ketone resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55—Epoxy resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof

Definitions

  • the present invention is a secondary treatment liquid comprising a phenolic resin epoxidized on polyester fibers and a copolymer of maleic anhydride-polybutadiene (Riccobond 7004, hereinafter referred to as 'maleic anhydride polybutadiene')
  • the present invention relates to a treated polyester fiber, a method for manufacturing the same, and a tire cord including the same, wherein the adhesive is an environmentally friendly adhesive that does not use environmentally harmful substances such as resorcinol, formalin, and ammonia.
  • Tire reinforcements generally represented by polyethylene terephthalate (polyester), have excellent mechanical strength, modulus of elasticity, dimensional stability and heat resistance, which are important properties of rubber reinforcements, such as rubber composites such as tires, It is widely used as a reinforcing material for belts or hoses.
  • polyethylene terephthalate polyethylene terephthalate
  • dimensional stability dimensional stability
  • heat resistance which are important properties of rubber reinforcements, such as rubber composites such as tires
  • It is widely used as a reinforcing material for belts or hoses.
  • higher performance reinforcement materials due to the high performance of automobiles, the development of driving roads, and the severe use of rubber composite materials.
  • the surface of the polyester fiber is inert, the adhesion to rubber is not good, so a method of improving the adhesion of the fiber to rubber by treating the surface of the epoxy and diisocyanate compounds has been studied for a long time.
  • the fibers are treated with a primary treatment liquid composed of epoxy and diisocyanate or parachlorophenol-based resins, and then secondary treatment with general resorcinol-formalin latex (hereinafter referred to as ⁇ ) ''.
  • ⁇ general resorcinol-formalin latex
  • the degree of reaction may vary depending on outdoor conditions such as temperature or humidity, or the application state of RFL may vary according to an oil or fiber property, which may cause non-uniformity of final tire cord properties.
  • the use of chemicals such as resorcinol, formalin, ammonia and the like can cause environmental problems.
  • a polyethylene terephthalate fiber is first treated with a mixture of epoxy and blocked isocyanate, and a polyol and an aromatic polyaldehyde are used to prepare a RFL by replacing the resorcinol-formalin resin.
  • a method for producing a polyethylene terephthalate tire cord that is secondary treated to impart adhesion is proposed.
  • this method can prepare environmentally friendly adhesives by not using environmentally harmful substances such as resorcinol and formalin, but acetic acid and ethanol are not dissolved in water because the polyalcohol and aromatic aldehydes are not dissolved in water.
  • the adhesive liquid should be prepared in an organic solvent such as a solvent, and the time for the reaction of the adhesive liquid is also long, and the reactivity of the polyphenol and the aromatic aldehyde is relatively low, so that the adhesive strength of the tire cord treated with the adhesive liquid may be low. have.
  • the international patent WO2014 / 091376 A1 discloses an environmentally friendly adhesive liquid that can replace the resorcinol-formalin resin using water-soluble acrylic resin (BASF, Acrodur 950) and glycerol epoxy (Nagase Chemtex, EX-313). I'm proposing.
  • This method has the advantage of expressing adhesion even at low Dip Pick Up (DPU) in the case of fibers having a reactor such as nylon 66 and rayon by the reaction of acrylic resin and epoxy, but the surface is inert like polyethylene terephthalate. In case of having a low adhesive strength.
  • DPU Dip Pick Up
  • the pH should be sensitively adjusted at the time of preparation, and when the pH is not adjusted, coagulum is generated by reaction with latex, and thus adhesives cannot be used. .
  • RFL which is a secondary treatment liquid
  • resorcinol, formalin, ammonia, etc. which are environmentally harmful substances
  • Formalin is registered as a primary carcinogen, and ammonia causes odors. Therefore, the use of resorcinol and formalin in 2019 will be banned in accordance with the REACH regulations in Europe and the United States, and the development of eco-friendly secondary treatment liquid that does not use such environmentally harmful substances is required. It is a reality.
  • the present invention relates to a polyester fiber treated with an environmentally friendly adhesive liquid on the surface of the polyester fiber, a method of manufacturing the same and a tire cord including the same.
  • Polyester fiber which can manufacture high performance tire cord which can improve the adhesive force, reduce the rigidity of tire cord, improve heat resistance and fatigue resistance, and prevent the peeling phenomenon of rubber and fiber generated at high speed of tire running, its manufacturing method and
