WO2021049106A1 - 回路基板、回路基板の製造方法、及び電子機器 - Google Patents
回路基板、回路基板の製造方法、及び電子機器 Download PDFInfo
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- WO2021049106A1 WO2021049106A1 PCT/JP2020/021855 JP2020021855W WO2021049106A1 WO 2021049106 A1 WO2021049106 A1 WO 2021049106A1 JP 2020021855 W JP2020021855 W JP 2020021855W WO 2021049106 A1 WO2021049106 A1 WO 2021049106A1
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- base material
- insulating base
- laminated body
- circuit board
- metal layer
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4644—Manufacturing multilayer circuits by building the multilayer layer by layer, i.e. build-up multilayer circuits
- H05K3/4652—Adding a circuit layer by laminating a metal foil or a preformed metal foil pattern
- H05K3/4655—Adding a circuit layer by laminating a metal foil or a preformed metal foil pattern by using a laminate characterized by the insulating layer
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/0058—Laminating printed circuit boards onto other substrates, e.g. metallic substrates
- H05K3/0067—Laminating printed circuit boards onto other substrates, e.g. metallic substrates onto an inorganic, non-metallic substrate
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
- H05K3/4614—Manufacturing multilayer circuits by laminating two or more circuit boards the electrical connections between the circuit boards being made during lamination
- H05K3/462—Manufacturing multilayer circuits by laminating two or more circuit boards the electrical connections between the circuit boards being made during lamination characterized by laminating only or mainly similar double-sided circuit boards
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0306—Inorganic insulating substrates, e.g. ceramic, glass
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/11—Printed elements for providing electric connections to or between printed circuits
- H05K1/115—Via connections; Lands around holes or via connections
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/4038—Through-connections; Vertical interconnect access [VIA] connections
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
- H05K3/4623—Manufacturing multilayer circuits by laminating two or more circuit boards the circuit boards having internal via connections between two or more circuit layers before lamination, e.g. double-sided circuit boards
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
- H05K3/4626—Manufacturing multilayer circuits by laminating two or more circuit boards characterised by the insulating layers or materials
- H05K3/4632—Manufacturing multilayer circuits by laminating two or more circuit boards characterised by the insulating layers or materials laminating thermoplastic or uncured resin sheets comprising printed circuits without added adhesive materials between the sheets
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/09—Use of materials for the conductive, e.g. metallic pattern
- H05K1/092—Dispersed materials, e.g. conductive pastes or inks
- H05K1/095—Dispersed materials, e.g. conductive pastes or inks for polymer thick films, i.e. having a permanent organic polymeric binder
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/14—Structural association of two or more printed circuits
- H05K1/141—One or more single auxiliary printed circuits mounted on a main printed circuit, e.g. modules, adapters
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0137—Materials
- H05K2201/0154—Polyimide
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0183—Dielectric layers
- H05K2201/0195—Dielectric or adhesive layers comprising a plurality of layers, e.g. in a multilayer structure
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/09563—Metal filled via
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/09—Shape and layout
- H05K2201/09209—Shape and layout details of conductors
- H05K2201/095—Conductive through-holes or vias
- H05K2201/096—Vertically aligned vias, holes or stacked vias
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/06—Lamination
- H05K2203/061—Lamination of previously made multilayered subassemblies
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/36—Assembling printed circuits with other printed circuits
- H05K3/368—Assembling printed circuits with other printed circuits parallel to each other
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/40—Forming printed elements for providing electric connections to or between printed circuits
- H05K3/4038—Through-connections; Vertical interconnect access [VIA] connections
- H05K3/4053—Through-connections; Vertical interconnect access [VIA] connections by thick-film techniques
- H05K3/4069—Through-connections; Vertical interconnect access [VIA] connections by thick-film techniques for via connections in organic insulating substrates
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4644—Manufacturing multilayer circuits by building the multilayer layer by layer, i.e. build-up multilayer circuits
- H05K3/4664—Adding a circuit layer by thick film methods, e.g. printing techniques or by other techniques for making conductive patterns by using pastes, inks or powders
Definitions
- This case relates to circuit boards, circuit board manufacturing methods, and electronic devices.
- circuit boards such as printed wiring boards have been widely used in order to compactly incorporate electronic components into electronic devices.
- the printed wiring board is obtained by etching a copper foil bonded to a laminated board according to an electronic circuit pattern, and although it is difficult to mount electronic components at high density, it is advantageous in terms of cost.
- a multi-layer printed wiring board which is a circuit board having a multi-layer structure
- a plurality of insulating base materials on which a wiring pattern is formed are bonded together by an adhesive layer.
- the adhesive layer is a material that is not required in the manufactured multilayer printed wiring board.
- the disclosed techniques include a method for manufacturing a circuit board capable of manufacturing a circuit board having a multi-layer structure without using an adhesive layer, a circuit board having a multi-layer structure without an adhesive layer for forming the multi-layer structure, and an electron having the circuit board.
- the purpose is to provide equipment.
- the method of manufacturing the circuit board of the present case is The first of the first insulating base materials in a first laminated body having a cured first insulating base material and a metal layer formed in a pattern on the first surface of the first insulating base material.
- the holes are conductive.
- One said third laminated body and the other said third laminated body so that the metal layer of one said third laminated body and the opening of the hole of the other said third laminated body face each other. Including the step of superimposing on the surface and performing thermocompression bonding.
- the circuit board in this case The cured first insulating base material, the metal layer formed in a pattern on the first surface of the first insulating base material, and the side opposite to the first surface of the first insulating base material.
- the cured second insulating base material arranged on the second surface was formed from the surface of the second insulating base material opposite to the first insulating base material side until the metal layer was reached.
- one said laminated body and the other said laminated body are placed on the surface of the metal layer of the one said laminated body and the second insulating base material of the other said laminated body. It is located opposite to the exposed via.
- the electronic device in this case has a disclosed circuit board and electronic components.
- a method for manufacturing a circuit board capable of manufacturing a circuit board having a multi-layer structure without using an adhesive layer it is possible to provide a circuit board having a multi-layer structure without an adhesive layer for forming the multi-layer structure. Further, on one side, it is possible to provide an electronic device using a circuit board having a multi-layer structure that does not have an adhesive layer for forming the multi-layer structure.
- FIG. 1 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 1).
- FIG. 2 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 2).
- FIG. 3 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 3).
- FIG. 4 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 4).
- FIG. 5 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 5).
- FIG. 6 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 6).
- FIG. 6 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 6).
- FIG. 7 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 7).
- FIG. 8 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 8).
- FIG. 9 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 9).
- FIG. 10 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 10).
- FIG. 11 is a schematic cross-sectional view for explaining an example of a method for manufacturing a circuit board (No. 11).
- FIG. 12 is a schematic cross-sectional view of the semiconductor package.
- the disclosed circuit board manufacturing method includes at least a step of obtaining a second laminated body, a step of obtaining a third laminated body, and a step of performing thermocompression bonding, and further includes other steps as necessary.
- the uncured second insulating base material and the resin film are placed in this order on the second surface opposite to the first surface of the first insulating base material in the first laminated body. It is obtained by stacking with and performing thermocompression bonding.
