WO2020120800A1 - Remplissage de gazon synthétique et gazon synthétique - Google Patents

Remplissage de gazon synthétique et gazon synthétique Download PDF

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Publication number
WO2020120800A1
WO2020120800A1 PCT/EP2019/085384 EP2019085384W WO2020120800A1 WO 2020120800 A1 WO2020120800 A1 WO 2020120800A1 EP 2019085384 W EP2019085384 W EP 2019085384W WO 2020120800 A1 WO2020120800 A1 WO 2020120800A1
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WIPO (PCT)
Prior art keywords
artificial turf
microporous zeolite
zeolite mineral
polyurethane coating
pores
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Ceased
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PCT/EP2019/085384
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English (en)
Inventor
Stephan Sick
Zdenka Finder
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Polytex Sportbelage Produktions GmbH
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Polytex Sportbelage Produktions GmbH
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Filing date
Publication date
Priority claimed from EP18212778.7A external-priority patent/EP3666975A1/fr
Priority claimed from EP18212783.7A external-priority patent/EP3666976B1/fr
Application filed by Polytex Sportbelage Produktions GmbH filed Critical Polytex Sportbelage Produktions GmbH
Publication of WO2020120800A1 publication Critical patent/WO2020120800A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C13/00—Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
    • E01C13/08—Surfaces simulating grass ; Grass-grown sports grounds

