WO2017155286A3 - 2,5-퓨란디카르복시산 제조용 촉매 및 이 촉매를 이용한 2,5-퓨란디카르복시산의 제조방법 - Google Patents

2,5-퓨란디카르복시산 제조용 촉매 및 이 촉매를 이용한 2,5-퓨란디카르복시산의 제조방법 Download PDF

Info

Publication number
WO2017155286A3
WO2017155286A3 PCT/KR2017/002462 KR2017002462W WO2017155286A3 WO 2017155286 A3 WO2017155286 A3 WO 2017155286A3 KR 2017002462 W KR2017002462 W KR 2017002462W WO 2017155286 A3 WO2017155286 A3 WO 2017155286A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
preparing
furancarboxylic acid
fdca
spinel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2017/002462
Other languages
English (en)
French (fr)
Other versions
WO2017155286A2 (ko
Inventor
김용진
조진구
신승한
이홍식
쿠마르미슈라 디네쉬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Korea Institute of Industrial Technology KITECH
Original Assignee
Korea Institute of Industrial Technology KITECH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Institute of Industrial Technology KITECH filed Critical Korea Institute of Industrial Technology KITECH
Priority to US16/082,918 priority Critical patent/US10661252B2/en
Priority to CN201780016089.2A priority patent/CN108712931B/zh
Priority to EP17763547.1A priority patent/EP3427822B1/en
Priority to JP2018547912A priority patent/JP6772287B2/ja
Publication of WO2017155286A2 publication Critical patent/WO2017155286A2/ko
Publication of WO2017155286A3 publication Critical patent/WO2017155286A3/ko
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8986—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
    • C07D307/48—Furfural
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/17—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/20—Constitutive chemical elements of heterogeneous catalysts of Group II (IIA or IIB) of the Periodic Table
    • B01J2523/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/20—Constitutive chemical elements of heterogeneous catalysts of Group II (IIA or IIB) of the Periodic Table
    • B01J2523/27—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
    • B01J2523/47—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
    • B01J2523/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/84—Metals of the iron group
    • B01J2523/842—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/84—Metals of the iron group
    • B01J2523/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

본 발명은 히드록시기 및 카르보닐기를 포함하는 퓨란계 화합물 또는 그 유도체의 카르복시화 촉매로서, 스피넬 구조의 지지체 내에 귀금속 나노 입자가 포함된 2,5-퓨란디카르복시산(FDCA) 제조용 촉매 및 스피넬 구조의 지지체 내에 귀금속 나노 입자가 포함된 촉매 존재 하에, 히드록시기 및 카르보닐기를 포함하는 퓨란계 화합물 또는 그 유도체를 카르복시화시키는 것을 포함하는 것인 2,5-퓨란디카르복시산(FDCA)의 제조방법을 제공한다.
PCT/KR2017/002462 2016-03-07 2017-03-07 2,5-퓨란디카르복시산 제조용 촉매 및 이 촉매를 이용한 2,5-퓨란디카르복시산의 제조방법 Ceased WO2017155286A2 (ko)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US16/082,918 US10661252B2 (en) 2016-03-07 2017-03-07 Catalyst for preparing 2,5-furancarboxylic acid and a method for preparing 2,5-furancarboxylic acid using the catalyst
CN201780016089.2A CN108712931B (zh) 2016-03-07 2017-03-07 用于制备2，5-呋喃二甲酸的催化剂和使用催化剂制备2，5-呋喃二甲酸的方法
EP17763547.1A EP3427822B1 (en) 2016-03-07 2017-03-07 Catalyst for preparing 2,5-furancarboxylic acid and method for preparing 2,5-furancarboxylic acid using catalyst
JP2018547912A JP6772287B2 (ja) 2016-03-07 2017-03-07 ２，５−フランジカルボン酸製造用触媒、およびその触媒を用いた２，５−フランジカルボン酸の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2016-0026921 2016-03-07
KR1020160026921A KR101835609B1 (ko) 2016-03-07 2016-03-07 2,5-퓨란디카르복시산 제조용 촉매 및 이 촉매를 이용한 2,5-퓨란디카르복시산의 제조방법

