WO2019083156A1 - Procédé de fabrication d'une structure d'anode en lithium métallique et structure d'anode en lithium métallique - Google Patents

Procédé de fabrication d'une structure d'anode en lithium métallique et structure d'anode en lithium métallique

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Publication number
WO2019083156A1
WO2019083156A1 PCT/KR2018/010431 KR2018010431W WO2019083156A1 WO 2019083156 A1 WO2019083156 A1 WO 2019083156A1 KR 2018010431 W KR2018010431 W KR 2018010431W WO 2019083156 A1 WO2019083156 A1 WO 2019083156A1
Authority
WO
WIPO (PCT)
Prior art keywords
lithium metal
current collector
tab
lithium
cathode structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2018/010431
Other languages
English (en)
Korean (ko)
Inventor
이상균
최백범
구자훈
김민욱
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Chem Ltd
Original Assignee
LG Chem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020180105740A external-priority patent/KR102722632B1/ko
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Priority to CN201880024857.3A priority Critical patent/CN110945690B/zh
Priority to PL18869520.9T priority patent/PL3598538T3/pl
Priority to JP2019559099A priority patent/JP7045555B2/ja
Priority to EP18869520.9A priority patent/EP3598538B1/fr
Priority to US16/604,930 priority patent/US11228029B2/en
Priority to ES18869520T priority patent/ES2980174T3/es
Publication of WO2019083156A1 publication Critical patent/WO2019083156A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/531—Electrode connections inside a battery casing
    • H01M50/534—Electrode connections inside a battery casing characterised by the material of the leads or tabs
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the present invention relates to a method of manufacturing a lithium metal cathode structure and a lithium metal cathode structure.
  • Electrochemical devices have attracted the most attention in this respect. Among them, the development of secondary electrons capable of charge and discharge has been the focus of attention. Recently, in developing such batteries, Research and development on the design of electrodes and batteries are underway.
  • the lyrium secondary battery developed in the early 1990s has advantages such as higher operating voltage and higher energy density than conventional batteries such as Ni-MH, Ni-Cd, and sulfuric acid-lead batteries using an aqueous electrolyte solution .
  • a lithium secondary battery includes a positive electrode, a negative electrode, and an electrode assembly including a separator interposed between the positive electrode and the negative electrode, and the nonaqueous electrolyte is injected into the battery case.
  • the lithium metal used as the cathode is a material which is most popular as a negative electrode material for a high energy density battery because the density (0.54 g / cm 3) is low and the standard reduction potential (-3.045 V SHE) is very low.
  • the recent development and rapid development of mobile communication and portable electronic devices have led to the development of high energy density secondary batteries As demands continue to increase, there is a continuing need for the use of lithium metal cathodes.
  • FIG. 1 is a plan view and a vertical sectional view of a negative electrode structure manufactured by adhering a lyrium foil on a conventional planar current collector.
  • 2 is a diagram schematically showing a method of manufacturing such a cathode structure.
  • a lyrium metal cathode sheet 10 in which a lithium metal 13 is rolled or deposited on a metal foil 11 of a current collector is punched out as a unit electrode for electrode production, The metal foil 11 is also cut at the same time to form the tabs 12.
  • the lithium metal 13 has a loose characteristic, so that the lithium metal 13 remains as a residue in the punching die, or a burr-like residual lithium metal 14 formed at the time of punching exists in the lithium metal cathode It is necessary to cut the current collector metal foil at the time of punching into the unit electrode, so that the tap forming portion where only the current collector metal foil is cut off, and the lithium metal and current collector metal foil The cutting strength between the unit electrode portions to be cut is different, so that the knife strength of the punching die must be taken into account, and the problem of the lithium metal of the loose characteristic being stuck in the male and female molds also occurs.