Definitions

  • the invention relates to artificial turf infill and an artificial turf.
  • Artificial turf or artificial grass is a surface that is made up of fibers and is used to replace grass.
  • the structure of the artificial turf is designed such that the artificial turf has an appearance that resembles grass.
  • Artificial turf is typically used as a surface for sports such as soccer, American football, rugby, tennis and golf, or for playing fields or exercise fields. Furthermore, artificial turf is frequently used for landscaping applications.
  • Artificial turf may be manufactured using techniques for manufacturing carpets. For example, artificial turf fibers, which have the appearance of grass blades, may be tufted or attached to a backing. Oftentimes, artificial turf infill is placed between the artificial turf fibers.
  • Artificial turf infill is a granular material that covers the bottom portion of the artificial turf fibers.
  • the use of artificial turf infill may have a number of advantages. For example, artificial turf infill may help the artificial turf fibers stand up straight. Artificial turf infill may also absorb impact from walking or running and provide an experience similar to that of being on real turf. The artificial turf infill may also help keep the artificial turf carpet flat and in place by weighing it down.
  • US 10,066,345 B2 discloses an artificial turf field system comprising a plurality of turf strands attached to a backing layer and an infill material positioned between the synthetic turf strands.
  • the infill material includes a plurality of porous particles, wherein at least a portion of the porous particles have a partial polymer coating thereon and wherein the porous particles have varying amounts of their outer surface covered by the coating. Since the porous particles disclosed in US 10,066,345 B2 show good water retention and the particles are partially covered, the porous particles are beneficial in inclement weather and the wear of the porous particles is reduced due to the partial cover.
  • US 10,066,345 B2 further discloses that this polymer cover is applied to the porous particles by, for example, atomization of the polymer and spraying of the polymer onto the particles as the particles are moving or falling. Hence, the particles are partially covered on one side with the polymer. The cover completely covers the pores of the porous particles in the area of the cover.
  • the invention provides for an improved artificial turf and artificial turf infill.
  • the problem is solved by the features as specified in the independent claims.
  • Embodiments of the invention are given in the dependent claims.
  • the embodiments and examples described herein can freely be combined with each other unless they are mutually exclusive.
  • the problem is solved by providing a microporous zeolite mineral particle, the microporous zeolite mineral particle having pores that form openings on the outer surface of the microporous zeolite mineral particle, wherein the outer surface of the microporous zeolite mineral particle is partly coated with a polyurethane coating, wherein the coating extends for a distance into some of the pores, forming reinforcements, the reinforcements forming openings that provide a passage for sorbing (absorbing and adsorbing) water into the pores and/or desorbing water from the pores.
  • microporous zeolite mineral particles can be used as artificial turf infill and may have advantageous effects.
  • the mechanical resistance of the particles is increased by the coating while extending the cooling effect on the artificial turf due to the reduced water desorption rate from the particles.
  • the slower desorption is due to the narrowing of some of the openings of the particles.
  • the invention relates to an artificial turf, comprising an artificial turf carpet, wherein the artificial turf carpet comprises multiple artificial turf fiber tufts and an artificial turf infill.
  • the artificial turf may have a pile height between 2.5 cm and 7.5 cm. The pile height is the length of the artificial turf fibers above the backing or base of the artificial turf carpet.
  • the artificial turf fiber tufts may be arranged in rows and may have a row spacing of between 0.5 cm and 1.95 cm.
  • the artificial turf further comprises granular artificial turf infill spread between the multiple artificial turf fiber tufts.
  • the artificial turf infill material may provide support for the artificial turf grass fibers and may have a thickness of about 5 mm to 60 mm.
  • the artificial turf infill is scattered or brushed between the multiple artificial turf fiber tufts. It is within the scope of the invention that the artificial turf infill comprises a plurality of microporous zeolite mineral particles, wherein the outer surface of at least some of the microporous zeolite mineral particles is partly coated with a polyurethane coating.
  • the outer surface of at least some of the microporous zeolite mineral particles is partly coated with a polyurethane coating, wherein the coating extends over some of the pores forming respective covers of the openings and wherein the polyurethane coating coats a portion of the inner surface of the covered pores in the region of the cover.
  • each of the partly coated microporous zeolite mineral particles have approximately the same amount of their outer surface coated by the coating relative to the total outer surface, or, in other words, that the polyurethane coating extends over the entire surface of each partly coated microporous zeolite mineral particle with a uniform coverage ratio, the coverage ratio being between 20% and 99%.
  • the microporous zeolite mineral particles may be partly coated with a polyurethane coating, wherein the coating extends for a distance into some of the pores forming reinforcements, the reinforcements forming openings that provide a passage for sorbing water into the pores or desorbing water from the pores.
  • each of the partly coated microporous zeolite mineral particles have approximately the same amount of their outer surface coated by the coating relative to the total outer surface, or, in other words, that the polyurethane coating extends over the entire surface of each partly coated microporous zeolite mineral particle with a uniform coverage ratio, the coverage ratio being between 20% and 99%.
  • zeolite mineral refers to a group of more than 60 soft, white aluminosilicate minerals of tectosilicate type - a three-dimensional framework of interconnected tetrahedra, comprising to a large extent aluminum, silicon and oxygen atoms. Zeolite minerals have a crystalline structure built from [AIO4] 5 and [SiC ] 4 bonded together in such a way that all four oxygen atoms, located at the corners of each tetrahedron, are shared with adjacent tetrahedral crystals.
  • zeolites can be described as Me2/ n 0 Al203 xSi02 yH 2 0, whereby Me is any alkaline or alkaline earth atom, n is the charge on that atom, x is the number of Si tetrahedrons (varying from 2 to 10), and y is the number of water molecules, typically between 2 and 7.
