WO2019197617A1 - Utilisation de dérivés d'acide tétramique pour lutter contre des bioagresseurs animaux par arrosage, pulvérisation, traitement de trou de plantation ou application sur raie. - Google Patents

Utilisation de dérivés d'acide tétramique pour lutter contre des bioagresseurs animaux par arrosage, pulvérisation, traitement de trou de plantation ou application sur raie. Download PDF

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Publication number
WO2019197617A1
WO2019197617A1 PCT/EP2019/059438 EP2019059438W WO2019197617A1 WO 2019197617 A1 WO2019197617 A1 WO 2019197617A1 EP 2019059438 W EP2019059438 W EP 2019059438W WO 2019197617 A1 WO2019197617 A1 WO 2019197617A1
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application
use according
alkyl
hydrogen
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English (en)
Inventor
Reiner Fischer
Matthias Haas
Leonardo Pitta
Elke Schrader
Christian Arnold
Udo Reckmann
Erich Sanwald
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Bayer CropScience AG
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Bayer CropScience AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests

Definitions

  • the present invention relates to the use of certain tetramic acid derivatives for combating animal pests such as insects and / or spider mites and / or nematodes by casting, droplet application, plant hole treatment or furrow application.
  • NH tetramic acid derivatives as crop protection agents are, for. B. known from (EP-A-442 073) and 1H-arylpyrrolidine-dione derivatives of (EP-A-456 063, EP-A-521 334, EP-A-596 298, EP-A-613 884, EP-A-613 885, WO 95/01 971, WO 95/26 954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96/35 664, WO 97/01 535 WO 97/02 243, WO 97/36868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/24437, WO 99/43649, WO 99/48869, WO 99 / 55673, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249, WO 03/
  • ketal-substituted 1-H-arylpyrrolidine-2,4-diones from WO 99/16748 and (spiro) -ketalsubstitutechnisch N-alkoxy-alkoxy-substituted aryl-pyrrolidindione from JP-A-14 205 984 and Ito M. et al. Bioscience, Biotechnology and Biochemistry 67, 1230-1238, (2003).
  • certain tetramic acid derivatives are also suitable for plant-hole treatment, after dipping root system, tubers or onions (known in the art as dip application), through hydroponic systems or soil injection (known in the art as "soil injection”). It has also been found that certain tetramic acid derivatives are well suited for controlling insects and / or spider mites and / or nematodes by furrow application.
  • the present invention accordingly relates to the use of tetramic acid derivatives for controlling animal pests such as insects and / or spider mites and / or nematodes by casting on the ground or in irrigation systems as a droplet application to the soil.
  • the use of tetramic acids to combat insects and / or spider mites and / or nematodes can also be done as a dip application of root system, tubers or onions or by soil injection.
  • the use of tetramic acids for controlling insects and / or spider mites and / or nematodes can also be carried out as a plant hole treatment or as a furrow application.
  • the present invention relates to these uses on natural (soil) or artificial substrates (e.g., rockwool, glass wool, silica sand, pebbles, expanded clay, vermiculite) in the field or in closed systems (e.g., greenhouses or under foil cover); in annuals (e.g., cotton, soybeans, tobacco, vegetables, spices, ornamental plants) or perennial crops (e.g., citrus plants, fruits, tropical crops, spices, nuts, wine, conifers, and ornamental plants).
  • natural soil
  • artificial substrates e.g., rockwool, glass wool, silica sand, pebbles, expanded clay, vermiculite
  • closed systems e.g., greenhouses or under foil cover
  • annuals e.g., cotton, soybeans, tobacco, vegetables, spices, ornamental plants
  • perennial crops e.g., citrus plants, fruits, tropical crops, spices, nuts, wine, conifers, and ornamental plants.
  • oil is understood to mean both natural growth substrate (soil, soil soil) and artificial growth substrate (for example rock wool, glass wool, quartz sand, pebbles, expanded clay, vermiculite).
