WO2019073404A1 - Système de décomposition de l'eau pour la séparation d'hydrogène et d'oxygène en l'absence de membrane échangeuse d'ions - Google Patents

Système de décomposition de l'eau pour la séparation d'hydrogène et d'oxygène en l'absence de membrane échangeuse d'ions Download PDF

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Publication number
WO2019073404A1
WO2019073404A1 PCT/IB2018/057846 IB2018057846W WO2019073404A1 WO 2019073404 A1 WO2019073404 A1 WO 2019073404A1 IB 2018057846 W IB2018057846 W IB 2018057846W WO 2019073404 A1 WO2019073404 A1 WO 2019073404A1
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Prior art keywords
generating chamber
electrolyte solution
water
gas
source
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PCT/IB2018/057846
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English (en)
Inventor
Tayirjan Taylor ISIMJAN
Kumudu MUDIYANSELAGE
Hicham Idriss
Khalid Albahily
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SABIC Global Technologies BV
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SABIC Global Technologies BV
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Priority to DE112018004479.3T priority Critical patent/DE112018004479T5/de
Priority to CN201880065938.8A priority patent/CN111212933A/zh
Priority to US16/754,614 priority patent/US20200354840A1/en
Publication of WO2019073404A1 publication Critical patent/WO2019073404A1/fr
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C25B1/55—Photoelectrolysis
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/02—Process control or regulation
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/01—Electrolytic cells characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • C25B9/77—Assemblies comprising two or more cells of the filter-press type having diaphragms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the invention generally concerns generation of hydrogen (H 2 ) and oxygen (0 2 ) from an aqueous solution. This can performed by using a reactor that includes a H 2 generation chamber and an 0 2 generation chamber.
  • the reactor does not have to include a H 2 and 0 2 permeable material such as an H 2 and 0 2 permeable membrane or an ionic bridge.
  • Hydrogen (H 2 ) is a clean alternative to fuel.
  • Conventional technology produces hydrogen on a commercial scale from steam reforming of methane. Due to the depletion of fossil fuels, there is a necessity to find an alternative feedstock to meet the growing demand for hydrogen production globally.
  • Water-splitting can be achieved through electrolysis of water, photocatalytic splitting of water, or electrophotocatalytic splitting of water. These approaches are performed in acidic or basic media in conjunction with ion exchange membranes.
  • the selection of the membrane can depend on the pH of the medium.
  • a proton exchange membrane (PEM) can be used in an acidic environment, while an alkaline anion exchange membrane can used in a basic environment.
  • PEM proton exchange membrane
  • alkaline anion exchange membrane can be used in a basic environment.
  • ⁇ Energy Environ. Sci., 2015, 8, 2003 describes a membrane-less electrolyzer for hydrogen production across the pH scale.
  • two parallel plates are coated with hydrogen and oxygen evolution catalysts, respectively, and are separated by less than a few hundreds of micrometers.
  • the electrolyte flows between the catalyst plates and the evolved gases move close to the corresponding catalyst surface due to the Segre ' -Silberberg effect.
  • Each of the product gas streams can be collected in dedicated outlets. Stacks of these planes in horizontal can be used for higher throughput.
  • Holmes-Gentle ⁇ Sustainable Energy Fuels, 2017, 1, 1184) describes a membrane-less photoelectrochemical cell similar to the Hashemi membrane-less electrolyzer.
  • the invention can address the problem associated with cross-contamination of H2 and O2 during the water-splitting process, and in particular, during the separation of H2 and O2 gases from the electrolyte solution. During this separation process, H2 and O2 combination can occur due to the continuous mixing of the aqueous solution with dissolved gasses.
  • a reactor design has been discovered that can generate H2 and O2 under electrolysis and/or photoelectrical conditions in separate chambers and allows for the electrolyte solution to be purged and recycled to the reactor.
  • the H2 and O2 is generated simultaneously.
  • This provides for an elegant flow through design with minimal cross- contamination of O2 in the H2 generating chamber and H2 in the O2 generating chamber.
  • cross-contamination of H2 in the O2 generating chamber and O2 in the H2 generating chamber can be limited to less than 0.2 mol.%. Limiting cross-contamination can result in a H2/O2 oxygen mixture having H2 and O2 ratios under the explosion limit (5%).
  • the reactor design can be operated in a cost efficient and safe manner that lends itself to commercial scale production
  • a water-splitting system for the production hydrogen (H2) gas and oxygen (O2) gas from an aqueous electrolyte solution.
  • the water-splitting system can include a reactor having H2 and O2 generating chambers that can be separate chambers but do not have to be separated by a H2 and/or O2 gas permeable material (e.g., a membrane, an ionic bridge, or both).
  • the H2 generating chamber can include a cathode and at least a first fluid inlet.
  • the O2 generating chamber can include an anode in electrical communication with the cathode and at least a first fluid inlet.
  • the first fluid inlets of each of the H2 and O2 generating chambers can be fluidly coupled to a purged electrolyte source, a purge gas source, or a combination thereof
  • the first fluid inlets can each receive a purged electrolyte solution, a purge gas, or a combination thereof.
  • the system can further include a H2 reservoir fluidly coupled to the H2 generating chamber.
  • the H2 reservoir can produce a H2 containing gas stream and a H2 containing electrolyte solution stream.
  • the system can further include a H2 purification system that can be fluidly coupled with an H2 outlet of the H2 reservoir, preferably a H2 permeable membrane.
  • the system can include an O2 reservoir fluidly coupled to the O2 generating chamber.
  • the O2 reservoir can produce an O2 containing gas stream and an O2 containing aqueous electrolyte solution stream.
  • the system can further include an O2 purification system that can be fluidly coupled to an O2 outlet of the O2 reservoir, preferably a O2 permeable membrane.
  • an electrolyte source e.g., a reservoir that contains the electrolyte source
  • the electrolyte source can be fluidly coupled to each of the first fluid inlets. The electrolyte source can receive and purge the electrolyte solution from the H2 generating chamber and/or the O2 generating chamber.
  • the purged electrolyte solution can be returned to the first fluid inlets of the H2 generating and O2 generating chambers using a fluid mover (e.g., pumped or pressurized to the chambers).
  • the first fluid inlets can be purge gas inlets.
  • the first fluid inlets can receive the purged electrolyte solution, and the H2 generating chamber and the O2 generating chamber each can further include a second fluid inlet. Each second fluid inlet can be fluidly coupled to a purge gas source.
  • the reactor can be a flow-through reactor.
  • the anode and the cathode are included in a H2 or O2 impermeable material positioned at least partially between or substantially between the H2 generating chamber and the O2 generating chamber.
  • the anode can include an oxidation catalyst, preferably a H2 generating photocatalyst in fluid communication with the aqueous electrolyte solution in the H2 generating chamber.
  • the H2 generating chamber can receive electromagnetic radiation, which can be used to excite the photocatalyst, which in turn catalyzes the production of H2 and holes.
  • the cathode can include a reduction catalyst, preferably an O2 generating photocatalyst, in fluid communication with the aqueous electrolyte solution in the O2 generating chamber.
  • the O2 generating chamber can receive electromagnetic radiation, which can be used to excite the photocatalyst, which in turn catalyzes the production of O2 and electrons.
  • the produced electrons can be transferred to the anode via an electrical connection between the cathode and anode ⁇ e.g., conductive material such as a conductive wire).
  • the H2 generating chamber can be fluidly coupled to the O2 generating chamber.
  • the H2 generating chamber can be coupled to the O2 generating chamber by one or more apertures.
  • first and second apertures are comprised in a conduit that connects the H2 generating chamber with the O2 generating chamber.