  • Examples of natural zeolites include chabazite, erionite, mordenite, clinoptilolite, phillipsite and stilbite.
  • Preferred zeolites according to the invention may include chabazite, erionite, mordenite, clinoptilolite, phillipsite and stilbite, and may be obtained by mining due to their abundance in nature, resulting in lower production costs compared with the same amount of synthetic zeolites, such as faujasite, zeolite A, zeolite L, zeolite Y, zeolite X and ZSM-5. Synthetic zeolite minerals may also be used instead of or in addition to natural zeolites.
  • microporous zeolite mineral particle refers to porous zeolite mineral particles such as those disclosed above, which are able to absorb and adsorb (also referred to as sorption) water, which can be reversibly released from the microporous zeolite mineral particles.
  • microporous zeolite mineral particles are distributed between the artificial turf fiber tufts, water may be taken up by the microporous zeolite mineral particles and stored within the microporous zeolite mineral particles in an enhanced matter, compared to known commonly used infill materials, such as rubber granules. In addition, seeping of water into the deeper layers of the sports flooring, from where it is not recoverable, may be reduced.
  • microporous zeolite mineral particles have pores that form openings on the outer surface of the microporous zeolite mineral particles.
  • the use of the microporous zeolite mineral as an infill material is advantageous, as the particles are able to regulate the presence of water and may thus provide for a cooling effect of the surface of the artificial turf. Hence, an increased playing comfort can be reached when the outside temperatures are high.
  • the invention relates to an artificial turf infill, wherein the artificial turf infill comprises a plurality of microporous zeolite mineral particles.
  • the microporous zeolite mineral particles comprise pores that form openings on the outer surface of the microporous zeolite mineral particles. It is within the scope of the invention that the outer surface of at least some of the microporous zeolite mineral particles is partly coated with a polyurethane coating, wherein the coating extends over some of the pores forming respective covers of the openings and wherein the polyurethane coating coats a portion of the inner surface of the covered pores in the region of the cover.
  • the invention relates to an artificial turf infill, wherein the artificial turf infill comprises a plurality of microporous zeolite mineral particles.
  • the microporous zeolite mineral particles comprise pores that form openings on the outer surface of the microporous zeolite mineral particles.
  • the outer surface of at least some of the microporous zeolite mineral particles is partly coated with a polyurethane coating, wherein the coating extends for a distance into some of the pores forming reinforcements, with the reinforcements forming openings that provide a passage for sorbing water into the pores or desorbing water from the pores.
  • each of the partly coated microporous zeolite mineral particles have approximately the same amount of their outer surface coated by the coating relative to the total outer surface, or, in other words, that the polyurethane coating extends over the entire surface of each partly coated microporous zeolite mineral particle with a uniform coverage ratio, the coverage ratio being between 20% and 99%.
  • the partial covering is applied on each side of each microporous zeolite mineral particle, but that there are gaps (holes) in the covering enclosing the particles.
  • the partial coating is advantageous, since water can be absorbed and/or released by the microporous zeolite mineral particles through the pores contained in its surface areas, which are not covered by the polyurethane coating.
  • the polyurethane coating may be advantageous, as the polymerization reaction may be controlled given that the polyurethane educts are smaller than those of many fully polymerized polymers, such as polymers in a molten plastic mass.
  • the surface and the micropores of the microporous zeolite mineral particles may be wetted with the educts (e.g., with a liquid polyurethane reaction mixture), and when the desired degree of wetting or the desired penetration depth into the surface pores is achieved, the polymerization can be initialized. Further, the reacted polyurethane polymer is chemically inert.
  • the microporous zeolite mineral particles are partly coated with the polyurethane coating, natural occurrence of abrasion and wear of the microporous zeolite mineral during use may be reduced, since the polyurethane coating may provide for a harder and thus protective surface compared to uncoated microporous zeolite mineral particles. It may also be advantageous that the Mohs hardness of the polyurethane coating may be chosen to be higher or much higher than the Mohs hardness of the microporous zeolite mineral particles. It may be thus beneficial that the Mohs hardness of the polyurethane coating is at least one Mohs unit higher than the Mohs hardness of the selected microporous zeolite mineral particles.
  • the gaps in the coating of the inventive infill material may result during the manufacture of the infill material, since during the mixing, e.g., in a flow reactor or a batch reactor or a tumbler, the microporous zeolite mineral particles and a liquid polyurethane reaction mixture are mixed and while they are being mixed a solidification reaction is initiated. During the mixing and while the solidification takes place, the microporous zeolite mineral particles physically touch and interact with each other, thereby causing collision defects such as gaps in the coating and partly leaving the surface of the microporous zeolite particles uncovered. Thus, water may still be absorbed and released by the microporous zeolite mineral particles in those areas in which the pores of the microporous zeolite minerals are not covered by the polyurethane coating.
  • the polyurethane coating extends over some of the pores forming respective covers of the pore openings, wherein the polyurethane coating coats a portion of the inner surface of the covered pores in the region of the cover.
  • the coating may penetrate a slight distance, for example between 0.2 pm and 500 pm, preferably between 1 pm and 150 pm and preferably between 10 pm and 100 pm, into the surface pores, and thus may either interfere with the pores in a form-locking manner or form reinforcements in the pores, with the reinforcements forming openings that provide a passage for sorbing water into the pores or desorbing water from the pores.
  • the hold of the coating on the microporous zeolite mineral particles may be increased and at the same time the overall stability and hardness of the microporous zeolite mineral particles may be increased.
