WO2020064256A1 - Composite polymère - Google Patents

Composite polymère Download PDF

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Publication number
WO2020064256A1
WO2020064256A1 PCT/EP2019/073032 EP2019073032W WO2020064256A1 WO 2020064256 A1 WO2020064256 A1 WO 2020064256A1 EP 2019073032 W EP2019073032 W EP 2019073032W WO 2020064256 A1 WO2020064256 A1 WO 2020064256A1
Authority
WO
WIPO (PCT)
Prior art keywords
polymer composite
olive
composite
present
extruder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2019/073032
Other languages
English (en)
Inventor
Orkun KAYMAKCI
Ismail KURUAL
Nuzhet Inci KILIC
Fatih TUTAL
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arcelik AS
Original Assignee
Arcelik AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arcelik AS filed Critical Arcelik AS
Publication of WO2020064256A1 publication Critical patent/WO2020064256A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
    • C08K11/005—Waste materials, e.g. treated or untreated sewage sludge
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/30—Applications used for thermoforming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/66—Substances characterised by their function in the composition
    • C08L2666/72—Fillers; Inorganic pigments; Reinforcing additives

Definitions

  • the present invention relates to a polymer composite, to the production method thereof and the use thereof in white goods.
  • the aim of the present invention is the use of polymeric composite, which is obtained by adding olive stone (dry olive pomace) powder into thermoplastic materials, in white goods applications.
  • the polymeric composite realized in order to attain the aim of the present invention, explicated in the first claim and the respective claims thereof comprises a thermoplastic material, a desiccant, a compatibilizer, olive stone (olive pomace) powder and, optionally, mineral additive and/or fibrous additive.
  • the polymer composite of the present invention can be used in white goods such as laundry washing machine, laundry drying machine, dishwasher, refrigerator, air conditioner, curling iron, hair straightener, water purifier, coffee machine, tea machine, air purifier, oven, cooker, kettle, etc.
  • Figure 1 is the scanning electron microscope view of the composite comprising A) Additive-free polypropylene (PP), B) PP + 10% Olive Stone Powder, C) PP + 40% Olive Stone Powder.
  • PP Additive-free polypropylene
  • the polymeric composite of the present invention comprises a desiccant, a thermoplastic material, a compatibilizer and, optionally, mineral additive and/or fibrous additive.
  • the desiccant retains the potential moisture from the olive stones. Thus, the risk of the moisture damaging the material during the process is prevented.
  • Maleic anhydride-grafted polypropylene compatibilize the hydrophilic olive stone powder and the hydrophilic polypropylene, thus improving the physical and mechanical properties of the materials.
  • the olive stone powder is coated with polypropylene, thus preventing the material from getting humid.
  • the polymeric composite of the present invention comprises olive stone (dry olive pomace) powder.
  • the olive stone material is added to a thermoplastic material and used in the production of the polymeric composite of the present invention in particular for satisfying the need for materials with high mechanical strength and providing alternatives for wooden-like parts.
  • the polypropylene matrix with the addition of the olive stone powder and maleic anhydride-grafted polypropylene (MA-g-PP), the lightness advantage of the thermoplastic material is maintained while the values of Young modulus, E modulus and bend strength are significantly improved.
  • white goods comprising recycled, environmentally-friendly polymer composite with improved mechanical properties and suitable for industrial use can be produced.
  • waste olive stone (dry olive pomace) powder is used in plastics, thus producing environmentally-friendly plastic composites.
  • waste materials are used in an innovative manner and environmentally-friendly plastic composites having fewer petroleum-based raw materials are produced.
  • cost advantage is provided by using dry olive pomace, which is very cheaper than polypropylene, in plastic composites.
  • the added powder olive pomace gives the plastics a wooden-like appearance.
  • the material can be used as a decorative component in plastic parts which are desired to have wooden-like appearance.
  • the polymeric composite comprises maleic anhydride-grafted polypropylene (MA-g-PP) as compatibilizer.
  • the polymeric composite comprises 56-86% thermoplastic material, 1.5% desiccant granules, 2.5% maleic anhydride-grafted polypropylene (MA-g-PP) and 10-40% olive stone (dry olive pomace) powder, and, optionally, mineral additive and/or fibrous additive.
  • the polymer composite production method of the present invention comprises the steps of
  • the polymeric composite of the present invention By using the olive stone powder in the polymeric composite of the present invention, the lightness of the polypropylene material is maintained while the rigidness thereof is increased, moreover providing cost advantage. Furthermore, the amount of petroleum-based raw materials used is minimized, the waste olive stones are made use of in the product, and environmentally-friendly polymeric composites with improved mechanical properties are obtained.
  • the polymeric composite of the present invention can be used in decorative parts designed with a wooden-like appearance. With the hydrophobic properties, chemical strength, high elasticity and mechanical properties of the polypropylene, said polymeric composite gains improved properties with respect to wood as well as having a wooden-like appearance.
  • the polymer composite of the present invention is used in white goods.
  • the polymer composite of the present invention is used in a laundry washing machine.
  • the polymer composite of the present invention is used in a laundry drying machine.
  • the polymer composite of the present invention is used in a dishwasher.
  • the polymer composite of the present invention is used in electrical home appliances.
  • the polymer composite of the present invention is used in an air conditioner.
  • the polymer composite of the present invention is used in a refrigerator.
  • the polymer composite of the present invention is used in a hair dryer.
  • the polymer composite of the present invention is used in a curling iron.
  • the polymer composite of the present invention is used in a hair straightener.
  • the polymer composite of the present invention is used in a water purifier.
  • the polymer composite of the present invention is used in a coffee/tea machine.
  • the polymer composite of the present invention is used in an oven.
  • the polymer composite of the present invention is used in a cooker.
  • the polymer composite of the present invention is used in an air purifier.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