  • fruit vegetables and inflorescences are understood to mean vegetables, for example peppers, hot peppers, tomatoes, aubergines, cucumbers, pumpkins, zucchini, melons, potatoes, beans such as field beans, carioca beans, runner beans, bush beans; Peas, artichokes, corn; but also leafy vegetables, such as lettuce, chicory, endives, kraken, ruffians, lamb's lettuce, iceberg lettuce, leeks, spinach, chard; tubers, root and stem vegetables, such as celery, beetroot, carrots, radishes, horseradish, salsify, asparagus, turnips, palm sprouts, bamboo shoots, as well as onion vegetables, such as onions, leeks, fennel, garlic; cabbage, such as cauliflower, broccoli, kohlrabi, red cabbage, cabbage, kale, savoy cabbage, Brussels sprouts, Chinese cabbage; also cotton, soy and tobacco.
  • vegetables for example peppers, hot peppers, tomatoes, aubergines, cucumbers, pumpkins, zucchini,
  • citrus such as oranges, grapefruit, tangerines, lemons, limes, bitter oranges, kumquats, satsumas are understood to be among the perennial crops; but also pomaceous fruits, such as apples, pears and quinces, and stone fruit, such as peaches, nectarines, cherries, plums, plums, apricots; wine, hops, olives, tea and tropical crops such as mangoes, papayas, figs, pineapples, dates, bananas, durians, kakis, coconuts, cocoa, coffee, avocados, lychees, passion fruits, guavas, almonds and Nuts such as hazelnuts, walnuts, pistachios, cashews, Brazil nuts, pecans, butternuts, chestnuts, hickory nuts, macadamias, peanuts, berries such as currants, gooseberries, raspberries, blackberries, blueberries, strawberries, cranberries,
  • ornamental plants are understood to be annual and perennial plants, e.g. Cut flowers such as roses, carnations, gerberas, lilies, daisies, chrysanthemums, tulips, daffodils, anemones, poppies, amyrillis, dahlias, azaleas, mallows, but also e.g. Bedding plants, potted plants and perennials such as roses, marigolds, pansies, geraniums, fuchsias, hibiscus, chrysanthemums, hardy licks, cyclamen, southern violets, sunflowers, begonias, furthermore e.g. Shrubs and conifers such as ficus, rhododendron, spruce, fir, pine, yew, juniper, pine, oleander.
  • Shrubs and conifers such as ficus, rhodo
  • spices perennial and perennial plants such as anise, chilli, pepper, pepper, vanilla, marjoram, thyme, cloves, juniper berries, cinnamon, tarragon, coriander, saffron, ginger.
  • the tetramic acid derivatives are preferably compounds of the formula (I)
  • W and Y are independently hydrogen, C
  • Vl is hydrogen, halogen, C
  • V 2 is hydrogen, halogen, C
  • V 2 is hydrogen or halogen
  • A, B and the carbon atom to which they are attached represent saturated Cg-Cg-cycloalkyl, in which one ring member is replaced by oxygen and which may be readily substituted by C j -Cg-alkyl,
  • G is hydrogen (a) or one of the groups E (d) in which E is a metal ion or an ammonium ion,
  • L is oxygen or sulfur and M is oxygen or sulfur
  • -Cg-alkyl represents straight-chain or branched C j -Cg-alkyl.
  • Tetramic acid derivatives of the abovementioned formula (I) in which the radicals have the following meaning are particularly preferably usable:
  • W is particularly preferably hydrogen or methyl
  • X is particularly preferably chlorine or methyl
  • Y is particularly preferably hydrogen.
  • Yl is particularly preferably fluorine or chlorine (highlighted for fluorine or chlorine in the 4-position), particularly preferably hydrogen or fluorine (highlighted for fluorine in the 3-position), is particularly preferably Hydrogen or fluorine (highlighted for fluorine in the 5-position),
  • A, B and the carbon atom to which they are attached are more preferably saturated C 9 -cycloalkyl in which one ring member is replaced by oxygen,
  • G is particularly preferably hydrogen (a) or one of the groups E (d), in which
  • E particularly preferably represents a metal ion equivalent or an ammonium ion (highlighted for sodium or potassium),
  • Rl particularly preferred for straight-chain or branched C
  • optionally substituted radicals may be monosubstituted or polysubstituted, with multiple substituents the substituents being the same or different.
  • Tetramic acid derivatives of the abovementioned formula (I) in which the radicals have the following meaning are particularly preferably usable:
  • tetramic acid derivatives can be carried out alone, but also in combination with other insecticides and / or acaricidal active substances and / or nematicides.