  • the apertures or conduit can be positioned in the lower portion of the two chambers to allow transport of ions into each chamber with limited or without cross-contamination of H2 and O2 into the O2 and H2 generating chambers, respectively.
  • the lower portion of the H2 and O2 generating chambers can include apertures that are on or in the side walls of each chamber and that are positioned anywhere in the bottom half of the reactor such as at half the height of the chambers or less.
  • the apertures or conduit can be positioned on the side wall of each chamber proximate the bottom of the chamber.
  • the aperture is a hole or a plurality of holes ⁇ e.g., a screen) in the H2 and O2 impermeable material that separates the H2 generating chamber with the O2 generating chamber.
  • a water-splitting process for production of H2 and O2 is described.
  • the process can include providing an electrolyte solution to any of the water- splitting systems of the present invention.
  • the electrolyte solution can include, water, a purge gas, and an electrolyte.
  • the electrolyte solution in the H2 generating chamber and the electrolyte solution in the O2 generating chamber can be subjected to conditions sufficient to produce a H2 containing aqueous electrolyte solution and an O2 containing aqueous electrolyte solution.
  • the purge gas, at least a portion of the generated H2, and at least a portion of the generated O2 can be dissolved in each of the aqueous electrolyte solutions.
  • a majority of or all of the generated H2 and/or generated O2 can be dissolved in the aqueous electrolyte solution.
  • the H2 containing aqueous electrolyte solution and/or the O2 containing aqueous electrolyte solution can be subjected to conditions suitable to produce a purge gas containing aqueous electrolyte solution, a gaseous H2 stream, and a gaseous O2 stream.
  • the purge gas containing aqueous electrolyte solution can be provided to the H2 generating chamber of the water- splitting system, the O2 generating chamber of the water-splitting system, or both.
  • the purge gas containing aqueous electrolyte solution can be free of H2 and O2.
  • the purge gas containing aqueous electrolyte solution can include H2 and O2 in molar H2/O2 ratio under the flammability limit.
  • the purge gas can by any gas, preferably an inert gas, most preferably nitrogen N2.
  • the purge gas can reduce or limit contamination of H2 into the O2 containing aqueous electrolyte stream, O2 into the H2 containing aqueous electrolyte stream, or both.
  • Water-splitting conditions can include a pressure of 0.010 MPa to 2.1 MPa, a temperature of 5 °C to 100 °C, a pH of 0 to 14, or a combination thereof.
  • Step (c) can include compressing the H2 containing aqueous electrolyte solution stream to produce a gaseous H2 stream and the electrolyte solution and/or (i) collecting the H2 containing aqueous electrolyte solution stream in the H2 reservoir, the O2 containing aqueous electrolyte solution stream in the O2 reservoir or both; (ii) separating the H2 gaseous stream from the H2 containing aqueous electrolyte solution and the O2 gaseous stream from the O2 containing aqueous electrolyte solution, or both; (iii) forming an aqueous electrolyte solution comprising residual H2, O2, or both; and (iv) purging the step (iii) aqueous electrolyte solution with the purge gas to form the purge gas containing aqueous electrolyte solution.
  • the process includes providing a purge gas to the H2 generating chamber, the O2 generating chamber, or both and/or providing the purged electrolyte solution to the H2 generating chamber and the O2 generating chamber.
  • Embodiment 1 describes a water-splitting system for the production of hydrogen (H2) gas and oxygen (O2) gas from an aqueous electrolyte solution, the system comprising a reactor comprising: a H2 generating chamber comprising a cathode and at least a first fluid inlet fluidly coupled to a purged electrolyte source, a purge gas source, or a combination thereof; and an O2 generating chamber comprising an anode in electrical communication with the cathode and at least a first fluid inlet fluidly coupled to the purged electrolyte source, the purge gas source, or a combination thereof, wherein the H2 and O2 generating chambers are not separated by a H2 or an O2 gas permeable material.
  • H2 and O2 generating chambers are not separated by a H2 or an O2 gas permeable material.
  • Embodiment 2 is the water-splitting system of embodiment 1, wherein the H2 or O2 gas permeable material is a membrane, an ionic bridge, or both.
  • Embodiment 3 is the water-splitting system of any one of embodiments 1 to 2, further comprising a H2 reservoir fluidly coupled to the H2 generating chamber, the purged electrolyte source and an H2 product outlet.
  • Embodiment 4 is the water-splitting system of embodiment 3, further comprising a H2 purification system, preferably a H2 permeable membrane, fluidly coupled to the H2 product outlet.
  • Embodiment 5 is the water- splitting system any one of embodiments 1 to 4, further comprising an O2 reservoir fluidly coupled to the O2 generating chamber, the purged electrolyte source, and an O2 product outlet.
  • Embodiment 6 is the water-splitting system of embodiment 5, further comprising an O2 purification system, preferably an O2 permeable membrane, fluidly coupled to the O2 product outlet.
  • Embodiment 7 is the water-splitting system of any one of embodiments 1 to 6, wherein purged electrolyte source is fluidly coupled to the purge gas source.
  • Embodiment 8 is the water- splitting system of any one of embodiments 1 to 7, wherein the first fluid inlets are fluidly coupled to the purged electrolyte source, and wherein the H2 generating chamber further comprises a second inlet and/or the O2 generating chamber further comprises a second inlet, each second inlet fluidly coupled to the purge gas source.
  • Embodiment 9 is the water-splitting system of any one of embodiments 1 to 8, wherein the H2 generating chamber and the O2 generating chamber are fluidly coupled by at least one aperture positioned at a lower portion of both chambers, the at least one aperture sized to allow transport of ions between each chamber.
  • Embodiment 10 is the water- splitting system of any one of embodiments 1 to 9, further comprising a conduit coupled to the H2 generating chamber and the O2 generating chamber, the conduit comprising a first aperture coupled to the H2 generating chamber and a second aperture coupled to the O2 generating chamber.
  • Embodiment 11 is the water-splitting system of any one of embodiments 1 to 10, wherein the anode and the cathode are comprised in a H2 and/or O2 gas impermeable material positioned at least partially between the H2 generating chamber and the O2 generating chamber.
  • Embodiment 12 is the water-splitting system of embodiment 11, wherein the anode comprises a photo-reduction catalyst in fluid communication with a purged electrolyte solution from the purged electrolyte source, and the H2 generating chamber is in communication with an electromagnetic radiation source.
  • Embodiment 13 is the water-splitting system of any one of embodiments 11 to 12, wherein the cathode comprises a photo-oxidation catalyst in fluid communication with a purged electrolyte solution from the purged electrolyte source, and the O2 generating chamber is in communication with an electromagnetic radiation source.
  • Embodiment 14 is the water-splitting system of any one of embodiments 11 to 13, wherein the H2 generating chamber and the O2 generating chamber are fluidly coupled by at least one aperture positioned at a lower portion of both chambers, and wherein the at least one aperture is comprised in the H2 and/or O2 gas impermeable material.
  • Embodiment 15 is a water-splitting system for the production of hydrogen (H2) gas and oxygen (O2) gas from an aqueous electrolyte solution, the system comprising: a reactor comprising: a H2 generating chamber comprising a cathode and at least a first fluid inlet fluidly coupled to a purged electrolyte source, a purge gas source, or a combination thereof; and an O2 generating chamber fluidly coupled to the H2 generating chamber, the O2 generating chamber comprising an anode in electrical communication with the cathode and at least a first fluid inlet fluidly coupled to the purged electrolyte source, the purge gas source, or a combination thereof, wherein the H2 and O2 generating chambers are not separated by a H2 or an O2 gas permeable material.