  • the inventors of the present application have conducted intensive research and various experiments and have found that in a method of manufacturing a lithium metal cathode structure, a photocurable material is applied and cured to a stepped portion of a coated portion of a lithium metal layer,
  • the above-described lithium metal cathode structure can be manufactured by forming an insulating layer made of a photo-curable material at the stepped portion of the coated portion of the tab and the lithium metal layer, Or an insulating tape, and it is possible to obtain a further effect of preventing a short circuit with the cathode material due to the exposure of the lyrium metal layer to the tab on the secondary battery.
  • the present invention has been accomplished based on this finding.
  • the manufacturing method according to the present invention may include a step of forming a tab by embossing a plain weave at the same time as the step (c), or after the step (c), (d) .
  • the inventors of the present application have conducted intensive studies to solve the above-mentioned problems that may occur when lithium metal is rolled or deposited on a current collector due to the loose nature of lithium metal, It has been confirmed that the conventional problems occurring in the punching step for forming the tab can be solved when the photocurable material is formed on the stepped portion of the non-coated portion of the current collector and the coated portion of the lithium metal layer before the punching or the insulating tape is attached.
  • the stepped portion has a portion having a width of 2 mm to 5 mm in the vertical direction up and down with reference to the boundary between the non-coated portion of the current collector and the coated portion having the lithium metal layer formed thereon it means. That is, it means a portion including a boundary line and having a width of 2 mm to 5 mm in the up-and-down direction, specifically, a portion having a width of 2 mm to 4 mm.
  • the photo-curable material to be coated and cured on the step portion is not limited, but may be an ultraviolet curable material that is crosslinked by ultraviolet rays, that is, it is cured by irradiating ultraviolet rays.
  • the ultraviolet curable material may be added in the form of an oligomer or a low molecular weight polymer having a viscosity of 10 cps to 100 cps which can be polymerized with the material, and then cured by irradiating ultraviolet rays.
  • the viscosity of the oligomer or low molecular weight polymer may be from 30 cps to 100 cps, and more specifically from 50 cps to 100 cps.
  • the viscosity refers to the viscosity measured according to a Brookfield viscometer, and visco tester 550 from HAAKE was used.
  • a general UV-curable material is a low-viscosity liquid state material composed of a monomer or an oligomer.
  • the material is injected into an oligomer having a viscosity within the above range or a polymer having a low molecular weight, It is easy to apply and there is almost no flow even after application, so that an optimum sealing property improving effect can be obtained.
  • the glycerol may be at least one selected from the group consisting of, for example, epoxy, urethane, acrylate, silicone, hydroxyl and acrylic acid derivatives.
  • the low molecular weight polymer may be an unsaturated polyester- Polyacrylate-based materials, and may be, for example, polyester acrylate, epoxy acrylate, urethane acrylate or polyurethane, but is not limited thereto.
  • TMPTA Trimethylolpropane Triacrylate
  • acrylate-based materials such as ETPTA (ethoxylated trimethylopropane triacrylate).
  • Such an ultraviolet curable material can be applied as a mixture of the oligomer or the low molecular weight polymer for crosslinking in the form of a crosslinking agent and a photoinitiator.
  • a crosslinking agent conventionally known crosslinking agents may be used, and examples thereof include, but are not limited to, acrylate compounds such as isocyanate compounds, epoxy compounds, aziridine compounds and TMSPA (3- (trimethoxysilyl) propylacrylate) Chelate-based compounds, and the like.
  • the photoinitiator may be any of the conventionally known photoinitiators, including, but not limited to, benzophenone, acetophenone, chloroacetophenone, diethoxyacetophenone (DEAP), benzoin, benzoin Benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether, benzoin benzoic acid, benzoin methyl benzoate, benzoin dimethyl ketal, 2,4-diethyl thioxanthone, Tetramethylurammonosulfide, azobisisobutyronitrile, benzyl, dibenzyl, diacetyl, betachloroanthraquinone, 2-benzyl-2-dimethylamino-1- (4-morpholinophenyl) 2-dimethylamino-1- (4-morpholinophenyl) -butanone-1 ⁇ , 2,4,6-trimethylbenzoy
  • the ultraviolet curable material may be added to the site in a state where a predetermined thickener is added as a monomer.