  • An object of the present invention is to provide a tire cord including the same.
  • the present invention comprises the steps of preparing a first treatment liquid comprising a blocked diisocyanate and an epoxy compound; Passing through the primary treatment liquid while applying a tensile force to the polyester twisted cord; Drying and heat-treating the fibers having passed through the primary treatment liquid; Passing the heat treated polyester fiber through a secondary treatment liquid comprising an epoxidized phenolic resin and a maleic hydride polybutadiene copolymer; And it provides a method for producing a polyester fiber comprising the step of drying and stabilizing the fiber passed through the secondary treatment liquid.
  • the epoxidized phenol resin and maleic hydride polybutadiene copolymer is preferably 1: 1 to 5: 1 by weight.
  • the present invention also provides a polyester tire cord, which is produced by the above production method and has the following physical properties.
  • the polyester fiber according to the present invention is a maleic anhydride- which can increase the binding force between the epoxidized phenolic resin and rubber latex and the epoxidized phenolic resin and rubber latex which can interact with rubber as a secondary treatment liquid.
  • a maleic anhydride- which can increase the binding force between the epoxidized phenolic resin and rubber latex and the epoxidized phenolic resin and rubber latex which can interact with rubber as a secondary treatment liquid.
  • the secondary treatment solution used in the present invention can be used immediately after mixing, it does not require a reaction aging time and does not use any environmental regulatory substances in the preparation of the treatment solution.
  • the degree and enabling the uniform treatment liquid to be attached it is possible to reduce the manufacturing processability and the production cost, and to provide the treatment liquid for the polyester fiber with improved quality uniformity.
  • the present invention provides a polyester fiber, a manufacturing method thereof and a tire cord comprising the same.
  • Method for producing a polyester fiber of the present invention comprises the steps of preparing a primary treatment liquid containing a blocked diisocyanate and an epoxy compound; Passing through the primary treatment liquid while applying a tensile force to the polyester yarn cord; Drying and heat-treating the fibers having passed through the primary treatment liquid; Passing the heat treated polyester fiber through a secondary treatment liquid comprising an epoxidized phenol resin and a Maleic Anhydride-Polybutadiene copolymer; And drying and stabilizing the fibers passing through the secondary treatment liquid.
  • the present invention uses a primary treatment liquid mainly composed of blocked isocyanates and epoxy to bond polyester fibers and rubber. Thereafter, a rubber latex is added to the mixed solution of the epoxidized phenolic resin and the maleic anhydride-polybutadiene copolymer to treat the polyester fiber with a secondary treatment solution capable of interacting with the rubber.
  • the secondary treatment solution may include a maleic anhydride polybutadiene copolymer in order to increase the bonding strength of the rubber latex and the epoxidized phenol resin.
  • the polyester fiber according to the present invention and the secondary treatment liquid consisting of the epoxidized phenol and maleic hydride polybutadiene copolymer and latex as follows.
  • a secondary treatment solution 0.5 to 10% by weight of epoxidized phenolic resin, 0.1 to 3% by weight maleic hydride polybutadiene copolymer, based on 100% by weight of the secondary treatment solution, vinylpyridine latex 15 To 20% by weight, and 0 to 5% by weight of styrene-butadiene latex.
  • the epoxidized phenolic resin serves to interact with the rubber.
  • Such epoxidized phenolic resin is a bisphenol-A and epichlorohydrin, a noble and epichlorohydrin, or a high molecular weight polyisocyanate at the end of the epoxy resin synthesized from resol and epichlorohydrin, and organic such as butanol It can be prepared by dispersing in a solvent.
  • the polymerized epoxy is synthesized by addition polymerization of a novolac or resol to a liquid epoxy resin synthesized using bisphenol-A and epichlorohydrin, and then an isocyanate blocked with resorcinol, phenol, caprolactam or the like is prepared.
  • a mixed solution may be prepared by applying a very strong shearing force while mixing a novolak or a resol-type epoxy and phenol resin together with water, a co-solvent, and a dispersant and heating. This mixed solution has a uniform dispersibility in the form of small particles and can be maintained in a stable state by the dispersant during the cooling process.
  • a co-solvent may be used alcohols or ether glycol (Glycol Ether).
  • the epoxidized phenol resin preferably contains 0.5 to 10% by weight based on 100% by weight of the secondary treatment liquid.