  • H2 and O2 generating chambers are not separated by a H2 or an O2 gas permeable material.
  • Embodiment 16 is a water-splitting process for the production of hydrogen (H2) gas and oxygen (O2) gas, the process comprising: (a) providing an electrolyte solution to each of the H2 generating chamber and the O2 generating chamber of the water-splitting system of any one of embodiments 1 to 15, the electrolyte solution comprising water, a purge gas, and an electrolyte; (b) subjecting the electrolyte solution in the H2 generating chamber and the electrolyte solution in the O2 generating chamber to conditions sufficient to produce a H2 containing electrolyte solution in the H2 generating chamber and an O2 containing electrolyte solution in the O2 generating chamber, wherein at least a portion of the generated H2 is dissolved in the H2 containing aqueous electrolyte solution, and at least a portion of the generated O2 is dissolved in the O2 containing electrolyte solution; and (c) subjecting the H2 containing electrolyte solution and/or
  • Embodiment 17 is the process of embodiment 16, further comprising providing the purge gas containing electrolyte solution to the H2 generating chamber of the water-splitting system, the O2 generating chamber of the water-splitting system, or both, wherein the purge gas containing electrolyte solution comprises H2 and O2 in a molar H2/O2 ratio under the explosion limit.
  • Embodiment 18 is the process of any one of embodiments 16 to 17, wherein the purge gas comprises any gas, preferably an inert gas, most preferably nitrogen N2, and wherein the purge gas is at least partially or fully solubilized in the aqueous electrolyte solution.
  • Embodiment 19 is the process of any one of embodiments 16 to 18, wherein the water-splitting conditions comprise a pressure of 0.010 MPa to 2.1 MPa, a temperature of 5 °C to 100 °C, a pH of 0 to 14, or a combination thereof.
  • Embodiment 20 is the process of any one of embodiments 16 to 19, wherein the purge gas reduces contamination of H2 into the O2 containing aqueous electrolyte stream, O2 into the H2 containing aqueous electrolyte stream, or both.
  • Embodiment 21 is the process of any one of embodiments 16 to 20, wherein step (c) comprises compressing the H2 containing aqueous electrolyte solution stream to produce a gaseous H2 stream and the electrolyte solution comprising the purge gas.
  • Embodiment 22 is the process of any one of embodiments 16 to 21, wherein step (c) comprises: (i) collecting the H2 containing aqueous electrolyte solution stream in the H2 reservoir, the O2 containing aqueous electrolyte solution stream in the O2 reservoir or both; (ii) separating the H2 gaseous stream from the H2 containing aqueous electrolyte solution and the O2 gaseous stream from the O2 containing aqueous electrolyte solution, or both; (iii) forming an aqueous electrolyte solution comprising residual H2, O2, or both; and (iv) purging the step (iii) aqueous electrolyte solution with the purge gas to form the purge gas containing aqueous electrolyte solution.
  • Embodiment 23 is the process of any one of embodiments 16 to 22, further comprising: providing a purge gas to the H 2 generating chamber, the 0 2 generating chamber, or both; and providing the purged electrolyte solution to the H 2 generating chamber and the 0 2 generating chamber.
  • Embodiment 24 is the process of any one of embodiments 16 to 23, wherein step (b) further comprises flowing the a portion of the electrolyte solution between the H 2 generating chamber and the 0 2 generating chamber through at least one of the apertures of embodiments 10, 11, or 15.
  • electromagnetic radiation refers to all wavelengths of light unless specified otherwise.
  • wavelengths of light include radio wave, microwave, infrared, visible light, ultraviolet, X-ray, and gamma radiation, or any combination thereof.
  • the electromagnetic radiation can include visible light or ultraviolet light or a combination of the two.
  • Coupled is defined as connected, although not necessarily directly, and not necessarily mechanically; two items that are “coupled” may be unitary with each other.
  • the terms “about” or “approximately” are defined as being close to the value, term, or phrase that follows, as understood by one of ordinary skill in the art. In one non-limiting embodiment, the terms are defined to be within 10%, preferably within 5%, more preferably within 1%, and most preferably within 0.5%.
  • the terms “wt.%,” “vol.%,” or “mol.%” refers to a weight, volume, or molar percentage of a component, respectively, based on the total weight, the total volume of material, or total moles, that includes the component. In a non-limiting example, 10 grams of component in 100 grams of the material is 10 wt.% of component.
  • the photoelectrochemical systems of the present invention can "comprise,” “consist essentially of,” or “consist of particular ingredients, components, compositions, etc. disclosed throughout the specification.
  • a basic and novel characteristic of the photoelectrochemical water- splitting systems of the present invention are their abilities to produce high purity H 2 and 0 2 in a continuous manner.
  • the H 2 and 0 2 generating chambers can be separate chambers, but are not separated by H 2 and 0 2 permeable membranes and/or an ionic bridge.
  • FIG. 1 depicts a schematic of the water-splitting system of the present invention.
  • FIG. 2 depicts a schematic of the water-splitting system of the present invention with a H 2 reservoir and an 0 2 reservoir.
  • FIG. 3A depicts a schematic of the water-splitting system of the present invention of FIG. 1 with an aperture between the H 2 generating chamber and the 0 2 generating chamber.
  • FIG. 3B depicts a schematic of the water-splitting system of the present invention of FIG. 2 with an aperture between the Fh generating chamber and the O2 generating chamber.
  • FIG. 4A depicts a schematic of the water-splitting system of the present invention with a H2 generating chamber and the O2 generating chamber and a Fh and O2 gas impermeable material positioned between the chambers.
  • FIG. 4B depicts a schematic of the water-splitting system of FIG. 4A with an aperture in the H2 and O2 gas impermeable material.
  • FIGS. 5A through 5D depict a (5 A) front view of a stacked water-splitting reactor, (5B) back view of the stacked water-splitting reactor, (5C) gas impermeable material with anodic material, and (5D) gas impermeable material with cathodic material.
  • FIGS. 6A through 6D depict a (6A) front view of a stacked water-splitting reactor having a purge gas inlet, an electrolyte source inlet and a gas outlet, (6B) back view of the stacked water-splitting reactor, (6C) gas impermeable material with anodic material, (6D) gas impermeable material with cathodic material.
  • FIG. 7 depicts a schematic of a monolithically integrated photocatalyst catalyst configuration of the water-splitting system of the present invention.
  • FIGS. 8A and 8B depict schematics of photocatalyst catalyst configurations of the water-splitting system of the present invention.
  • FIGS. 9A and 9B are graphs of addition of H 2 (FIG. 9A) and O2 (FIG. 9B) into a H 2 reservoir and O2 reservoir of the system of the present invention.
  • FIGS. 10A and 10B are graphs of moles of H2 and O2 after injecting both separately to a H2 reservoir and O2 reservoir of the system of the present invention as a function of time.
  • the discovery is premised on a reactor that does not require the use of a H2 and/or O2 gas permeable material such as a membrane or an ionic bridge.
  • a reactor of the present invention can provide purged electrolyte solution to a hydrogen generating chamber and an oxygen generating chamber with a minimal amount of H2 or O2 cross contamination in the respective chambers.
  • FIGS. 1 to 6 can also include various equipment that is not shown and is known to one of skill in the art of chemical processing. For example, some controllers, piping, computers, valves, pumps, heaters, thermocouples, pressure indicators may not be shown.
  • Water-splitting reactor 102 can include Fh generating chamber 106 and O2 generating chamber 108.
  • the chambers can receive electromagnetic radiation.
  • the electromagnetic radiation can be visible light (e.g., sunlight or artificially produced visible light) or ultraviolet radiation or a combination of the two.
