WO2024192011A1 - Formulation d'huile de moteur compatible avec un système de post-traitement - Google Patents

Formulation d'huile de moteur compatible avec un système de post-traitement Download PDF

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Publication number
WO2024192011A1
WO2024192011A1 PCT/US2024/019553 US2024019553W WO2024192011A1 WO 2024192011 A1 WO2024192011 A1 WO 2024192011A1 US 2024019553 W US2024019553 W US 2024019553W WO 2024192011 A1 WO2024192011 A1 WO 2024192011A1
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WO
WIPO (PCT)
Prior art keywords
koh
ppm
lubricating oil
oil composition
detergent
Prior art date
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Ceased
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PCT/US2024/019553
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English (en)
Inventor
David S. Lee
Ramoun Mourhatch
Michael Mclaughlin
Patrick Bohan
Taiki Hattori
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Chevron Oronite Co LLC
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Chevron Oronite Co LLC
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Priority to CN202480022805.8A priority Critical patent/CN120981554A/zh
Priority to JP2025553665A priority patent/JP2026508618A/ja
Priority to KR1020257034023A priority patent/KR20250161009A/ko
Priority to EP24717501.1A priority patent/EP4680703A1/fr
Publication of WO2024192011A1 publication Critical patent/WO2024192011A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26—Overbased carboxylic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26—Overbased carboxylic acid salts
    • C10M2207/262—Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbased sulfonic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/38—Catalyst protection, e.g. in exhaust gas converters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines

Definitions

  • This disclosure relates to engine oil formulations. More specifically, this disclosure relates to engine oil formulations designed to reduce emissions from an internal combustion engine.
  • Aftertreatment system is a method or device that aims to reduce harmful exhaust emissions from internal combustion engines.
  • Some aftertreatment systems may employ a diesel particulate filter (DPF) which trap emission particles.
  • DPF diesel particulate filter
  • SCR selective catalytic reduction
  • NO X tailpipe nitrogen oxide
  • N2 diatomic nitrogen
  • Potential drawbacks of SCR are its susceptibility to plugging and poisoning from soot and ash. In particular, the presence of metals from engine oil can poison the catalysts used in selective catalytic reduction.
  • a method of reducing catalyst poisoning in a diesel engine aftertreatment system comprising a selective catalytic reduction device, the method comprising: lubricating the engine with a lubricating oil composition comprising: a major amount of oil of lubricating viscosity; and a detergent system comprising at least one magnesium-containing detergent or at least one magnesium-containing detergent and at least one calcium-containing detergent.
  • a method of reducing catalyst poisoning in a diesel engine aftertreatment system comprising a selective catalytic reduction device, the method comprising: lubricating the engine with a lubricating oil composition comprising: a major amount of oil of lubricating viscosity; and a detergent system comprising Mg detergent or Mg detergent and at least one calcium-containing detergent, wherein the lubricating oil composition is devoid of Ca sulfonate.
  • a lubricating oil composition to reduce catalyst poisoning in a diesel engine aftertreatment system comprising a selective catalytic reduction device, the lubricating oil composition comprising: a major amount of oil of lubricating viscosity; and a detergent system comprising at least one magnesium-containing detergent or at least one magnesium- containing detergent and at least one calcium-containing detergent.
  • Aftertreatment systems may feature selective catalytic reduction which is a means of converting nitrogen oxide (NO X ) with the aid of a catalyst into diatomic nitrogen (N2) and water (H2O).
  • NO X nitrogen oxide
  • N2O diatomic nitrogen
  • H2O water
  • This reduction chemistry takes place as exhaust gases pass through a catalyst chamber.
  • a reductant is injected and mixed with the exhaust gases.
  • the reductant typically ammonia
  • its precursors e.g., aqueous ammonia, urea
  • Catalysts include oxides of base metals (such as molybdenum and tungsten), zeolites, metals, or activated carbon.
  • the present disclosure relates to a lubricating oil composition formulated to enhance or improve the performance of an aftertreatment system, particularly one that is equipped with selective catalytic reduction system.
  • the specific formulation of these lubricating oil compositions is critical because metals from commonly used lubricant additives such as detergents (e.g., salicylates, sulfonates, phenates) or anti-wear agents (e.g., zinc dithiophosphates) are considered catalyst poisoning compounds.
  • the lubricating oil composition of this disclosure reduces harmful emissions by reducing the poisoning of catalysts which are used to convert harmful emissions into less harmful compounds.