  • the infill material of both alternatives is preferably produced by mixing the microporous zeolite mineral particles with a liquid polyurethane reaction mixture and initializing the solidification reaction during the mixing, the polyurethane coating extends over the entire surface of each partly coated microporous zeolite mineral particle with a uniform coverage ratio.
  • the microporous zeolite mineral particles have substantially the same amount of their outer surface covered by the coating relative to the total outer surface. Substantially the same amount means that the outer surface of each of the partly coated microporous zeolite mineral particles is coated between 20% and 99% with the polyurethane coating.
  • the coverage ratio of the polyurethane coating of each of the partly coated microporous zeolite mineral particles is between 50% and 98% or between 70% and 99%. With increased coverage ratio, the overall stability and hardness of the microporous zeolite mineral particles may be further increased. Further, since the outer surface of each of the partly coated microporous zeolite mineral particles may be - with the exception of the gaps or the openings in the reinforced pores - essentially fully coated, fine dusts may be bound.
  • the microporous zeolite mineral particle is selected from the group consisting of chabazite, erionite, mordenite, clinoptilolite, faujasite, phillipsite, zeolite A, zeolite L, zeolite Y, zeolite X and ZSM-5.
  • the zeolite used within the scope of the invention may thus be a zeolite that can be natural or obtained by synthesis.
  • a microporous zeolite with a Mohs hardness above 3 and/or a strong absorbent power and/or a color that approximately resembles one of the well- known surface colors (e.g., red, brown, green), may preferably be used.
  • the most preferred microporous zeolite mineral may be of the chabazite and/or clinoptinolite and/or mordenite type.
  • the specific surface area of the microporous zeolite mineral particle can be chosen to be smaller than a predetermined maximum specific surface area.
  • the maximum specific surface area of the mineral may, for example, be determined as the surface specific area that enables the water in the mineral to release, under a certain ambient temperature, at a predefined minimum rate.
  • the granular artificial turf infill of both alternative artificial turf infills may further comprise rubber granules and/or cork granules, which may be coated with a polyurethane coating.
  • microporous zeolite mineral particles may be charged with salt ions in order to allow for an increased water adsorption and/or water desorption effect.
  • microporous zeolite mineral particles allows a synergy to operate between the following properties: the adsorption, absorption and release of water of the microporous zeolite mineral particle, and the ability to lower the freezing temperature of the water.
  • the microporous mineral particle in a position to adsorb and/or absorb this humidity in order to prevent, on the one hand, a surface formation of a layer of slippery frost, in the case of a negative temperature, and on the other hand, an agglomeration of the artificial turf infills.
  • the microporous mineral particle loaded with salt and water, may allow a further increased release of the water and the maintenance of relative humidity at the surface of said turf.
  • the microporous mineral particle loaded with salt adsorbs and/or absorbs the water and then continuously releases those water molecules by desorption. This continuous release of the water by the microporous mineral particles prevents rapid evaporation of the water after the surface is watered, and allows a lower than ambient temperature to be maintained at the level of the field surface.
  • microporous mineral particles loaded with salt thus further allow the amount of watering usually necessary to refresh a turf surface to be reduced. It can also be within the present invention that the grain size of the microporous zeolite minerals is between 0.03 mm and 8.0 mm.
  • the layer thickness of the polyurethane coating is between 0.001 mm and 2.0 mm.
  • the polyurethane coating of the artificial turf infill comprises at least one further component selected from the group consisting of sand, colored sand, chalk, lime, colored pigments, copper(ll) sulfate particles, flame retardants, U.V. absorbers and fillers.
  • Adding one or more of these further components to the polyurethane coating of the artificial turf infill may be beneficial in several different situations.
  • the colored pigments may be infrared-reflective pigments, which are beneficial due to their ability to reflect infrared light. This may further reduce the heating of the artificial turf infill. Further, as the infrared-reflective colored pigments may be contained solely in the partially applied polyurethane coating, the cost of the comparably expensive and precious pigments, since they are merely on the partly covered surface of the zeolite minerals, is reduced from that of fully coated infill materials.
  • the colored pigments may be copper(ll) sulfate particles, chromium oxide particles or iron oxide particles.
  • Copper(ll) sulfate particles and/or or iron oxide particles and/or chromium oxide particles may be beneficial due to their color, relatively low manufacturing costs and/or antibacterial properties.
  • Other antibacterial components that may be used are silver and/or chitosan particles, which both have natural antibacterial properties.
  • Sand, colored sand, chalk or lime can be beneficial since they are relatively cheap starting materials and they are naturally earth-colored.
  • sand, colored sand, chalk or lime can be beneficial due to their ability to increase the viscosity of the polyurethane coating during the coating process.
  • the coating which may be based on a liquid polyurethane reaction mixture, may thus solidify into the polyurethane coating while covering the microporous zeolite mineral particles. High viscosity of the polyurethane coating may largely prevent too- deep of penetration of the polyurethane coating into the surface pores of the microporous minerals.
  • the color of the artificial turf infill is identical or similar to the color of the fibers or tufts that are used to manufacture an artificial turf carpet. This may provide a more realistic-looking playing surface or field.
  • the zeolite mineral particles which are usually softer than conventionally used artificial turf infill materials, may be strengthened by the polyurethane coating with added further components and may therefore have superior wear qualities or increased weight, or may be better protected from environmental influences such as rain, acid rain and wind.
  • Fillers may be beneficial, as they may increase the weight of the coating and thus the overall weight of the artificial turf infill.
  • the used fillers may be selected from the group consisting of barium sulphate (barite), calcium carbonate (chalk), china clay (kaolin) and cold fly ash.
  • the coating may comprise between 0.1 wt.% and 80 wt.% of fillers.