  • reactor 102, H2 generating chamber 106, and O2 generation chamber 108 can include one or portions or sides that are transparent to light, either sunlight, or artificial light.
  • transparent materials include glass, quartz, organic polymers, silica-based polymers and the like.
  • chamber 106 or 108 can be opaque and a light source can be placed within said chambers, affixed to the walls of said chambers, and/or built into the walls of said chambers (not shown).
  • Reactor 102 can include a housing 1 10 (shown with dotted lines) that houses H2 generation chamber 106 and O2 generation chamber 108. Housing and chambers can include spacers and connectors suitable to position the chambers in the housing (See, for example FIGS. 4A-4D). In some embodiments, a portion or all of housing 1 10 can be transparent.
  • the chambers are aligned in a parallel configuration in the housing such that electromagnetic radiation passes through the housing, a chamber, and into the adjacent chamber.
  • a housing is not necessary and/or sides of the housing make up the sides of the chambers.
  • H2 generating chamber 106 and O2 generating chamber 108 have four distinct sides.
  • H2 generating chamber 106 and O2 generating chamber 108 can have a shared wall that is impermeable to H2 and O2 gases.
  • all or portions of the reactor 102, housing 1 10, H2 generating chamber 106, and O2 generation chamber 108 can be manufactured from a polymeric material (e.g., polymethylmethacrylate (PMMA)).
  • H2 generating chamber 106 can include cathode 1 12 capable of reducing H + ions in electrolyte solution 1 14.
  • cathode 1 12 is a photocatalyst capable of accepting electromagnetic radiation and catalyzing the generation of H2 from water and electrolyte solution 1 14.
  • H2 generating chamber 106 can include H2 outlet 1 16 and electrolyte solution outlet 1 18.
  • H2 outlet 1 16 can allow generated H2 to be removed from the H2 generating chamber and be in fluid communication with purification systems and/or collection systems (not shown).
  • Electrolyte solution outlet 118 can be in fluid communication with electrolyte source 104 via piping 120 to allow H 2 containing electrolyte solution to be removed from H 2 generating chamber 106 and be provided to electrolyte source 104.
  • 0 2 generating chamber 108 can include anode 124 capable of oxidizing OH " in electrolyte solution 114 to 0 2 .
  • anode 124 include a photocatalyst capable of catalyzing generation of O2 from water and electrolyte solution 114.
  • Anode 124 and cathode 112 can be electrically coupled through circuit 126.
  • Circuit 126 can be a wire ⁇ e.g., copper wire) that connects the two electrodes.
  • circuit 126 can include a power source to supply electricity to one or more electrons. It should be understood, that one of skill in the art can electrically connect the cathode and anode as needed depending on the chosen electrode or catalyst.
  • O2 generating chamber 108 can include O2 outlet 128 and electrolyte solution outlet 130.
  • O2 outlet 128 can allow generated O2 to be removed from the O2 generating chamber and be in fluid communication with purification systems and/or collection systems (not shown).
  • Electrolyte solution outlet 130 can be in fluid communication with electrolyte source 104 via piping 132 to allow O2 containing electrolyte solution to be removed from O2 generating chamber 108 and be provided to electrolyte source 104.
  • Electrolyte source 104 can include electrolyte solution inlet 134, purge gas ⁇ e.g., N2, argon, inert gas, or other gases) inlet 136, and electrolyte solution outlet 138.
  • Electrolyte solution inlet 134 can be in fluid communication with piping 120 and/or other piping that allow gas containing ⁇ e.g., H 2 and/or O2) electrolyte solutions and/or fresh electrolyte solution to enter electrolyte source 104.
  • Purge gas inlet 136 can be in fluid communication with sparging system (not shown) capable of delivering a sufficient amount of purge gas to substantially or completely remove (degas) dissolved reactive gases ⁇ e.g., H 2 and/or O2), forming degassed electrolyte solution 140.
  • the purge gas can be any gas that does not react with the water- splitting materials or reagents ⁇ e.g., cathode material, anode material, intermediate reactants, products, or water).
  • Non-limiting examples of purge gas include nitrogen (N2), helium (H 2 ), argon (Ar), carbon dioxide (CO2), hydrocarbon gases ⁇ e.g., methane, ethane, propane and butane).
  • N 2 is used as the purge gas.
  • System 100 can include fluid mover 146 ⁇ e.g., a pump).
  • Degassed electrolyte solution 140 can be moved using fluid mover 146 to H 2 generating chamber electrolyte inlet 142, O2 generating chamber inlet 144, via degassed electrolyte solution outlet 138 and piping 148, 150, and 152.
  • Piping 148, 150, and 152 can fluidly couple the H 2 generating chamber with the O2 generating chamber.
  • pressure from purge gas entering inlet 136 is sufficient to move the electrolyte solution to the various chambers.
  • Removing the H 2 and O2 from the electrolyte solution can minimize or inhibit cross-contamination of H2 into the O2 generating chamber and/or O2 into the H2 generating chamber. Such cross contamination can cause formation of water molecules from reactions of H + and or OH " with the generated O2, H2 respectively.
  • the reactive gas mixture can be removed from the electrolyte source via reactive gas outlet 154.
  • Reactive gas mixture can be a mixture of H2, O2 and purge gas and have a molar H2 to O2 ratio under the flammability limit.
  • Reactive gas outlet 154 can be in fluid communication with a collection unit, purification unit, transportation line, or the like.
  • system 100 is an electrolysis system or a photoelectrochemical system.
  • the water-splitting system includes a H2 reservoir and an O2 reservoir fluidly coupled to the electrolyte source and the H2 generating chamber and the O2 generating chamber. Inclusion of H2 and O2 reservoirs can allow for separation of the H2 gas and/or O2 gas from the H2 and O2 containing electrolyte solutions prior to the electrolyte solution entering electrolyte source 104.
  • FIG. 2A a schematic of water-splitting system 200 of the present invention is depicted that includes H2 collection unit (reservoir) 202 and O2 collection unit (reservoir) 204.
  • System 200 shown in FIG. 2 includes water-splitting reactor 102, electrolyte source 104 and other components of FIG. 1.
  • H2 reservoir 202 can be in fluid communication with H2 generating chamber 106 of reactor 102 via H2 outlet 116, piping 206, and reservoir H2 inlet 208.
  • H2 is generated in H2 generation chamber 106, a mixture of electrolyte solution with dissolved and free H2 can exit the H2 generation chamber and enter H2 reservoir.
  • aqueous electrolyte droplets can separate from the gaseous H2.
  • the purge gas can enter H2 generating chamber through inlet 142 or through a second inlet (not shown) and purge or sweep gaseous H2 from H2 generating chamber 106 into the H2 reservoir 202.
  • Addition of the purge gas into H2 generating chamber 106 can saturate the cathode with purge gas and inhibit H + ions present to combine with any OH " present to form H2O.
  • Gaseous H2 can exit H2 reservoir 202 via H2 outlet 210 and be in fluid communication with H2 permeable membrane 212 via piping 214.
  • Membrane 212 can be a H2 permeable membrane capable of separating H2 from the purge gas and trace amounts of O2.
  • O2 reservoir 204 can be in fluid communication with O2 generating chamber 108 of reactor 102 via O2 outlet 128, piping 218, and reservoir O2 inlet 220. As O2 is generated in O2 generation chamber 108, a mixture of electrolyte solution with dissolved and free O2 can exit the O2 generation chamber and enter O2 reservoir. In O2 reservoir 204, aqueous electrolyte droplets separate from the gaseous O2. In some embodiments, the purge gas can enter O2 generating chamber 108 through inlet 144 or a second inlet (not shown) and purge or sweep gaseous O2 from O2 generating chamber 108 into O2 reservoir 204.
