WO2020259934A1 - Produit de nettoyage à forte consistance - Google Patents

Produit de nettoyage à forte consistance Download PDF

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Publication number
WO2020259934A1
WO2020259934A1 PCT/EP2020/064354 EP2020064354W WO2020259934A1 WO 2020259934 A1 WO2020259934 A1 WO 2020259934A1 EP 2020064354 W EP2020064354 W EP 2020064354W WO 2020259934 A1 WO2020259934 A1 WO 2020259934A1
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WO
WIPO (PCT)
Prior art keywords
preparation
surfactant
weight
amino acid
total weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2020/064354
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German (de)
English (en)
Inventor
Philipp Rübenhaus
Michael WÖHRMANN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
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Beiersdorf AG
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Filing date
Publication date
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Publication of WO2020259934A1 publication Critical patent/WO2020259934A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations

Definitions

  • the present invention describes a cleaning preparation which has such a high consistency that the preparation is suitable for removal from a crucible. Furthermore, the preparation is mild, so that the preparation is preferably intended for facial cleansing.
  • Cleansing products are designed to cleanse the skin and hair. After the cleaning process, the user ideally has a feeling of cleanliness, freshness and well-being. Man has always had the need to purify, i.e. Removing dirt from the skin or hair.
  • the aim of the cleaning process is to remove dirt from the surface of the skin.
  • the dirt film consists of solid or liquid components that have reached the skin from the outside. The film of dirt also includes excess skin lipids and dead body cells. With the help of surface-active ingredients in the cleaning compositions, the components of the
  • the StdT contains documents that include reveal various components that can have an impact on the consistency of a preparation.
  • EP 2682161 A2 describes that there are pH-sensitive amino acid surfactants which have a maximum viscosity in a certain pH range.
  • pH-sensitive amino acid surfactants which have a maximum viscosity in a certain pH range.
  • Sodium cocoyl sarcosinate, sodium lauroyl sarcosinate, sodium cocoyl glutamate and sodium cocoylalanate are mentioned as pH-sensitive amino acid surfactants.
  • EP 2320862 A1 discloses preparations for cleaning hair which contain amino acid surfactants with a certain structure, glyceryl ethers with a certain structure and fatty alcohols. These components are intended to help ensure that the foam develops quickly and has sufficient stability and creaminess.
  • At least one amino acid surfactant in particular an acylglycic acid and / or a physiologically acceptable salt thereof, in an amount of 2 to 20% by weight, based on the total weight of the preparation,
  • At least one thickener in particular an acrylate-based thickener tel in an amount of 0.1 to 5.0 wt .-%, based on the total weight of the preparation and
  • At least one unbranched fatty alcohol with a chain length of 12 to 20 carbon atoms, in an amount of 0.5 to 5.0 wt .-%, based on the total weight of the preparation in the preparation and
  • the pH of the preparation being between 4.0 and 9.0 and
  • the weight ratio of the at least one amino acid to the at least one fatty alcohol is 15: 1 to 2: 1, preferably 12: 1 to 3: 1, particularly preferably 10: 1 to 5: 1.
  • the preparation is a cosmetic preparation and is intended for cleaning the skin, in particular facial skin.
  • the preparation is applied to the skin and, after a short exposure time (5 seconds to 5 minutes), is removed, preferably rinsed off with water.
  • the preparation is an aqueous preparation; It is advantageous if the preparation contains 50 to 80% by weight, in particular 60 to 70% by weight, of water.
  • the preparation according to the invention contains at least one amino acid surfactant, which can be described with the following formula: where Ri is a saturated or unsaturated, branched or unbranched alkyl radical,
  • R is a hydrogen atom or a methyl group
  • R is a hydrogen atom, COO M + , CH COO M + or COOH,
  • n is a number between 0 and 2
  • M is independently a hydrogen atom [H + ], Na + or K + .
  • the at least one amino acid surfactant is an acyl glycinate, more preferably a sodium cocoyl glycinate.
  • Sodium cocoyl glycinate can be obtained, for example, from Clariant under the trade name Hostapon SG.
  • the at least one amino acid surfactant is contained in the preparation according to the invention in an amount of 2 to 20% by weight, preferably 3 to 15% by weight, more preferably 4 to 10% by weight, based on the total weight of the preparation.
  • the preparation according to the invention contains at least one thickener.
  • Thickeners can also be called “hydrocolloids", a more precise description is the term “hydrophilic colloid”.
