WO2022149960A1 - 전지셀 및 이를 포함하는 전지 모듈 - Google Patents
전지셀 및 이를 포함하는 전지 모듈 Download PDFInfo
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- WO2022149960A1 WO2022149960A1 PCT/KR2022/000495 KR2022000495W WO2022149960A1 WO 2022149960 A1 WO2022149960 A1 WO 2022149960A1 KR 2022000495 W KR2022000495 W KR 2022000495W WO 2022149960 A1 WO2022149960 A1 WO 2022149960A1
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- lead film
- lead
- battery cell
- depression
- electrode
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/184—Sealing members characterised by their shape or structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/105—Pouches or flexible bags
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/172—Arrangements of electric connectors penetrating the casing
- H01M50/174—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
- H01M50/178—Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for pouch or flexible bag cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/19—Sealing members characterised by the material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/19—Sealing members characterised by the material
- H01M50/191—Inorganic material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/19—Sealing members characterised by the material
- H01M50/193—Organic material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/19—Sealing members characterised by the material
- H01M50/198—Sealing members characterised by the material characterised by physical properties, e.g. adhesiveness or hardness
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/30—Arrangements for facilitating escape of gases
- H01M50/394—Gas-pervious parts or elements
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/533—Electrode connections inside a battery casing characterised by the shape of the leads or tabs
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/186—Sealing members characterised by the disposition of the sealing members
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/534—Electrode connections inside a battery casing characterised by the material of the leads or tabs
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/547—Terminals characterised by the disposition of the terminals on the cells
- H01M50/548—Terminals characterised by the disposition of the terminals on the cells on opposite sides of the cell
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/552—Terminals characterised by their shape
- H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/552—Terminals characterised by their shape
- H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
- H01M50/557—Plate-shaped terminals
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a battery cell and a battery module including the same, and more particularly, to a battery cell with improved external emission of gas generated inside the battery cell and a battery module including the same.
- secondary batteries are of great interest not only as mobile devices such as mobile phones, digital cameras, notebooks, and wearable devices, but also as energy sources for power devices such as electric bicycles, electric vehicles, and hybrid electric vehicles.
- the electrode assembly built into the battery case is a power generating element that can be charged and discharged by having a positive electrode, a negative electrode, and a separator structure interposed between the positive electrode and the negative electrode, and a separator between the positive electrode and the negative electrode of a long sheet type coated with an active material. It is classified into a jelly-roll type, which is wound therebetween, and a stack type, in which a plurality of positive and negative electrodes are interposed in a separator and sequentially stacked.
- a pouch-type battery having a structure in which a stack-type or stack/folding-type electrode assembly is embedded in a pouch-type battery case of an aluminum laminate sheet is used gradually for reasons of low manufacturing cost, small weight, easy deformation, etc. is increasing
- FIG. 1 is a top view of a conventional battery cell.
- FIG. 2 is a cross-sectional view taken along the axis a-a' in FIG. 1 . 1 and 2, the conventional battery cell 10, the electrode assembly 11 is mounted on the receiving portion 21, the outer periphery comprising a sealing portion 25 of a sealed structure by thermal fusion.
- a battery case (20) includes an electrode lead 30 protruding outward of the battery case 20 via the sealing part 25 , and a lead film 40 between the upper and lower parts of the electrode lead 30 and the sealing part 25 . ) is located.
- An object of the present invention is to provide a battery cell with improved external emission of gas generated inside the battery cell and a battery module including the same.
- a battery cell includes: a battery case including an electrode assembly mounted on a receiving part, and a sealing part having an outer periphery sealed by thermal fusion; an electrode lead electrically connected to the electrode tab included in the electrode assembly and protruding outwardly of the battery case via the sealing part; and a lead film positioned at a portion corresponding to the sealing portion in at least one of the upper and lower portions of the electrode lead, wherein a depression is formed inside the lead film, and the depression extends through the sealing portion, However, it is closed in the lead film.
- the material constituting the inner layer may have a higher melting point than the material constituting the lead film, and may not react to the electrolyte.
- the lead film may include a polyolefin-based material.
- the inner layer may include at least one of a polyolefin-based material, a fluorine-based material, and a porous ceramic-based material.
- a length of the lead film may be greater than a width of the electrode lead.
- the depression may be located on the electrode lead.
- the depression may be positioned between an end of the electrode lead and an end of the lead film.