  • the lubricating oil composition improves the performance of the selective catalytic reduction system.
  • the present disclosure provides a method for reducing catalyst poisoning in a diesel engine equipped with an aftertreatment system comprising a selective catalytic reduction system. In some embodiments, the present disclosure provides a method for improving the performance of a diesel engine equipped with an aftertreatment system comprising a selective catalytic reduction system. In some embodiments, the present disclosure provides a use of a lubricating oil composition for a diesel engine equipped with an aftertreatment system comprising a selective catalytic reduction system.
  • the method of this disclosure involves lubricating the engine with a lubricating composition comprising a major amount of oil of lubricating viscosity and a detergent system comprising a mixture of detergents, wherein the mixture includes least one magnesium-containing detergent and at least one calcium-containing detergent.
  • the lubricating oil composition of this disclosure includes a detergent system.
  • the detergent system includes at least one magnesium-containing detergent or at least one magnesium-containing detergent and at least one calcium-containing detergent.
  • the lubricating oil composition comprising the detergent system can unexpectedly improve the ATS conversion rate or the efficiency of NO X conversion.
  • a typical detergent is an anionic material that contains a long chain hydrophobic portion of the molecule and a smaller anionic or oleophobic hydrophilic portion of the molecule.
  • metal detergents can be described as salts. Salts that contain stoichiometric amount of the metal are described as neutral salts and have a total base number (TBN) of from 0 to 80 mg KOH/g as measured by ASTM D-2896.
  • TBN total base number
  • Many detergents are overbased, containing large amounts of a metal base that is achieved by reacting an excess of a metal compound (e.g., a metal hydroxide or oxide) rich an acidic gas (e.g., carbon dioxide).
  • a metal compound e.g., a metal hydroxide or oxide
  • an acidic gas e.g., carbon dioxide
  • Useful detergents can be neutral or overbased (including low overbased, medium overbased, and/or high overbased). Overbased detergents help neutralize acidic impurities produced by the combustion process and entrapped in the oil. The degree of overbasing generally depends on the ratio of metallic ion to anionic portion of the detergent on an equivalent basis.
  • An overbased detergent will typically have a TBN of 10 mg KOH/g or higher as measured by ASTM D-2896, such as from 15 mg KOH/g or higher, 25 mg KOH/g or higher, 50 mg KOH/g or higher, 75 mg KOH/g or higher, 100 mg KOH/g or higher, 125 mg KOH/g or higher, 150 mg KOH/g or higher, 175 mg KOH/g or higher, 200 mg KOH/g or higher, 225 mg KOH/g or higher, 250 mg KOH/g or higher, 275 mg KOH/g or higher, 300 mg KOH/g or higher, 325 mg KOH/g or higher, 350 mg KOH/g or higher, 375 mg KOH/g or higher, 400 mg KOH/g or higher, 425 mg KOH/g or higher, 450 mg KOH/g or higher, 475 mg KOH/g or higher, 500 mg KOH/g or higher, 525 mg KOH/g or higher, 550 mg KOH/g or higher,
  • the overbased detergent has a TBN of 10 to 650 mg KOH/g as measured by ASTM D-2896, such as 10 to 600 mg KOH/g, 10 to 550 mg KOH/g, 10 to 500 mg KOH/g, 10 to 450 mg KOH/g, 10 to 400 mg KOH/g, 10 to 350 mg KOH/g, 10 to 300 mg KOH/g, 10 to 250 mg KOH/g, 10 to 200 mg KOH/g, 10 to 150 mg KOH/g, 10 to 100 mg KOH/g, 10 to 50 mg KOH/g, 50 to 650 mg KOH/g, 50 to 600 mg KOH/g, 50 to 550 mg KOH/g, 50 to 500 mg KOH/g, 50 to 450 mg KOH/g, 50 to 400 mg KOH/g, 50 to 350 mg KOH/g, 50 to 300 mg KOH/g, 50 to 250 mg KOH/g, 50 to 200 mg KOH/g, 50 to 150 mg KOH/g, 50 to 100
  • the overbased detergent has a TBN of 10 to 150 mg KOH/g, such as from 10 to 140 mg KOH/g, 10 to 130 mg KOH/g, 10 to 120 mg KOH/g, 10 to 110 mg KOH/g, 10 to 100 mg KOH/g, 10 to 90 mg KOH/g, 10 to 80 mg KOH/g, 10 to 70 mg KOH/g, 10 to 60 mg KOH/g, 10 to 50 mg KOH/g, 10 to 40 mg KOH/g, 10 to 30 mg KOH/g, 10 to 20 mg KOH/g, 20 to 150 mg KOH/g, 20 to 140 mg KOH/g, 20 to 130 mg KOH/g, 20 to 120 mg KOH/g, 20 to 110 mg KOH/g, 20 to 100 mg KOH/g, 20 to 90 mg KOH/g, 20 to 80 mg KOH/g, 20 to 70 mg KOH/g, 20 to 60 mg KOH/g, 20 to 50 mg KOH/g, 20 to 40 mg KOH/g, 10 to 30 mg KOH/
  • Salicylate detergents may be prepared by reacting a basic metal compound with at least one carboxylic acid and removing water from the reaction product.
