WO2017183814A3 - 리튬이온 이차전지 음극용 샌드위치형 그래핀 복합구조체와 이의 제조방법 - Google Patents
리튬이온 이차전지 음극용 샌드위치형 그래핀 복합구조체와 이의 제조방법 Download PDFInfo
- Publication number
- WO2017183814A3 WO2017183814A3 PCT/KR2017/003076 KR2017003076W WO2017183814A3 WO 2017183814 A3 WO2017183814 A3 WO 2017183814A3 KR 2017003076 W KR2017003076 W KR 2017003076W WO 2017183814 A3 WO2017183814 A3 WO 2017183814A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sandwich
- composite structure
- graphene composite
- type graphene
- manufacturing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/124—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one nitrogen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/20—Graphite
- C01B32/21—After-treatment
- C01B32/23—Oxidation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/02—Silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/32—Modified amine-aldehyde condensates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
- C08G2261/324—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed
- C08G2261/3241—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain condensed containing one or more nitrogen atoms as the only heteroatom, e.g. carbazole
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/90—Applications
- C08G2261/96—Applications coating of particles
- C08G2261/964—Applications coating of particles coating of inorganic particles
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Carbon And Carbon Compounds (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
탄소가 코팅된 실리콘 나노입자 및 그래핀으로 형성된 샌드위치형 그래핀 복합구조체와 그 제조방법이 제공된다. 친환경적인 여과공정을 통하여 탄소가 코팅된 실리콘 그래핀을 샌드위치형 그래핀 복합구조체로 형성한다. 형성된 샌드위치형 그래핀 복합구조체는 실리콘의 부피팽창을 완화한다. 또한, 실리콘 표면에 코팅된 탄소에 의해 전기전도성을 향상시켜 고용량의 음극재로 사용될 수 있다.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16/092,147 US11217791B2 (en) | 2016-04-20 | 2017-03-22 | Sandwich-type graphene composite structure for anode material of lithium ion secondary battery and manufacturing method thereof |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020160048330A KR101828676B1 (ko) | 2016-04-20 | 2016-04-20 | 리튬이온 이차전지 음극용 샌드위치형 그래핀 복합구조체와 이의 제조방법 |
| KR10-2016-0048330 | 2016-04-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2017183814A2 WO2017183814A2 (ko) | 2017-10-26 |
| WO2017183814A3 true WO2017183814A3 (ko) | 2018-01-04 |
Family
ID=60116118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/KR2017/003076 Ceased WO2017183814A2 (ko) | 2016-04-20 | 2017-03-22 | 리튬이온 이차전지 음극용 샌드위치형 그래핀 복합구조체와 이의 제조방법 |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US11217791B2 (ko) |
| KR (1) | KR101828676B1 (ko) |
| WO (1) | WO2017183814A2 (ko) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109686960A (zh) * | 2019-01-16 | 2019-04-26 | 河南电池研究院有限公司 | 一种碳包覆硅纳米片和硅基复合材料及其制备方法 |
| US10985366B2 (en) * | 2019-01-16 | 2021-04-20 | GM Global Technology Operations LLC | High-performance electroactive material within a sandwiched structure |
| KR102276657B1 (ko) | 2019-12-18 | 2021-07-13 | 우석대학교 산학협력단 | 그래핀-탄소나노튜브-실리콘 함유 복합소재 이차전지 음극재 및 그 제조방법 |
| KR102276658B1 (ko) | 2019-12-19 | 2021-07-13 | 우석대학교 산학협력단 | 그래핀-맥신-실리콘 함유 복합소재 이차전지 음극재 및 그 제조방법 |
| KR102228769B1 (ko) | 2019-12-19 | 2021-03-18 | 우석대학교 산학협력단 | 그래핀-은나노와이어-실리콘 함유 복합소재 이차전지 음극재 및 그 제조방법 |
| CN113122044B (zh) * | 2020-01-10 | 2022-04-08 | 中国科学院宁波材料技术与工程研究所 | 阳离子多巴胺功能化石墨烯水性防腐涂料、其制法与应用 |
| KR102405605B1 (ko) | 2020-03-20 | 2022-06-03 | 우석대학교 산학협력단 | 그래핀-안티몬-실리콘 함유 복합소재 이차전지 음극재 및 그 제조방법 |
| KR102405612B1 (ko) | 2020-03-20 | 2022-06-03 | 우석대학교 산학협력단 | 실리콘-그래핀-은나노와이어 함유 복합소재 이차전지 음극재 및 그 제조방법 |
| KR102405622B1 (ko) | 2020-03-20 | 2022-06-03 | 우석대학교 산학협력단 | 실리콘-그래핀-탄소나노튜브 코어쉘 복합소재 이차전지 음극재 및 그 제조방법 |
| KR102405615B1 (ko) | 2020-03-20 | 2022-06-03 | 우석대학교 산학협력단 | 실리콘-그래핀-안티몬 코어쉘 복합소재 이차전지 음극재 및 그 제조방법 |
| KR102388203B1 (ko) | 2020-03-20 | 2022-04-20 | 우석대학교 산학협력단 | 실리콘-그래핀-맥신 함유 복합소재 이차전지 음극재 및 그 제조방법 |
| KR102353967B1 (ko) * | 2020-05-12 | 2022-01-24 | 울산과학기술원 | 이차원물질-폴리머 복합체의 제조방법 및 이차원물질-폴리머 복합체 |
| KR102524484B1 (ko) * | 2020-10-23 | 2023-04-20 | 고려대학교 산학협력단 | 사전-리튬화된 금속 산화물을 포함하는 다층 복합 구조체 및 그 제조방법 |
| CN116964802A (zh) * | 2021-02-19 | 2023-10-27 | 加利福尼亚大学董事会 | 长循环寿命、高容量的硅阳极及其制造和使用方法 |
| CN113659125B (zh) * | 2021-07-02 | 2022-07-12 | 广东墨睿科技有限公司 | 一种硅碳复合材料及其制备方法 |