- a width of the lead film may be greater than a width of the sealing portion, and may be smaller than a length of the electrode lead.
- Both ends of the recessed portion may be positioned between an end of the sealing portion and an end of the lead film, respectively.
- the depression may have a rectangular shape.
- the depression portion may include a pair of first depressions and a pair of second depressions that are connected to each other, and the first depressions may extend along a protruding direction of the electrode lead, and the second depressions The portion may extend in a longitudinal direction of the sealing portion.
- the lead film may include a first lead film and a second lead film, the first lead film may be positioned above the electrode lead, and the second lead film may be positioned under the electrode lead.
- the electrode lead may be positioned between the first lead film and the second lead film, and the first lead film and the second lead film may be connected to each other.
- the depression may be positioned in at least one of the first lead film and the second lead film.
- the other end of the recessed part may be located outside the outer surface of the battery case.
- One end of the recessed part may be located inside the inner surface of the battery case.
- An area in which the depression is located outside the outer surface of the battery case may be the same as an area in which the depression is located inward than the inner surface of the battery case.
- An area in which the depression is located outside the outer surface of the battery case may be larger than an area in which the depression is located inward than the inner surface of the battery case.
- the width of the lead film surrounding the entire surface of the depression may be 2 mm or more.
- the thickness of the lead film surrounding the upper surface of the depression may be 100 to 300 ⁇ m.
- the lead film may have a gas permeability of 20 to 60 barrer at 60°C.
- the moisture penetration amount of the lead film may be 0.02 to 0.2 g for 10 years at 25 °C, 50 %RH.
- a battery module according to another embodiment of the present invention may include the above-described battery cells.
- the present invention provides a battery cell having a recessed portion formed inside a lead film and a battery module including the same, so that external emission of gas generated inside the battery cell can be improved.
- 1 is a top view of a conventional battery cell.
- FIG. 2 is a cross-sectional view taken along the axis a-a' in FIG. 1 .
- FIG 3 is a top view of the battery cell according to the present embodiment.
- FIG. 4 is a perspective view of an electrode lead included in the battery cell of FIG. 3 .
- FIG. 5 is a cross-sectional view taken along the c-c' axis in FIG. 4 .
- FIG. 6 is a cross-sectional view taken along the axis d-d' in FIG. 4 .
- FIG. 7 is a cross-sectional view taken along the axis b-b' in FIG. 3 .
- FIG. 8 is a diagram illustrating a flow in which gas generated inside a battery cell is discharged to the outside.
- FIG. 9 is an enlarged view of an electrode lead portion in the battery cell of FIG. 3 .
- FIG. 10 is a view of an electrode lead according to another embodiment in FIG. 9 .
- FIG. 11 is an enlarged view of an electrode lead according to a position of a sealing part in FIG. 9A .
- planar view it means when the target part is viewed from above, and when it is referred to as “cross-section”, it means when the cross-section obtained by cutting the target part vertically is viewed from the side.
- the pouch battery cell 100 according to an embodiment of the present invention will be described. However, here, the description will be made based on one side of both sides of the pouch battery cell 100 , but the description is not necessarily limited thereto, and the same or similar contents may be described in the case of the other side.
- FIG 3 is a top view of the battery cell according to the present embodiment.
- the battery cell 100 includes a battery case 200 , an electrode lead 300 , and a lead film 400 .
- the battery case 200 includes a sealing part 250 having a structure in which the electrode assembly 110 is mounted on the receiving part 210 and the outer periphery is sealed by thermal fusion.
- the battery case 200 may be a laminate sheet including a resin layer and a metal layer. More specifically, the battery case 200 is made of a laminate sheet, and may be composed of an outer resin layer forming the outermost layer, a barrier metal layer preventing penetration of materials, and an inner resin layer for sealing.
- the electrode assembly 110 may have a jelly-roll type (winding type), a stack type (laminated type), or a composite type (stack/folding type) structure. More specifically, the electrode assembly 110 may include an anode, a cathode, and a separator disposed therebetween.
- the electrode lead 300 and the lead film 400 will be mainly described.
- FIG. 4 is a perspective view of an electrode lead included in the battery cell of FIG. 3 .
- the electrode lead 300 is electrically connected to an electrode tab (not shown) included in the electrode assembly 110 , and is connected to the battery case 200 via the sealing part 250 . It protrudes outward.