  • content of the epoxy compound is less than 0.5% by weight, it is difficult to express sufficient adhesiveness to the fiber by providing sufficient reactivity to the fiber, and when it exceeds 10% by weight, the workability is decreased due to the high rigidity and the fatigue resistance of the cord is reduced. In addition, manufacturing costs will increase.
  • the epoxidized phenol resin and the maleic anhydride-polybutadiene copolymer are preferably 1: 1 to 5: 1 by weight. If it is out of the above range, not only sufficient adhesion is not expressed, but also the rigidity is so high that fatigue resistance, which is one of the main required characteristics of the tire cord, is degraded, resulting in deterioration of tire durability.
  • the content of the vinylpyridine latex is preferably 15 to 20% by weight based on 100% by weight of the primary treatment solution, and when the content of the vinylpyridine latex is 15% by weight or less, sufficient adhesion with rubber may not be expressed. If it is more than 20% by weight, the initial adhesive strength is increased, but the latex layer is formed thick, which may cause peeling phenomenon in the latex layer at a high temperature, and the stiffness is increased due to the high adhesion amount, thereby reducing the fatigue resistance. May cause deterioration in workability or increase in final product defects.
  • the polyester fiber thus prepared is a mixture of epoxidized phenolic resins and rubber latexes that can interact with rubber and maleic anhydride-polybutadiene copolymers that can increase the bonding strength of the epoxidized phenolic resins and rubber latex.
  • the secondary treatment solution used in the present invention can be used immediately after mixing, it does not require a reaction aging time, and does not use any environmental regulatory substances in the preparation of the treatment solution.
  • the secondary treatment solution used in the present invention can be used immediately after mixing, it does not require a reaction aging time, and does not use any environmental regulatory substances in the preparation of the treatment solution.
  • the primary treatment solution was prepared by mixing 96.5 wt% water, 0.5 wt% epoxy compound, 1.0 wt% diisocyanate, 1.5 wt% vinylpyridine latex, and 0.5 wt% heat resistant additive. It was prepared by adjusting as shown in Table 1.
  • the twisted yarn cord produced by using 1500 denier 2ply of polyester fiber for tire cords as 37 (Twist / 10cm) and 37 (Twist / 10cm) soft water was immersed in the primary treatment liquid while applying a tension of 0.1 g / d. Passed through, dried at 160 ° C. for 2 minutes and heat treated at 245 ° C.
  • the polyester fiber was further subjected to the binding treatment between the epoxidized phenol resin (Allnex Corp. VPW-1942), vinylpyridine latex and styrene-butadiene latex, and the epoxidized phenolic resin and rubber latex. It was made into a polyester tire cord by being impregnated into an adhesive solution consisting of an increaseable maleic hydride polybutadiene copolymer (Ricobond 7004 from Cray Valley), followed by drying at 160 ° C. and stabilization at 245 ° C.
  • an adhesive solution consisting of an increaseable maleic hydride polybutadiene copolymer (Ricobond 7004 from Cray Valley), followed by drying at 160 ° C. and stabilization at 245 ° C.
  • a polyethylene terephthalate tire cord was manufactured in the same manner as in Example 1, except that the content of the secondary treatment liquid composition was adjusted as shown in Table 1 below.
  • Example 2 Secondary liquid composition (% by weight) water 76.5 75.0 77.5 76.5 77.5 Caustic soda 0.1 0.4 - - - Resorcinol 2.4 3.0 - - - formalin 0.8 1.2 - - - Epoxylated Phenolic Resin - - 2.5 2.5 4.0 Ricobond7004 - - - 1.0 1.0 Vinyl pyridine latex 20.0 17.5 20.0 17.5 15.0 SBR Latex - 2.5 - 2.5 2.5 ammonia 0.2 0.4 - - - - -
  • the cord As a method of showing the adhesive strength between the heat treated cord and the rubber, the cord is placed in a rubber block and vulcanized at a pressure of 50 kgf / cm 2 at 160 ° C. for 20 minutes (initial) or 170 ° C. for 60 minutes (heat resistance). Adhesion is measured at a tensile rate of 200 m / min using an elongation type tensile tester. The same test was carried out 10 times to obtain an average value. Other methods were performed according to ASTM D4776-98.
  • a measure of the resistance value against external stress of the heat treatment cord which simulates tire running conditions.
  • the evaluation of the disc fatigue resistance was evaluated using Ueshima Seisakusho Co., Ltd. FT-6110. Fatigue test conditions were 6% tensile and 12% compression. After 8 hours of fatigue at 120 ° C at 2500rpm, the cord was collected and the strength was measured. Cord strength measurement method was carried out according to the ASTM D885 method.
  • the polyester tire cord according to the present invention shows that the adhesion and fatigue resistance are improved as compared with the comparative example without addition of the maleic hydride polybutadiene copolymer. Can be.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Tires In General (AREA)