  • the invention relates to the use of the compounds of the formula (I) as pesticides, in particular as crop protection agents by casting, droplet application, dipping application, soil injection, Graphloch aspect or furrow application.
  • pest control always includes the term pesticides.
  • the compounds of formula (I) are suitable for good plant compatibility, favorable warm-blooded toxicity and good environmental compatibility for the protection of plants and plant organs Increasing crop yields, improving the quality of the crop and controlling animal pests, particularly insects, arachnids and nematodes, which are found in agriculture, horticulture, forests and gardens and recreational facilities. They can preferably be used as pesticides. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the above mentioned pests include:
  • Pests from the strain of Arthropoda in particular from the class of Arachnida z. Acarus spp., E.g. Acarus siro, Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., E.g. Aculus fockeui, Aculus badendali, Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp., E.g. B.
  • Oligonychus coffeae Oligonychus coniferarum, Oligonychus ilicis, Oligonychus indicus, Oligonychus mangiferus, Oligonychus pratensis, Oligonychus punicae, Oligonychus yothersi, Ornithodorus spp., Ornithonyssus spp., Panonychus spp., E.g.
  • Panonychus citri Metatetranychus citri
  • Panonychus ulmi Metatetranychus ulmi
  • Phyllocoptruta oleivora Platytetranychus multidigituli
  • Polyphagotarsonemus latus Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Steneotarsonemus spp. Steneotarsonemus spinki, Tarsonemus spp. Tarsonemus confusus, Tarsonemus pallidus, Tetranychus spp., E.g.
  • Epitrix cucumeris Epitrix fuscula, Epitrix hirtipennis, Epitrix subcrinita, Epitrix tuberis, Faustinus spp., Gibbium psylloides, Gnathocerus cornutus, Hellula and alis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrupes b Camillus, Hypera postica, Hypomeces squamosus, Hypothenemus spp., z.
  • Hypothenemus hampei Hypothenemus obscurus, Hypothenemus pubescens, Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae, Lathridius spp., Lema spp., Leptinotarsa decemlineata, Leucoptera spp., E.g. Luperoptera spp., Luperodes spp., Luperomorpha xanthodera, Lyctus spp., Megacyllene spp., E.g. Megacyllene robiniae, Megascelis spp., Melanotus spp., E.g.
  • Melanotus longulus oregonensis Meligethes aeneus, Melolontha spp., E.g. Melolontha melolontha, Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp., Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorhynchus spp., E.g.
  • Otiorhynchus cribricollis Otiorhynchus ligustici, Otiorhynchus ovatus, Otiorhynchus rugosostriarus, Otiorhynchus sulcatus, Oulema spp., E.g. Oulema melanopus, Oulema oryzae, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllophaga helleri, Phyllotreta spp., E.g.
  • Phyllotreta armoraciae Phyllotreta pusilla, Phyllotreta ramosa, Phyllotreta striolata, Popillia japonica, Premnotrypes spp., Prostephanus truncatus, Psylliodes spp., E.g.
  • Tribolium audax Tribolium castaneum, Tribolium confusum, Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp., E.g. Zabrus tenebrioides; from the order of Diptera z.
  • Aedes spp. Z. Aedes aegypti, Aedes albopictus, Aedes sticticus, Aedes vexans, Agromyza spp., E.g. Agromyza frontella, Agromyza parvicornis, Anastrepha spp., Anopheles spp., E.g.
  • Anopheles quadrimaculatus, Anopheles gambiae, Asphondylia spp., Bactrocera spp. E.g. Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera oleae, Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis capitata, Chironomus spp., Chrysomya spp., Chrysops spp., Chrysozona pluvialis, Cochliomya spp., Contarinia spp., E.g.
  • Acyrthosiphon pisum Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurocanthus spp., Aleyrodes proletella, Aleurolobus barodensis, Aleurothrixus floccosus, Allocaridara malayensis, Amrasca spp., E.g. Amrasca bigutulla, Amrasca devastans, Anuraphis cardui, Aonidiella spp.
  • Eg Icerya purchasi, Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., E.g. B. Lecanium corni ( Parthenolecanium corni), Lepidosaphes spp., Z. Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma americanula, Macrosiphum spp., E.g.
  • Macrosiphum euphorbiae Macrosiphum lilii, Macrosiphum rosae, Macrosteles facifrons, Mahanarva spp., Melanaphis sacchari, Metcalfiella spp., Metcalfa pruinosa, Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., E.g.