- the lead film 400 is positioned at a portion corresponding to the sealing part 250 in at least one of the upper and lower portions of the electrode lead 300 . Accordingly, the lead film 400 may prevent a short circuit from occurring in the electrode lead 300 during thermal fusion, while improving sealing properties between the sealing part 250 and the electrode lead 300 .
- FIG. 5 is a cross-sectional view taken along the c-c' axis in FIG. 4 .
- 6 is a cross-sectional view taken along the axis d-d' in FIG. 4 .
- a depression 450 is formed inside the lead film 400 , and the depression 450 extends via the sealing part 250 . , is closed in the lead film 400 .
- the gas generated inside the battery case 200 may be discharged to the recessed part 450 according to a pressure difference between the inside of the recessed part 450 and the recessed part 450 .
- the introduced gas may be discharged toward the outside according to a pressure difference with the outside.
- the lead film 400 since the lead film 400 has the recessed part 450 closed, the recessed part 450 may not be exposed to the electrolyte inside the battery case 200 , and the airtightness and durability of the pouch can also be secured. There is this.
- FIG. 7 is a cross-sectional view taken along the axis b-b' in FIG. 3 .
- one end of the recessed part 450 may be located inside the inner surface of the battery case 200 .
- the other end of the recessed portion 450 may be located outside the outer surface of the battery case (200).
- the inner surface of the battery case 200 means the inner end of the battery of the sealing part 250 of the battery case 200 .
- the outer surface of the battery case 200 means the outer end of the battery of the sealing part 250 of the battery case 200 .
- the lead film 400 may maximize the area of the depression 450 to discharge a large amount of gas.
- the area in which the depression 450 is located outside the outer surface of the battery case 200 is equal to the area in which the depression 450 is located inward than the inner surface of the battery case 200 and may be the same.
- the area in which the depression 450 is located outside the outer surface of the battery case 200 is greater than the area in which the depression 450 is located inward than the inner surface of the battery case 200 .
- the gas discharge is proportional to the product of the gas discharge area and the pressure. Since the pressure inside the battery case 200 is greater than the pressure outside the battery case 200 , the recessed part 450 is larger than the outer surface of the battery case 200 .
- the gas generated inside the battery case 200 may be more easily discharged to the outside.
- the area in which the depression 450 is located outside the outer surface of the battery case 200 may be 40 to 80 mm 2 .
- This is a size in which about 0.5 to 3 cc of gas can be discharged per day based on an internal pressure of 1 atm at 60°C.
- the moisture penetration amount is a size that can be 0.02 to 0.2 g for 10 years at 25 °C, 50 %RH.
- the thickness H of the lead film 400 surrounding the upper and/or lower surfaces of the depression 450 may be 100 to 300 ⁇ m, or 100 to 200 ⁇ m.
- the gas inside the battery case 200 may be more easily discharged to the outside.
- the width W of the lead film 400 surrounding the front and/or rear surface of the depression 450 is 2 mm or more, or 2 mm to It may be 3 mm.
- the width of the lead film 400 surrounding the entire surface of the depression 450 is between the outer end of the battery case 200 of the depression 450 and the outer end of the battery case 200 of the lead film 400 .
- the width of the lead film 400 surrounding the rear surface of the recessed part 450 is the inner end of the battery case 200 of the recessed part 450 and the battery case of the lead film 400 .
- 200 means the maximum value of the distance between the inner ends.
- the lead film 400 surrounding the front and/or rear surface of the recessed portion 450 satisfies the above-described range, in the process in which the gas generated inside the battery case 200 is discharged to the outside, the lead It may be easier to prevent the film 400 from tearing.
- FIG. 8 is a diagram illustrating a flow in which a gas generated inside a battery cell is discharged to the outside in this embodiment.
- the gas generated inside the battery cell 100 may be discharged toward the depression 450 of the lead film 400 .
- the internal pressure of the battery cell 100 is higher than the internal pressure of the depression 450 , and the resulting pressure difference may act as a driving force of the gas.
- the inside of the recessed part 450 may be different from the external pressure due to the gas introduced from the inside of the battery cell 100 , so that the gas introduced into the recessed part 450 may be discharged to the outside. .
- the gas generated inside the battery cell 100 may be discharged toward the depression 450 , and the gas introduced into the depression 450 may be easily discharged toward the outside.
- the external discharge amount of the gas generated inside the battery cell 100 may also be increased.