| CN113717615B (zh) * | 2021-09-17 | 2022-11-08 | 浙江鱼童新材料股份有限公司 | 一种耐磨防腐的石墨烯/二氧化硅/环氧树脂超滑移复合涂层的制备方法 |
| CN115548291A (zh) * | 2022-09-19 | 2022-12-30 | 中南大学 | 一种以废旧动力电池的石墨负极制备石墨烯/硅碳复合材料的制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140144590A (ko) * | 2013-06-11 | 2014-12-19 | 한국과학기술원 | 왕겨 유래 리튬 이차전지 음극용 활물질 및 그 제조방법 |
-
2016
- 2016-04-20 KR KR1020160048330A patent/KR101828676B1/ko active Active
-
2017
- 2017-03-22 WO PCT/KR2017/003076 patent/WO2017183814A2/ko not_active Ceased
- 2017-03-22 US US16/092,147 patent/US11217791B2/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140144590A (ko) * | 2013-06-11 | 2014-12-19 | 한국과학기술원 | 왕겨 유래 리튬 이차전지 음극용 활물질 및 그 제조방법 |
Non-Patent Citations (4)
| Title |
|---|
| FANG, C. ET AL.: "Improving the Electrochemical Performance of Si Nanoparticle Anode Material by Synergistic Strategies of Polydopamine and Graphene Oxide Coatings", THE JOURNAL OF PHYSICAL CHEMISTRY C, vol. 119, 9 January 2015 (2015-01-09), pages 1720 - 1728, XP055451897 * |
| LI, H. ET AL.: "A Straightforward Approach towards Si@C/graphene Nanocomposite and Its Superior Lithium Storage Performance", ELECTROCHIMICA ACTA, vol. 120, 24 December 2013 (2013-12-24), pages 96 - 101, XP028666296 * |
| SUN, F. ET AL.: "A Rationally Designed Composite of Alternating Strata of Si Nanoparticles and Graphene: a High-performance Lithium-ion Battery Anode", NANOSCALE, vol. 5, 2 July 2013 (2013-07-02), pages 8586 - 8592, XP055451892 * |
| WANG, B. ET AL.: "Adaptable Silicon-Carbon Nanocables Sandwiched between Reduced Graphene Oxide Sheets as Lithium Ion Battery Anodes", ACSNANO, vol. 7, no. 2, 2 January 2013 (2013-01-02), pages 1437 - 1445, XP055306035 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US11217791B2 (en) | 2022-01-04 |
| WO2017183814A2 (ko) | 2017-10-26 |
| KR101828676B1 (ko) | 2018-02-14 |
| US20190157675A1 (en) | 2019-05-23 |
| KR20170120254A (ko) | 2017-10-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| He et al. | Porous carbon nanosheets: Synthetic strategies and electrochemical energy related applications | |
| WO2016008455A3 (zh) | 一种多元复合负极材料、其制备方法及包含其的锂离子电池 | |
| EP4036944A3 (en) | Electrode film for use in an energy storage device | |
| Seman et al. | Systematic gap analysis of carbon nanotube-based lithium-ion batteries and electrochemical capacitors | |
| Kucinskis et al. | Graphene in lithium ion battery cathode materials: A review | |
| JP2016197610A5 (ja) | 蓄電装置、及び蓄電装置用正極活物質 | |
| WO2015157324A3 (en) | Energy storage device, anode thereof, and method of fabricating an energy storage device | |
| WO2017105572A3 (en) | Process for producing lithium batteries having an ultra-high energy density | |
| WO2014201275A3 (en) | High capacity hard carbon materials comprising efficiency enhancers | |
| WO2019078702A3 (ko) | 음극 활물질 및 이를 포함하는 전고체 전지용 음극 | |
| MY191109A (en) | Cathode slurry for lithium ion battery | |
| JP2013030472A5 (ja) | 蓄電装置 | |
| WO2019093681A3 (ko) | 다공성 탄소, 이를 포함하는 양극 및 리튬 이차전지 | |
| WO2014141732A8 (ja) | 金属スズ-炭素複合体、その製造方法、それで得られた非水系リチウム二次電池用負極活物質、これを含む非水系リチウム二次電池用負極及び非水系リチウム二次電池 | |
| JP2014203555A5 (ko) | ||
| CA2899307C (en) | Process for forming a battery containing an iron electrode | |
| JP2016085965A5 (ja) | 蓄電池用電極の製造方法 | |
| WO2011137448A3 (en) | Silicon-carbon nanostructured electrodes | |
| MY179133A (en) | Polyolefin porous film, separator for batteries which is manufactured using said porous film, and methods respectively for manufacturing said porous film and said separator | |
| WO2017034650A3 (en) | Germanium-containing carbon nanotube arrays as electrodes | |
| RU2015144284A (ru) | Аноды для литий-ионного аккумулятора, содержащие частицы графенового углерода | |
| WO2014085233A3 (en) | Lithium-ion capacitors and methods of production | |
| WO2018062836A3 (ko) | 천연 흑연 및 인조 흑연을 포함하는 다층 음극 및 이를 포함하는 리튬 이차전지 | |
| EP4287337A3 (en) | Method for manufacturing electrode including polymer electrolyte | |
| HK1244951A1 (zh) | 有机锂电池 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 17786083 Country of ref document: EP Kind code of ref document: A2 |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 17786083 Country of ref document: EP Kind code of ref document: A2 |