  • Paratrioza cockerelli Parlatoria spp., Pemphigus spp., E.g. B. Pemphigus bursarius, Pemphigus populivenae, Peregrinus maidis, Perkinsiella spp., Phenacoccus spp., Z. Phenacoccus madeirensis, Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., E.g. Phylloxera devastatrix, Phylloxera notabilis, Pinnaspis aspidistrae, Planococcus spp., E.g. B.
  • Planococcus citri Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Z. Pseudococcus calceolariae, Pseudococcus comstocki, Pseudococcus longispinus, Pseudococcus maritimus, Pseudococcus viburni, Psyllopsis spp., Psylla spp., E.g.
  • Rhopalosiphum maidis Rhopalosiphum oxyacanthae, Rhopalosiphum padi, Rhopalosiphum rufiabdominal, Saissetia spp., E.g.
  • Trioza spp. E.g. Trioza diospyri, Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp .; from the subordination of Heteroptera z.
  • Aelia spp. Anasa tristis, Antestiopsis spp., Boisea spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., E.g.
  • Cimex adjunctus Cimex hemipterus, Cimex lectularius, Cimex pilosellus, Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., E.g.
  • Hoplocampa cookei Hoplocampa testudinea, Lasius spp., Linepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp., Paravespula spp., Plagiolepis spp., Sirex spp., E.g. Sirex noctilio, Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., E.g. Vespa crabro, Wasmannia auropunctata, Xeris spp .; from the order of Isopoda z.
  • Cydia nigricana Cydia pomonella, Dalaca noctuides, Diaphania spp., Diparopsis spp., Diatraea saccharalis, Dioryctria spp., E.g. B. Dioryctria tremani, Earias spp., Ecdytolopha aurantium, Elasmopalpus lignosellus, Eldana saccharina, Ephestia spp., E.g.
  • Grapholita molesta Grapholita prunivora, Hedylepta spp., Helicoverpa spp., Z. Helicoverpa armigera, Helicoverpa zea, Heliothis spp. Homo. Spp., Hyponomeuta padella, Kakivoria flavofasciata, Lampides spp., Laphygma spp., Laspeyresia molesta, Leucinodes orbonalis, Leucoptera spp., E.g. B. Leucoptera coffeella, Lithocolletis spp., Z. B.
  • Trichoplusia ni Tryporyza incertulas, Tuta absolutea, Virachola spp .; from the order of Orthoptera or Saltatoria z.
  • Thrips palmi Thrips tabaci
  • Bursaphelenchus cocophilus, Bursaphelenchus eremus, Bursaphelenchus xylophilus, Cacopaums spp., E.g. Cacopaums pestis, Criconemella spp., E.g. Criconemella curvata, Criconemella onoensis, Criconemella ornata, Criconemella msium, Criconemella xenoplax ( Mesocriconema xenoplax), Criconemoides spp., E.g.
  • Pratylenchus penetrans Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus spp., E.g. Radopholus citrophilus, Radopholus similis, Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., E.g. Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., E.g. Tylenchorhynchus annulatus, Tylenchulus spp., E.g. B. Tylenchulus semipenetrans, Xiphinema spp., Z. B. Xiphinema index.
  • a nematocide in crop protection as described herein has the ability to control nematodes.
  • controlling nematodes means killing the nematodes or preventing or aggravating their development or growth or preventing or hindering their penetration into or their sucking on the plant tissue.
  • Methods are known to the person skilled in the art, such as mortalities, bile formation, cyst formation, nematode density per soil volume, nematode density per root, number of nematode eggs per soil volume, mobility of the nematodes.
  • the use of a compound of the formula (I) can maintain the plant in a healthy state and also involves a reduction in the damage caused by nematodes and an increase in the amount of harvest.
  • nematodes in the present context refers to plant nematodes, under which one summarizes all nematodes that damage plants. Include plant nematodes plant parasitic nematodes and nematodes living in the soil. Plant parasitic nematodes include ectoparasites such as Xiphinema spp., Longidorus spp. and Trichodorus spp .; Semi-parasites such as Tylenchulus spp .; migratory endoparasites such as Pratylenchus spp., Radopholus spp.
  • ectoparasites such as Xiphinema spp., Longidorus spp. and Trichodorus spp .