Publications (2)

Publication Number Publication Date
WO2017155286A2 WO2017155286A2 (ko) 2017-09-14
WO2017155286A3 true WO2017155286A3 (ko) 2018-09-07

Family

ID=59790746

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2017/002462 Ceased WO2017155286A2 (ko) 2016-03-07 2017-03-07 2,5-퓨란디카르복시산 제조용 촉매 및 이 촉매를 이용한 2,5-퓨란디카르복시산의 제조방법

Country Status (6)

Country Link
US (1) US10661252B2 (ko)
EP (1) EP3427822B1 (ko)
JP (1) JP6772287B2 (ko)
KR (1) KR101835609B1 (ko)
CN (1) CN108712931B (ko)
WO (1) WO2017155286A2 (ko)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7458147B2 (ja) 2016-01-13 2024-03-29 ストラ エンソ オーユーイー ２，５－フランジカルボン酸ならびにその中間体および誘導体の製造方法
CA3069521A1 (en) 2017-07-12 2019-01-17 Stora Enso Oyj Purified 2,5-furandicarboxylic acid pathway products
KR102176738B1 (ko) * 2018-07-09 2020-11-09 한국생산기술연구원 퓨란-2,5-디알킬카르복실레이트의 제조방법
TWI725347B (zh) * 2018-10-18 2021-04-21 遠東新世紀股份有限公司 2,5-呋喃二甲酸的製備方法
KR102133304B1 (ko) * 2018-11-16 2020-07-13 한국생산기술연구원 5-히드록시메틸퍼퓨랄로부터 2,5-퓨란디메탄올 및 2,5-테트라히드로퓨란 디메탄올의 제조방법
CN110102350B (zh) * 2019-06-10 2021-12-10 湖南师范大学 用于氧化合成2,5-呋喃二甲酸的催化剂及其制备方法和应用
CN110368953A (zh) * 2019-06-25 2019-10-25 华东师范大学 一种复合氧化物负载铂催化剂及其制备和应用
CN113117705B (zh) * 2019-12-31 2024-05-07 中国石油化工股份有限公司 一种改性钌基催化剂及由其催化制备2,5-呋喃二羧酸的方法
CN113117706B (zh) * 2019-12-31 2024-04-12 中国石油化工股份有限公司 一种金属改性的钌基催化剂及由其催化制备2,5-呋喃二羧酸的方法
KR102326588B1 (ko) * 2020-03-10 2021-11-12 코오롱인더스트리 주식회사 디카르본산 방향족 헤테로환 화합물 제조용 촉매 및 디카르본산 방향족 헤테로환 화합물의 제조방법
CN111548330A (zh) * 2020-04-29 2020-08-18 南京工业大学 锰基尖晶石催化剂上选择氧化5-羟甲基糠醛制备2,5-呋喃二甲醛的方法
KR102573854B1 (ko) * 2020-09-22 2023-09-01 코오롱인더스트리 주식회사 디카르본산 방향족 헤테로환 화합물 제조용 촉매 및 디카르본산 방향족 헤테로환 화합물의 제조 방법
WO2022065687A1 (ko) * 2020-09-22 2022-03-31 코오롱인더스트리 주식회사 디카르본산 방향족 헤테로환 화합물 제조용 촉매 및 디카르본산 방향족 헤테로환 화합물의 제조 방법
KR102526165B1 (ko) * 2020-11-23 2023-05-04 한국생산기술연구원 아디프산 제조용 스피넬 구조 촉매 및 그를 이용한 아디프산의 제조방법
CN113275019B (zh) * 2021-06-04 2022-10-18 云南大学 磁性镍钴氧化物负载金催化剂及其制备方法和应用、2,5-呋喃二甲酸的制备方法
WO2023008611A1 (ko) * 2021-07-28 2023-02-02 코오롱인더스트리 주식회사 디카르본산 방향족 헤테로환 화합물 및 제조방법
EP4360755A4 (en) * 2021-07-28 2025-05-07 Kolon Industries, Inc. Catalyst for producing an aromatic heterocyclic dicarboxylic acid compound and process for producing an aromatic heterocyclic dicarboxylic acid compound
CN113801081B (zh) * 2021-10-14 2023-04-11 新乡学院 一种2,5-呋喃二甲酸及其制备方法
CN114085200B (zh) * 2021-11-15 2023-03-14 华东师范大学 一种2-呋喃甲酸为原料一锅法制备2,5-呋喃二甲酸的方法
CN117085701B (zh) * 2022-05-12 2026-03-27 中国石油化工股份有限公司 贵金属催化剂及其制备方法与应用、2,5-呋喃二甲酸的制备方法
CN115814814B (zh) * 2022-11-18 2024-06-14 吉林化工学院 负载钌的铁铬双金属氧化物催化剂制备方法及应用该催化剂合成2,5-呋喃二甲酸的方法
KR102793190B1 (ko) 2022-11-28 2025-04-07 한국화학연구원 전기화학적 산화 반응을 통한 고효율의 2,5-푸란디카복실산 제조용 촉매, 이의 제조방법, 이를 이용한 2,5-푸란디카복실산 제조방법 및 촉매 재생방법
KR102938361B1 (ko) 2023-04-12 2026-03-12 한국화학연구원 2,5-퓨란 디카르복실산 제조용 촉매 및 2,5-퓨란 디카르복실산 제조방법