  • Thickening agents that can increase the viscosity of such materials include carboxymethyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol, polyvinylacrylate, and the like. have.
  • the ultraviolet ray-curable material having such a viscosity can be cured by being irradiated with ultraviolet rays (UV) within a range of 3 to 20 seconds after being added to the stepped portion.
  • UV ultraviolet rays
  • an insulating tape may be attached as a more convenient method.
  • the insulating tape may be a polyethylene terephthalate or a polyimide material.
  • the coating thickness of the photocurable material or the thickness of the insulating tape may be 10 nm to 1 Lambda, specifically, 100 nm to 500 nm.
  • the punching process is inefficient due to, for example, the strength of the knife in the punching process for forming the electrode and the punching process for forming the tab, and if the punching process is too thin, It is not preferable.
  • the collector in which the lithium metal layer is formed may have a thickness of 3 to 200.
  • a current collector is not particularly limited as long as it has conductivity without causing a chemical change in the battery, and examples thereof include copper, a copper alloy, stainless steel, aluminum, nickel, titanium, sintered carbon, The surface of the stainless steel may be surface treated with carbon, nickel, titanium, silver or the like, and an aluminum-cadmium alloy may be used. Specifically, copper, copper alloy, stainless steel, aluminum, nickel, , Copper can be used.
  • the current collector may form fine irregularities on its surface to increase the adhesive force of the electrode active material, and various forms such as a film, a sheet, a foil, a net, a porous body, and a foam : a nonwoven fabric are possible.
  • the lyrium metal layer may have a thickness of 20 to 150 liters, more specifically 20 to 100.
  • the thickness of the lithium metal layer is too small, the amount of lithium metal acting as an active material is smaller than that of the current collector, so that a sufficient capacity can not be exhibited. If the thickness is too large, output characteristics are deteriorated. It is difficult to prevent problems due to the characteristics, which is not preferable.
  • the lithium metal layer is formed on the current collector.
  • the lithium metal layer may be formed by depositing or rolling lithium metal. More specifically, And it can be formed by rolling.
  • the size of the rolling can be appropriately selected in consideration of the thickness of the lithium metal layer and the like.
  • the present invention also provides a lithium metal cathode structure thus produced, wherein the lithium metal cathode structure comprises:
  • An insulating layer made of a photo-curable material may be formed on the stepped portion of the map and the lithium metal layer, or an insulating tape may be attached.
  • the lithium metal cathode structure may be formed by forming an insulating layer on the stepped portion of the tab and the lithium metal layer or attaching an insulating tape to the unit electrode before the electrode is formed, It is possible to obtain a further effect of preventing a short circuit between the lithium metal layer and the anode material due to the exposure of the lithium metal layer on the tab without any additional process.
  • the lithium metal cathode structure according to the present invention minimizes the generation of burrs, thereby solving the safety problem that may be caused by burr-like residual lithium present in the cathode structure, It is possible to prevent a short circuit that may occur due to contact with the cathode material thereafter, local heat generation and explosion due to the short circuit, and it is very effective to improve the safety of the battery.
  • the tab may be integrally formed with the current collector. That is, the tab may be formed by punching an uncoated portion not coated with a lithium metal layer as described above.
  • the step where the insulating layer or the insulating tape is formed and the stepped portion of the lithium metal layer are the same as those described in the above manufacturing method and the insulating layer or the insulating tape is the same as that formed in the manufacturing method, In detail, it may be 2 mm to 4 mm, and the thickness may be 10 nm to 1, specifically, 100 nm to 500 nm in the vertical direction as a standard.
  • the thickness means the length in the stacking direction of the current collector and the lithium metal layer.
  • the width of the insulating layer or the insulating tape may be the same as the width of the unit or slightly extend in the outward direction of the unit electrode to be in a range of 1 mm to 5 mm .
  • the negative electrode structure may be used in a secondary battery, and a specific structure of the secondary battery will be described below.