  • Semi-parasites such as Tylenchulus spp .
  • migratory endoparasites such as Pratylenchus spp., Radopholus spp.
  • the plant parasitic nematodes include e.g. Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Rotylenchus spp. Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.
  • Anguina spp. Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera
  • the active ingredient of the formula (I) can be used in the customary formulations and in the use forms prepared therefrom as pesticides such. B. drench, drip and spray liquors are transferred.
  • the uses include other pesticides and / or effect-improving adjuvants such as penetration enhancers, e.g. As vegetable oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of fatty acids such as rapeseed oil or soybean oil or alkanol alkoxylates and / or spreading agents such as alkyl siloxanes and / or salts, eg.
  • organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-promoting agents such.
  • organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-promoting agents such.
  • dioctyl sulfosuccinate or hydroxypropyl guar polymers and / or humectants such.
  • glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizer.
  • Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS). ; these and other possible formulation types are described, for example, by Crop Life International and in Pesticide Specifications, Manual on development and use of FAO and WHO specifications for pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576. If appropriate, the formulations contain, in addition to one or more compounds of the formula (I), further agrochemical active substances.
  • formulations are prepared in a known manner, for. Example by mixing the compounds of formula (I) with excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants.
  • excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants.
  • the preparation of the formulations is carried out either in suitable systems or before or during use.
  • Excipients which can be used are those which are suitable for imparting special properties to the formulation of the compounds of the formula (I) or the use forms prepared from these formulations (such as, for example, usable pesticides such as spray mixtures or seed dressing), such as certain physical, technical and / or to confer biological properties.
  • xylene toluene or alkylnaphthalenes
  • chlorinated aromatic or chlorinated aliphatic hydrocarbons such.
  • chlorobenzene chloroethylene, or methylene chloride, aliphatic hydrocarbons such.
  • cyclohexane paraffins, petroleum fractions, mineral and vegetable oils, alcohols such.
  • acetone As acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethyl sulfoxide, carbonates such as propylene carbonate, butylene carbonate, diethyl carbonate, dibutyl carbonate, nitriles such as acetonitrile or propanenitrile, and water.
  • strong polar solvents such as dimethyl sulfoxide
  • carbonates such as propylene carbonate, butylene carbonate, diethyl carbonate, dibutyl carbonate
  • nitriles such as acetonitrile or propanenitrile
  • Suitable carriers can be used.
  • carriers are in particular question: z.
  • ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic minerals such as finely divided silica, alumina and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used.
  • Suitable carriers for granules are: z.
  • Phosphoric acid esters of polyethoxylated alcohols or phenols fatty acid esters of polyols and derivatives of the compounds containing sulfates, sulfonates and phosphates, eg.
  • alkylaryl polyglycol ethers alkylsulfonates, alkyl sulfates, arylsulfonates, protein hydrolysates, lignin-Sulphatablaugen and methylcellulose.
  • the presence of a surfactant is advantageous when one of the compounds of formula (I) and / or one of the inert carriers is not soluble in water and when applied in water.
  • auxiliaries can in the formulations and the applications derived therefrom dyes such as inorganic pigments, eg.
  • dyes such as inorganic pigments, eg.
  • iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and Metallphthalocyaninfarbstoffe and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc may be present.
  • auxiliaries may be present in the formulations and in the use forms derived therefrom.
  • additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestering agents, complexing agents, humectants, spreading agents.
  • the compounds of formula (I) may be combined with any solid or liquid additive commonly used for formulation purposes.
  • retention promoters are all those substances which reduce the dynamic surface tension such as dioctylsulfosuccinate or increase the visco-elasticity such as hydroxypropyl guar polymers.
  • the formulations preferably contain between 0.00000001 and 98 wt .-% of the compound of formula (I), more preferably between 0.01 and 95 wt .-% of the compound of formula (I), most preferably between 0.5 and 90% by weight of the compound of formula (I), based on the weight of the formulation.
  • the content of the compound of the formula (I) in the forms of application prepared from the formulations (in particular pesticides) can vary within wide ranges.
  • the concentration of the compound of the formula (I) in the use forms may usually be between 0.00000001 and 95% by weight of the compound of the formula (I), preferably between 0.00001 and 1% by weight, based on the weight of the application form , lie.