- the first laminated body has a cured first insulating base material and a metal layer formed in a pattern on the first surface of the first insulating base material.
- the first insulating base material has been cured.
- the first insulating base material is not particularly limited as long as it is an insulating base material used in a circuit board, and can be appropriately selected depending on the intended purpose.
- an inorganic woven fabric using a glass cloth or the like examples thereof include an inorganic base material such as an inorganic non-woven fabric, an organic woven fabric, and a base material whose hardness is reinforced by an organic base material such as an organic non-woven fabric.
- the first insulating base material for example, a glass epoxy base material (a glass woven cloth base material impregnated with an epoxy resin, a glass non-woven fabric base material impregnated with an epoxy resin), Examples thereof include a glass woven fabric base material impregnated with bismaleimide triazine resin, an aramid non-woven fabric base material impregnated with an epoxy resin, and a glass woven fabric base material impregnated with a modified polyphenylene ether resin.
- the glass epoxy base material is a base material obtained by impregnating a glass fiber cloth (woven cloth or non-woven fabric) with an epoxy resin.
- the first insulating base material has been cured.
- the cured state is, for example, a state in which heat generation of about 100% of the total heat generation amount of curing is completed, and for example, a state in which almost no heat generation can be observed when the differential scanning calorimetry is performed.
- the cured product may be referred to as a C stage.
- the degree of curing that has not reached the C stage may be referred to as the B stage.
- the first insulating base material is usually in the form of a flat plate.
- the average thickness of the first insulating base material is not particularly limited and may be appropriately selected depending on the intended purpose. For example, it may be 10 ⁇ m or more and 200 ⁇ m or less, or 30 ⁇ m or more and 100 ⁇ m or less. ..
- the metal forming the metal layer is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include nickel and copper.
- the structure of the metal layer may be a single-layer structure or a multi-layer structure. Examples of the metal layer include a single-layer structure of copper and a two-layer structure of copper and nickel.
- the pattern of the metal layer is not particularly limited and can be appropriately selected according to the purpose.
- the method for forming the patterned metal layer is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a subtractive (etching) method and a semi-additive method (plating method). These can be done by utilizing a photolithography method.
- the surface of the metal layer on the side opposite to the first insulating base material side is preferably a rough surface. Since the surface of the metal layer on the side opposite to the first insulating base material side is a rough surface, when the first third laminated body and the other third laminated body are thermocompression bonded, the laminated body thereof. Adhesion is improved. Further, since the surface of the metal layer on the side opposite to the first insulating base material side is a rough surface, the first third laminated body and the other third laminated body can be combined with each other of the first third laminated body.
- the method for roughening the surface of the metal layer is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include CZ treatment (treatment of copper surface of zigzag). Examples of the arithmetic mean roughness (Ra) of the rough surface include 1.0 ⁇ m or more and 2.0 ⁇ m or less.
- the average thickness of the metal layer is not particularly limited and may be appropriately selected depending on the intended purpose. For example, it may be 5 ⁇ m or more and 40 ⁇ m or less, or 10 ⁇ m or more and 30 ⁇ m or less.
- the second insulating substrate is not cured.
- the second insulating base material is not particularly limited as long as it is an insulating base material used in a circuit board, and can be appropriately selected depending on the intended purpose.
- an inorganic woven fabric using a glass cloth or the like examples thereof include an inorganic base material such as an inorganic non-woven fabric, an organic woven fabric, and a base material whose hardness is reinforced by an organic base material such as an organic non-woven fabric.
- the second insulating base material for example, a glass epoxy base material (a glass woven cloth base material impregnated with an epoxy resin, a glass non-woven fabric base material impregnated with an epoxy resin), examples thereof include a glass woven fabric base material impregnated with bismaleimide triazine resin, an aramid non-woven fabric base material impregnated with an epoxy resin, and a glass woven fabric base material impregnated with a modified polyphenylene ether resin.
- the glass epoxy base material is a base material obtained by impregnating a glass fiber cloth (woven cloth or non-woven fabric) with an epoxy resin.
- the glass epoxy base material as the first insulating base material and the glass epoxy base material as the second insulating base material are the same glass epoxy base material.
- the characteristic values volume contraction / expansion, mechanical rigidity, etc.
- the same glass epoxy base material means that the same properties are exhibited in the cured (C stage) state.
- the same glass epoxy base material as the C stage glass epoxy base material which is the first insulating base material is used as the second insulating base material in the B stage state, they are the same glass epoxy base material. is there.
- the material of the second insulating base material may be a thermosetting resin.
- a thermosetting resin a fluorine resin, a polyphenylene ether resin (PPE / PPO resin), a polyimide resin (PI resin), and a bismaleimide triazine resin (BT resin) are preferable. Since these resins have a low dielectric constant and a low dielectric loss tangent, the transmission loss of an electric signal can be reduced by using these resins.
- the second insulating base material is usually in the form of a flat plate.
- the average thickness of the second insulating base material is not particularly limited and may be appropriately selected depending on the intended purpose. For example, it may be 10 ⁇ m or more and 150 ⁇ m or less, or 20 ⁇ m or more and 100 ⁇ m or less. ..
- the ratio of the average thickness of the first insulating base material to the average thickness of the second insulating base material is not particularly limited and depends on the purpose. Although it can be appropriately selected, 4.0: 1.0 to 1.0 to 1.0 is preferable, and 2.0: 1.0 to 1.0 is preferable from the viewpoint of circuit board manufacturability and thickness dimension control. 5: 1.0 is more preferable.
- the resin film is not particularly limited as long as it is a resin film that does not melt during thermal pressure bonding, and can be appropriately selected depending on the intended purpose.
- the resin film includes a polyimide film.
- the surface of the resin film on the second insulating base material side is preferably a rough surface.
- the method for roughening the surface of the resin film is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include blasting, embossing, and coating. Examples of the arithmetic mean roughness (Ra) of the rough surface include 1.0 ⁇ m and more and 2.0 ⁇ m or less.
- the average thickness of the resin film is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include 10 ⁇ m and more and 100 ⁇ m or less.
- the uncured second insulating substrate and the resin film are placed on the second surface of the first laminate opposite to the first surface of the first insulating substrate. And are stacked in this order to perform thermocompression bonding. By doing so, it is possible to temporarily bond the first laminate to the second insulating base material and to temporarily bond the second insulating base material to the resin film.
- the second insulating base material does not have sufficient adhesiveness at room temperature and under normal pressure. Therefore, if thermocompression bonding is not performed, the temporary adhesion between the first laminated body and the second insulating base material becomes insufficient, and the first laminated body and the second insulating base material are peeled off in other steps. There is a risk of doing.
- thermocompression bonding is not performed, the temporary adhesion between the second insulating base material and the resin film becomes insufficient, and the second insulating base material and the resin film may be peeled off in other steps. .. That is, thermocompression bonding is performed so that the first laminated body and the second insulating base material do not peel off, and the second insulating base material and the resin film do not unintentionally peel off. preferable.
- the temperature, pressure, and time for thermocompression bonding are not particularly limited and can be appropriately selected depending on the intended purpose.
- Examples of the temperature include 50 ° C. and higher and 100 ° C. and lower.