  • Useful salicylates include hydrocarbyl-substituted salicylic acid such as long chain alkyl salicylates.
  • hydrocarbyl refers to a chemical group or moiety derived from hydrocarbons including saturated and unsaturated hydrocarbons. Examples of hydrocarbyl groups include alkenyl, alkyl, polyalkenyl, polyalkyl, phenyl, and the like.
  • Hydrocarbyl-substituted salicylic acids may be prepared from phenols by the Kolbe reaction (see U.S. Patent No. 3,595,791).
  • the metal salts of the hydrocarbyl- substituted salicylic acids may be prepared by double decomposition of a metal salt in a polar solvent such as water or alcohol.
  • the calcium salicylate may be present in an amount to provide about 500 to about 5000 ppm of calcium to the lubricating oil composition, such as from about 500 to about 4500 ppm, 500 to 4000 ppm, 500 to 3500 ppm, 500 to 3000 ppm, 500 to 2500 ppm, 500 to 2000 ppm, 500 to 1500 ppm, 500 to 1000 ppm, 1000 to 5000 ppm, 1000 to 4500 ppm, 1000 to 4000 ppm, 1000 to 3500 ppm, 1000 to 3000 ppm, 1000 to 2500 ppm, 1000 to 2000 ppm, 1000 to 1500 ppm, 1500 to 5000 ppm, 1500 to 4500 ppm, 1500 to 4000 ppm, 1500 to 3500 ppm, 1500 to 3000 ppm, 1500 to 2500 ppm, 1500 to 2000 ppm, 2000 to 5000 ppm, 2500 to 4500 ppm, 2500 to 4000 ppm, 1500 to 3500 ppm, 1500 to 3000
  • the ppm values are based on total weight of the lubricating oil composition.
  • the hydrocarbyl-substituted salicylate is a long chain alkyl salicylate represented by the following generalized structure:
  • R" is a C1 to C30 (e.g., C 13 to C30) alkyl group; n is an integer from 1 to 4; and M is an alkaline earth metal (e.g., Ca or Mg).
  • the salicylate is derived from C10-C40 isomerized normal alpha olefins (NAO) and is made from an alkylphenol with an alkyl group derived from an isomerized NAO having an isomerization level (i) from about 0.10 to about 0.40, from about 0.10 to about 0.35, preferably from about 0.10 to about 0.30, from about 0.12 to about 0.30, from about 0.12 to about 0.25, from about 0.12 to about 0.23, from about 0.12 to about 0.22, from about 0.12 to about 0.20, from about 0.13 to about 0.19, from about 0.14 to about 0.18, from about 0.15 to about 0.17.
  • NAO normal alpha olefins
  • the lubricating oil composition may include Ca phenate detergent. Any phenate compatible with the present invention may be used.
  • conventional phenate detergents include alkyl phenols which are used to prepare sulfurized metal alkyl phenate.
  • the sulfurized metal alkyl phenate can be used as a detergent additive in lubricating oil compositions.
  • a sulfurized metal alkyl phenate can be prepared by (1) neutralizing an alkyl phenol with a base (e.g., calcium hydroxide) in the presence of a glycol promoter to form an metal alkyl phenate (e.g., alkyl calcium phenate); (2) sulfurizing the metal alkyl phenate with sulfur to crosslink the aromatic rings of the metal alkyl phenate to form a sulfurized metal alkyl phenate; and (3) overbasing the crosslinked sulfurized metal alkyl phenate with carbon dioxide to increase the total base number (TBN) of the product.