La présente invention concerne un composite polymère produit pour être utilisé dans des produits blancs et son procédé de production.
PCT/EP2019/073032 2018-09-26 2019-08-29 Composite polymère Ceased WO2020064256A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2018/13944 2018-09-26
TR201813944 2018-09-26

Publications (1)

Publication Number Publication Date
WO2020064256A1 true WO2020064256A1 (fr) 2020-04-02

Family

ID=67841050

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2019/073032 Ceased WO2020064256A1 (fr) 2018-09-26 2019-08-29 Composite polymère

Country Status (1)

Country Link
WO (1) WO2020064256A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022071800A1 (fr) * 2020-09-30 2022-04-07 Coda Intellectual Property B.V. Composite polymère comprenant de la drêche et/ou du marc de raisin
NL2026597B1 (en) * 2020-09-30 2022-05-30 Coda Intellectual Property B V Polymer composite comprising pomace

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002014432A1 (fr) 2000-08-16 2002-02-21 REHAU SA (Société Anonyme) Piece en matiere thermoplastique chargee de farine de noyaux de fruits et procede d'obtention d'une telle piece
CN102492198A (zh) 2011-11-18 2012-06-13 河南工业大学 一种聚烯烃环境友好复合材料的制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002014432A1 (fr) 2000-08-16 2002-02-21 REHAU SA (Société Anonyme) Piece en matiere thermoplastique chargee de farine de noyaux de fruits et procede d'obtention d'une telle piece
CN102492198A (zh) 2011-11-18 2012-06-13 河南工业大学 一种聚烯烃环境友好复合材料的制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NADIR AYRILMIS ET AL: "Utilization of olive mill sludge in manufacture of lignocellulosic/polypropylene composite", JOURNAL OF MATERIALS SCIENCE, KLUWER ACADEMIC PUBLISHERS, BO, vol. 45, no. 5, 9 December 2009 (2009-12-09), pages 1336 - 1342, XP019770495, ISSN: 1573-4803 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022071800A1 (fr) * 2020-09-30 2022-04-07 Coda Intellectual Property B.V. Composite polymère comprenant de la drêche et/ou du marc de raisin
NL2026597B1 (en) * 2020-09-30 2022-05-30 Coda Intellectual Property B V Polymer composite comprising pomace

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