- Examples of the pressure include 0.5 MPa or more and 1.2 MPa or less.
- Examples of the time include 60 seconds or more and 120 seconds or less.
- the second insulating base material is not completely cured, but it is preferable to cure it. That is, it is preferable that the second insulating base material is not cured to the C stage during thermocompression bonding. If holes are formed in the second insulating base material after the second insulating base material is cured, the dimensional stability of the holes is improved. On the other hand, if a plurality of third laminated bodies are laminated and then thermocompression bonded to manufacture a circuit board without completely curing the second insulating base material, the second insulating base material of the first third laminated body and the second insulating base material can be obtained. The adhesiveness of the other third laminated body to the first insulating base material is excellent.
- the metal layer of one third laminated body becomes the second insulating material of the other third laminated body. It becomes easy to be embedded in a sex substrate, and a circuit board having a uniform thickness can be obtained.
- the third laminated body In the third laminated body, holes reaching the metal layer are formed in the resin film, the second insulating base material, and the first insulating base material from the resin film side of the second laminated body, and then the conductive paste is formed in the holes. It is obtained by filling with and further peeling off the resin film.
- the method of forming a hole is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a method of forming a hole using a laser.
- the laser is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a CO 2 laser and a YAG laser.
- the output of the laser is not particularly limited and can be appropriately selected according to the purpose.
- the size (opening diameter) of the hole is not particularly limited and may be appropriately selected according to the purpose. It can be, for example, 50 ⁇ m or more and 500 ⁇ m or less, or 100 ⁇ m or more and 300 ⁇ m or less.
- the hole size (opening diameter) here refers to, for example, the opening diameter of the surface of the second insulating base material on the resin film side.
- the shape of the hole is not particularly limited and may be appropriately selected depending on the intended purpose.
- a shape (tapered shape) in which the diameter gradually decreases from the opening on the resin film side toward the metal layer can be mentioned. Be done.
- the number of holes formed in the second laminated body is not particularly limited and can be appropriately selected according to the purpose.
- the conductive paste is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a conductive paste containing metal particles (conductive filler) and a binder resin. Examples of the metal constituting the metal particles include copper, gold, silver, palladium, nickel, tin, lead, bismuth and the like. These may be used alone or in combination of two or more. Examples of the binder resin include thermosetting resins such as epoxy resins. However, the binder resin is not limited to this, and may be another resin such as a polyimide resin. The binder resin may be liquid at room temperature or solid.
- the conductive paste is used by heating it to a temperature equal to or higher than the melting temperature of the binder resin, for example.
- the conductive paste can be obtained, for example, by kneading a binder resin and metal particles.
- the conductive paste may contain a flux or the like.
- the conductive paste may be a pressure welding type or a molten type.
- the pressure welding type is a conductive paste that enables conductive connection between layers by contacting the conductive fillers with each other only by the pressure during lamination, without melting the low resistance metal powder (conductive filler) with the heat during lamination. is there.
- the resin contained in the conductive paste is thermally cured and loses its fluidity.
- the melt type is a conductive connection between layers by melting the low melting point metal powder (conductive filler) with the heat during lamination and hardening it so as to surround the high melting point metal powder (conductive filler) to form an alloy layer. It is a conductive paste that makes it possible.
- the method of filling the holes with the conductive paste is not particularly limited and may be appropriately selected depending on the intended purpose. For example, a method of filling the holes with the conductive paste under air or vacuum using a squeegee jig. And so on.
- the method for peeling the resin film is not particularly limited and may be appropriately selected depending on the intended purpose. For example, a method of grasping the end portion of the resin film with a jig and pulling it away from the second insulating base material can be mentioned. Be done.
- thermocompression bonding The first third laminated body and the other third laminated body are laminated so that the metal layer of the first third laminated body and the opening of the hole of the other third laminated body face each other, and thermocompression bonding is performed. Will be done.
- the temperature, pressure, and time for thermocompression bonding are not particularly limited and can be appropriately selected depending on the intended purpose.
- Examples of the temperature include 200 ° C. and higher and 500 ° C. and lower.
- Examples of the pressure include 2 MPa and more and 10 MPa or less.
- Examples of the time include 3 hours or more and 5 hours or less.
- thermocompression bonding it is preferable to completely cure the second insulating base material. That is, when performing thermocompression bonding, it is preferable to cure the second insulating base material to the C stage. By doing so, a circuit board is obtained.
- ⁇ Process of curing the surface of conductive paste In the method for manufacturing a circuit board, it is preferable to perform a step of curing the surface of the conductive paste protruding from the holes in the third laminated body. By curing the surface of the conductive paste protruding from the hole, the shape of the conductive paste protruding from the hole can be maintained. Further, by curing the surface of the conductive paste protruding from the hole, the conductive paste flows unnecessarily when the first third laminated body and the other third laminated body are laminated and thermocompression bonded. It can be avoided to spread.
- the degree of curing is not particularly limited and can be appropriately selected according to the purpose, and does not need to be completely cured.
- the heating method is not particularly limited and can be appropriately selected according to the purpose.
- the disclosed circuit board has a plurality of laminated bodies.
- one of the plurality of laminated bodies and the other laminated body are exposed to the metal layer of the one laminated body and the surface of the second insulating base material of the other laminated body. Are located opposite each other.
- the disclosed circuit board is manufactured by, for example, the method of manufacturing the disclosed circuit board.
- the laminate has a first insulating base material, a metal layer, a second insulating base material, and vias.
- the first insulating base material has been cured. That is, the first insulating base material is the C stage.
- the first insulating base material is not particularly limited as long as it is an insulating base material used in a circuit board, and can be appropriately selected depending on the intended purpose.
- an inorganic woven fabric using a glass cloth or the like examples thereof include an inorganic base material such as an inorganic non-woven fabric, an organic woven fabric, and a base material whose hardness is reinforced by an organic base material such as an organic non-woven fabric.
- the first insulating base material for example, a glass epoxy base material (a glass woven cloth base material impregnated with an epoxy resin, a glass non-woven fabric base material impregnated with an epoxy resin), Examples thereof include a glass woven fabric base material impregnated with bismaleimide triazine resin, an aramid non-woven fabric base material impregnated with an epoxy resin, and a glass woven fabric base material impregnated with a modified polyphenylene ether resin.
- the glass epoxy base material is a base material obtained by impregnating a glass fiber cloth (woven cloth or non-woven fabric) with an epoxy resin.
- the first insulating base material is usually in the form of a flat plate.
- the average thickness of the first insulating base material is not particularly limited and may be appropriately selected depending on the intended purpose. For example, it may be 10 ⁇ m or more and 200 ⁇ m or less, or 30 ⁇ m or more and 100 ⁇ m or less. ..
- the metal layer is formed in a pattern on the first surface of the first insulating base material.
- the metal forming the metal layer is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include nickel and copper.
- the structure of the metal layer may be a single-layer structure or a multi-layer structure. Examples of the metal layer include a single-layer structure of copper and a two-layer structure of copper and nickel.
- the pattern of the metal layer is not particularly limited and can be appropriately selected according to the purpose.