Abstract

La présente invention concerne une fibre de polyester traitée au moyen d'un liquide de traitement secondaire écologique, la fibre de polyester contenant une résine phénolique époxydée, un copolymère anhydride maléique-polybutadiène, ainsi que du latex de vinylpyridine et du latex de styrène-butadiène, un procédé de préparation pour celle-ci, et un câble pour pneu, ce par quoi un câble pour pneu hautement fonctionnel qui peut empêcher un phénomène de délaminage entre le caoutchouc et la fibre, qui se produit au moment de l'entraînement à grande vitesse du pneu, peut être préparé par l'amélioration de la force d'adhérence, de la résistance à la chaleur, et de la résistance à la fatigue du câble pour pneu.
PCT/KR2017/000146 2016-01-15 2017-01-05 Fibre de polyester, procédé de préparation pour celle-ci, et câble pour pneu la comportant Ceased WO2017122964A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201780005345.8A CN108431328B (zh) 2016-01-15 2017-01-05 聚酯纤维及其制备方法，以及包含所述聚酯纤维的轮胎帘线
TR2018/07702T TR201807702T1 (tr) 2016-01-15 2017-01-05 Polyester elyaf, bunu ve bunu içeren lastik kordunu hazırlama yöntemi.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2016-0005571 2016-01-15
KR1020160005571A KR101807613B1 (ko) 2016-01-15 2016-01-15 폴리에스테르 섬유, 이의 제조방법 및 이를 포함하는 타이어 코드

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WO2017122964A1 true WO2017122964A1 (fr) 2017-07-20

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PCT/KR2017/000146 Ceased WO2017122964A1 (fr) 2016-01-15 2017-01-05 Fibre de polyester, procédé de préparation pour celle-ci, et câble pour pneu la comportant

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KR (1) KR101807613B1 (fr)
CN (1) CN108431328B (fr)
TR (1) TR201807702T1 (fr)
WO (1) WO2017122964A1 (fr)

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CN110387744A (zh) * 2018-04-19 2019-10-29 北京化工大学 一种纤维骨架材料浸胶液、制备方法及浸渍方法
EP3992357A4 (fr) * 2019-07-03 2022-09-07 Beijing University of Chemical Technology Composition pour le traitement de surface de fibres et procédé de traitement de fibres

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CN109082893B (zh) * 2018-08-16 2020-11-17 联新（开平）高性能纤维有限公司 一种环保型纤维骨架材料浸胶液及其制备工艺和应用
WO2020105438A1 (fr) * 2018-11-22 2020-05-28 株式会社ブリヂストン Pneu
CN114921862A (zh) * 2020-12-22 2022-08-19 南通新帝克单丝科技股份有限公司 一种性能优异的电子元器件用高dpf聚酰胺工业丝
CN114921861A (zh) * 2020-12-22 2022-08-19 南通新帝克单丝科技股份有限公司 一种性能优异的高dpf聚酯工业丝
CN116289194B (zh) * 2023-04-19 2024-11-12 中国科学院理化技术研究所 一种表面改性剂在碳纤维改性中的应用
KR102836918B1 (ko) 2023-07-31 2025-07-23 에이치에스효성첨단소재 주식회사 폴리에스테르 타이어 코드용 접착제 조성물, 폴리에스테르 타이어 코드의 제조방법 및 타이어 코드

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KR100422027B1 (ko) * 1999-08-23 2004-03-11 데이진 가부시키가이샤 접착-처리된 폴리에스테르 섬유 코드의 제조 방법
CA2565035C (fr) * 2004-05-14 2013-04-23 Sartomer Technology Co., Inc. Procede permettant de faire adherer un tissu a du caoutchouc, tissu traite et composites tissu-caoutchouc
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US5300569A (en) * 1990-08-21 1994-04-05 Ricon Resins, Inc. Adhesive rubber compounds
JPH1046475A (ja) * 1996-07-25 1998-02-17 Teijin Ltd ポリエステル繊維の処理方法
KR20120023706A (ko) * 2009-04-28 2012-03-13 가부시키가이샤 브리지스톤 유기 섬유 코드용 접착제 조성물 및 그것을 사용한 고무 보강재, 타이어 및 접착 방법
KR20110078152A (ko) * 2009-12-30 2011-07-07 주식회사 효성 폴리에스테르 타이어코드의 제조 방법
KR20150113745A (ko) * 2014-03-31 2015-10-08 코오롱인더스트리 주식회사 고무 보강 소재용 접착 조성물

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110387744A (zh) * 2018-04-19 2019-10-29 北京化工大学 一种纤维骨架材料浸胶液、制备方法及浸渍方法
EP3992357A4 (fr) * 2019-07-03 2022-09-07 Beijing University of Chemical Technology Composition pour le traitement de surface de fibres et procédé de traitement de fibres

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CN108431328A (zh) 2018-08-21

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