  • Addition of the purge gas into O2 generating chamber 106 can saturate the anode with purge gas and inhibit OH " ions present to combine with any H + present to form H2O.
  • Gaseous O2 can exit O2 reservoir 204 via O2 outlet 222 and be in fluid communication with O2 permeable membrane 224 via piping 226.
  • Membrane 224 can be an O2 permeable membrane capable of separating O2 from the purge gas and/or trace amounts of H2.
  • H2 reservoir 202 and O2 reservoir 204 can be in fluid communication with electrolyte source inlet 146 via piping 228 and 230, respectively.
  • Electrolyte source 104 can receive electrolyte solution from H2 reservoir 202, O2 reservoir 204, or both. Such an electrolyte solution can have dissolved H2 and O2 in the solution. The dissolved H2 and O2 can be removed from the electrolyte solution to produce a degassed electrolyte solution that can be returned to H2 generating chamber and O2 generating chamber via piping 146, 148 and 150 as described for system 100.
  • the H2 generating chamber and the O2 generating chamber can be in direct fluid communication with each other.
  • the two chambers can include an aperture that connects the two chambers.
  • the aperture can be any size or shape ⁇ e.g., parabolic, circular, elliptical, trapezoid, parallelogram, square, rectangular, polygonal, or the like).
  • the aperture can be sized to be sufficient to allow mass transport of ions (H + ) and (OH " ) at a rate sufficient to sustain a water-splitting reaction. Such sizing can be determined by known engineering methods depending on the size of the reactor.
  • FIG. 3A depicts system 300 that includes the water-splitting system of FIG.
  • FIG. 3B system 300 that includes the water-splitting system of FIG. 2 having the H2 generating chamber directly coupled with O2 generating chamber via an aperture.
  • a first aperture 302 and a second aperture 304 are included in conduit 306.
  • first aperture 302 and second aperture 304 can be a single hole or a plurality of holes ⁇ e.g., a screen). Fluid can equilibrate between the two chambers so that the solutions remain pH neutral. As shown the aperture(s) are positioned at the lower portion of the chambers.
  • apertures 302 and 304 can include covers (not shown) that can cover the apertures during use.
  • the apertures can be covered when cross-contamination of O2 is detected in the H2 generating chamber or cross-contamination of H2 is detected in the O2 generating chamber.
  • the covers can be electronically controlled.
  • circuit 126 can be connected through conduit 302 (not shown) instead of outside the reactor.
  • the water-splitting system includes a H2 and/or O2 impermeable material.
  • FIGS. 4A and 4B a schematic of water-splitting reactor 102 having H2 generating chamber 106, O2 generating chamber 108, and H2 and/or O2 impermeable material 402 positioned between the two chambers.
  • impermeable material 402 includes aperture 404 that allows H2 generating chamber and O2 generating chamber to be fluidly coupled.
  • aperture can be a hole or a plurality of holes that allows transport of ions into each chamber.
  • Reactor 102 of system 400 can be coupled to electrolyte source 104, H2 reservoir 202, O2 reservoir 204 as described in FIGS. 1, 2, 3 A and 3B.
  • FIGS. 4A and 4B H2 and/or O2 impermeable material 302 can be made of the same materials as H2 generating chamber 106, O2 generating chamber 108, and/or housing 1 10.
  • H2 or O2 impermeable material is an inner wall of both chambers.
  • a portion of the surface of H2 or O2 impermeable material 302 in the H2 generating chamber can include the cathode and/or a photocatalyst capable of generating H2 from water.
  • the cathode material and/or the photocatalyst can be deposited on the surface or coated on the surface of the impermeable material.
  • the opposite surface of H2 or O2 impermeable material 302 in the O2 generating chamber can be include the anode and/or photocatalyst capable of generating O2 from water.
  • the anode and/or photocatalyst can be deposited on the surface or coated on the surface of the impermeable material.
  • circuit 126 is not necessary.
  • H2 and O2 generated in their respective chambers can be captured as previously described.
  • the electrolyte solution from the chambers can be in fluid communication with the electrolyte source as previously described.
  • the water-splitting system of the present invention can have a stacked configuration as shown in FIGS. 5A-5D.
  • FIG. 5A is a front view of the stacked water- splitting reactor of the present invention that includes H2 generating chamber 106, electrolyte inlet 142, and Fb/electrolyte solution outlet 1 16.
  • FIG. 5B is a back view of a stacked water-splitting reactor that includes O2 generating chamber 108, electrolyte inlet 138, and C /electrolyte solution outlet 128.
  • Gas impermeable material 302 can be positioned between the two chambers and can include a cathode material and/or photocatalyst (e.g., 1 12) and an anode material and/or photocatalyst (e.g., 124) as shown in FIGS. 5C and 5D.
  • Cathode material 1 12 can be in fluid communication with electrolyte solution flowing into inlet 142.
  • Cathode material 124 can be in fluid communication with electrolyte solution flowing into inlet 138.
  • Spacers 502 and 504 can be positioned between the gas impermeable material and the H2 generating chamber and the O2 generating chamber, respectively.
  • reactor 102 includes transparent region 506 allows light to be transmitted through the cell to the photocatalysts.
  • the reactor can be any suitable size for performing a water-splitting reaction.
  • the reactor can be 10 cm x 4.8 cm x 4.9 cm.
  • the volume ratio of the H2 generating chamber 106 and the volume of O2 generating chamber 108 to the H2 and O2 reservoir 202 and 204, and the electrolyte reservoirs 104 can be 1 :90:20 to 1 : 100:30, or 1 :95 :25, or any ratio there between.
  • the water-splitting system of the present invention can have a reactor having a stacked configuration that includes inlets for purge gas and electrolyte solution and outlets for H2 containing electrolyte solution and O2 containing electrolyte solution as shown in FIGS. 5A-5D.
  • FIG. 5A is a front view of the stacked water-splitting reactor of the present invention that includes H2 generating chamber 106, electrolyte inlet 142, Fh/electrolyte solution outlet 1 16, and purge gas inlet 502.
  • FIG. 5A is a front view of the stacked water-splitting reactor of the present invention that includes H2 generating chamber 106, electrolyte inlet 142, Fh/electrolyte solution outlet 1 16, and purge gas inlet 502.
  • H2 generating chamber 106 include electrolyte inlet 142 and Fb/electrolyte solution outlet 1 16, and purge gas inlet 502 and O2 generating chamber 108 includes electrolyte inlet 138, 02/electrolyte solution outlet 128, and purge gas inlet 502.
  • both chambers include the purge gas inlet 602.
  • Gas impermeable material 302 can be positioned between the two chambers and includes a cathode material and/or photocatalyst (e.g., catalyst 1 12) and an anode material and/or photocatalyst (e.g., catalyst 124) as shown in FIGS. 6C and 6D.
  • Cathode material 1 12 can be in fluid communication with electrolyte solution flowing into inlet 142.
  • Cathode material 124 can be in fluid communication with electrolyte solution flowing into inlet 138.
  • Spacers 502 and 504 can be positioned between the gas impermeable material and the Fh generating chamber and the O2 generating chamber, respectively.
  • reactor 102 includes transparent region 506 allows light to be transmitted through the cell to the photocatalysts.
  • the systems of the present invention can be made from transparent or opaque polymeric materials.
  • polymeric materials include thermoset and thermoplastic materials.