  • a base e.g., calcium hydroxide
  • the calcium phenate may be present in an amount to provide about 500 to about 5000 ppm of calcium to the lubricating oil composition, such as from about 500 to about 4500 ppm, 500 to 4000 ppm, 500 to 3500 ppm, 500 to 3000 ppm, 500 to 2500 ppm, 500 to 2000 ppm, 500 to 1500 ppm, 500 to 1000 ppm, 1000 to 5000 ppm, 1000 to 4500 ppm, 1000 to 4000 ppm, 1000 to 3500 ppm, 1000 to 3000 ppm, 1000 to 2500 ppm, 1000 to 2000 ppm, 1000 to 1500 ppm, 1500 to 5000 ppm, 1500 to 4500 ppm, 1500 to 4000 ppm, 1500 to 3500 ppm, 1500 to 2500 ppm,
  • the lubricating oil composition may include Mg sulfonate detergent. Any sulfonate compatible with the present invention may be used.
  • sulfonate detergents are obtained from monoalkylates of aromatics (e.g., benzene, toluene, etc.). Other sulfonate detergents can have dialkylates. Still other sulfonate detergents can have a mixture of monoalkylates and dialkylates. The resulting alkylated group or groups can be linear or branched.
  • US 6,479,440 describes a process for making alkylaryl sulfonate detergents, the contents of which are hereby incorporated by reference.
  • the magnesium sulfonate may be present in an amount to provide about 500 to about 5000 ppm of magnesium to the lubricating oil composition, such as from about 500 to about 4500 ppm, 500 to 4000 ppm, 500 to 3500 ppm, 500 to 3000 ppm, 500 to 2500 ppm, 500 to 2000 ppm, 500 to 1500 ppm, 500 to 1000 ppm, 1000 to 5000 ppm, 1000 to 4500 ppm, 1000 to 4000 ppm, 1000 to 3500 ppm, 1000 to 3000 ppm, 1000 to 2500 ppm, 1000 to 2000 ppm, 1000 to 1500 ppm, 1500 to 5000 ppm, 1500 to 4500 ppm, 1500 to 4000 ppm, 1500 to 3500 ppm, 1500 to 3000 ppm, 1500 to 2500 ppm, 1500 to 2000 ppm, 2000 to 5000 ppm, 2500 to 4500 ppm, 1500 to 4000 ppm, 1500 to 3500 ppm, 1500 to
  • the lubricating oil composition is devoid of Ca sulfonate. In some embodiments, the lubricating oil composition contains about 50 or less ppm of Ca sourced from Ca sulfonate.
  • the present lubricating oil compositions may also contain conventional lubricant additives for imparting auxiliary functions to give a finished lubricating oil composition in which these additives are dispersed or dissolved.
  • the lubricating oil compositions can be blended with antioxidants, ashless dispersants, anti-wear agents, rust inhibitors, dehazing agents, demulsifying agents, friction modifiers, metal deactivating agents, pour point depressants, viscosity modifiers, antifoaming agents, co-solvents, package compatibilizers, corrosion-inhibitors, dyes, extreme pressure agents and the like and mixtures thereof.
  • a variety of the additives are known and commercially available. These additives, or their analogous compounds, can be employed for the preparation of the lubricating oil compositions of the invention by the usual blending procedures.
  • each of the foregoing additives when used, is used at a functionally effective amount to impart the desired properties to the lubricant.
  • a functionally effective amount of this ashless dispersant would be an amount sufficient to impart the desired dispersancy characteristics to the lubricant.
  • the concentration of each of these additives, when used may range, unless otherwise specified, from about 0.001 to about 20 wt. %, such as about 0.01 to about 10 wt. %.
  • the lubricating oil composition of the present invention may optionally include nitrogen-containing dispersants. These include polyalkenyl succinimide dispersants such as those described herein.
  • the nitrogen content from the nitrogen-containing dispersant based on the lubricating oil composition is from about 0.010 wt % to about 0.30 wt % such as from about 0.050 to about 0.25 wt %, about 0.050 to about 0.20 wt %, and about 0.050 to about 0.15 wt %.
  • a polyalkenyl bis-succinimide can be obtained by reacting a polyalkenyl-substituted succinic anhydride below o wherein R is a polyalkenyl substituent is derived from a polyalkene group having a number average molecular weight of from about 500 to about 3000, with a polyamine.
  • R is a polyalkenyl substituent derived from a polyalkene group having a number average molecular weight of from about 1000 to about 2500.
  • R is a polyisobutenyl substituent derived from a polyisobutene having a number average molecular weight of from about 500 to about 3000.