- the gas generated inside the battery case 200 may be discharged along the Z-axis direction through the depression 450 and the lead film 400 surrounding the upper surface of the depression.
- the gas generated inside the battery case 200 passes through the recessed part 450 and the lead film 400 surrounding the upper surface of the recessed part on the Z axis. It can be ejected along the direction.
- the gas permeability (permeability) of the lead film 400 is 20 to 60 barrer, or 30 to 40 at 60 °C It can be a barrer.
- the carbon dioxide permeability of the lead film 400 may satisfy the above-described range.
- the gas permeability based on the thickness of the lead film 400 200 ⁇ m may satisfy the above-described range at 60 °C. When the gas permeability of the lead film 400 satisfies the above-described range, it may be more effective to discharge the gas generated inside the secondary battery.
- gas permeability may be measured by ASTM F2476-20.
- the moisture penetration amount of the lead film 400 may be 0.02 to 0.2 g, or 0.02 to 0.04 g, or 0.06 g or 0.15 g for 10 years at 25° C. and 50 %RH.
- the moisture penetration amount of the lead film 400 satisfies the aforementioned range, it may be more effective to prevent penetration of moisture flowing from the lead film 400 .
- the lead film 400 may have a gas permeability (permeability) of 20 to 60 barrer at 60 °C and a moisture penetration amount of 0.02 to 0.2 g at 25 °C, 50 %RH for 10 years.
- gas permeability and moisture penetration amount of the lead film 400 satisfy the above-described ranges, it may be more effective to prevent moisture penetration from the outside while discharging the gas generated inside the secondary battery.
- the moisture penetration amount of the lead film 400 may be measured by adopting the ASTM F 1249 method. At this time, it can be measured using equipment officially certified by MCOON.
- the lead film 400 may include a polyolefin-based resin.
- the lead film 400 may include a polyolefin-based resin satisfying the above-described gas permeability and/or moisture permeation value.
- the polyolefin-based resin may include at least one material selected from the group consisting of polypropylene, polyethylene, and polyvinyldifluoride (PVDF).
- PVDF polyvinyldifluoride
- the gas permeability of the lead film 400 may be 20 to 60 barrer at 60°C.
- the moisture penetration amount may be 0.06 g to 0.15 g. In this case, the gas generated inside the secondary battery may be more effectively discharged, and it may be easy to prevent the penetration of moisture from the outside.
- the lead film 400 is made of the above-described material, it is possible to maintain the airtightness of the battery cell 100, it is also possible to prevent leakage of the internal electrolyte.
- the lead film 400 may further include an inner layer 410 covering at least one of the inner surfaces of the recessed portion 450 .
- the inner layer 410 in the depression 450 may cover the entire surface of the lead film 400 . That is, the inner layer 410 may be formed on the entire inner surface of the depression 450 .
- the recessed part 450 is thermally fused by the inner layer 410 . It can be preserved untouched.
- the inner layer 410 may cover an upper surface or a lower surface of the inner surfaces of the recessed part 450 . That is, the recessed portion 450 may have an inner layer 410 formed on at least one of the upper and lower surfaces facing each other.
- the inner layer 410 formed in the depression 450 may be minimized, and the depression 450 may be preserved in a non-thermal-sealed state by the inner layer 410 .
- the manufacturing process can be simplified and the cost can be reduced.
- the inner layer 410 may be made of a material having a higher melting point than the material constituting the lead film 400 .
- the inner layer 410 may be made of a material that does not react to the electrolyte contained in the battery case 200 . Accordingly, the inner layer 410 is made of the above-described material, and without a separate reaction with the electrolyte, thermal fusion, thermal deformation, etc. do not occur during the high temperature thermal fusion process, so that the recessed portion 450 is kept blank. can be In addition, the gas generated in the battery case 200 can be easily discharged to the outside.
- the thickness of the inner layer 410 may be 100 ⁇ m or less.
- the gas permeability (permeability) of the inner layer 410 may be 40 barrer or more.
- the carbon dioxide permeability of the inner layer 410 may satisfy the above-described range.
- the inner layer 410 may include at least one of a polyolefin-based material, a fluorine-based material, and a porous ceramic-based material.
- the inner layer 410 may include at least one of a polyolefin-based material, a fluorine-based material, and a porous ceramic-based material satisfying the above-described gas permeability value.
- the polyolefin-based material may include at least one material selected from the group consisting of polypropylene, polyethylene, and polyvinyldifluoride (PVDF).