  • the polyurethane coating of the artificial turf infill comprises fillers, in particular barium sulphate (barite) and/or calcium carbonate (chalk), to increase the total weight of the artificial turf infill.
  • fillers in particular barium sulphate (barite) and/or calcium carbonate (chalk)
  • Barium sulphate and calcium carbonate may be particularly advantageous, as they have a high density; calcium carbonate has a density of 2.7 g/cm 3 and barium sulphate has a density of between 4.0 and 4.5 g/cm 3 . They are also relatively cheap materials and may be used to provide a dense coating.
  • the coating may comprise between 0.1 wt.% and 80 wt.%, preferably between 20 wt.% and 50 wt.%, of barium sulfate as filler, or between 0.1 wt.% and 65 wt.%, preferably between 20 wt.% and 40 wt.%, of calcium carbonate as filler.
  • the increase in total weight of the artificial turf infill may provide the advantage that the artificial turf infill may be better protected from being washed away by rain or wind.
  • the polyurethane coating of the artificial turf infill comprises a rheology additive that is adapted to induce a thixotropic flow behavior in a liquid polyurethane reaction mixture, which may be used as a basis of the coating.
  • Adding a rheology additive with thixotropic capabilities may be advantageous in order to achieve a controllable viscosity-increasing thixotropic flow behavior (i.e. , liquid or fluid) of a polyurethane coating while applying it (e.g., by mixing the liquid polyurethane reaction mixture with the microporous zeolite mineral particles) to the surface of the microporous zeolite mineral particles in order to control or reduce the depth of penetration of the liquid polyurethane reaction mixture into the pores contained in the surfaces of the microporous zeolite mineral particles.
  • a controllable viscosity-increasing thixotropic flow behavior i.e. , liquid or fluid
  • Suitable rheology additives are fumed silica (e.g., synthetic, hydrophobic,
  • amorphous silica also known as pyrogenic silica, made from flame pyrolysis of silicon tetrachloride or from quartz sand vaporized in a 3000° C electric arc, hydrophobic fumed silica, bentonite, acrylates or a combination of the
  • the polyurethane coating of the artificial turf infill is based on a liquid polyurethane reaction mixture, which may be a dispersion or solution, comprising
  • hydroxyl component wherein the hydroxyl component is selected from the group of polyether polyol or polyester polyol;
  • At least one catalyst selected from the group consisting of linear or cyclic tertiary amines such as triethylenediamine, or e.g.,1 ,4- Diazabicyclo[2.2.2]octane; cyclic amines such as 1 ,8- Diazabicyclo(5.4.0)undec-7-ene (DBU); and inorganic compounds such as sodium hydroxide (NaOH), chromium(lll) oxide (Cr 2 03) and zinc oxide (ZnO).
  • linear or cyclic tertiary amines such as triethylenediamine, or e.g.,1 ,4- Diazabicyclo[2.2.2]octane
  • cyclic amines such as 1 ,8- Diazabicyclo(5.4.0)undec-7-ene (DBU)
  • inorganic compounds such as sodium hydroxide (NaOH), chromium(lll) oxide (Cr 2 03) and zinc oxide (ZnO
  • liquid polyurethane reaction mixture may be advantageous, because it is a reaction mixture that can be solidified or cured (e.g., by cross-linking) under heat and/or by adding water. Therefore, the zeolite mineral particles and the liquid polyurethane reaction mixture may be mixed and solidified simultaneously in a batch reactor, a continuous reactor or a tumbler, resulting in the partial polyurethane coating as described above for both alternatives or the coating with gaps. Further, the resulting polyurethane coating may be a waterborne polyurethane coating.
  • the polyurethane coating of the artificial turf infill is based on a liquid polyurethane reaction mixture comprising
  • NCO-terminal polymer one or more components selected from a pre polymer, a polymeric isocyanate, an oligomeric isocyanate or a monomer, such as
  • aromatic diisocyanate of the group of toluene diisocyanate and/or methylene-2, 2-diisocyanate;
  • liquid polyurethane reaction mixture may be advantageous, because it is a reaction mixture that can be solidified or cured (e.g., by cross-linking) by adding a catalyst, such as a secondary amine catalyst or a tertiary amine catalyst, such as triethylenediamine, or e.g., 1 ,4- Diazabicyclo[2.2.2]octane, cyclic amines such as 1 ,8-Diazabicyclo(5.4.0)undec-7- ene (DBU) or a metal organic catalyst, and water. Therefore, the zeolite mineral particles and the liquid polyurethane reaction mixture may be mixed and solidified simultaneously in a controlled manner in a batch or continuous reactor, resulting in the partial polyurethane coating as described above for both alternatives or the coating with gaps.
  • a catalyst such as a secondary amine catalyst or a tertiary amine catalyst, such as triethylenediamine, or e.g., 1 ,4- Diazabicyclo[
  • the polyurethane coating is a reaction product of a liquid polyurethane reaction mixture comprising
  • DBU 1,8-diazabicyclo(5.4.0)undec-7-ene
  • the NCO-terminal prepolymer of this embodiment may be an NCO-terminal isocyanic prepolymer, which is a (oligomeric) urethane having at least one free isocyanate group, and which may be obtained by reacting polyisocyanates with polyols.
  • the NCO-terminal prepolymer of this embodiment may have an NCO content of 5.5% to 11.5%, preferably an NCO content of 6.5% to 10.5% or, most preferred, an NCO content of 8.0% to 9.0%.
  • the NCO-terminal prepolymer of this embodiment may have a curing time in air of 35 hours to 45 hours.
  • a suitable prepolymer is known under the trade name P2440 (Polytex Sportbelage styles GmbH).
  • the prepolymer may be mixed with the microporous zeolite particles in a batch or continuous reactor and the solidification reaction may be initialized (during the mixing) by adding water and/or a catalyst.
  • the prepolymer may be advantageously used for a moisture-curing 1 K system, in which the reaction
  • DBU diazabicyclo(5.4.0)undec-7-ene
  • the curing rate of the polyurethane formation may be controlled by the addition of the DBU water mixture, time and temperature, so that, for example, the polyurethane coating may only penetrate the pores to a certain depth or the curing takes place very quickly.
  • curing may also be achieved such that the individual coated zeolite particles do not stick to each other.
  • the optional further component may provide further advantages.
  • the colored pigments may be copper(ll) sulfate particles and/or iron oxide particles and/or chromium oxide particles. Which colored particles are used depends on the desired color.
  • the filler in this embodiment may be calcium carbonate and/or china clay.
  • the rheology additive in this embodiment may be fumed silica and/or bentonite. The advantages of adding color pigments and copper(ll) sulfate to the polyurethane coating are described above.
  • a hindered amine light stabilizer As a U.V. absorber, a hindered amine light stabilizer (HALS), which is able to protect the polyurethane coating against U.V. degradation, may be used.