  • the secondary battery is not particularly limited in its kind, but specific examples thereof include a lithium ion (Li-ion) secondary battery having advantages such as high energy density, discharge voltage, and output stability, a lithium polymer secondary battery Battery, or a lithium secondary battery such as a lithium ion polymer secondary battery.
  • a lithium ion (Li-ion) secondary battery having advantages such as high energy density, discharge voltage, and output stability
  • a lithium polymer secondary battery Battery or a lithium secondary battery such as a lithium ion polymer secondary battery.
  • the lyrium secondary battery is composed of a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte containing a lithium salt.
  • the positive electrode is prepared, for example, by coating a positive electrode current collector with a mixture of a positive electrode active material, a conductive material and a binder, and drying the positive electrode current collector. If necessary, a laminating agent may be further added to the mixture.
  • the cathode current collector and / or the elongated current collector are generally made to have a thickness of 3 to 500 micrometers.
  • the positive electrode current collector and the elongate current collector are not particularly limited as long as they have high conductivity without causing a chemical change in the battery, and examples thereof include stainless steel, aluminum, nickel, titanium, A surface treated with carbon, nickel, titanium, or silver on the surface of stainless steel may be used.
  • the anode current collector and the elongate current collector may have various shapes such as a film, a sheet, a foil, a net, a porous body, a foam, a nonwoven fabric, or the like by forming fine irregularities on the surface thereof to increase the adhesive force of the cathode active material. '
  • the cathode active material may be a layered compound such as lithium cobalt oxide (LiCoO 2 ), lithium nickel oxide (LiNiO 2 ), or a compound substituted with one or more transition metals;
  • the conductive material is usually added in an amount of 1 to 30 wt% based on the total weight of the charge including the cathode active material.
  • a conductive material is not particularly limited as long as it has electrical conductivity without causing chemical changes in the battery, and for example, natural materials such as natural or artificial rhizome; Carbon black such as carbon black, acetylene black, ketjen black, channel black, furnace black, lamp black, and summer black; Conductive fibers of carbon fiber or metal fiber; Metal powders such as carbon fluoride, aluminum, and nickel powder; Conductive whiskey such as zinc oxide and potassium titanate; Conductive metal oxides such as titanium oxide; Conductive materials such as polyphenylene derivatives and the like can be used. '
  • the binder is a component that assists in binding of the active material and the conductive material and bonding to the current collector, and is usually added in an amount of 1 to 30% by weight based on the total weight of the composite material containing the cathode active material.
  • binders include polyvinylidene fluoride, polyvinyl alcohol, carboxymethylcellulose, cellulose derivatives such as rosewood (CMC), starch, hydroxypropyl sal, rosewax, polyvinylpyridone, tetrafluoroethylene, polyethylene , Polypropylene, ethylene-propylene-diene terpolymer (EPDM), sulfonated EPDM, styrene butylene rubber, fluorine rubber, various copolymers and the like.
  • the filler is optionally used as a component for suppressing the expansion of the anode, and is not particularly limited as long as it is a fibrous material without causing a chemical change in the battery.
  • the filler include olefin polymers such as polyethylene and polypropylene; Fibrous materials such as glass fibers and carbon fibers are used.
  • the cathode may be made of a lithium metal cathode formed with a lithium metal deposit on the current collector.
  • the separation membrane is interposed between the anode and the cathode, and an insulating thin film having high ion permeability and mechanical strength is used.
  • the pore diameter of the membrane Generally, it is 0.01 to 10 micrometers, and the thickness is generally 5 to 300 micrometers.
  • Such separators include, for example, olefin polymers such as polypropylene, which is chemically resistant and hydrophobic; A sheet or nonwoven fabric made of glass fiber, polyethylene or the like is used. When a polymer solid electrolyte is used as an electrolyte, the solid electrolyte may also serve as a separation membrane.
  • the electrolytic solution may be a non-aqueous electrolytic solution containing a lithium salt, and is composed of a non-aqueous electrolytic solution and a lithium salt.