- the fluorine-based material may include at least one material selected from the group consisting of polytetrafluoroethylene and polyvinylidene fluoride.
- the inner layer 410 includes a getter material, gas permeability can be increased while water permeability can be minimized.
- the getter material may be calcium oxide (CaO), barium oxide (BaO), lithium chloride (LiCl), silica (SiO 2 ), etc., but is not limited thereto, and reacts with water (H 2 O). Any material can be used.
- the inner layer 410 may include an adhesive material between the lead film 400 and the inner layer 410 or may be extruded together with the lead film 400 to adhere to the lead film 400 .
- the adhesive material may include an acrylic type.
- the gas permeability of the inner layer 410 may be 40 barrer or more.
- FIG. 9 is an enlarged view of an electrode lead portion in the battery cell of FIG. 3 .
- 10 is a view of an electrode lead according to another embodiment in FIG. 9 .
- FIG. 11 is an enlarged view of an electrode lead according to a position of a sealing part in FIG. 9A .
- the depression 450 may be formed at various positions with respect to the electrode lead 300 .
- the depression 450 may be positioned on the electrode lead 300 . More specifically, the depression 450 may be formed at a position corresponding to the center of the electrode lead 300 .
- the length of the lead film 400 may be greater than the width of the electrode lead 300 , and the recessed portion 450 is an end of the electrode lead 300 . and the end of the lead film 400 .
- the length of the lead film 400 means the maximum value of the distance between one end and the other end of the lead film 400 in a direction orthogonal to the protruding direction of the electrode lead 300
- the width of the electrode lead 300 is It means the maximum value of the distance between one end and the other end of the electrode lead 300 in a direction orthogonal to the protruding direction of the electrode lead 300 .
- the depression 450 may be formed at a position avoiding the electrode lead 300 .
- the position of the depression 450 is not limited to the above description, and may be formed at an appropriate position within the lead film 400 .
- the size of the recessed part 450 may be adjusted according to the position of the recessed part 450 , thereby simplifying the manufacturing process and reducing the cost.
- the depression 450 may be formed in various shapes.
- the depression 450 includes a pair of first depressions and a pair of second depressions that are connected to each other as shown in FIG. 9 , and the first depressions determine the protrusion direction of the electrode lead 300 .
- the second recessed part may extend along the longitudinal direction of the sealing part 250 .
- the longitudinal direction of the sealing part 250 refers to a direction perpendicular to the protrusion direction of the electrode lead 300 .
- the depression 450 may have a rectangular shape as shown in FIG. 10 .
- the width of the lead film 400 may be greater than the width of the sealing part 250 , but may be smaller than the length of the electrode lead 300 .
- the width of the lead film 400 means the maximum value of the distance between one end and the other end of the lead film in the protruding direction of the electrode lead 300 .
- the width of the sealing part 250 means the maximum value of the distance between one end and the other end of the sealing part 250 in the protruding direction of the electrode lead 300 .
- the length of the electrode lead 300 means the maximum value of the distance between one end and the other end of the electrode lead 300 in the protruding direction of the electrode lead 300 .
- both ends of the recessed part 450 may be positioned between the end of the sealing part 250 and the end of the lead film 400 , respectively.
- the shape of the depression 450 is not limited to the above description, and may be formed in an appropriate shape within the lead film 400 .
- the durability and airtightness of the lead film 400 can be controlled by adjusting the shape of the depression 450 formed in the lead film 400 .
- the manufacturing process may be simplified and cost may be reduced.
- one surface adjacent to the outside in the depression 450 may be formed adjacent to the end of the lead film 400 . Comparing FIGS. 11 (a) and (b), even if the position of the sealing part 250 in contact with the lead film 400 is changed, it can be confirmed that the depression part 450 does not have an effect on one surface adjacent to the outside. .
- FIG. 11 relates to the depression 450 having the shape of FIG. 9 , the same description may be applied to the case of FIG. 10 .
- one surface adjacent to the outside of the recessed part 450 is the battery case 200 . It is possible to maintain a uniform area located outside the , and an area in which the gas in the battery case 200 introduced into the depression 450 can be discharged to the outside can also be maintained uniformly. Accordingly, there is an advantage that the gas exhaust effect by the depression 450 can also be maintained.
- the lead film 400 includes a first lead film and a second lead film, the first lead film is located on the electrode lead 300 , and the second lead film is It may be located under the electrode lead 300 .