- the method for forming the patterned metal layer is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a subtractive (etching) method and a semi-additive method (plating method). These can be done by utilizing a photolithography method.
- the average thickness of the metal layer is not particularly limited and may be appropriately selected depending on the intended purpose. For example, it may be 5 ⁇ m or more and 40 ⁇ m or less, or 10 ⁇ m or more and 30 ⁇ m or less.
- Second Insulating Substrate In the circuit board, the second insulating base material has been cured. That is, in the circuit board, the second insulating base material is, for example, the C stage.
- the second insulating base material is not particularly limited as long as it is an insulating base material used in a circuit board, and can be appropriately selected depending on the intended purpose.
- an inorganic woven fabric using a glass cloth or the like examples thereof include an inorganic base material such as an inorganic non-woven fabric, an organic woven fabric, and a base material whose hardness is reinforced by an organic base material such as an organic non-woven fabric.
- the second insulating base material for example, a glass epoxy base material (a glass woven cloth base material impregnated with an epoxy resin, a glass non-woven fabric base material impregnated with an epoxy resin), examples thereof include a glass woven fabric base material impregnated with bismaleimide triazine resin, an aramid non-woven fabric base material impregnated with an epoxy resin, and a glass woven fabric base material impregnated with a modified polyphenylene ether resin.
- the glass epoxy base material is a base material obtained by impregnating a glass fiber cloth (woven cloth or non-woven fabric) with an epoxy resin.
- the glass epoxy base material as the first insulating base material and the glass epoxy base material as the second insulating base material are the same glass epoxy base material.
- the characteristic values volume contraction / expansion, mechanical rigidity, etc.
- the same glass epoxy base material means that the same properties are exhibited in the cured (C stage) state.
- the same glass epoxy base material as the C stage glass epoxy base material which is the first insulating base material is used as the second insulating base material in the B stage state, they are the same glass epoxy base material. is there.
- the material of the second insulating base material may be a cured product of a thermosetting resin.
- a thermosetting resin a fluorine resin, a polyphenylene ether resin (PPE / PPO resin), a polyimide resin (PI resin), and a bismaleimide triazine resin (BT resin) are preferable. Since these resins have a low dielectric constant and a low dielectric loss tangent, the transmission loss of an electric signal can be reduced by using these resins.
- the second insulating base material is usually in the form of a flat plate.
- the average thickness of the second insulating base material is not particularly limited and may be appropriately selected depending on the intended purpose. For example, it may be 10 ⁇ m or more and 150 ⁇ m or less, or 20 ⁇ m or more and 100 ⁇ m or less. ..
- the ratio of the average thickness of the first insulating base material to the average thickness of the second insulating base material is not particularly limited and depends on the purpose. Although it can be appropriately selected, 4.0: 1.0 to 1.0 to 1.0 is preferable, and 2.0: 1.0 to 1.0 is preferable from the viewpoint of circuit board manufacturability and thickness dimension control. 5: 1.0 is more preferable.
- a via is a conductor formed inside a hole formed for electrical connection between laminated bodies in a circuit board.
- the conductor is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include a cured product of a conductive paste and plating. When the conductor is a cured product of the conductive paste, vias are usually formed by curing the conductive paste after filling the entire inside of the hole with the conductive paste. When the conductor is plated, the inner walls of the holes are usually electroplated or electroless plated to form vias.
- the conductive paste is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include the conductive paste described in the disclosed circuit board manufacturing method.
- the disclosed electronic device includes at least the disclosed circuit board and electronic components, and, if necessary, other members.
- the electronic device is not particularly limited and may be appropriately selected according to the purpose.
- personal computers notebook personal computers, desktop personal computers
- telephones mobile phones, tablet mobile terminals, smartphones, copiers, facsimiles, various printers, digital cameras, televisions, videos, CD devices, DVD devices, air conditioners, remote control devices. And so on.
- a double-sided copper-coated substrate in which metal layers 2 and 3 which are copper foils are bonded to both sides of the first insulating base material 1 is prepared (FIG. 1).
- the first insulating base material 1 is, for example, a cured glass epoxy base material, and the average thickness thereof is, for example, 60 ⁇ m.
- the average thickness of the metal layers 2 and 3 is, for example, 15 ⁇ m.
- the dry film resists 4 and 5 are bonded to both sides of the double-sided copper-coated substrate using a laminator (FIG. 2).
- the dry film resist 4 is selectively exposed and developed to form a resist pattern for forming a patterned metal layer (FIG. 3).
- the dry film resist 5 is completely dissolved by development.
- the dry film resists 4 and 5 are not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include positive type dry film resists and negative type dry film resists.
- the exposure wavelength in the selective exposure is not particularly limited as long as the dry film resist can be exposed to light, and can be appropriately selected depending on the intended purpose.
- the developing method is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include development with an alkaline aqueous solution.
- the metal layers 2 and 3 are etched using the patterned dry film resist 4 as a mask to obtain the patterned metal layer 2 (FIG. 4).
- Examples of the etching method include wet etching. From the above, the first laminated body is obtained. Next, the uncured second insulating base material 6 and the resin film 7 are placed on the second surface 1B opposite to the first surface 1A of the first insulating base material 1 in the first laminated body. The layers are stacked in this order and thermocompression bonded to obtain a second laminated body (FIG. 5).
- the second insulating base material 6 before thermocompression bonding is, for example, a B-stage glass epoxy base material. In thermocompression bonding, it is preferable to heat-cure the second insulating base material 6.
- thermosetting is not the thermosetting up to the C stage, but the thermosetting to the extent that the curing proceeds more moderately in the B stage is preferable.
- holes 8 reaching the metal layer 3 are formed in the resin film 7, the second insulating base material 6, and the first insulating base material 1 from the resin film 7 side of the second laminated body (FIG. 6). ..
- the hole 8 can be formed, for example, by irradiating a laser.
- the hole 8 is filled with the conductive paste 9 (FIG. 7).
- the method of filling the hole 8 with the conductive paste 9 is not particularly limited and may be appropriately selected depending on the intended purpose. For example, the hole is filled with the conductive paste under air or vacuum using a squeegee jig.
- the resin film 7 is peeled off (FIG. 8). By doing so, it is possible to obtain a state in which the conductive paste 9 protrudes from the opening of the second insulating base material 6 by the thickness of the resin film 7. From the above, the third laminated body 100 is obtained. Next, with respect to the plurality of third laminated bodies 100, one third laminated body 100 and the other third laminated body 100 are combined with the metal layer 2 of the first third laminated body 100 and the other third laminated body. The holes 8 of 100 are overlapped so as to face each other (FIG. 9). At this time, it is preferable to provide a non-patterned metal layer above and below the laminate made of the plurality of stacked laminates.
- a non-patterned metal layer 22 is laminated on the third laminated body 100 located at the top. Further, as the lowermost laminated body 101, a laminated body in which the patterned metal layer 2 is not arranged in the third laminated body 100 is used. Then, the metal layer 12 is arranged under the laminated body 101. Next, the plurality of stacked third laminated bodies 100 are thermocompression bonded (FIG. 10). By doing so, the metal layer 2 of one third laminated body 100 is embedded in the second insulating base material 6 of the other third laminated body 100. In addition, the conductive paste 9 is cured. In addition, the second insulating base material 6 is completely cured. That is, the second insulating base material 6 is cured to the C stage. Next, the metal layer 12 and the metal layer 22 are processed into a pattern (FIG. 11). By doing so, the circuit board is completed.