  • R is a polyisobutenyl substituent derived from a polyisobutene having a number average molecular weight of from about 1000 to about 2500.
  • Suitable polyamines for use in preparing the bis-succinimide dispersants include polyalkylene polyamines. Such polyalkylene polyamines will typically contain about 2 to about 12 nitrogen atoms and about 2 to 24 carbon atoms. Particularly suitable polyalkylene polyamines are those having the formula: H2N — (R'NH)x — H wherein R' is a straight- or branched-chain alkylene group having 2 or 3 carbon atoms and x is 1 to 9.
  • suitable polyalkylene polyamines include ethylenediamine, diethylenetriamine, triethylenetetraamine, tetraethylenepentamine, pentaethylene hexamine, and heavy polyamines (e.g., Ethyleneamine E-100, available from Huntsman Company).
  • the polyalkenyl-substituted succinic anhydride is reacted with the polyamine at a temperature of about 130°C to about 220°C (e.g., 145°C to 175°C).
  • the reaction can be carried out under an inert atmosphere, such as nitrogen or argon.
  • a suitable molar charge of polyamine to polyalkenyl-substituted succinic anhydride is from about 0.35:1 to about 0.6:1 (e.g., 0.4:1 to 0.5:1).
  • the "molar charge of polyamine to polyalkenyl-substituted succinic anhydride" means the ratio of the number of moles of polyamine to the number of succinic groups in the succinic anhydride reactant.
  • polyalkenyl succinimides may be represented by the following:
  • the succinimide dispersant may be post-treated by a reactive boron compound or organic carbonate.
  • Suitable boron compounds that can be used as a source of boron include, for example, boric acid, a boric acid salt, a boric acid ester, and the like.
  • Representative examples of a boric acid include orthoboric acid, metaboric acid, paraboric acid, and the like.
  • Representative examples of a boric acid salt include ammonium borates, such as ammonium metaborate, ammonium tetraborate, ammonium pentaborate, ammonium octaborate, and the like.
  • boric acid ester examples include monomethyl borate, dimethyl borate, trimethyl borate, monoethyl borate, diethyl borate, triethyl borate, monopropyl borate, dipropyl borate, tripropyl borate, monobutyl borate, dibutyl borate, tributyl borate, and the like.
  • the lubricating oil composition disclosed herein may optionally comprise one or more anti-wear agent.
  • Antiwear agents reduce wear of metal parts.
  • Suitable anti-wear agents include dihydrocarbyl dithiophosphate metal salts such as zinc dihydrocarbyl dithiophosphates (ZDDP) of the following structure:
  • R1 and R2 may be the same of different hydrocarbyl radicals having from 1 to 18 (e.g., 2 to 12) carbon atoms and including radicals such as alkyl, alkenyl, aryl, arylalkyl, alkaryl and cycloaliphatic radicals.
  • R1 and R2 groups are alkyl groups having from 2 to 8 carbon atoms (e.g., the alkyl radicals may be ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, n-pentyl, isopentyl, n-hexyl, isohexyl, 2-ethylhexyl).
  • the total number of carbon atoms i.e., R1 +R2 will be at least 5.
  • the zinc dihydrocarbyl dithiophosphate can therefore comprise zinc dialkyl dithiophosphates.
  • the zinc dialkyl dithiophosphate is a primary, secondary zinc dialkyl dithiophosphate, or a combination thereof.
  • ZDDP may be present at 3 wt. % or less (e.g., 0.1 to 1.5 wt. %, or 0.5 to 1.0 wt %) of the lubricating oil composition.
  • the lubricating oil composition may optionally comprise an antioxidant compound.
  • the antioxidant is an aromatic amine antioxidant.
  • Typical aromatic amine antioxidants have at least two aromatic groups attached directly to one amine nitrogen.
  • Typical aromatic amine antioxidants have alkyl substituent groups of at least 6 carbon atoms.
  • aromatic amine antioxidants useful herein include 4,4'- dioctyldiphenylamine, 4,4'-dinonyldiphenylamine, N-phenyl-1 -naphthylamine, N-(4- tert-octyphenyl)-1 -naphthylamine, and N-(4-octylphenyl)-1 -naphthylamine.
  • Antioxidants may be present at 0.01 to 5 wt. % (e.g., 0.1 to 2 wt. %) of the lubricating oil composition.
  • the oil of lubricating viscosity (sometimes referred to as “base stock” or “base oil”) is the primary liquid constituent of a lubricant, into which additives and possibly other oils are blended, for example to produce a final lubricant (or lubricant composition).