- the electrode lead 300 is heat-sealed together with the sealing part 250 in a state located between the first lead film and the second lead film, so that the first lead film and the second lead film are connected to each other. may have been
- the lead film 400 may prevent the side surface of the electrode lead 300 from being exposed to the outside, while improving the sealing properties of the sealing part 250 and the electrode lead 300 .
- the depression 450 may be located in at least one of the first lead film and the second lead film. More specifically, in the lead film 400 , the depression 450 is formed in the first lead film or the second lead film based on the electrode lead 300 , or the depression 450 is formed in the electrode lead ( 300) may be formed on both the first lead film and the second lead film.
- the number of the depressions 450 is not limited to the above description, and may be formed in an appropriate number in the lead film 400 .
- the manufacturing process may be simplified and cost may be reduced.
- the recessed portion 450 may be partially expanded toward the upper and lower portions as compared to FIG. 7 by the gas inside the battery cell 100 .
- the degree of expansion may be relatively small, and thus the deformation of the component may also be small.
- a battery module according to another embodiment of the present invention includes the battery cells described above. Meanwhile, one or more battery modules according to the present embodiment may be packaged in a pack case to form a battery pack.
- the above-described battery module and battery pack including the same may be applied to various devices.
- a device may be applied to transportation means such as an electric bicycle, an electric vehicle, and a hybrid vehicle, but the present invention is not limited thereto and is applicable to various devices that can use a battery module and a battery pack including the same. belong to the scope of the invention.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Gas Exhaust Devices For Batteries (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
Description
Claims (24)
- 전극조립체가 수납부에 장착되되, 외주변이 열융착에 의해 밀봉된 구조의 실링부를 포함하는 전지케이스;상기 전극조립체에 포함된 전극 탭과 전기적으로 연결되되, 상기 실링부를 경유하여 상기 전지케이스의 외측 방향으로 돌출되어 있는 전극 리드; 및상기 전극 리드의 상부 및 하부 중 적어도 하나에서, 상기 실링부에 대응되는 부분에 위치하는 리드 필름을 포함하고,상기 리드 필름 내부에 함몰부가 형성되어 있고,상기 함몰부는 상기 실링부를 경유하여 연장되어 있되, 상기 리드 필름 내에 폐쇄되어 있는 전지셀.
- 제1항에서,상기 리드 필름의 함몰부 내면 중 적어도 일면을 덮는 내부층을 더 포함하는 전지셀.
- 제2항에서,상기 내부층을 이루는 소재는, 상기 리드 필름을 이루는 소재 대비하여 녹는점이 높고, 전해액에 반응하지 않는 전지셀.
- 제1항에서,상기 리드 필름은 폴리올레핀 계열의 물질을 포함하는 전지셀.
- 제3항에서,상기 내부층은 폴리올레핀 계열, 불소 계열, 및 다공성 세라믹 계열 중 적어도 하나의 물질을 포함하는 전지셀.
- 제1항에서,상기 리드 필름의 길이는 상기 전극 리드의 폭보다 큰 전지셀.
- 제1항에서,상기 함몰부는 상기 전극 리드 상에 위치하는 전지셀.
- 제6항에서,상기 함몰부는 상기 전극 리드의 단부와 상기 리드 필름의 단부 사이에 위치하는 전지셀.
- 제1항에서,상기 리드 필름의 폭은 상기 실링부의 폭보다 크되, 상기 전극 리드의 길이보다 작은 전지셀.
- 제9항에서,상기 함몰부의 양단부는 각각 상기 실링부의 단부와 상기 리드 필름의 단부 사이에 위치하는 전지셀.
- 제10항에서,상기 함몰부는 직사각형 형상을 가지는 전지셀.
- 제10항에서,상기 함몰부는 서로 연결되어 있는 한 쌍의 제1 함몰부 및 한 쌍의 제2 함몰부를 포함하고,상기 제1 함몰부는 상기 전극 리드의 돌출 방향을 따라 연장되어 있고,상기 제2 함몰부는 상기 실링부의 길이 방향을 따라 연장되어 있는 전지셀.
- 제1항에서,상기 리드 필름은 제1 리드 필름 및 제2 리드 필름을 포함하고,상기 제1 리드 필름은 상기 전극 리드의 상부에 위치하고,상기 제2 리드 필름은 상기 전극 리드의 하부에 위치하는 전지셀.