- the circuit board formed by the disclosed circuit board manufacturing method and the disclosed circuit board can be used as a motherboard (support board), as an interposer (relay board), and further, a semiconductor. It can also be used as a circuit board that constitutes an element.
- FIG. 12 shows a schematic cross-sectional view of the semiconductor package.
- the semiconductor package of FIG. 12 includes a motherboard 500 having a solder ball 550, an interposer 600 connected to the motherboard 500 via bumps 650, and a semiconductor element 700 arranged on the interposer 600.
- Examples of the semiconductor element 700 include an FPGA (Field Programmable Gate Array) chip and the like.
- the circuit board formed by the disclosed circuit board manufacturing method and the disclosed circuit board can be used as the motherboard 500 and the interposer 600 in FIG. 12, and further, a semiconductor element. It can also be used as a circuit board constituting the 700.
- a method for manufacturing a circuit board which comprises a process of superimposing on a surface and performing thermocompression bonding.
- the first insulating base material is a glass epoxy base material
- the first insulating base material is a glass epoxy base material.
- one said laminated body and the other said laminated body are placed on the surface of the metal layer of the one said laminated body and the second insulating base material of the other said laminated body.
- a circuit board characterized in that it is located opposite to an exposed via. The first insulating base material is a glass epoxy base material, and the first insulating base material is a glass epoxy base material.
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Abstract
Description
硬化済みの第1絶縁性基材と、前記第1絶縁性基材の第1表面にパターン状で形成された金属層とを有する第1積層体における前記第1絶縁性基材の前記第1表面とは反対側の第2表面上に、硬化済みではない第2絶縁性基材と、樹脂フィルムとをこの順で重ねて、熱圧着をして第2積層体を得る工程と、
前記第2積層体の前記樹脂フィルム側から、前記樹脂フィルム、前記第2絶縁性基材、及び前記第1絶縁性基材に、前記金属層に達する穴を形成した後に、前記穴に導電性ペーストを充填し、更に、前記樹脂フィルムを剥離し、第3積層体を得る工程と、
一の前記第3積層体と、他の前記第3積層体とを、一の前記第3積層体の前記金属層と、他の前記第3積層体の前記穴の開口部とが対向するように重ね、熱圧着を行う工程と、を含む。
硬化済みの第1絶縁性基材と、前記第1絶縁性基材の第1表面にパターン状で形成された金属層と、前記第1絶縁性基材の前記第1表面とは反対側の第2表面に配された硬化済みの第2絶縁性基材と、前記第2絶縁性基材の前記第1絶縁性基材側とは反対側の表面から前記金属層に達するまで形成されたビアとを有する積層体を複数有し、
複数の前記積層体のうち、一の前記積層体と、他の前記積層体とが、一の前記積層体の前記金属層と、他の前記積層体の前記第2絶縁性基材の表面に露出したビアとが対向して位置する。
また、一つの側面では、多層構造を形成するための接着層を有しない多層構造の回路基板を提供できる。
また、一つの側面では、多層構造を形成するための接着層を有しない多層構造の回路基板を用いた電子機器を提供できる。
開示の回路基板の製造方法は、第2積層体を得る工程と、第3積層体を得る工程と、熱圧着を行う工程とを少なくとも含み、更に必要に応じてその他の工程を含む。
第2積層体は、第1積層体における第1絶縁性基材の第1表面とは反対側の第2表面上に、硬化済みではない第2絶縁性基材と、樹脂フィルムとをこの順で重ねて、熱圧着を行うことで得られる。
第1積層体は、硬化済みの第1絶縁性基材と、第1絶縁性基材の第1表面にパターン状で形成された金属層とを有する。
第1絶縁性基材は、硬化済みである。
第1絶縁性基材としては、回路基板で用いられる絶縁性基材であれば、特に制限はなく、目的に応じて適宜選択することができ、例えば、ガラスクロス等を用いた無機織布、無機不織布等の無機基材、有機織布、有機不織布等の有機基材により硬度強化された基材などが挙げられる。
第1絶縁性基材としては、より具体的には、例えば、ガラスエポキシ基材(エポキシ樹脂を浸み込ませたガラス織布基材、エポキシ樹脂を浸み込ませたガラス不織布基材)、ビスマレイミドトリアジン樹脂を浸み込ませたガラス織布基材、エポキシ樹脂を浸み込ませたアラミド不織布基材、変性ポリフェニレンエーテル樹脂を浸み込ませたガラス織布基材などが挙げられる。
ここで、ガラスエポキシ基材とは、ガラス繊維の布(織布又は不織布)にエポキシ樹脂をしみ込ませて得られる基材である。
第1絶縁性基材の平均厚みとしては、特に制限はなく、目的に応じて適宜選択することができ、例えば、10μm以上200μm以下であってもよいし、30μm以上100μm以下であってもよい。
金属層を形成する金属としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、ニッケル、銅などが挙げられる。
金属層の構造としては、単層構造であってもよいし、多層構造であってもよい。金属層としては、例えば、銅の単層構造、銅とニッケルとの2層構造などが挙げられる。
金属層の表面を粗面にする方法としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、CZ処理(treatment of copper surface of zigzag)などが挙げられる。粗面の算術平均粗さ(Ra)としては、例えば、1.0μm以上2.0μm以下などが挙げられる。