  • a non-aqueous electrolyte non-aqueous organic solvents, organic solid electrolytes, inorganic solid electrolytes, and the like are used, but the present invention is not limited thereto.
  • non-aqueous organic solvent examples include N-methyl-2-pyrrolidone, propylene carbonate, ethylene carbonate, butylene carbonate, dimethyl carbonate, diethyl carbonate, But are not limited to, gamma -butyrolactone, 1,2-dimeroxyethane, tetrahydroxyfuran, 2-methyltetrahydrofuran, dimethylsulfoxide, 1,3-dioxolane, formamide, dimethylformamide, But are not limited to, cyclic ethers such as methylene chloride, methyl ethyl ketone, methyl ethyl ketone, cyclohexanone, cyclohexanone, cyclohexanone, cyclohexanone, cyclohexanone, Ethers, methyl pyrophonate, ethyl propionate and the like can be used as the organic solvent.
  • cyclic ethers such as methylene chloride, methyl eth
  • organic solid electrolyte examples include a polymer electrolyte such as a polyethylene derivative, a polyethylene oxide derivative, a polypropylene oxide derivative, a phosphate ester polymer, an agitation lysine, a polyester sulfide, a polyvinyl alcohol, a polyvinylidene fluoride, Polymers containing ionic dissociation groups, and the like can be used.
  • a polymer electrolyte such as a polyethylene derivative, a polyethylene oxide derivative, a polypropylene oxide derivative, a phosphate ester polymer, an agitation lysine, a polyester sulfide, a polyvinyl alcohol, a polyvinylidene fluoride, Polymers containing ionic dissociation groups, and the like can be used.
  • Examples of the inorganic solid electrolyte include Li 3 N, Lil, Li 5 NI 2 , Li 3 N-LiI-LiOH, LiSiO 4 , LiSiO 4 -LiI-LiOH, Li 2 SiS 3 , Li 4 SiO 4 , Nitrides, halides, sulfates and the like of Li such as Li 4 Si0 4 -LiI-LiOH and Li 3 PO 4 -Li 2 S-SiS 2 can be used.
  • the lithium salt is a material that is readily soluble in the non-aqueous electrolyte, for example, LiCl, LiBr, Lil, LiC10 4, LiBF 4, LiB 10 Cl 10, LiPF 6, LiCF 3 S0 3, LiCF 3 C0 2, LiAsF 6, LiSbF 6, LiAlCl 4, CH 3 S0 3 Li, CF 3 S0 3 Li, (CF 3 S0 2) 2 NLi, chloroborane lithium, lower aliphatic carboxylic acid lithium, lithium tetraphenyl borate and imide have.
  • LiCl, LiBr, Lil, LiC10 4, LiBF 4, LiB 10 Cl 10, LiPF 6, LiCF 3 S0 3, LiCF 3 C0 2, LiAsF 6, LiSbF 6, LiAlCl 4, CH 3 S0 3 Li, CF 3 S0 3 Li, (CF 3 S0 2) 2 NLi, chloroborane lithium, lower aliphatic carboxylic acid lithium, lithium tetraphenyl borate and imide have
  • the nonaqueous electrolytic solution includes, for example, pyridine, triethylphosphite, triethanolamine, cyclic ether, ethylene Substituted imidazolidinone, N, N-substituted imidazolidine, ethylene glycol dialkyl ether, an ammonium salt, an imidazoline derivative, an imidazoline derivative,
  • a halogen-containing solvent such as carbon tetrachloride, ethylene trifluoride and the like may be further added to impart nonflammability, and a high-temperature storage property may be added (FEC), propylene sul- fone (PRS), and the like may be further included.
  • LiPF 6, LiC10 4, LiBF 4, LiN (S0 2 CF 3) 2 such as a lithium salt, a highly dielectric solvent of DEC, DMC or EMC Fig solvent cyclic carbonate and a low viscosity of the EC or PC of To a non-aqueous solvent of a linear carbonate to prepare a non-aqueous electrolyte containing a lithium salt.