  • the application is done in a custom forms adapted to the application.
  • the compounds of the formula (I) are preferably used after casting (drench) against animal pests from the following pest families:
  • bladder lice Pemphigidae: Eriosoma spp., Pemphigus spp., In cultures such as e.g. Citrus, pome fruit, stone fruit, leafy vegetables, root and tuber vegetables and ornamental plants.
  • Diaspididae quadraspidiotus spp., Aonidiella spp., Lepidosaphes spp., Aspidiotus spp., Aspis spp., Diaspis spp., Parlatoria spp., Pseudaulacaspis spp., Unaspis spp., Pinnaspis spp. , Selenaspidus spp., In cultures such as Citrus, pome fruit, stone fruit, almonds, pistachios, nuts, olives, tea, ornamentals, wine, tropical crops.
  • Phorodon humuli in hops
  • thrips Thripidae: Anaphothrips spp., Basothrips spp., Caliothrips spp., Frankl iniella spp., Heliothrips spp., Hercinothrips spp., Rhipiphorothrips spp., Scirtothrips spp., Kakothrips spp., Selenothrips spp. and Thrips spp., in crops such as fruit, cotton, wine, tea, nuts, tropical crops, ornamentals, conifers, tobacco, spices, vegetables, berries, melons, citrus and potatoes.
  • crops such as fruit, cotton, wine, tea, nuts, tropical crops, ornamentals, conifers, tobacco, spices, vegetables, berries, melons, citrus and potatoes.
  • leaf flies Agromyzidae
  • flower flies Anthomyiidae
  • Agromyza spp. Amauromyza spp.
  • Amauromyza spp. Atherigona spp.
  • Chlorops spp. Liriomyza spp.
  • Oscinella spp. Pegomyia spp. in crops such as vegetables, melons, potatoes, nuts, ornamental plants.
  • Caloptilia spp. Gracillaria spp., Lithocolletis spp., Leucoptera spp., Phtorimaea spp., Phyllocnistis spp. in crops such as pome fruit, stone fruit, wine, nuts, citrus, conifers, potatoes, coffee.
  • Contarinia spp. Dasineura spp., Diplosis spp., Prodiplosis spp., Thecodiplosis spp., Sitodiplosis spp., Haplodiplosis spp. in crops such as citrus, pome fruit, stone fruit, vegetables, potatoes, spices, berry fruit, conifers, hops.
  • Anastrepha spp. Ceratitis spp., Dacus spp., Rhagoletis spp. in crops such as vegetables, soft fruits, melons, pome and stone fruits, ornamental plants, potatoes, wine, tropical crops, citrus, olives.
  • Tetranychus spp. Tetranychus spp., Panonychus spp., Aculops spp. in crops such as vegetables, potatoes, ornamental plants, citrus, wine, conifers.
  • Eriosoma pyricola in pome fruit such as e.g. Apples and pears
  • leafy vegetables e.g. Lettuce
  • root vegetables such as e.g. Carrots
  • ornamentals such as e.g. Chrysanthemums.
  • Psylla pyricola in pome fruit such as e.g. Pears, apples, in stone fruits, such as Cherries, plums, plums, peaches, nectarines, Psylla piri in pome fruit such as e.g. pears,
  • Paratrioza cockerelli in fruit vegetables such as tomatoes, peppers, chilli, in root vegetables such as carrots, in potatoes, Tenalaphara malayensis in tropical cultures such as durians (stinky fruits),
  • Diaphorina citri in citrus such as e.g. Oranges, tangerines, limes, grapefruit,
  • Trioza erythrae in citrus such as e.g. Oranges, grapefruit.
  • Napfschildläuse (Coccidae) Very particularly preferred is the control of the following species from the family of Napfschildläuse (Coccidae) in the following cultures:
  • Tube shield lice (Ortheziidae)
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with water to the desired concentration.
  • the kill of the eggs or larvae is determined in%. 100% means that all animals have been killed; 0% means that no animals were killed.
  • the evaluation takes place 5, 10, 13 and 17 days after the treatment by scoring the killing of the lice on the plants.
  • the evaluation takes place 14, 15 and 18 days after the treatment by scoring the killing of the animals (nymphs) on the leaves.
  • the evaluation is carried out 7, 14 and 21 days after the first treatment by scoring the kill of the larvae in the mines on 12 leaves each.