第2絶縁性基材は、硬化済みではない。
第2絶縁性基材としては、回路基板で用いられる絶縁性基材であれば、特に制限はなく、目的に応じて適宜選択することができ、例えば、ガラスクロス等を用いた無機織布、無機不織布等の無機基材、有機織布、有機不織布等の有機基材により硬度強化された基材などが挙げられる。
第2絶縁性基材としては、より具体的には、例えば、ガラスエポキシ基材(エポキシ樹脂を浸み込ませたガラス織布基材、エポキシ樹脂を浸み込ませたガラス不織布基材)、ビスマレイミドトリアジン樹脂を浸み込ませたガラス織布基材、エポキシ樹脂を浸み込ませたアラミド不織布基材、変性ポリフェニレンエーテル樹脂を浸み込ませたガラス織布基材などが挙げられる。
ここで、ガラスエポキシ基材とは、ガラス繊維の布(織布又は不織布)にエポキシ樹脂をしみ込ませて得られる基材である。
ここで、同じガラスエポキシ基材であるとは、硬化済み(Cステージ)状態において、同じ特性を示すことを意味する。例えば、第1絶縁性基材であるCステージのガラスエポキシ基材と同じガラスエポキシ基材をBステージの状態で第2絶縁性基材として用いている場合、それらは、同じガラスエポキシ基材である。
第2絶縁性基材の平均厚みとしては、特に制限はなく、目的に応じて適宜選択することができ、例えば、10μm以上150μm以下であってもよいし、20μm以上100μm以下であってもよい。
樹脂フィルムとしては、熱圧着の際に溶融しない樹脂フィルムであれば、特に制限はなく、目的に応じて適宜選択することができ、例えば、ポリエチレンテレフタレートフィルム、ポリエチレンナフタレートフィルム、ポリフェニレンサルファイトフィルム、ポリイミドフィルムなどが挙げられる。
樹脂フィルムの表面を粗面にする方法としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、ブラスト加工、エンボス加工、コーティング加工などが挙げられる。粗面の算術平均粗さ(Ra)としては、例えば、1.0μm以上2.0μm以下などが挙げられる。
第2絶縁性基材は、接着層と異なり、常温及び常圧下においては、十分な接着性を有していない。そのため、熱圧着を行わないと、第1積層体と第2絶縁性基材との一時的な接着が不十分となり、他の工程において、第1積層体と第2絶縁性基材とが剥離する恐れがある。また、熱圧着を行わないと、第2絶縁性基材と樹脂フィルムとの一時的な接着が不十分となり、他の工程において、第2絶縁性基材と樹脂フィルムとが剥離する恐れがある。
すなわち、熱圧着は、第1積層体と第2絶縁性基材とが剥離しないよう、かつ第2絶縁性基材と樹脂フィルムとが意図せずに剥離しないようにするために行われることが好ましい。
温度としては、例えば、50℃以上100℃以下が挙げられる。
圧力としては、例えば、0.5MPa以上1.2MPa以下が挙げられる。
時間としては、例えば、60秒以上120秒以下が挙げられる。
第3積層体は、第2積層体の樹脂フィルム側から、樹脂フィルム、第2絶縁性基材、及び第1絶縁性基材に、金属層に達する穴を形成した後に、穴に導電性ペーストを充填し、更に、樹脂フィルムを剥離することで得られる。
穴(ビアホール)を形成する方法としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、レーザーを用いて穴を形成する方法などが挙げられる。
レーザーの出力としては、特に制限はなく、目的に応じて適宜選択することができる。
ここでの穴の大きさ(開口径)は、例えば、第2絶縁性基材の樹脂フィルム側の表面の開口径を指す。
導電性ペーストとしては、特に制限はなく、目的に応じて適宜選択することができ、例えば、金属粒子(導電性フィラー)と、バインダー樹脂とを含有する導電性ペーストなどが挙げられる。
金属粒子を構成する金属としては、例えば、銅、金、銀、パラジウム、ニッケル、錫、鉛、ビスマスなどが挙げられる。これらは、1種単独で使用してもよいし、2種以上を併用してもよい。
バインダー樹脂としては、例えば、エポキシ樹脂等といった熱硬化性樹脂などが挙げられる。ただし、バインダー樹脂はこれに限られず、例えば、ポリイミド樹脂等、他の樹脂であってもよい。
バインダー樹脂は、常温で液状であってもよいし、固体であってもよい。バインダー樹脂が常温で固体の場合には、導電性ペーストは、例えば、バインダー樹脂の溶融温度以上の温度に熱して使用される。
導電性ペーストは、例えば、バインダー樹脂、及び金属粒子を混練することで得られる。導電性ペーストは、フラックスなどを含有していてもよい。
圧接タイプとは、積層時の熱では低抵抗金属粉末(導電性フィラー)が溶融せず積層時の圧力だけで導電性フィラー同士が接触することで層間の導通接続を可能とする導電性ペーストである。圧接タイプは、導電性ペーストに含まれる樹脂が熱硬化することで流動性を失う。
溶融タイプとは、積層時の熱で低融点金属粉末(導電性フィラー)が溶融し、高融点金属粉末(導電性フィラー)を取り巻くように硬化して合金層を形成することで層間の導通接続を可能とする導電性ペーストである。
樹脂フィルムを剥離する方法としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、樹脂フィルムの端部を治具によりつかみ、第2絶縁性基材から引き離す方法などが挙げられる。
一の第3積層体と、他の第3積層体とを、一の第3積層体の金属層と、他の第3積層体の穴の開口部とが対向するように重ねて熱圧着が行われる。
温度としては、例えば、200℃以上500℃以下が挙げられる。
圧力としては、例えば、2MPa以上10MPa以下が挙げられる。
時間としては、例えば、3h以上5h以下が挙げられる。
その他の工程としては、導電ペーストの表面を硬化させる工程などが挙げられる。
回路基板の製造方法においては、第3積層体における穴から突出している導電ペーストの表面を硬化させる工程を行うことが好ましい。
穴から突出している導電ペーストの表面を硬化させることで、穴から突出している導電性ペーストの形状を維持することができる。更に、穴から突出している導電ペーストの表面を硬化させることで、一の第3積層体と、他の第3積層体とを重ねて熱圧着を行う際に、導電性ペーストが不必要に流れ広がることを避けることができる。
開示の回路基板は、積層体を複数有する。
回路基板は、複数の積層体のうち、一の積層体と、他の積層体とが、一の積層体の金属層と、他の積層体の第2絶縁性基材の表面に露出したビアとが対向して位置する。
積層体は、第1絶縁性基材と、金属層と、第2絶縁性基材と、ビアとを有する。
第1絶縁性基材は、硬化済みである。すなわち、第1絶縁性基材は、Cステージである。
第1絶縁性基材としては、回路基板で用いられる絶縁性基材であれば、特に制限はなく、目的に応じて適宜選択することができ、例えば、ガラスクロス等を用いた無機織布、無機不織布等の無機基材、有機織布、有機不織布等の有機基材により硬度強化された基材などが挙げられる。
第1絶縁性基材としては、より具体的には、例えば、ガラスエポキシ基材(エポキシ樹脂を浸み込ませたガラス織布基材、エポキシ樹脂を浸み込ませたガラス不織布基材)、ビスマレイミドトリアジン樹脂を浸み込ませたガラス織布基材、エポキシ樹脂を浸み込ませたアラミド不織布基材、変性ポリフェニレンエーテル樹脂を浸み込ませたガラス織布基材などが挙げられる。
ここで、ガラスエポキシ基材とは、ガラス繊維の布(織布又は不織布)にエポキシ樹脂をしみ込ませて得られる基材である。
第1絶縁性基材の平均厚みとしては、特に制限はなく、目的に応じて適宜選択することができ、例えば、10μm以上200μm以下であってもよいし、30μm以上100μm以下であってもよい。
金属層は、第1絶縁性基材の第1表面にパターン状で形成されている。