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150133388A (ko) * 2014-05-19 2015-11-30 한국생산기술연구원 활성탄에 담지된 금속촉매를 이용한 2,5-디포밀퓨란의 제조방법

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7119225B1 (en) * 2000-08-18 2006-10-10 E. I. Du Pont De Nemours And Company Gold catalyst for selective oxidation
CN100335171C (zh) * 2004-10-21 2007-09-05 北京大学 一种过渡金属－γ－Fe2O3纳米材料及其制备方法与应用
US7829140B1 (en) * 2006-03-29 2010-11-09 The Research Foundation Of The State University Of New York Method of forming iron oxide core metal shell nanoparticles
WO2010132740A2 (en) * 2009-05-14 2010-11-18 Archer Daniels Midland Company Oxidation of furfural compounds
JP5550303B2 (ja) 2009-10-19 2014-07-16 キヤノン株式会社 ２，５−フランジカルボン酸の製造方法
CN103724303B (zh) * 2012-10-15 2016-02-10 中国科学院大连化学物理研究所 一种催化氧化制备2,5-呋喃二甲酸的方法
CN104607202A (zh) * 2015-01-16 2015-05-13 中南民族大学 磁性纳米材料负载钌催化剂及其在催化5-羟甲基糠醛制备2,5-二甲基呋喃中的应用
CN111362892A (zh) * 2020-04-13 2020-07-03 南京工业大学 锰铜尖晶石催化剂上选择氧化5-羟甲基糠醛制备2,5-呋喃二甲酸的方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150133388A (ko) * 2014-05-19 2015-11-30 한국생산기술연구원 활성탄에 담지된 금속촉매를 이용한 2,5-디포밀퓨란의 제조방법

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
GORBANEV, YURY Y. ET AL.: "Effect of Support in Heterogeneous Ruthenium Catalysts Used for the Selective Aerobic Oxidation of HMF in Water", TOPICS IN CATALYSIS, vol. 54, no. 16-18, 2011, pages 1318 - 1324, XP055546021 *
GORBANEV, YURY Y. ET AL.: "Selective Aerobic Oxidation of 5-hydroxymethylfurfural in Water over Solid Ruthenium Hydroxide Catalysts with Magnesium-based Supports", CATALYSIS LETTERS, vol. 141, no. 12, 2011, pages 1752 - 1760, XP055538292 *
MISHRA, DINESH KUMAR ET AL.: "MnCo2O4 Spinel Supported Ruthenium Catalyst for Air-oxidation ofHMF to FDCA under Aqueous Phase and Base-free Conditions", GREEN CHEMISTRY, vol. 19, no. 7, 2017, pages 1619 - 1623, XP055546055, [retrieved on 20170206] *
WAN, XIAOYUE ET AL.: "Base-free Aerobic Oxidation of 5-hydroxymelhyl-furfural to 2,5-furandicarboxylic Acid in Water Catalyzed by Functionalized Carbon Nanotube-supported Au-Pd Alloy Nanoparticles", ACS CATALYSIS, vol. 4, no. 7, 2014, pages 2175 - 2185, XP055546048 *
ZHANG, ZEHUI ET AL.: "Recent Advances in the Catalytic Synthesis of 2,5-furandicarboxylic Acid and Its Derivatives", ACS CATALYSIS, vol. 5, no. 11, 2015, pages 6529 - 6544, XP055546012 *