  • FIG. 1 is a schematic view of a conventional negative electrode structure
  • FIG. 2 is a schematic view illustrating a process of manufacturing the negative electrode structure of FIG. 1;
  • FIG. 3 is a schematic view of a process of manufacturing a negative electrode structure according to one embodiment of the present invention.
  • FIG. 4 is a photograph of a mold after punching to produce a conventional negative electrode structure
  • FIG. 5 is a photograph of a negative electrode structure after punching to manufacture a conventional negative electrode structure
  • FIG. 6 is a photograph of a cathode structure after punching to manufacture the cathode structure according to Embodiment 1 of the present invention.
  • FIG. 7 is a photograph of a cathode structure after punching to manufacture the cathode structure according to still another embodiment 2 of the present invention.
  • FIG. 3 is a schematic view illustrating a process of manufacturing a cathode structure according to an embodiment of the present invention.
  • the photocurable material 140 is applied and cured to the stepped portion of the non-coated portion 110 and the coated portion 130 of the lithium metal layer, or the insulating tape 140 is attached to the stepped portion, .
  • the lithium metal cathode structure 100 is punched out as a unit electrode for manufacturing an electrode, and at the same time, the non-punched portion 110 is also punched to form a tab 120.
  • the lithium metal cathode structure 100 manufactured as described above can be manufactured by forming an insulating layer made of a photocurable material between the map 120 extending from the current collector and the step portion of the coating portion 130 of the lithium metal layer by the above- Or a structure in which an insulating tape 140 is attached.
  • a negative electrode sheet was prepared by depositing lithium metal (thickness: 40 m ) except for one side so that a solid portion for forming a tab remained on the entire collector (thickness: 30 m ) made of copper.
  • a punching process for forming a lap while being manufactured as a unit electrode Respectively.
  • Fig. 4 and Fig. 5 show photographs of the mold after the punching process and optical photographs of the front and rear surfaces of the unit electrodes.
  • a negative electrode sheet was produced by depositing lithium metal (thickness: 40) except for one side so as to leave an unoccupied portion for forming a tab on the current collector made of copper (thickness: 30) Insulation tape (thickness:
  • FIG. 6 shows an optical photograph of the front and rear surfaces of the unit electrode after the punching process.
  • the unit electrode is smoothly punched out without being pushed out of the outer portion of the electrode, as shown in the rear view.
  • Lithium metal was deposited (thickness: 40) on the collector (thickness: 30) made of copper except for one side so as to leave an unoccupied part for formation of the lap, and a negative electrode sheet was produced.
  • (Trimethoxysilyl) propylacrylate as a crosslinking agent, and 2-hydiOxy-2-methylpropiophenone as a photoinitiator were mixed in a weight ratio of 10: 0.5: 0.5 (thickness: 500 nm, width: 3 mm including the border between the coated portion and the non-coated portion, the length was applied in the same manner as the tab length to be formed later) and cured by UV curing method.
  • FIG. 7 shows optical photographs of the front and rear surfaces of the unit electrodes after the punching process. Referring to FIG. 7, it can be seen that the unit electrode is smoothly punched out without being pushed out of the outer portion of the electrode, as shown in the rear view.
  • the positive electrode active material (LiCo0 2) 90 parts by weight 0/0, Super-P (conductive material) 5 parts by weight 0/0, and PVDF (a binder) in NMP (N-methyl solvent a positive electrode material mixture of 5% by weight of composition -2-pyrrolidone) to prepare a positive electrode slurry and then coated on an aluminum current collector to prepare a positive electrode.
  • NMP N-methyl solvent a positive electrode material mixture of 5% by weight of composition -2-pyrrolidone
  • the unit electrode prepared in Comparative Examples 1 and 1 was used as a negative electrode, and a polyethylene film (Celgard, thickness: 20 ⁇ ) as a separator and a 1: 2 mixture of ethylene carbonate, dimethylene carbonate and diethyl carbonate : in to a solvent heunhap to 1 using a liquid electrolyte with a LiPF 6 dissolved in 1M, it was prepared secondary battery 10 by one.