金属層を形成する金属としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、ニッケル、銅などが挙げられる。
金属層の構造としては、単層構造であってもよいし、多層構造であってもよい。金属層としては、例えば、銅の単層構造、銅とニッケルとの2層構造などが挙げられる。
回路基板において、第2絶縁性基材は、硬化済みである。すなわち、回路基板において、第2絶縁性基材は、例えば、Cステージである。
第2絶縁性基材としては、より具体的には、例えば、ガラスエポキシ基材(エポキシ樹脂を浸み込ませたガラス織布基材、エポキシ樹脂を浸み込ませたガラス不織布基材)、ビスマレイミドトリアジン樹脂を浸み込ませたガラス織布基材、エポキシ樹脂を浸み込ませたアラミド不織布基材、変性ポリフェニレンエーテル樹脂を浸み込ませたガラス織布基材などが挙げられる。
ここで、ガラスエポキシ基材とは、ガラス繊維の布(織布又は不織布)にエポキシ樹脂をしみ込ませて得られる基材である。
ここで、同じガラスエポキシ基材であるとは、硬化済み(Cステージ)状態において、同じ特性を示すことを意味する。例えば、第1絶縁性基材であるCステージのガラスエポキシ基材と同じガラスエポキシ基材をBステージの状態で第2絶縁性基材として用いている場合、それらは、同じガラスエポキシ基材である。
第2絶縁性基材の平均厚みとしては、特に制限はなく、目的に応じて適宜選択することができ、例えば、10μm以上150μm以下であってもよいし、20μm以上100μm以下であってもよい。
ビアは、第2絶縁性基材の第1絶縁性基材側とは反対側の表面から金属層に達するまで形成されている。
ビアとは、回路基板における積層体間の電気的接続のため、形成された穴の内部に導体を形成したものである。導体としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、導電性ペーストの硬化物、メッキなどが挙げられる。
導体が導電性ペーストの硬化物である場合、通常、穴の内部全体に導電性ペーストが充填された後、導電性ペーストを硬化させることによりビアが形成される。
導体がメッキである場合、通常、穴の内壁に電解メッキ又は無電解メッキが施されてビアが形成される。
開示の電子機器は、開示の回路基板と、電子部品とを少なくとも有し、更に必要に応じて、その他の部材を有する。
電子機器としては、特に制限はなく、目的に応じて適宜選択することができる。例えば、パソコン(ノート型パソコン、デスクトップ型パソコン)、電話機、携帯電話、タブレット型携帯端末、スマートフォン、コピー機、ファクシミリ、各種プリンター、デジタルカメラ、テレビ、ビデオ、CD装置、DVD装置、エアコン、リモコン装置などが挙げられる。
まず、第1絶縁性基材1の両面に銅箔である金属層2、3が貼り合わせられた両面銅貼基板を用意する(図1)。第1絶縁性基材1は、例えば、硬化済みのガラスエポキシ基材であり、その平均厚みは、例えば、60μmである。金属層2、3の平均厚みは、例えば、15μmである。
次に、ラミネーターを用いて、両面銅貼基板の両面にドライフィルムレジスト4、5を貼り合わせる(図2)。
次に、ドライフィルムレジスト4に対して選択的露光及び現像を行うことにより、パターン状の金属層を作成するためのレジストパターンを形成する(図3)。なお、ドライフィルムレジスト5については現像により全面溶解させる。ドライフィルムレジスト4、5としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、ポジ型ドライフィルムレジスト、ネガ型ドライフィルムレジストなどが挙げられる。選択的露光における露光波長としては、ドライフィルムレジストを感光させることができる限り、特に制限はなく、目的に応じて適宜選択することができる。現像の方法としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、アルカリ水溶液による現像などが挙げられる。
次に、パターン化されたドライフィルムレジスト4をマスクとして、金属層2、3のエッチングを行い、パターン化された金属層2を得る(図4)。エッチングの方法としては、ウェットエッチングなどが挙げられる。
以上により、第1積層体が得られる。
次に、第1積層体における第1絶縁性基材1の第1表面1Aとは反対側の第2表面1B上に、硬化済みではない第2絶縁性基材6と、樹脂フィルム7とをこの順で重ねて、熱圧着をして第2積層体を得る(図5)。熱圧着する前の第2絶縁性基材6は、例えば、Bステージのガラスエポキシ基材である。熱圧着では、第2絶縁性基材6を熱硬化させることが好ましい。ただし、熱硬化は、Cステージまでの熱硬化ではなく、Bステージにおいて更に適度に硬化が進む程度の熱硬化が好ましい。
次に、第2積層体の樹脂フィルム7側から、樹脂フィルム7、第2絶縁性基材6、及び第1絶縁性基材1に、金属層3に達する穴8を形成する(図6)。穴8の形成は、例えば、レーザーを照射することにより行うことができる。
次に、穴8に導電性ペースト9を充填する(図7)。導電性ペースト9を穴8に充填する方法としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、スキージ治具を使用し大気又は真空下で穴に導電性ペーストを充填する方法などが挙げられる。
次に、樹脂フィルム7を剥離する(図8)。そうすることにより、樹脂フィルム7の厚みの分だけ、導電性ペースト9が第2絶縁性基材6の開口から突出した状態が得られる。
以上により、第3積層体100が得られる。
次に、複数の第3積層体100について、一の第3積層体100と、他の第3積層体100とを、一の第3積層体100の金属層2と、他の第3積層体100の穴8の開口部とが対向するように重ねる(図9)。この際、重ねられた複数の積層体による積層物の上下には、パターン状ではない金属層を設けることが好ましい。例えば、最も上に位置する第3積層体100の上に、パターン状ではない金属層22を重ねる。また、最も下に位置する積層体101としては、第3積層体100においてパターン状の金属層2が配されていない積層体を用いる。そして、その積層体101の下に、金属層12を配する。
次に、重ねた複数の第3積層体100を熱圧着する(図10)。そうすることにより、一の第3積層体100の金属層2が、他の第3積層体100の第2絶縁性基材6に埋め込まれる。加えて、導電性ペースト9が硬化する。加えて、第2絶縁性基材6が完全硬化する。すなわち、第2絶縁性基材6がCステージまで硬化する。
次に、金属層12、及び金属層22をパターン状に加工する(図11)。
そうすることにより、回路基板が完成する。
ここで、開示の回路基板の製造方法により形成される回路基板、及び開示の回路基板は、図12におけるマザーボード500としても使用可能であり、インターポーザ600としても使用可能であり、更には、半導体素子700を構成する回路基板としても使用可能である。
(付記1)
硬化済みの第1絶縁性基材と、前記第1絶縁性基材の第1表面にパターン状で形成された金属層とを有する第1積層体における前記第1絶縁性基材の前記第1表面とは反対側の第2表面上に、硬化済みではない第2絶縁性基材と、樹脂フィルムとをこの順で重ねて、熱圧着をして第2積層体を得る工程と、
前記第2積層体の前記樹脂フィルム側から、前記樹脂フィルム、前記第2絶縁性基材、及び前記第1絶縁性基材に、前記金属層に達する穴を形成した後に、前記穴に導電性ペーストを充填し、更に、前記樹脂フィルムを剥離し、第3積層体を得る工程と、
一の前記第3積層体と、他の前記第3積層体とを、一の前記第3積層体の前記金属層と、他の前記第3積層体の前記穴の開口部とが対向するように重ね、熱圧着を行う工程と、を含むことを特徴とする回路基板の製造方法。
(付記2)
前記第1絶縁性基材が、ガラスエポキシ基材であり、
前記第2絶縁性基材が、ガラスエポキシ基材である付記1に記載の回路基板の製造方法。