- 제13항에서,상기 전극 리드는 상기 제1 리드 필름과 상기 제2 리드 필름 사이에 위치하되, 상기 제1 리드 필름과 상기 제2 리드 필름은 서로 연결되어 있는 전지셀.
- 제14항에서,상기 제1 리드 필름과 상기 제2 리드 필름 중 적어도 하나에 상기 함몰부가 위치하는 전지셀.
- 제1항에서,상기 함몰부의 타단부는 상기 전지케이스의 외측면보다 외측에 위치하는 전지셀.
- 제16항에서,상기 함몰부의 일단부는 상기 전지케이스의 내측면보다 내측에 위치하는 전지셀.
- 제16항에서,상기 함몰부가 상기 전지케이스의 외측면보다 외측에 위치하는 면적이 함몰부가 전지케이스의 내측면보다 내측에 위치하는 면적과 동일한 전지셀.
- 제16항에서,상기 함몰부가 상기 전지케이스의 외측면보다 외측에 위치하는 면적이 함몰부가 전지케이스의 내측면보다 내측에 위치하는 면적보다 큰 전지셀.
- 제1항에서,상기 전극 리드의 돌출 방향을 기준으로,상기 함몰부의 전면을 감싸는 리드 필름의 폭이 2 mm 이상인 전지셀.
- 제1항에서,상기 함몰부의 상면을 감싸는 리드 필름의 두께가 100 내지 300 ㎛인 전지셀.
- 제1항에서,상기 리드 필름의 가스 투과도(permeability)가 60℃에서 20 내지 60 barrer인 전지셀.
- 제1항에서,상기 리드 필름의 수분 침투량이 25℃, 50 %RH에서 10년간 0.02 내지 0.2 g인 전지셀.
- 제1항에 따른 전지셀을 포함하는 전지 모듈.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17/923,137 US12500297B2 (en) | 2021-01-11 | 2022-01-11 | Battery cell and battery module including the same |
| JP2022566249A JP7498302B2 (ja) | 2021-01-11 | 2022-01-11 | 電池セル及びそれを含む電池モジュール |
| CN202280002856.5A CN115191057B (zh) | 2021-01-11 | 2022-01-11 | 电池单元及包括该电池单元的电池模块 |
| EP22736937.8A EP4178015B1 (en) | 2021-01-11 | 2022-01-11 | Battery cell and battery module including same |
| CN202510003588.4A CN119764699A (zh) | 2021-01-11 | 2022-01-11 | 电池单元及包括该电池单元的电池模块 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20210003185 | 2021-01-11 | ||
| KR10-2021-0003185 | 2021-01-11 |
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| Publication Number | Publication Date |
|---|---|
| WO2022149960A1 true WO2022149960A1 (ko) | 2022-07-14 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/KR2022/000495 Ceased WO2022149960A1 (ko) | 2021-01-11 | 2022-01-11 | 전지셀 및 이를 포함하는 전지 모듈 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US12500297B2 (ko) |
| EP (1) | EP4178015B1 (ko) |
| JP (1) | JP7498302B2 (ko) |
| KR (1) | KR102748203B1 (ko) |
| CN (2) | CN115191057B (ko) |
| WO (1) | WO2022149960A1 (ko) |
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| WO2024142565A1 (ja) * | 2022-12-26 | 2024-07-04 | 株式会社豊田自動織機 | 蓄電モジュール |
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- 2022-01-11 CN CN202510003588.4A patent/CN119764699A/zh active Pending
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| US12132215B2 (en) | 2021-01-11 | 2024-10-29 | Lg Energy Solution, Ltd. | Battery cell and battery module including the same |
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Also Published As
| Publication number | Publication date |
|---|---|
| US12500297B2 (en) | 2025-12-16 |
| EP4178015A1 (en) | 2023-05-10 |
| JP2023524709A (ja) | 2023-06-13 |
| EP4178015B1 (en) | 2026-03-04 |
| JP7498302B2 (ja) | 2024-06-11 |
| KR102748203B1 (ko) | 2024-12-31 |
| US20230178830A1 (en) | 2023-06-08 |
| CN115191057A (zh) | 2022-10-14 |
| EP4178015A4 (en) | 2024-10-30 |
| CN119764699A (zh) | 2025-04-04 |
| CN115191057B (zh) | 2025-01-10 |
| KR20220101578A (ko) | 2022-07-19 |
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