  • HALS hindered amine light stabilizer
  • This embodiment may further comprise a thermo-stabilizing agent, protecting the polyurethane coating against thermal degradation.
  • Fig. 1 illustrates an example of an artificial turf carpet
  • Fig. 2 illustrates an example of artificial turf
  • Fig. 3 illustrates a sectional view of a microporous zeolite mineral
  • Fig. 4 illustrates a section of the sectional view of Fig. 3;
  • Fig. 5 illustrates a sectional view of a microporous zeolite mineral particle, which is partly coated with a polyurethane coating
  • Fig. 6 illustrates a section of the sectional view of Fig. 5, in which the
  • polyurethane coating comprises a further component and a rheology additive
  • Fig. 7 illustrates a further section of the sectional view of Fig. 6;
  • Fig. 8 illustrates an artificial turf infill
  • Fig. 9 illustrates a sectional view of a partly coated microporous zeolite mineral particle, the coating of which extends for a distance into a pore and forms a reinforcement.
  • Figs. 1 and 2 illustrate the manufacture of an artificial turf 600 using an artificial turf carpet 500 and artificial turf infill 10.
  • an artificial turf carpet 500 is shown.
  • the artificial turf carpet 500 contains a backing 502.
  • the artificial turf carpet 500 shown in Fig. 1 is a tufted artificial turf carpet.
  • the artificial turf carpet is formed by artificial turf fiber tufts 504 that are tufted into the backing 502.
  • the artificial turf fiber tufts 504 are tufted in rows. There is row spacing 506 between adjacent rows of tufts.
  • the artificial turf fiber tufts 504 also extend a distance above the backing 502. The distance that the fibers 504 extend above the backing 502 is the pile height 508.
  • the artificial turf carpet 500 has been installed by placing or attaching it to the ground 510 or to a floor.
  • the artificial turf infill is made with partially polyurethane-coated zeolite mineral particles such as those shown in Figs. 5 and 6 and is spread out on the surface and distributed between the artificial turf fiber tufts 504.
  • Fig. 2 shows the artificial turf carpet 500 after the artificial turf infill 10 has been spread out and distributed between the artificial turf fiber tufts 504. It can be seen that the artificial turf infill 10 is a granulate made up of individual grains 100 or granules, such as is depicted in Figs. 3 and 5.
  • Fig. 3 shows a schematic sectional view of a microporous zeolite mineral particle 110, whose surface contains pores (indicated by the dots).
  • the microporous zeolite mineral 110 could be of the chabazite, erionite, mordenite or clinoptilolite type.
  • a dotted circle is indicated, the schematic content of which is enlarged in Fig. 4.
  • the surface of the microporous zeolite mineral particle 110 contains pores 111 , through which water may be absorbed and adsorbed and through which water can be reversibly released.
  • Fig. 5 shows the same microporous zeolite mineral particle after it has been partially coated with a polyurethane coating 120 and may thus be used as an infill material 10. As can be seen, at least some parts of the surface of the coated microporous zeolite mineral particle 110 are not covered by the polyurethane coating. In Fig. 5, a dotted circle is also indicated, the schematic content of which is enlarged in Fig. 6.
  • the microporous zeolite mineral particle 110 which contains pores 111 , has been partially coated with a
  • the polyurethane coating 120 was formed by providing microporous zeolite mineral particles 110 and a liquid polyurethane reaction mixture in a batch reactor, tumbler or continuous reactor. Simultaneous mixing and initialization of the solidification reaction lead to the desired partial coating of the polyurethane coating 120 on the surface of the microporous zeolite mineral particle 110.
  • the partial coating results from microporous zeolite mineral particles 110 colliding while being mixed with the initialized liquid polyurethane reaction mixture. Since the initialization of the solidification reaction takes place simultaneously, uncovered spaces (e.g., gaps or holes) created by collisions, remain on the surface of the microporous zeolite mineral particles and thus the artificial turf infill 10.
  • the polyurethane coating 120 coats a portion of the inner surface of the microporous zeolite mineral particle 110 in the region of the cover.
  • the coating 120 may penetrate a slight distance, for example between 0.2 pm and 500 pm, preferably between 1 pm and 150 pm and most preferred between 10 pm and 100 pm, into the surface pores 111 and thus may interfere with the pores 111 in a form-locking manner; this will increase the hold of the coating on the microporous zeolite mineral particle 110, and at the same time the overall stability and hardness of the microporous zeolite mineral particle 110 may be increased.
  • the infill material 10 is preferably produced by mixing the microporous zeolite mineral particles with a liquid polyurethane reaction mixture (here comprising 0.1 wt.% to 80 wt.% of an NCO-terminal prepolymer and optionally at least one further component selected from the group consisting of 0.001 wt.% to 30.0 wt.% colored pigments, 0.001 wt.% to 3.0 wt.% copper(ll) sulfate, 0.05 wt.% to 60 wt.% flame retardants, 0.01 wt.% to 1.0 wt.% U.V.
  • a liquid polyurethane reaction mixture here comprising 0.1 wt.% to 80 wt.% of an NCO-terminal prepolymer and optionally at least one further component selected from the group consisting of 0.001 wt.% to 30.0 wt.% colored pigments, 0.001 wt.% to 3.0 wt.% copper(ll)
  • the microporous zeolite mineral particles have substantially the same amount of their outer surface covered by the coating relative to the total outer surface.
  • the same amount means that the outer surface of each microporous zeolite mineral particle is covered between 20% and 99%, preferably between 50% and 98% or between 70% and 99%, with the polyurethane coating 120. Since the outer surface of each microporous zeolite mineral particle 110 is, with the exception of the gaps, essentially fully coated, fine dusts may be bound.
  • the polyurethane coating 120 of this artificial turf infill granule contains a further component 121.
  • the further component 121 may be, for example, sand and/or colored sand and/or chalk and/or lime. With the addition of sand and/or colored sand and/or chalk and/or lime to the liquid
  • the viscosity of the liquid polyurethane reaction mixture can be increased.
  • some portions of the surfaces of the microporous zeolite mineral particles remain open upon application of the
  • the polyurethane coating 120 of this artificial turf infill may comprise a rheology additive 122.
  • the purpose of the rheology additive may be to achieve thixotropic flow behavior of the liquid polyurethane reaction mixture during mixing of the liquid polyurethane reaction mixture with the microporous zeolite mineral particle 110.