(付記3)
前記第1絶縁性基材としての前記ガラスエポキシ基材と、前記第2絶縁性基材としての前記ガラスエポキシ基材とが、同じガラスエポキシ基材である付記2に記載の回路基板の製造方法。
(付記4)
前記第2絶縁性基材の材質が、ふっ素樹脂、ポリフェニレンエーテル樹脂、ポリイミド樹脂、及びビスマレイミドトリアジン樹脂からなる群から選択される熱硬化性樹脂である付記1に記載の回路基板の製造方法。
(付記5)
一の前記第3積層体と、他の前記第3積層体とを、熱圧着する際、一の前記第3積層体の前記金属層が、他の前記第3積層体の前記第2絶縁性基材に埋め込まれる付記1から4のいずれかに記載の回路基板の製造方法。
(付記6)
更に、前記第3積層体における前記穴から突出している前記導電ペーストの表面を硬化させる工程を含む付記1から5のいずれかに記載の回路基板の製造方法。
(付記7)
一の前記第3積層体と、他の前記第3積層体とを、一の前記第3積層体の前記金属層と、他の前記第3積層体の前記穴の開口部とが対向するように重ね、熱圧着を行う際に、前記第2絶縁性基材を完全硬化させる、付記1から6のいずれかに記載の回路基板の製造方法。
(付記8)
硬化済みの第1絶縁性基材と、前記第1絶縁性基材の第1表面にパターン状で形成された金属層と、前記第1絶縁性基材の前記第1表面とは反対側の第2表面に配された硬化済みの第2絶縁性基材と、前記第2絶縁性基材の前記第1絶縁性基材側とは反対側の表面から前記金属層に達するまで形成されたビアとを有する積層体を複数有し、
複数の前記積層体のうち、一の前記積層体と、他の前記積層体とが、一の前記積層体の前記金属層と、他の前記積層体の前記第2絶縁性基材の表面に露出したビアとが対向して位置することを特徴とする回路基板。
(付記9)
前記第1絶縁性基材が、ガラスエポキシ基材であり、
前記第2絶縁性基材が、ガラスエポキシ基材である付記8に記載の回路基板。
(付記10)
前記第1絶縁性基材としての前記ガラスエポキシ基材と、前記第2絶縁性基材としての前記ガラスエポキシ基材とが、同じガラスエポキシ基材である付記9に記載の回路基板。
(付記11)
前記第2絶縁性基材の材質が、ふっ素樹脂、ポリフェニレンエーテル樹脂、ポリイミド樹脂、及びビスマレイミドトリアジン樹脂からなる群から選択される熱硬化性樹脂の硬化物である付記8に記載の回路基板の製造方法。
(付記12)
一の前記第3積層体の前記金属層が、他の前記第3積層体の前記第2絶縁性基材に埋め込まれている付記8から11のいずれかに記載の回路基板。
(付記13)
付記1から7のいずれかに記載の回路基板と、電子部品とを有することを特徴とする電子機器。
Claims (9)
- 硬化済みの第1絶縁性基材と、前記第1絶縁性基材の第1表面にパターン状で形成された金属層とを有する第1積層体における前記第1絶縁性基材の前記第1表面とは反対側の第2表面上に、硬化済みではない第2絶縁性基材と、樹脂フィルムとをこの順で重ねて、熱圧着をして第2積層体を得る工程と、
前記第2積層体の前記樹脂フィルム側から、前記樹脂フィルム、前記第2絶縁性基材、及び前記第1絶縁性基材に、前記金属層に達する穴を形成した後に、前記穴に導電性ペーストを充填し、更に、前記樹脂フィルムを剥離し、第3積層体を得る工程と、
一の前記第3積層体と、他の前記第3積層体とを、一の前記第3積層体の前記金属層と、他の前記第3積層体の前記穴の開口部とが対向するように重ね、熱圧着を行う工程と、を含むことを特徴とする回路基板の製造方法。 - 前記第1絶縁性基材が、ガラスエポキシ基材であり、
前記第2絶縁性基材が、ガラスエポキシ基材である請求項1に記載の回路基板の製造方法。 - 前記第1絶縁性基材としての前記ガラスエポキシ基材と、前記第2絶縁性基材としての前記ガラスエポキシ基材とが、同じガラスエポキシ基材である請求項2に記載の回路基板の製造方法。
- 前記第2絶縁性基材の材質が、ふっ素樹脂、ポリフェニレンエーテル樹脂、ポリイミド樹脂、及びビスマレイミドトリアジン樹脂からなる群から選択される熱硬化性樹脂である請求項1に記載の回路基板の製造方法。
- 一の前記第3積層体と、他の前記第3積層体とを、熱圧着する際、一の前記第3積層体の前記金属層が、他の前記第3積層体の前記第2絶縁性基材に埋め込まれる請求項1から4のいずれかに記載の回路基板の製造方法。
- 更に、前記第3積層体における前記穴から突出している前記導電ペーストの表面を硬化させる工程を含む請求項1から5のいずれかに記載の回路基板の製造方法。
- 一の前記第3積層体と、他の前記第3積層体とを、一の前記第3積層体の前記金属層と、他の前記第3積層体の前記穴の開口部とが対向するように重ね、熱圧着を行う際に、前記第2絶縁性基材を完全硬化させる、請求項1から6のいずれかに記載の回路基板の製造方法。
- 硬化済みの第1絶縁性基材と、前記第1絶縁性基材の第1表面にパターン状で形成された金属層と、前記第1絶縁性基材の前記第1表面とは反対側の第2表面に配された硬化済みの第2絶縁性基材と、前記第2絶縁性基材の前記第1絶縁性基材側とは反対側の表面から前記金属層に達するまで形成されたビアとを有する積層体を複数有し、
複数の前記積層体のうち、一の前記積層体と、他の前記積層体とが、一の前記積層体の前記金属層と、他の前記積層体の前記第2絶縁性基材の表面に露出したビアとが対向して位置することを特徴とする回路基板。 - 請求項1から7のいずれかに記載の回路基板と、電子部品とを有することを特徴とする電子機器。
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| KR (1) | KR102914349B1 (ja) |
| CN (1) | CN114342574B (ja) |
| TW (1) | TWI864015B (ja) |
| WO (1) | WO2021049106A1 (ja) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| TWI751554B (zh) * | 2020-05-12 | 2022-01-01 | 台灣愛司帝科技股份有限公司 | 影像顯示器及其拼接式電路承載與控制模組 |
| KR20250096481A (ko) * | 2023-12-20 | 2025-06-27 | 주식회사 두산 | 다층 인쇄회로기판 및 이의 제조방법 |
| JP2025177964A (ja) * | 2024-05-24 | 2025-12-05 | Fict株式会社 | 多層基板、多層基板の製造方法、及び電子機器 |
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Also Published As
| Publication number | Publication date |
|---|---|
| US20220322534A1 (en) | 2022-10-06 |
| CN114342574B (zh) | 2024-03-12 |
| JP2021044332A (ja) | 2021-03-18 |
| TWI864015B (zh) | 2024-12-01 |
| KR20220061099A (ko) | 2022-05-12 |
| EP3996474A4 (en) | 2022-09-07 |
| KR102914349B1 (ko) | 2026-01-16 |
| CN114342574A (zh) | 2022-04-12 |
| JP7031955B2 (ja) | 2022-03-08 |
| TW202112197A (zh) | 2021-03-16 |
| EP3996474A1 (en) | 2022-05-11 |
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