  • the polymeric material can include a thermoplastic polymer, such as, for example, polyethylene terephthalate, polycarbonate (PC), polybutylene terephthalate (PBT), poly(l,4-cyclohexylidene cyclohexane-l,4-dicarboxylate) (PCCD), glycol-modified polycyclohexyl terephthalate (PCTG), poly(phenylene oxide) (PPO), polypropylene (PP), polyethylene (PE), polyvinyl chloride (PVC), polystyrene (PS), polymethyl methacrylate (PMMA), polyethyleneimine or polyetherimide (PEI) or a derivative thereof, a thermoplastic elastomer (TPE), a terephthalic acid (TPA) elastomer, poly(cyclohexaned
  • the polymeric material can comprise a thermoset material, such as, for example, an unsaturated polyester resin, a polyurethane, bakelite, duroplast, urea-formaldehyde, diallyl-phthalate, epoxy resin, an epoxy vinylester, a polyimide, a cyanate ester of a polycyanurate, dicyclopentadiene, a phenolic, a benzoxazine, a co-polymer thereof, or a blend thereof.
  • a thermoset material such as, for example, an unsaturated polyester resin, a polyurethane, bakelite, duroplast, urea-formaldehyde, diallyl-phthalate, epoxy resin, an epoxy vinylester, a polyimide, a cyanate ester of a polycyanurate, dicyclopentadiene, a phenolic, a benzoxazine, a co-polymer thereof, or a blend thereof.
  • Polycarbonate polymers suitable for use in the present disclosure can have any suitable structure.
  • a polycarbonate polymer can include a linear polycarbonate polymer, a branched polycarbonate polymer, a polyester carbonate polymer, or a combination thereof.
  • a polycarbonate polymer can include a polycarbonate-polyorganosiloxane copolymer, a polycarbonate-based urethane resin, a polycarbonate polyurethane resin, or a combination thereof.
  • Such a polycarbonate polymer can include an aromatic polycarbonate resin.
  • aromatic polycarbonate resins can include the divalent residue of dihydric phenols bonded through a carbonate linkage and can be represented by the formula:
  • Ar is a divalent aromatic group.
  • the divalent aromatic group can be represented by the formula: — An— Y— Ar 2 — , where An and Ar 2 each represent a divalent carbocyclic or heterocyclic aromatic group having from 5 to 30 carbon atoms (or a substituent therefor) and Y represents a divalent alkane group having from 1 to 30 carbon atoms.
  • — An— Y— Ar 2 — is An-C(CH3)-Ar 2 , where An and Ar 2 are the same.
  • “carbocyclic” means having, relating to, or characterized by a ring composed of carbon atoms.
  • heterocyclic means having, relating to, or characterized by a ring of atoms of more than one kind, such as, for example, a ring of atoms including a carbon atom and at least one atom that is not a carbon atom.
  • Heterocyclic aromatic groups are aromatic groups having one or more ring nitrogen, oxygen, or sulfur atoms.
  • An and Ar 2 can each be substituted with at least one substituent that does not affect the polymerization reaction.
  • Such a substituent can include, for example, a halogen atom, an alkyl group having from 1 to 10 carbon atoms, an alkoxy group having from 1 to 10 carbon atoms, a phenyl group, a phenoxy group, a vinyl group, a cyano group, an ester group, an amide group, or a nitro group.
  • Aromatic polycarbonate resins suitable for use in the present disclosure can be commercially available, such as, for example, Lexan® HF1110, available from SABIC Innovative Plastics (U.S.A.), or can be synthesized using any method known by those skilled in the art.
  • Polycarbonate polymers for use in the present disclosure can have any suitable molecular weight; for example, an average molecular weight of such a polycarbonate polymer can be from approximately 5,000 to approximately 40,000 grams per mol (g/mol).
  • the electrolyte solution can be an aqueous solution that has a pH of 0 to 14.
  • the electrolyte solution is a buffer solution have a pH of 6 to 7.5, or greater than, equal to , or between any two of 6.0, 6.1, 6.2, 6.3, 6.4, 6.5, 6.6., 6.7, 6.8, 6.9, 7.0, 7.1, 7.2, 7.3, 7.4 and 7.5.
  • the amount of electrolyte solution can be varied to fit the system.
  • an amount of electrolyte in the H 2 and 0 2 reservoirs is minimal.
  • the amount of electrolyte is at least 5 vol% of the total volume of the reservoirs.
  • the amount of electrolyte solution in the reactor is 5 to 100% of the volume of the reactor.
  • the electrolyte solution can be an aqueous solution of inorganic salts.
  • the inorganic salts can have positive (K + , Na + , H 4 + , Ca 2+ ) and negative (NO3-, S0 4 2" , P0 4 3" , ⁇ 2 ⁇ 0 4 " , HPC 2" ) ions that do not involve any kind of redox reaction under water oxidation condition in order to avoid possible redox reaction except pure water splitting reaction.
  • buffer solutions include phosphonium salts, sulfate salts, carbonate salts, and mixtures thereof.
  • any anode or cathode material known for water-splitting reactions can be used.
  • Non- limiting examples of anode material include metal oxides.
  • Non-limiting examples of cathode material include metals or metal alloys.
  • the metal oxide and metals can include platinum (Pt), cobalt (Co), molybdenum (Mo), nickel (Ni), iron (Fe, tungsten (W), tin (Sn), ruthenium (Ru), irdium (Ir), copper (Cu), manganese (Mn), chromium (Cr), zinc (Zn), cerium (Ce), lanthanum (La) or oxides, or alloys thereof.
  • Non-limiting examples of oxygen evolution catalysts include Ir, Ru, Co, Co/phosphorus (P), CoFe, Cu, Fe, FeMn, Ni, NiCe, NiCo, NiCr, NiFe, NiCe, NiCeCoCe, NiLa, NiMoFe, NiSn, NiZn, or oxides thereof, or combinations thereof .
  • Non-limiting examples of hydrogen evolution catalysts can include, Pt, Co, CoMo, CoNiFe, Fe, FeMo, Mo/sulfur (S), Ni, NiCo, NiFe, NiMo, NiMoC, NiMoFe, NiSn, NiW, or combinations thereof.
  • the photocatalysts useful in the present invention is suitable to generate H 2 and 0 2 from water.
  • Z-scheme catalysts using two different semiconductor materials.
  • the anodic catalyst can include metal oxides and the cathodic catalyst can include metal/metal alloy.
  • semiconductor materials include strontium (Sr), titanium (Ti), Co, and thallium (Tl), and arsenic (As).
  • Dopants such as phosphorous (P), sulfur (S) and barium (Ba) can be added.
  • Non-limiting examples of semiconductor-type catalysts include SrTi0 3 , BaTi0 3 , GaN, CoPS, GaAs, GaAs/InGaP, NiMo/GaAs, InGaP/Ti0 2 Ni, or combinations thereof.
  • the photocatalysts can have layers of metals, metal oxides, and other materials of various thicknesses (e.g., 1 nm to 300 microns or any value there between.
  • a cathodic photocatalyst can include a bottom Ga layer, a InGaAs layer, a Tl layer, backsurface field layer (BSF), two InGaAs layers, an InGaP layer, a Tl layer, a BSF layer, two InGaP layers, an AllnP layer, and a top layer of InGaAs.
  • BSF backsurface field layer
  • an anodic photocatalyst can include be a p-n junction type catalyst that can include a GaAs layer on a support with InAlP layer, InGaP layer, a InGaP layer, a AlInGaP layer, a AlGaAs layer, an InGaP layer, an InAlP layer, a GaAs layer, a InGa P layer, a GaAs layer, and a Ni substrate layer as the top layer.
  • FIGS. 4A, 4B, 7, 8A, and 8B systems 100, 200, 300 and 400 can have photocatalysts arranged as shown in FIGS. 4A, 4B, 7, 8A, and 8B.