  • a polyethylene film (Celgard, thickness: 20 ⁇ ) as a separator and a 1: 2 mixture of ethylene carbonate, dimethylene carbonate and diethyl carbonate : in to a solvent heunhap to 1 using a liquid electrolyte with a LiPF 6 dissolved in 1M, it was prepared secondary battery 10 by one.
  • the secondary batteries were subjected to a layer discharge for 10 cycles at intervals of 2.5 V - 4.35 V at 1.0 C to measure the number of short-circuited and ignited cells. The results are shown in Table 1 below.
  • a photo-curing substance is formed at the step portion of the coated portion of the lithium metal layer and the non-
  • the present invention can solve the problem of the occurrence of a burr occurring in the conventional punching process and can be used for laser punching or punching, There is no need to add a separate step such as rolling to flatten the remaining lithium metal in the burr form, which is effective in terms of cost and process.
  • the lithium metal cathode structure thus manufactured includes an insulating layer or an insulating tape made of a photo-curable material by the above process at a stepped portion of the coating portion of the tap and the lithium metal layer. Then, in the secondary battery, It is possible to obtain a further effect of preventing a short circuit with the cathode material due to exposure to the cathode material.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

La présente invention concerne un procédé de fabrication d'une structure d'anode en lithium métallique et une structure d'anode en lithium métallique, le procédé comprenant les étapes suivante: (a) la formation d'une partie revêtue d'une couche de lithium métallique sur une surface ou les deux surfaces d'un collecteur de courant pour fabriquer un stratifié, une face du collecteur de courant comprenant une partie non revêtue sur laquelle une carte doit être formée; (b) l'application d'un matériau photodurcissable sur des parties étagées de la partie non revêtue et la partie revêtue d'une couche de lithium métallique pour durcir le matériau ou fixer une bande isolante sur les parties étagées; et (c) la découpe du stratifié en électrodes unitaires afin de fabriquer une structure d'anode en lithium métallique.
PCT/KR2018/010431 2017-10-27 2018-09-06 Procédé de fabrication d'une structure d'anode en lithium métallique et structure d'anode en lithium métallique Ceased WO2019083156A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN201880024857.3A CN110945690B (zh) 2017-10-27 2018-09-06 用于制造锂金属负极结构的方法和锂金属负极结构
PL18869520.9T PL3598538T3 (pl) 2017-10-27 2018-09-06 Sposób wytwarzania struktury elektrody ujemnej z litem metalicznym i struktura elektrody ujemnej z litem metalicznym
JP2019559099A JP7045555B2 (ja) 2017-10-27 2018-09-06 リチウム金属負極構造体の製造方法およびリチウム金属負極構造体
EP18869520.9A EP3598538B1 (fr) 2017-10-27 2018-09-06 Procédé de fabrication d'une structure d'anode en lithium métallique et structure d'anode en lithium métallique
US16/604,930 US11228029B2 (en) 2017-10-27 2018-09-06 Method for producing lithium metal negative electrode structure and lithium metal negative electrode structure
ES18869520T ES2980174T3 (es) 2017-10-27 2018-09-06 Método para producir estructura de electrodo negativo de metal de litio y estructura de electrodo negativo de metal de litio

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KR1020180105740A KR102722632B1 (ko) 2017-10-27 2018-09-05 리튬 금속 음극 구조체의 제조방법 및 리튬 금속 음극 구조체
KR10-2018-0105740 2018-09-05

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KR20150098445A (ko) * 2014-02-20 2015-08-28 주식회사 엘지화학 절연물질이 코팅되어 있는 전극을 포함하는 전지셀
KR20160091732A (ko) * 2015-01-26 2016-08-03 주식회사 엘지화학 절연 코팅부를 포함하는 양극의 제조 방법 및 이를 사용하여 제조되는 양극
KR20170055722A (ko) * 2015-11-12 2017-05-22 주식회사 엘지화학 노칭부를 포함하는 전극 시트를 이용하여 전극판을 제조하는 방법

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