  • a base oil which is useful for making concentrates as well as for making lubricating oil compositions therefrom, may be selected from natural (vegetable, animal or mineral) and synthetic lubricating oils and mixtures thereof.
  • Oils used as the base oil will be selected or blended depending on the desired end use and the additives in the finished oil to give the desired grade of engine oil, e.g. a lubricating oil composition having an Society of Automotive Engineers (SAE).
  • SAE Society of Automotive Engineers
  • the lubricating oil composition is a multi-grade oil for heavy duty or passenger car.
  • the multi-grade oil may have a viscosity grade SAE of OW-8, 0W- 12, OW-16, 0W-20, 0W-30, 0W-40, 0W-50, 0W-60, 5W, 5W-20, 5W-30, 5W-40, 5W- 50, 5W-60, 10W, 10W-20, 10W-30, 10W-40, 10W-50, 15W, 15W-20, 15W-30, or 15W-40.
  • SAE viscosity grade SAE of OW-8, 0W- 12, OW-16, 0W-20, 0W-30, 0W-40, 0W-50, 0W-60, 5W, 5W-20, 5W-30, 5W-40, 5W- 50, 5W-60, 10W, 10W-20, 10W-30, 10W-40, 10W-50, 15W, 15W-20, 15W-30, or 15W-40.
  • base stocks and base oils in this disclosure are the same as those found in American Petroleum Institute (API) Publication 1509 Annex E ("API Base Oil Interchangeability Guidelines for Passenger Car Motor Oils and Diesel Engine Oils," December 2016).
  • Group I base stocks contain less than 90% saturates and/or greater than 0.03% sulfur and have a viscosity index greater than or equal to 80 and less than 120 using the test methods specified in Table E-1.
  • Group II base stocks contain greater than or equal to 90% saturates and less than or equal to 0.03% sulfur and have a viscosity index greater than or equal to 80 and less than 120 using the test methods specified in Table E-1.
  • Group III base stocks contain greater than or equal to 90% saturates and less than or equal to 0.03% sulfur and have a viscosity index greater than or equal to 120 using the test methods specified in Table E-1.
  • Group IV base stocks are polyalphaolefins (PAO).
  • Group V base stocks include all other base stocks not included in Group I, II, III, or IV.
  • Natural oils include animal oils, vegetable oils (e.g., castor oil and lard oil), and mineral oils. Animal and vegetable oils possessing favorable thermal oxidative stability can be used. Of the natural oils, mineral oils are preferred. Mineral oils vary widely as to their crude source, for example, as to whether they are paraffinic, naphthenic, or mixed paraffinic-naphthenic. Oils derived from coal or shale are also useful. Natural oils vary also as to the method used for their production and purification, for example, their distillation range and whether they are straight run or cracked, hydrorefined, or solvent extracted.
  • Synthetic oils include hydrocarbon oil.
  • Hydrocarbon oils include oils such as polymerized and interpolymerized olefins (e.g., polybutylenes, polypropylenes, propylene isobutylene copolymers, ethylene-olefin copolymers, and ethylenealphaolefin copolymers).
  • Polyalphaolefin (PAO) oil base stocks are commonly used synthetic hydrocarbon oil.
  • PAOs derived from Cs to Cu olefins e.g., Cs, Cw, C12, C14 olefins or mixtures thereof, may be utilized.
  • base oils include non-conventional or unconventional base stocks that have been processed, preferably catalytically, or synthesized to provide high performance characteristics.
  • Non-conventional or unconventional base stocks/base oils include one or more of a mixture of base stock(s) derived from one or more Gas-to-Liquids (GTL) materials, as well as isomerate/isodewaxate base stock(s) derived from natural wax or waxy feeds, mineral and or non-mineral oil waxy feed stocks such as slack waxes, natural waxes, and waxy stocks such as gas oils, waxy fuels hydrocracker bottoms, waxy raffinate, hydrocrackate, thermal crackates, or other mineral, mineral oil, or even nonpetroleum oil derived waxy materials such as waxy materials received from coal liquefaction or shale oil, and mixtures of such base stocks.
  • Other base oils include Coal to liquid (CTL) products and alkyl-naphthalene.
  • Base oils for use in the lubricating oil compositions of present disclosure are any of the variety of oils corresponding to API Group I, Group II, Group III, Group IV, and Group V oils, and mixtures thereof, preferably API Group II, Group III, Group IV, and Group V oils, and mixtures thereof, more preferably the Group III to Group V base oils due to their exceptional volatility, stability, viscometric and cleanliness features.