  • the viscosity of the liquid polyurethane reaction mixture is controllable via the addition of the rheology additive, and thus the depth of penetration of the liquid polyurethane reaction mixture into the pores 111 contained in the surfaces of the microporous zeolite mineral particles 110 can be controlled. As seen in Fig.
  • the polyurethane coating is mainly solidified or cured on the outer surface of the microporous zeolite mineral particles 110, but the polyurethane coating 120 also coats a portion of the inner surface of the pores 111 in the region of the cover.
  • the coating 120 may penetrate a slight distance, for example between 1 pm and 500 pm, into the surface pores 111 , thereby interfering with the pores 111 in a form-locking manner.
  • the hold of the coating on the microporous zeolite mineral particles 110 may be increased and at the same time the overall stability and hardness of the microporous zeolite mineral particles 110 may be increased.
  • Fig. 7 is an enlarged sectional view of the enlarged sectional view indicated in Fig. 6 by the dotted square
  • the microporous zeolite mineral particle 110 which contains pores 111 , has been partially coated with a
  • the microporous zeolite mineral particles 110 contain pores 111 that have openings on the outer surface of the microporous zeolite mineral particles 110.
  • the outer surface of the microporous zeolite mineral particle 110 is partly coated with a polyurethane coating 120, wherein the coating extends over some of the pores 111 , forming covers (equal to the pore size at the outer surface; indicated by 130) of the openings.
  • the cover 130 covers the pore 111 in the area of the pore opening.
  • the polyurethane coating 120 coats a portion of the inner surface of the covered pores 111 in the region of the cover 130.
  • the polyurethane coating 120 of the inner surface may be in the form of a plug, as indicated in the left covered pore 111 or in the form of a film, as indicated in the right covered pore 111.
  • Fig. 8 depicts an inventive artificial turf infill granule 10 (i.e., partly coated
  • microporous zeolite mineral particles 110 The microporous zeolite mineral particle 110 has pores 111 that form openings on the outer surface of the microporous zeolite mineral particles 110. As shown, the outer surface of the microporous zeolite mineral particles 110 is partly coated with a polyurethane coating 120, wherein the coating extends over most of the pores 111 , thereby forming covers over the openings.
  • the polyurethane coating 120 was formed by providing a plurality of microporous zeolite mineral particles 110 and a liquid polyurethane reaction mixture in a batch reactor, tumbler or continuous reactor.
  • Simultaneous mixing and initialization of the solidification reaction lead to the desired partial coating of the polyurethane coating 120 on the surface of the microporous zeolite mineral particles 110.
  • the partial coating results from collisions of microporous zeolite mineral particles 110 while being mixed with the initialized liquid polyurethane reaction mixture. Since the initialization of the solidification reaction takes place
  • uncovered spaces e.g., gaps or holes
  • the artificial turf infill 10 granule As indicated in Fig. 8, it may be possible that 75% to 99% of the outer surface of the microporous zeolite mineral particle is partly covered with a polyurethane coating 120.
  • microporous zeolite mineral particle 110 which contains pores 111 , has been partially coated with a
  • the polyurethane coating 120 was formed by providing microporous zeolite mineral particles 110 and a liquid polyurethane reaction mixture in a batch reactor, tumbler or continuous reactor. Simultaneous mixing and initialization of the solidification reaction lead to the desired partial coating of the polyurethane coating 120 on the surface of the microporous zeolite mineral particle 110. The partial coating results from microporous zeolite mineral particles 110 colliding while being mixed with the initialized liquid polyurethane reaction mixture and from controlling the polymerization reaction.
  • the polyurethane coating 120 extends for a distance into the pore 111 , forming a reinforcement 140, with the reinforcement 140 forming an opening 150 that provides a passage for sorbing water into the pore 111 or desorbing water from the pore 111.
  • the coating 120 may penetrate with a slight distance, for example between 0.2 pm and 500 pm, preferably between 1 pm and 150 pm and most preferred between 10 pm and 100 pm, into the surface pores 111 , and thus may interfere with the pores 111 in a form-locking manner. This may increase the hold of the coating on the microporous zeolite mineral particle 110, and at the same time the overall stability and hardness of the microporous zeolite mineral particle 110 may be increased.
  • the infill material 10 is preferably produced by mixing the microporous zeolite mineral particles with a liquid polyurethane reaction mixture (here, comprising 0.1 wt.% to 80 wt.% of an NCO-terminal prepolymer and optionally at least one further component selected from the group consisting of 0.001 wt.% to 30.0 wt.% colored pigments, 0.001 wt.% to 3.0 wt.% copper(ll) sulfate, 0.05 wt.% to 60 wt.% flame retardants, 0.01 wt.% to 1.0 wt.% U.V. absorbers, 0.01 wt.% to 60 wt.% filler and 0.01 wt.% to 1.0 wt.% rheology additive) and initializing the group consisting of 0.001 wt.% to 30.0 wt.% colored pigments, 0.001 wt.% to 3.0 wt.% copper(ll) sulf
  • the microporous zeolite mineral particles have substantially the same amount of their outer surface covered by the coating relative to the total outer surface. Substantially the same amount means that the outer surface of each microporous zeolite mineral particle is covered between 20% and 99%, preferably between 50% and 98% or between 70% and 99%, with the polyurethane coating 120.
  • each microporous zeolite mineral particle 110 is, with the exception of the gaps and the reinforcements 140 with the openings 150, essentially fully coated, fine dusts may be bound.
  • the viscosity of the liquid polyurethane reaction mixture may be controlled by an addition of a rheology additive. Therefore the depth of penetration of the liquid polyurethane reaction mixture into the pores 111 contained in the surfaces of the microporous zeolite mineral particles 110 may be controlled.
  • the polyurethane coating is mainly solidified or cured on the outer surface of the microporous zeolite mineral particles 110, but the polyurethane coating 120 also coats a circumferential portion of the inner surface of the pores 111.
  • the coating 120 may penetrate a slight distance, for example between 1 pm and 500 pm, into the surface pores 111 , thereby interfering with the pores 111 in a form-locking manner. This may increase the hold of the coating on the microporous zeolite mineral particles 110, and at the same time the overall stability and hardness of the microporous zeolite mineral particles 110 may be increased.