  • Hydrocolloids are macromolecules that have a largely linear shape and have intermolecular interaction forces that enable secondary and main valence bonds between the individual molecules and thus the formation of a network-like structure. Some of them are water-soluble natural or synthetic polymers that form gels or viscous solutions in aqueous systems. They increase the viscosity of the water by either binding water molecules (hydration) or by absorbing and enveloping the water in their interwoven macromolecules, while at the same time restricting the mobility of the water.
  • Such soluble polymers represent a large group of chemically very different natural and synthetic polymers, the common feature of which is their solubility or swellability in water or aqueous media. A prerequisite for this is that these polymers have a sufficient number of hydrophilic ones for their solubility or swellability in water Own groups and are not overly networked.
  • the hydrophilic groups can be non-ionic, anionic or cationic in nature.
  • the group of cosmetically and dermatologically relevant hydrocolloids can be divided into:
  • organic, modified natural substances such as B. carboxymethyl cellulose and other cellulose ethers, hydroxyethyl and -propyl cellulose and the like,
  • organic, fully synthetic compounds such as. B. polyacrylic and polymethacrylic compounds, vinyl polymers, polycarboxylic acids, polyethers, polyimines, polyamides, inorganic compounds, such as. B. polysilicic acids, clay minerals such as montmorillonites, zeolites, silicas.
  • Hydrocolloids preferred according to the invention are organic, fully synthetic compounds, in particular polyacrylic and / or polymethacrylic compounds.
  • Polyacrylates can be homopolymers of acrylic acid, which are then referred to as carbomers.
  • An advantageous carbomer can be obtained from Lubrizol Advanced Materials under the trade name Carbopol 980, for example.
  • Polyacrylates or polymethacrylates can also be copolymers which, in addition to acrylic acid and / or methacrylic acid, have been synthesized from other monomers. It is advantageous according to the invention if the further monomers are alkyl acrylates and / or alkyl methacrylates, particularly advantageous with alkyl radicals having 10 to 30 carbon atoms (C10-C30).
  • Such a polymer is, for example, an Acrylates / C10-C30 Alkylcryate Crosspolymer (INCI name), which is available from Lubrizol Advanced Materials under the trade name Carbopol ETD 2020.
  • the at least one thickener is present in an amount of 0.1 to 5.0% by weight, preferably 0.5 to 2.5% by weight, particularly preferably 0.5 to 1.5% by weight %, based on the total weight of the preparation.
  • the preparation according to the invention contains at least one unbranched fatty alcohol, with a chain length of 12 to 20 carbon atoms, in an amount of 0.5 to 5.0% by weight, preferably 0.5 to 2.0% by weight, based on the Total weight of the preparation.
  • the fatty alcohols according to the invention can be described by the following formula:
  • R 4 is an unbranched, saturated alkyl radical with 12 to 20 carbon atoms. It is preferred if the alkyl radical has 14 to 18 carbon atoms. It is particularly preferred if cetyl alcohol is contained. It is further particularly preferred if the fatty alcohol is only in the form of cetyl alcohol and no other fatty alcohols are contained.
  • the pH of the preparation according to the invention is between 4.0 and 9.0, preferably between 4.5 and 6.5.
  • the pH value can be adjusted and kept stable with the agents customary in the technical field of cosmetics. According to the invention, however, it is preferred if a base is added first; it is particularly preferred if the base is added in two successive steps. It is preferred according to the invention if the base is an inorganic compound, particularly preferably sodium hydroxide and / or potassium hydroxide, more particularly preferably sodium hydroxide.
  • the pH value can be lowered again with an acid.
  • the acid is an organic acid, in particular citric acid is given.
  • further surfactants are contained in the preparation according to the invention.
  • These further surfactants can be selected from the group of anionic surfactants and / or the photeric surfactants, with the proviso that the at least one amino acid surfactant is not included in the group of further anionic surfactants.
  • Suitable further anionic surfactants can be selected from:
  • Carboxylic acids and their salts for example capric acid, lauric acid / salt, aluminum stearate, magnesium alkoxide and zinc undecylenate, stearic acid / salt, palmitic acid / salt, myristic acid / salt,
  • Ester carboxylic acids for example calcium stearoyl lactylate, laureth-6 citrate and sodium PEG-4 lauramide carboxylate,
  • Ether carboxylic acids for example sodium laureth-13-carboxylate and sodium PEG-6-cocamide carboxylate
  • Phosphoric acid esters and salts such as DEA-Oleth-10-Phosphate and Dilaureth-Phosphate
  • acyl isethionates e.g. Sodium / ammonium cocoyl isethionate, sodium lauryl methyl isethionate,
  • alkyl sulfonates for example sodium coconut monoglyceride sulfate, sodium C12-14 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate,
  • Sulfosuccinates for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate, disodium undecylenamido-MEA sulfosuccinate and PEG-5 lauryl citrate sulfosuccinate.
  • Sulfuric acid ester such as
  • Alkyl sulfates for example sodium, ammonium and TEA lauryl sulfate, sodium ammonium and TEA coconut sulfate.