  • the lubricating oil composition may have a high temperature shear (HTHS) viscosity at 150° C of 3.7 cP or less, such as 3.6 cP or less, 3.5 cP or less, 3.4 cP or less, 3.3 cP or less, 3.2 cP or less, 3.1 cP or less, 3.0 cP or less, 2.9 cP or less, 2.8 cP or less, 2.7 cP or less, 2.6 cP or less, 2.5 cP or less, 2.4 cP or less, 2.3 cP or less, 2.2 cP or less, 2.1 cP or less, 2.0 cP or less, 1.9 cP or less, 1.8 cP or less, 1.7 cP or less, 1.6 cP or less, 1.5 cP or less, 1.4 cP or less, 1.3 cP or less, 1.2 cP or less, 1.1 cP or less, 1.0 cP or less,
  • the lubricating oil composition may have a viscosity index of at least 135 (e.g., 135 to 400, or 135 to 250), at least 150 (e.g., 150 to 400, 150 to 250), at least 165 (e.g., 165 to 400, or 165 to 250), at least 190 (e.g., 190 to 400, or 190 to 250), or at least 200 (e.g., 200 to 400, or 200 to 250). If the viscosity index of the lubricating oil composition is less than 135, it may be difficult to improve fuel efficiency while maintaining the HTHS viscosity at 150° C. If the viscosity index of the lubricating oil composition exceeds 400, evaporation properties may be reduced, and deficits due to insufficient solubility of the additive and matching properties with a seal material may be caused.
  • the base oil may have a kinematic viscosity at 100°C (ASTM D445) in a range of 1.4 to 20 mm 2 /s such as 3 to 12 mm 2 /s, such as 3 to 11 mm 2 /s, 3 to 10 mm 2 /s,
  • the lubricating oil composition contains 0.8 to 1.5 wt% of ash, such as 0.8 to 1.4 wt%, 0.8 to 1.3 wt%, 0.8 to 1.2 wt%, 0.8 to 1.1 wt%, 0.8 to 1.0 wt%, 0.8 to 0.9 wt%, 0.9 to 1.5 wt%, 0.9 to 1.4 wt%, 0.9 to 1.3 wt%, 0.9 to 1.2 wt%, 0.9 to 1.1 wt%, 0.9 to 1.0 wt%, 1.0 to 1.5 wt%, 1.0 to 1.4 wt%, 1.0 to 1.3 wt%, 1.0 to 1.2 wt%, 1.0 to 1.1 wt%, 1.1 to 1.5 wt%, 1.1 to 1.4 wt%, 1.1 to 1.3 wt%, 1.1 to 1.2 wt%, 1.0 to 1.1 wt%, 1.1 to 1.5 wt%, 1.1 to 1.4
  • the lubricating oil composition contains greater than 600 ppm of phosphorus, such as greater than 650 ppm, greater than 700 ppm, greater than 750 ppm, greater than 800 ppm, greater than 850 ppm, greater than 900 ppm, greater than 950 ppm, and greater than 1000 ppm.
  • All samples include the following baseline formulation: SAE 10-30W viscosity grade heavy duty diesel lubricating oil composition prepared by blending the following components: a) mixture of borated and non-borated succinimide b) diphenylamine antioxidant c) mixture of primary and secondary ZnDTP d) detergent system comprising Mg sulfonate and one or more calcium- containing detergent (Ca phenate, Ca salicylate, and/or Ca sulfonate)
  • the remainder of the lubricating oil composition includes base oil, viscosity index improver, and pour point depressant. Each sample was subjected to NOx conversion bench test as described below.
  • NQx Conversion Bench Test This test measures the reduction of the NOx conversion rate in a SCR catalyst after contamination with a lubricating oil. Before the SCR tests can be performed, the catalyst must be prepared, which involves taking solid vanadium EU6 catalyst monolith and crushing, filtering, hydrothermallyaging, and impregnating/calcinating the material.
  • the catalyst material Once the catalyst material has been crushed & filtered, it is soaked in the oil samples and hot filtered until there is no visible oil.
  • the oil impregnated catalyst is calcinated under positive airflow to remove hydrocarbons.
  • the SCR tests were performed in typical diesel exhaust conditions (temperature ramped from 175 to 550 ,;, C). More specifically, the SCR catalyst materials came into contact with a simulated gas feed which is a mixture of NO (500ppm), NH3 (500ppm), H2O (5%), O2 (10%) and balancing amount of N2.