Also Published As

Publication number Publication date
EP3427822B1 (en) 2021-10-06
JP2019513538A (ja) 2019-05-30
KR20170104216A (ko) 2017-09-15
US10661252B2 (en) 2020-05-26
CN108712931B (zh) 2021-07-23
WO2017155286A2 (ko) 2017-09-14
US20190083960A1 (en) 2019-03-21
EP3427822A2 (en) 2019-01-16
KR101835609B1 (ko) 2018-03-08
CN108712931A (zh) 2018-10-26
EP3427822A4 (en) 2020-01-01
JP6772287B2 (ja) 2020-10-21

Similar Documents

Publication Publication Date Title
WO2017155286A3 (ko) 2,5-퓨란디카르복시산 제조용 촉매 및 이 촉매를 이용한 2,5-퓨란디카르복시산의 제조방법
EP3398948A3 (en) 2,4,6,7-tetrasubstituted pteridine compounds and methods of synthesis and use thereof
EP4349405A3 (en) Respiratory virus vaccines
EP3283470A4 (en) Processes for producing 2,5-furandicarboxylic acid and derivatives thereof and polymers made therefrom
WO2015048547A3 (en) Methods for using and biomarkers for ampk-activating compounds
WO2018175258A8 (en) Methods and compositions for preparing nucleic acid libraries
EP4353257A3 (en) Method for producing rna compositions
EP3183241A4 (en) Catalyst and process for producing 2,5-furandicarboxylic acid from hydromethylfurfural in water
CL2015000501A1 (es) Nanopartícula polimérica de finasterida y minoxidil, proceso de preparación, suspensión acuosa conteniendo la misma, composición farmacéutica, y su uso.
EP3180118A4 (en) Systems and methods for synthesizing chemical products, including active pharmaceutical ingredients
WO2014037529A3 (en) Anti-dandruff composition comprising 1-acetoxychavicol acetate
EP4327880A3 (en) Solid state form of ribociclib succinate
WO2015185023A3 (zh) 一种载体颗粒及其制备方法
EP4234483A3 (en) Synthesis and hydrogen storage properties of novel metal hydrides
EP3263213A4 (en) Catalyst for manufacturing unsaturated aldehyde and/or unsaturated carboxylic acid and manufacturing method of same, and manufacturing method of unsaturated aldehyde and/or unsaturated carboxylic acid
MY184384A (en) Catalyst
WO2015066668A8 (en) Methods of removing alpha-galactose
JP2013074936A5 (ko)
HK1203815A1 (en) Pharmaceutical compositions and methods for their preparation
WO2015161468A8 (en) Methods and systems for producing isosorbide from biomass
WO2015055942A3 (fr) Catalyseur métallique supporté et son utilisation pour l'oxydation sélective du glycérol
JOP20240234A1 (ar) تخليق مشتقات إستر بورونات واستخداماتها
IT201600105530A1 (it) Procedimento per la preparazione di polibutadiene 1,2 sindiotattico in presenza di un sistema catalitico comprendente un complesso piridilico di ferro
WO2017222819A3 (en) Solid state forms of ixazomib citrate
PH12017501244A1 (en) Process for the preparation of diosmin

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2018547912

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2017763547

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 2017763547

Country of ref document: EP

Effective date: 20181008

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17763547

Country of ref document: EP

Kind code of ref document: A2