  • Dasineura brassicae, Dasineura mali, Dasineura piri in carrots, tubers, rootlets and stalks vegetables such as e.g. Asparagus, fruit vegetables such as Peppers, tomatoes, cucumbers; Potatoes, cotton, cabbage, pome fruit, spices.
  • Fruit vegetables tomatoes, peppers), citrus (e.g., limonene, oranges, grapefruit, clementines), cereals (e.g., wheat, barley), conifers, and forest.
  • Contarinia lycopersici Contarinia maculipennis, Contarina humuli, Contarinia johnsoni, Contarinia nasturti, Contarina okadai, Contarinia tritici, Contarinia pisi, Contarina sorghicola, Contarinia medicaginis, Contarinia mali in vegetables such.
  • the evaluation is carried out 29, 36 and 43 days after the treatment by counting live animals on 20 leaves each.
  • the effectiveness is determined using the Abbott formula.
  • the compounds of the formula (I) are preferably used after being used in a drip against animal pests from the following pest families:
  • bladder lice Pemphigidae: Eriosoma spp., Pemphigus spp., In cultures such as e.g. Citrus, pome fruit, stone fruit, leafy vegetables, root and tuber vegetables and ornamental plants.
  • mothback lice family (Aleyrodidae): Bemisia tabaci, Bemisia argentifolii, Trialeurodes vaporariorum, Aleurothrixus floccosus, Aleurodes spp., Dialeurodes spp., Parabemisia myricae in crops such as e.g. Vegetables, melons, potatoes, tobacco, berry fruits, citrus, ornamental plants, cotton, soybeans and tropical crops.
  • crops such as e.g. Vegetables, melons, potatoes, tobacco, berry fruits, citrus, ornamental plants, cotton, soybeans and tropical crops.
  • Phorodon humuli in hops
  • Toxoptera spp. In citrus, stone fruits, almonds, nuts, spices,
  • thrips Thripidae: Anaphothrips spp., Basothrips spp., Caliothrips spp., Frankl iniella spp., Heliothrips spp., Hercinothrips spp., Rhipiphorothrips spp., Scirtothrips spp., Kakothrips spp., Selenothrips spp. and Thrips spp., in cultures such as e.g. Fruit, cotton, wine, tea, nuts, tropical crops, ornamental plants, conifers, tobacco, spices, vegetables, berries, melons, citrus and potatoes.
  • cultures such as e.g. Fruit, cotton, wine, tea, nuts, tropical crops, ornamental plants, conifers, tobacco, spices, vegetables, berries, melons, citrus and potatoes.
  • Agromyza spp. Agromyza spp., Amauromyza spp., Atherigona spp., Chlorops spp., Liriomyza spp., Oscinella spp., Pegomyia spp. in cultures such as e.g. Vegetables, melons, potatoes, nuts, ornamental plants.
  • Caloptilia spp. Gracillaria spp., Lithocolletis spp., Leucoptera spp., Phtorimaea spp., Phyllocnistis spp. in crops such as pome fruit, stone fruit, wine, nuts, citrus, conifers, potatoes, coffee.
  • Contarinia spp. Dasineura spp., Diplosis spp., Prodiplosis spp., Thecodiplosis spp., Sitodiplosis spp., Haplodiplosis spp. in crops such as citrus, pome fruit, stone fruit, vegetables, potatoes, spices, berry fruit, conifers, hops.
  • Anastrepha spp. Ceratitis spp., Dacus spp., Rhagoletis spp. in crops such as vegetables, soft fruits, melons, pome and stone fruits, ornamental plants, potatoes, wine, tropical crops, citrus, olives.
  • Tetranychus spp. Tetranychus spp., Panonychus spp., Aculops spp. in crops such as vegetables, potatoes, ornamental plants, citrus, wine, conifers.
  • the invention is illustrated by the following examples. These are in no way limiting.