  • FIGS. 4A and 4B represent an electrolysis system with the electrodes being attached to a voltage source.
  • the photocatalyst can be attached to the impermeable material 402 as shown in FIG. 7.
  • This type of catalyst can be a monolithically integrated system and the entire catalyst and any hydrogen and oxygen co-catalysts 702 integrated into a thin film. During use, where one side of the film generates H 2 (cathode) and the other side generates 0 2 (anode) as shown in FIG. 7, when exposed to irradiation source 704.
  • Non-limiting examples of these types of photocatalysts are monolithically integrated solar-driven water- splitting devices can be based on tandem, Z-scheme or multi -junction structures.
  • photocatalysts can be are used either for generating H 2 or 0 2 and they can separated from corresponding counter electrodes.
  • the photocatalysts (e.g., 112 and/or 124) and corresponding electrodes (e.g., 112 and/or 124) can be connected through circuit 126 (e.g. a copper wire).
  • the photocatalyst can be based on tandem, Z-scheme or multi -junction structures.
  • circuit 126 can be attached to impermeable material 402 or conduit 302. Referring to FIG. 8A, cathodic photocatalyst 802 is attached to support 804 and is positioned in in hydrogen generating chamber 106.
  • Cathodic photocatalyst 802 is separated from oxygen generating chamber 108 conduit 302 or impermeable material 402 (not shown). Cathodic photocatalyst 802 is connected to metal (e.g., Pt) anodic electrode 806 via circuit 126 (e.g., copper wire) through conduit 302.
  • metal e.g., Pt
  • circuit 126 e.g., copper wire
  • anodic photocatalyst 808 is attached to support 804 and is positioned in oxygen generation chamber 108.
  • Anodic photocatalyst 808 is separated from hydrogen generating chamber by conduit 302 or impermeable material 402 (not shown).
  • Anodic photocatalyst 808 is connected to metal (e.g., Pt) cathodic electrode 810 via circuit 126 (e.g., copper wire) through conduit 302.
  • circuit 126 e.g., copper wire
  • Hydrogen selective and oxygen selective membranes used to purify the generated H 2 and/or 0 2 can be manufactured or be obtained from commercial sources.
  • commercial membrane sources are Air Products (U.S.A.), Membrane Technology Research, Inc. (U.S.A.), Air Liquid (U.S.A.), UBE Industries, LTD. (JAPAN), or the like.
  • Non-limiting examples of materials that compose the hydrogen separation membrane include polymeric and carbon membranes.
  • Polymeric membranes typically achieve hydrogen selective molecular separation via control of polymer free volume.
  • Polymeric membranes may be comprised, for example, of glassy polymers, epoxies, polysulfones, polyimides (e.g., polyimide membrane from UBE, or ProteusTM membranes from Membrane Technology and Research, Inc., and other materials, and may include crosslinks and matrix fillers of non-permeable (e.g., dense clay) and permeable (e.g., zeolites) varieties to modify polymer properties.
  • non-permeable e.g., dense clay
  • permeable e.g., zeolites
  • Carbon membranes are generally microporous and substantially graphitic layers of carbon prepared by pyrolysis of polymer membranes or hydrocarbon layers. Carbon membranes may include carbonaceous or inorganic fillers, and are generally applicable at both low and high temperature.
  • the hydrogen separation membrane may be a dense membrane composed only of the above-mentioned materials, or may be a dense thin membrane composed of the above-mentioned materials supported on a porous body. In the case of the former, the thickness of the hydrogen separation membrane is preferably 0.1 ⁇ or more and more preferably 0.5 ⁇ to 5 ⁇ from the viewpoints of mechanical strength and hydrogen permeability.
  • the thickness of the thin membrane is 0.1 to 25 ⁇ or more and more preferably 0.1 ⁇ to 2 ⁇ from the viewpoint of processability.
  • the hydrogen separation membrane includes the dense thin membrane composed of the above-described materials and the porous body supporting the membrane thereon, the replacement of gaseous species tends to be inhibited on the side of the porous body and, thus, it is preferable for a dense thin membrane to be the side contacted with a mixed gas, and a porous body to be the side contacted with permeated hydrogen.
  • Oxygen selective membranes can include a perfluorocarbon material, a polysiloxane material, a fluorinated polysiloxane material, a perfluorinated polyethers material, and an alkyl methacrylate-based copolymeric material.
  • Oxygen selective membranes are available from commercial sources. For example, Sepuran® membranes from Evonik Industries (Austria) can be used. In some embodiments, oxygen can be released to the environment.
  • the water-splitting systems of the present invention can be used to produce Fh and O2 from water.
  • an electrolyte solution e.g., electrolyte solution 1 14
  • Purge gas can enter electrolyte solution 140 and the solution can be purged until no or substantially no Fh and O2 are present in the electrolyte solution.
  • the solution can include 1 vol.% or less, 0.05 vol.% or less, or 0.005 vol.% or less or undetectable amounts of Fh and/or O2.
  • the degassed electrolyte solution 1 14 can be moved (e.g., pumped or pressurized) from electrolyte source 104 to the Fh and O2 generating chambers.
  • the degassed electrolyte solution 1 14 can include purge gas, but Fh and O2 are preferably removed from solution 1 14 prior to entering the Fh and O2 generating chambers.
  • degassed electrolyte solution 1 14 is added to the reservoirs independently.
  • purge gas can enter Fh generating chamber through inlet 502 of FIG. 5 A. Purge gas can be provided to Fh generating chamber or the Fh and O2 generating chambers continuously or intermittently.
  • the electrolyte solution prior to starting the water-splitting reaction, can be added to the chambers and purge gas can be provided to the chambers until the electrolyte solution includes little to no O2 present as measured using known analytical techniques (e.g., gas detectors).
  • the purge gas can be slowed or discontinued in the Fh and O2 generating chambers and/or the electrolyte source for a desired amount of time. Purging can be resumed when detectable amounts of O2 and/or Fh are found in the electrolyte solutions exiting the Fh and O2 generating chambers, respectively.
  • Such monitoring and addition of purge gas can inhibit and/or prevent Fh or O2 cross-contamination in the Fh and O2 generating chambers during the water-splitting reaction.
  • current and/or electromagnetic radiation can be applied to anode 124 to generated electrons, which travel through circuit 126 to cathode 1 12 to generate Fh.
  • both anode and cathode photocatalysts can receive electromagnetic radiation.
  • voltage and light are applied.
  • the source of the electromagnetic radiation can be natural (e.g., sunlight) or artificial (e.g., a lamp).
  • a non-limiting example of an artificial source is a UV lamp that provides light at 300 to 400 nm.
  • Excitation of the photocatalyst 1 12 in the presence of water can generate hydrogen ion (H + ).
  • Conditions for the water-splitting can include temperature and pressure.
  • the reaction temperature can be greater than, equal to, or between any two of 5 °C, 10 °C, 20 °C, 30 °C, 40 °C, 50 °C, 60 °C, 70 °C, 80 °C, 90 °C and 100 °C.
  • the reaction pressure can be greater than, equal to, or between any two of 0.01 MPa, 0.1 MPa, 0.5 MPa, 1 MPa, 1.1 MPa, 1.2 MPa, 1.3 MPa, 1.4 MPa, 1.5 MPa, 1.6 MPa, 1.7 MPa, 1.8 MPa, 1.9 MPa, 2.0 MPa and 2.1 MPa.
  • electrolyte solution 1 14 having H 2 and O2 dissolved therein exits chambers 104 and 106 and enters H 2 reservoir 202 and O2 reservoir 204, respectively.