  • the further surfactants from the group of alkyl ether sulfates; it is particularly further advantageous to select lauryl ether sulfate.
  • the preparation according to the invention does not contain any soap-based surfactants.
  • Soaps include the water-soluble sodium or potassium salts of saturated and unsaturated higher fatty acids were understood.
  • Suitable amphoteric surfactants can be selected from:
  • Acyl / dialkylethylenediamine for example sodium acylamphoacetate, disodium acylamphodipropionate, disodium alkylamphodiacetate, disodium cocoamphodiacetate, disodium cocoamphomonoacetate, sodium acylamphohydroxypropylsulfonate, disodium acylamphodampiacetate and sodium,
  • N-alkylamino acids for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.
  • Alkyl betaines for example coco betaine, Alkylamidopropyl betaine, for example cocoamidopropyl betaine,
  • Sultaines for example lauryl hydroxy sultaine.
  • surfactants are contained in the preparation according to the invention, these are present with a total content of 2 to 11% by weight, preferably 2 to 8% by weight, based on the total weight of the preparation. It is advantageous if the other anionic surfactants with a content of 2 to 5 wt .-%, based on the total weight of the preparation and / or the amphoteric surfactants with a content of 2 to 6 wt .-%, based on the total weight of the preparation. The content of the at least one amino acid surfactant is not included in the total content of the further surfactants.
  • the preparation according to the invention can advantageously contain at least one preservative.
  • Preservatives are those preserving substances that are approved for use in cosmetic products for Europe in accordance with the Cosmetics Regulation for Germany and Regulation (EC) No. 1223/2009 on cosmetic products.
  • the at least one preservative can advantageously be selected from the group phenoxyethanol, methyl paraben, ethyl paraben, benzoic acid and / or a physiological salt thereof, in particular sodium benzoate, sorbic acid and / or a physiological salt thereof, in particular sodium sorbate and / or salicylic acid and / or a physiological salt thereof, especially sodium salicylate.
  • the preparation according to the invention contains preservatives, they are present with a total content of 1.0 to 4.0% by weight, preferably 1.5 to 2.0% by weight, based on the total weight of the preparation.
  • Humectants can, for example, give the skin moisture and / or help prevent moisture loss in the skin.
  • the humectants are hygroscopic substances that can bind water. This water-binding capacity is based on hydrophilic groups such as hydroxyl groups, but also amine groups and carboxyl groups.
  • Humectants are for example Glycerine, butylene glycol, propylene glycol, Biosaccaride Gum-1, ethylhexyloxyglycerine, pyrrolidonecarboxylic acid, urea, sorbitol, xylitol, aloe vera gel and others. According to the invention, the use of propylene glycol and / or glycerol is preferred.
  • the preparation according to the invention also contains one or more humectants
  • the humectant (s) has a total content of 0.01 to 30% by weight, preferably 5 to 20% by weight, based on the total weight of the preparation tung, before.
  • At least one dye and / or color pigment can also be included.
  • the dyes and pigments can be selected from the corresponding positive list of the Cosmetics Ordinance or the EC list of cosmetic colorants. In most cases, they are identical to the food coloring agents.
  • Suitable color pigments are, for example, titanium dioxide, mica, iron oxides (e.g. Fe 2 0 3 , Fe 3 0 4 , FeO (OH)) and / or tin oxide.
  • Suitable dyes are, for example, carmine, Prussian blue, chrome oxide green, ultramarine blue and / or manganese violet. It is advantageous to choose the dyes and / or color pigments from the Rowe Color Index, 3rd edition, Society of Dyers and Colourists, Bradford, England, 1971.
  • titanium dioxide CI 77891
  • CI 77891 titanium dioxide
  • the total content of the at least one dye and / or the at least one colored pigment is in the range from 0.01 to 0.3% by weight, preferably from 0.05 to 0 To choose 2 wt .-%, based on the total weight of the preparation.
  • the preparation according to the invention can contain cosmetic auxiliaries such as are customarily used in such preparations, eg. B. preservatives, complexing agents, bactericides, perfumes, substances to increase foaming, fillers that improve the feel of the skin, fats, oils, waxes or other common ingredients of a cosmetic or dermatological formulation such as alcohols, foam stabilizers, electrolytes, organic solvents or silicone derivatives .
  • cosmetic auxiliaries such as are customarily used in such preparations, eg. B. preservatives, complexing agents, bactericides, perfumes, substances to increase foaming, fillers that improve the feel of the skin, fats, oils, waxes or other common ingredients of a cosmetic or dermatological formulation such as alcohols, foam stabilizers, electrolytes, organic solvents or silicone derivatives .
  • the preparation according to the invention can be produced by any method customary in the cosmetic industry and suitable for this form of preparation. However, it is advantageous if the preparation is made in the following way:
  • the heated surfactant to the polymer phase (batch) at about 60 ° C; If the preparation contains further surfactants, it is advantageous to add the amphoteric surfactant (for example coco-betaine) first, then the at least one amino acid surfactant (for example sodium cocoyl glycinate) and then the other anionic surfactant (for example sodium lauryl ether sulfate) admit;
  • the amphoteric surfactant for example coco-betaine
  • the at least one amino acid surfactant for example sodium cocoyl glycinate
  • the other anionic surfactant for example sodium lauryl ether sulfate
  • the dissolver stirrer can be, for example, a dissolver stirrer from IKA.
  • the stirrer should have a speed of 50 to 2000 rpm, advantageously a stirrer should be selected for the manufacture of the pasty preparation according to the invention, which can move the stirrer at 400 to 1200 rpm.
  • amino acid surfactants using the example of sodium cocoyl glycinate
  • amphoteric surfactants using the example of coco-betaine and other anionic surfactants, in particular alkyl ether sulfates, using the example of sodium lauryl ether sulfate
  • alkyl ether sulfates using the example of sodium lauryl ether sulfate
  • sodium laureth sulfate in which the pH value was gradually raised to 5.1; none of these preparations showed a thickening effect.
  • a combination of at least one amino acid surfactant (based on the example of sodium cocoyl glycinate) and at least one fatty alcohol (based on the example of cetyl alcohol) leads to a further thickening of the preparation, which can be read from even higher consistency values. It was also analyzed whether and what effect the amount of amino acid surfactant (e.g. sodium cocoyl glycinate) or fatty alcohol (e.g. cetyl alcohol) has on the consistency.
  • the consistency measurement device is a conventional spring balance dynamometer that has been optimized so that cosmetic samples can be measured.
  • the dynamometer is a Mixor brand dynamometer.
  • the sample to be measured is filled into a 75 ml aluminum crucible and stored. The measurements are carried out at fixed intervals during storage. The sample to be measured in the aluminum crucible is placed in the holder.
  • the dynamometer is attached to the machine using the bracket provided.
  • the indicator for determining the maximum consistency a red pointer, is set to zero.
  • the sensor initially points upwards.
  • the machine is started with the green button.
  • the holder with the sample is now fixed accordingly.
  • the measurement begins when the start button (white) is pressed.
  • the dynamometer with the probe, which is immersed in the sample, rotates through 360 ° at a defined speed of 10 rpm.
  • the force is now measured that is necessary for the probe to move once through the sample.
  • the black pointer of the dynamometer shows the measured force in real time and the red pointer shows the maximum force applied during the measurement process.
  • the measured value on the scale corresponds to 1g / cN per unit.
  • the accuracy of the measuring device is given with a measured value of ⁇ 1 per scale unit.
  • a dynamometer with a scale from 25 to 250, the scale being displayed in steps of 5, the result is thus given with a reproducibility of ⁇ 5g / cN. Measurements are taken at a temperature of 25 ° C. The sample is stored in the same room, but at least in a room of the same temperature.
  • the pH was measured by means of a commercially available pH meter (for example the laboratory pH meter 766, Knick brand).
  • an example recipe was produced and distributed to 35 users who describe their skin as sensitive.
  • the users used the named product once a day for 14 days. After this test period, a questionnaire had to be filled out.
  • the present invention also relates to the use of a combination of at least one amino acid surfactant and at least one fatty alcohol for thickening a cosmetic cleaning preparation to a pasty consistency.
  • Particularly advantageous is the use of a combination of at least one amino acid surfactant and at least one fatty alcohol for thickening a cosmetic cleaning preparation to a pasty consistency
  • the at least one amino acid surfactant being an acylglycic acid and / or a physiologically compatible salt thereof and in an amount of 2 to 20 wt .-%, based on the total weight of the preparation, is present
  • the least one unbranched fatty alcohol with a chain length of 12 to 20 carbon atoms in an amount of 0.5 to 5.0 wt .-%, based on the Total weight of the preparation is present and that the weight ratio of amino acid surfactant to fatty alcohol is 15: 1 to 2: 1, preferably 12: 1 to 5: 1.
  • the following examples are intended to illustrate the present invention without restricting it.
  • the numerical values in the examples mean percentages by weight, based on the total weight of the respective preparations.
  • the information relates to the respective active content.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une préparation de nettoyage cosmétique pâteuse contenant un tensio-actif d'amino-acide et un alcool gras non ramifié qui peut être fourni dans un creuset.
PCT/EP2020/064354 2019-06-24 2020-05-25 Produit de nettoyage à forte consistance Ceased WO2020259934A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102019209058.3A DE102019209058A1 (de) 2019-06-24 2019-06-24 Reinigungsprodukt mit hoher Konsistenz
DE102019209058.3 2019-06-24