  • Eriosoma lanigerum in pome fruit e.g. Apples, pears and stone fruits, such as Cherries, plums, plums,
  • leafy vegetables e.g. Lettuce
  • root vegetables such as e.g. Carrots
  • ornamentals such as e.g. chrysanthemums
  • Psyllidae Psylla pyricola in pome fruit such. Pears, apples, in stone fruits, such as Cherries, plums, plums, peaches, nectarines,
  • Psylla costalis in pome fruit such as apples
  • Paratrioza cockerelli in fruit vegetables such as tomatoes, peppers, chilli
  • root vegetables such as carrots, in potatoes
  • Diaphorina citri in citrus such as e.g. Oranges, tangerines, limonene, grapefruit, trioza erythrae in citrus e.g. Oranges, grapefruit.
  • Tube shield lice (Ortheziidae)
  • Example 14 6 m 2 plots of "Tomohauk” eggplant (plant growth stage BBCH 14) are identified in three replications against Bemisia tabaci (BEMITA) with 200 pL / plant of a drug solution containing the active ingredient Example (1-7) (050 SL) and the Comparison with 14.2 mg / plant (WG 70) of the standard Imidacloprid treated by Dripper.
  • the evaluation was carried out 14, 21, 28, 35 and 42 days after the treatment by counting living nymphs on 20 leaves each. The effectiveness is determined using the Abbott formula.
  • Approximately 12.5 m 2 parcels with "Dorata di Bologna" bulbs are in three replications against Thrips tabaci (THRITB) with 4000 ml / ha of a drug solution containing the active ingredient example (1-7) (050 SL) and treated for comparison with 1000 ml / ha of the standard Imidacloprid (200 SL) by means of dripper with a water application rate of 12000 1 / ha.
  • the application is carried out twice with the above quantities at intervals of 7 days *.
  • the evaluation is carried out 6, 14, 22, 29 and 36 days after the first treatment by counting living thrips - nymphs on 20 plants each. The effectiveness is determined using the Abbott formula.
  • Dasineura brassicae, Dasineura mali, Dasineura piri in carrots, tubers, rootlets and stalks vegetables such as e.g. Asparagus, fruit vegetables such as Peppers, tomatoes, cucumbers; Potatoes, cotton, cabbage, pome fruit, spices.
  • Prodiplosis vaccinii Prodiplosis longifila, Thecodiplosis brachyntera, Thecodiplosis japonensis, Sitodiplosis mosellana, Haplodiplosis equestris in vegetables such.
  • Fruit vegetables tomatoes, peppers), citrus (eg limonene, oranges, grapefruit, clementines), cereals (eg wheat, barley), conifers and forest.
  • Contarinia lycopersici Contarinia maculipennis, Contarina humuli, Contarinia johnsoni, Contarina nasturti, Contarina okadai, Contarinia tritici, Contarina pisi, Contarina sorghicola, Contarinia medicaginis, Contarinia mali in vegetables such as. B. cabbage, fruit vegetables; Cereals such. Wheat, sorghum; Pome fruit; Hop. Fruit flies (Tenhritidae)
  • Approximately 4 m 2 parcels with eggplant of the variety "Paris” are in three replications against Tetranychus urticae (TETRUR) with 1000 ml / ha and 2000 ml / ha of a drug solution containing the active ingredient Example (1-7) (050 SL) in 250 ml / plant of water using a dripper and applied for comparison 200 ml / ha of the standard spirotetramat (240 SC) in a spray application with lg / l rapeseed oil methyl ester in 750l / ha of water.
  • the application is carried out twice with the above quantities at intervals of 7 days *.
  • the evaluation is carried out 3, 7, 10, 14, 21 and 28 days after the first treatment by counting live mites (larvae) on 5 leaves each. The effectiveness is determined using the Abbott formula.
  • the SL formulations (050 SL) and the SC formulation (025 SC) of the compound of the formula (1-7) can be prepared analogously to the formulations described in WO 2009/115262.

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
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Abstract

L'invention concerne des composés de formule (II) dans laquelle A, B, G, W, X, Y, V1, V2, V3 peuvent être tels que spécifiés dans la description, ces composés convenant à la lutte contre des bioagresseurs animaux tels que des insectes et/ou tétranyques et/ou nématodes par traitement du sol/substrat de croissance par arrosage, pulvérisation, traitement de trou de plantation ou application sur raie.
PCT/EP2019/059438 2018-04-13 2019-04-12 Utilisation de dérivés d'acide tétramique pour lutter contre des bioagresseurs animaux par arrosage, pulvérisation, traitement de trou de plantation ou application sur raie. Ceased WO2019197617A1 (fr)

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