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Road Paving Structures (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Prostheses (AREA)
  • Materials For Medical Uses (AREA)

Abstract

La présente invention concerne un remplissage de gazon synthétique (10) et un gazon synthétique (600) comportant le remplissage de gazon synthétique (10). Le remplissage de gazon synthétique (10) comporte une pluralité de particules minérales de zéolite microporeuses, les particules ayant des pores qui forment des ouvertures sur la surface extérieure des particules minérales de zéolite microporeuses, la surface extérieure d'au moins une partie des particules minérales de zéolite microporeuses étant partiellement revêtue d'un revêtement de polyuréthane, le revêtement s'étendant sur certains des pores, formant des couvercles respectifs des ouvertures, le revêtement de polyuréthane recouvrant une partie de la surface interne des pores recouverts dans la région du couvercle, et le revêtement de polyuréthane s'étendant sur toute la surface de chaque particule minérale de zéolite microporeuse partiellement revêtue avec un rapport de couverture uniforme, le rapport de couverture étant compris entre 20 % et 99 %.
PCT/EP2019/085384 2018-12-14 2019-12-16 Remplissage de gazon synthétique et gazon synthétique Ceased WO2020120800A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP18212778.7A EP3666975A1 (fr) 2018-12-14 2018-12-14 Gazon artificiel et matériau de remplissage pour gazon artificiel
EP18212783.7A EP3666976B1 (fr) 2018-12-14 2018-12-14 Matériau de remplissage de gazon artificiel et gazon artificiel
EP18212778.7 2018-12-14
EP18212783.7 2018-12-14

Publications (1)

Publication Number Publication Date
WO2020120800A1 true WO2020120800A1 (fr) 2020-06-18

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PCT/EP2019/085384 Ceased WO2020120800A1 (fr) 2018-12-14 2019-12-16 Remplissage de gazon synthétique et gazon synthétique
PCT/EP2019/085381 Ceased WO2020120799A1 (fr) 2018-12-14 2019-12-16 Remplissage de gazon artificiel et gazon artificiel

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EP (1) EP3894632A1 (fr)
AU (2) AU2019398780B2 (fr)
CA (1) CA3118800A1 (fr)
MA (1) MA54444A (fr)
WO (2) WO2020120800A1 (fr)

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EP4053340A4 (fr) * 2019-11-01 2023-12-06 Coool Co., Ltd. Gazon artificiel, charge pour gazon artificiel et procédé de production de gazon artificiel
EP4008432A3 (fr) 2020-11-13 2022-07-27 Pigmentsolution GmbH Granulés de linoléum pour l'usage extérieur
CN112746547A (zh) * 2020-12-08 2021-05-04 江苏联创人造草坪股份有限公司 一种运动型人造草坪及其制备方法
NL2027211B1 (en) * 2020-12-23 2022-07-20 Ten Cate Thiolon Bv Natural artifical turf infill
NL2027212B1 (en) * 2020-12-23 2022-07-20 Ten Cate Thiolon Bv Artifical turf infill with natural rubber granules
EP4334530B1 (fr) * 2021-05-07 2025-04-23 Goe-Ip As Particule de remplissage pour gazon artificiel, procédé de production d'une telle particule de remplissage et utilisation de ladite particule de remplissage
IT202100021329A1 (it) * 2021-08-05 2023-02-05 Adalberto Principi Processo per la realizzazione di materiale riempitivo per manti erbosi sintetici, relativa struttura e composizione
EP4339368A1 (fr) * 2022-09-09 2024-03-20 Polytex Sportbeläge Produktions-GmbH Procédé de fabrication d'un remplissage de gazon artificiel avec des fragments de noyaux d'olive arrondis
WO2026008490A1 (fr) 2024-07-02 2026-01-08 Coderch Negra Maria Luisa Remplissage pour gazon artificiel

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EP2749350A2 (fr) * 2012-12-28 2014-07-02 Benoit Pintat Composition destinée à réguler la présence d'eau sur une surface extérieure
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EP3216821A1 (fr) * 2016-03-11 2017-09-13 Polytex Sportbeläge Produktions-GmbH Remplissage de gazon artificiel
US10066345B2 (en) 2014-04-25 2018-09-04 Profile Products Llc Artificial turf field system

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EP2749350A2 (fr) * 2012-12-28 2014-07-02 Benoit Pintat Composition destinée à réguler la présence d'eau sur une surface extérieure
US10066345B2 (en) 2014-04-25 2018-09-04 Profile Products Llc Artificial turf field system
US20160333535A1 (en) * 2015-05-15 2016-11-17 Bayer Materialscience Llc Free-flowing coated rubber particles, methods for their production and use
EP3216821A1 (fr) * 2016-03-11 2017-09-13 Polytex Sportbeläge Produktions-GmbH Remplissage de gazon artificiel

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CA3118800A1 (fr) 2020-06-18
WO2020120799A1 (fr) 2020-06-18
EP3894632A1 (fr) 2021-10-20
MA54444A (fr) 2022-03-23
AU2019398780B2 (en) 2023-02-02
AU2019398780A1 (en) 2021-07-01
US20220042252A1 (en) 2022-02-10
AU2023202696A1 (en) 2023-05-18

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