Publications (1)

Publication Number Publication Date
WO2020259934A1 true WO2020259934A1 (fr) 2020-12-30

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PCT/EP2020/064354 Ceased WO2020259934A1 (fr) 2019-06-24 2020-05-25 Produit de nettoyage à forte consistance

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DE (1) DE102019209058A1 (fr)
WO (1) WO2020259934A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115404134A (zh) * 2022-10-09 2022-11-29 广州立白企业集团有限公司 一种透明自增稠清洁组合物

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0687721A2 (fr) * 1994-06-15 1995-12-20 Ajinomoto Co., Inc. Composition détergente
WO2004043416A1 (fr) * 2002-11-12 2004-05-27 Beiersdorf Ag Preparation cosmetique nettoyante thermoresistante a base de celluloses d'hydroxyalkyle
EP2161017A1 (fr) * 2008-09-05 2010-03-10 KPSS-Kao Professional Salon Services GmbH Composition de nettoyage
WO2011025898A1 (fr) 2009-08-26 2011-03-03 Qualcomm Incorporated Système et procédé de fabrication de mémoire magnétique à accès aléatoire
EP2682161A2 (fr) 2012-05-16 2014-01-08 Kreuzkamp, Markus Agent de nettoyage et d'entretien liquide
WO2015071298A2 (fr) 2013-11-13 2015-05-21 L'oreal Composition moussante comprenant au moins un surfactant de type glycinate

Family Cites Families (2)

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Publication number Priority date Publication date Assignee Title
US5632978A (en) * 1994-08-24 1997-05-27 The Procter & Gamble Company Mild shower gel composition comprising fatty alcohol which imparts improved lathering and thickening properties
EP2335681A1 (fr) * 2009-12-18 2011-06-22 KPSS-Kao Professional Salon Services GmbH Composition de nettoyage

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0687721A2 (fr) * 1994-06-15 1995-12-20 Ajinomoto Co., Inc. Composition détergente
WO2004043416A1 (fr) * 2002-11-12 2004-05-27 Beiersdorf Ag Preparation cosmetique nettoyante thermoresistante a base de celluloses d'hydroxyalkyle
EP2161017A1 (fr) * 2008-09-05 2010-03-10 KPSS-Kao Professional Salon Services GmbH Composition de nettoyage
EP2320862A1 (fr) 2008-09-05 2011-05-18 KPSS-Kao Professional Salon Services GmbH Composition de lavage
WO2011025898A1 (fr) 2009-08-26 2011-03-03 Qualcomm Incorporated Système et procédé de fabrication de mémoire magnétique à accès aléatoire
EP2682161A2 (fr) 2012-05-16 2014-01-08 Kreuzkamp, Markus Agent de nettoyage et d'entretien liquide
WO2015071298A2 (fr) 2013-11-13 2015-05-21 L'oreal Composition moussante comprenant au moins un surfactant de type glycinate
EP3068368A2 (fr) 2013-11-13 2016-09-21 L'oreal Composition moussante comprenant au moins un surfactant de type glycinate

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE GNPD [online] MINTEL; 24 April 2017 (2017-04-24), ANONYMOUS: "Cleansing Paste", XP055715872, retrieved from www.gnpd.com Database accession no. 4762447 *
DATABASE GNPD [online] MINTEL; 29 October 2010 (2010-10-29), ANONYMOUS: "Transparent Cleansing Cream", XP055715902, retrieved from www.gnpd.com Database accession no. 1439506 *
DATABASE GNPD [online] MINTEL; 5 January 2017 (2017-01-05), ANONYMOUS: "Oily Scalp Clay Treatment", XP055633634, retrieved from www.gnpd.com Database accession no. 4525757 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115404134A (zh) * 2022-10-09 2022-11-29 广州立白企业集团有限公司 一种透明自增稠清洁组合物
CN115404134B (zh) * 2022-10-09 2023-12-26 广州立白企业集团有限公司 一种透明自增稠清洁组合物

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