  • electrolyte solution 1 14 exiting H 2 generating chamber 106 passes through a compressor and gaseous H 2 is separated from the electrolyte solution and enters purification unit 212.
  • a compressor is not used.
  • dissolved H 2 is released from the electrolyte solution producing an electrolyte solution that can have less than 0.2 ppm or 0 to 0.2 ppm dissolved H 2 remaining.
  • Released H 2 can exit H 2 reservoir 202 and enter purification and/or collection unit 212.
  • released H 2 can be provided directly to other units or used as a fuel.
  • O2 reservoir 204 dissolved O2 is released from the electrolyte solution producing an electrolyte solution that can have 0.2 ppm to 0.4 ppm or greater than, equal to, or between any two of 0.2 ppm, 0.25 ppm, 0.3 ppm, 0.35 ppm and 4 ppm of O2 remaining.
  • Released O2 can exit O2 reservoir 202 and enter purification and/or collection unit 214.
  • released O2 can be provided directly to other units for use as an oxidant. Release of H 2 and O2 can be facilitated by purging, compression, heating or any known techniques to degas an aqueous solution.
  • the electrolyte solutions can exit reservoirs 202, 204, and enter electrolyte source 104. As shown in the FIGS. 2 and 3B, the solutions are combined prior to entering electrolyte source 104. However, the solutions can each independently enter electrolyte source 104. As the electrolyte solutions are combined the concentration of the H 2 and O2 can remain under the flammability limit. Combining the electrolyte solutions can restore the pH gradient of the electrolyte solution used in the H 2 and O2 generating chambers. In electrolyte source 104, the residual or low amounts of H 2 and O2 are removed from the electrolyte solution and exit electrolyte source 104 via outlet 154.
  • H 2 and O2 can be facilitated by purging, compression, heating or any known techniques to degas an aqueous solution.
  • the remaining H2 and O2 are removed by purging with nitrogen gas.
  • the exiting gases can be sent to a collection unit, purification unit or transported to other processing units.
  • the purged electrolyte solution exits electrolyte source (e.g., reservoir) via outlet 138 and enters H2 generating chamber 106 via inlet 142 and O2 generating chamber 108 via inlet 144.
  • the process is conducted in a continuous manner with electrolyte solution being added to the chambers while H2 and O2 are being removed.
  • reservoirs 202 and 204 are not used and the H2 and O2 are removed from the electrolyte solution in electrolyte source 104.
  • a water-splitting system included a reactor having electrolyte (200 mL, 0.1 M Na2S0 4 ), an anode (Pt coated-Ni mesh) in an O2 generating chamber, a cathode (GaAs based triple junction solar cell) in an H2 generating chamber.
  • the H2 generating chamber connected to a H2 reservoir and the O2 generating chamber were connected to an O2 reservoir.
  • the reactor and the H2 and O2 reservoirs were connected to an electrolyte reservoir.
  • the reactor was irradiated with a solar simulator at the intensity of 1 Sun (lOOmW/cm 2 ). The light intensity reaching the reactor was maintained at 100 mW/cm 2 by adjusting the distance between the lamp and the reactor cell.
  • the distance range was typically between is between 20 cm to 50 cm depending on the desired light flux.
  • Table 1 lists the total water splitting results with multi -junction system using the membrane-less reactor without the N2 purging during the water-splitting reaction. From the data, it was determined that the dissolved H2 gas was transferred from the H2 reservoir (Compartment 1) to the O2 reservoir (Compartment 2) via the O2 chamber (See, FIG. 2) and then released to the gas phase until equilibrium was released. Table 1
  • Electrolyte Solution as a Function of Flow [0072] Using the experimental reactor system of Example, 1 the cross-over of H 2 to the 0 2 chamber was studied as a function of nitrogen flow. In this study, H 2 was injected into the H 2 reservoir (CI in FIGS. 9A & 9B, e.g., H 2 reservoir 202 in FIG. 2) and the amount of H 2 was measured in both reservoirs (CI and C2 in FIGS. 9A & 9B, e.g., H 2 reservoir 202 and O2 reservoir 204 in FIG. 2) with gas chromatography as a function of time while circulating water with a flow rate of about 80 mL/min and a N2 purge rate of about 1 mL/s during the experiment.
  • H 2 was injected into the H 2 reservoir (CI in FIGS. 9A & 9B, e.g., H 2 reservoir 202 in FIG. 2) and the amount of H 2 was measured in both reservoirs (CI and C2 in FIGS. 9A & 9
  • FIGS. 9A and 9B are graphs of addition of H 2 (FIG. 9A) and O2 (FIG. 9B) into their respective reservoir.
  • the data line 900 the changes of H 2 concentration with time in the H 2 - injected reservoir (CI) and data line 902 shows the changes of H 2 concentration in the O2 reservoir (C2).
  • data line 904 shows the changes of O2 concentration with time in the Cfe-injected reservoir (C2)
  • data line 906 shows the changes of O2 concentration in the H 2 reservoir (CI).
  • H 2 and 0 2 were injected into H 2 reservoir (CI, FIGS. 10A and 10B) and 0 2 reservoir (C2, FIGS. 8 A and 8B), respectively, and the amounts of gases were measured in both reservoirs with gas chromatography as a function of time.
  • data line 1000 shows the changes of H 2 concentration with time in the Fh-injected reservoir (CI)
  • data line 1002 shows the changes of O2 concentration in the same reservoir (CI).
  • data line 1004 shows the changes of O2 concentration with time in the C -injected reservoir (C2) and data line 1006 shows the changes of H 2 concentration in the same reservoir (C2).

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Abstract

L'invention concerne des systèmes et des procédés d'obtention de dihydrogène (H2) et de dioxygène (O2) gazeux à partir d'une solution électrolytique aqueuse. Un système de décomposition d'eau peut comprendre un réacteur qui comprend des chambres de génération de H2 et O2, celles-ci pouvant être des chambres distinctes mais n'étant pas séparées par un matériau perméable au H2 et/ou au O2 gazeux. La chambre de génération de H2 peut comprendre une cathode et au moins une première entrée de fluide. La chambre de génération d'O2 peut comprendre une anode en liaison électrique avec la cathode et au moins une première entrée de fluide. Les première et seconde entrées de fluide peuvent chacune être configurées de sorte à recevoir une solution d'électrolyte purgée, un gaz de purge ou un mélange de ceux-ci.
PCT/IB2018/057846 2017-10-11 2018-10-10 Système de décomposition de l'eau pour la séparation d'hydrogène et d'oxygène en l'absence de membrane échangeuse d'ions Ceased WO2019073404A1 (fr)

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DE112018004479.3T DE112018004479T5 (de) 2017-10-11 2018-10-10 Wasserspaltungssystem zur wasserstoff- und sauerstofftrennung in abwesenheit einer ionentauschermembran
CN201880065938.8A CN111212933A (zh) 2017-10-11 2018-10-10 没有离子交换膜的用于氢和氧分离的水分解系统
US16/754,614 US20200354840A1 (en) 2017-10-11 2018-10-10 Water splitting system for hydrogen and oxygen separation in the absence of an ion exchange membrane

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DK181493B1 (en) * 2022-07-06 2024-03-08 Stiesdal Hydrogen As Method for operating an electrolysis system with periodic polarity reversal
WO2025035075A1 (fr) * 2023-08-09 2025-02-13 Georgia Tech Research Corporation Membranes o2/h2 sélectives inverses
DE102023210066A1 (de) 2023-10-13 2025-04-17 Robert Bosch Gesellschaft mit beschränkter Haftung Verfahren und Vorrichtung zum Entgasen eines wasserstoffhaltigen Gas-Flüssigkeit-Gemischs

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