  • ranges from any lower limit may be combined with any upper limit to recite a range not explicitly recited, as well as, ranges from any lower limit may be combined with any other lower limit to recite a range not explicitly recited, in the same way, ranges from any upper limit may be combined with any other upper limit to recite a range not explicitly recited.
  • ranges from any upper limit may be combined with any other upper limit to recite a range not explicitly recited.
  • within a range includes every point or individual value between its end points even though not explicitly recited. Thus, every point or individual value may serve as its own lower or upper limit combined with any other point or individual value or any other lower or upper limit, to recite a range not explicitly recited.
  • compositions, an element or a group of elements are preceded with the transitional phrase “comprising,” it is understood that we also contemplate the same composition or group of elements with transitional phrases “consisting essentially of,” “consisting of,” “selected from the group of consisting of,” or “is” preceding the recitation of the composition, element, or elements and vice versa.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

La présente invention concerne un procédé de réduction de l'empoisonnement du catalyseur dans un moteur diesel équipé d'un système de post-traitement comprenant un dispositif de réduction catalytique sélective. Le procédé comprend la lubrification du moteur avec une composition d'huile lubrifiante. La composition d'huile lubrifiante comprend une quantité majeure d'huile de viscosité lubrifiante ; et un système détergent comprenant au moins un détergent contenant du magnésium ou au moins un détergent contenant du magnésium et au moins un détergent contenant du calcium.
PCT/US2024/019553 2023-03-13 2024-03-12 Formulation d'huile de moteur compatible avec un système de post-traitement Ceased WO2024192011A1 (fr)

Priority Applications (4)

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CN202480022805.8A CN120981554A (zh) 2023-03-13 2024-03-12 后处理系统友好型发动机油制剂
JP2025553665A JP2026508618A (ja) 2023-03-13 2024-03-12 後処理システム対応型エンジンオイル配合物
KR1020257034023A KR20250161009A (ko) 2023-03-13 2024-03-12 후처리 시스템 친화적 엔진 오일 제형
EP24717501.1A EP4680703A1 (fr) 2023-03-13 2024-03-12 Formulation d'huile de moteur compatible avec un système de post-traitement

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US202363451725P 2023-03-13 2023-03-13
US63/451,725 2023-03-13

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WO2024192011A1 true WO2024192011A1 (fr) 2024-09-19

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WO (1) WO2024192011A1 (fr)

Citations (5)

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US3595791A (en) 1969-03-11 1971-07-27 Lubrizol Corp Basic,sulfurized salicylates and method for their preparation
US6479440B1 (en) 1999-06-10 2002-11-12 Chevron Oronite S. A. Alkaline earth alkylaryl sulfonates, their application as an additive for lubricating oil, and methods of preparation
US6569818B2 (en) * 2000-06-02 2003-05-27 Chevron Oronite Company, Llc Lubricating oil composition
EP1803793A1 (fr) * 2005-12-28 2007-07-04 Infineum International Limited Composiitons d'huile lubrifiante
EP2371934A1 (fr) * 2010-03-31 2011-10-05 Infineum International Limited Composition d'huile lubrifiante

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3595791A (en) 1969-03-11 1971-07-27 Lubrizol Corp Basic,sulfurized salicylates and method for their preparation
US6479440B1 (en) 1999-06-10 2002-11-12 Chevron Oronite S. A. Alkaline earth alkylaryl sulfonates, their application as an additive for lubricating oil, and methods of preparation
US6569818B2 (en) * 2000-06-02 2003-05-27 Chevron Oronite Company, Llc Lubricating oil composition
EP1803793A1 (fr) * 2005-12-28 2007-07-04 Infineum International Limited Composiitons d'huile lubrifiante
EP2371934A1 (fr) * 2010-03-31 2011-10-05 Infineum International Limited Composition d'huile lubrifiante

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Title
KROCHER ET AL: "Chemical deactivation of V"2O"5/WO"3-TiO"2 SCR catalysts by additives and impurities from fuels, lubrication oils, and urea solution", APPLIED CATALYSIS B. ENVIRONMENTAL, ELSEVIER, AMSTERDAM, NL, vol. 77, no. 3-4, 29 November 2007 (2007-11-29), pages 215 - 227, XP022369681, ISSN: 0926-3373, DOI: 10.1016/J.APCATB.2007.04.021 *
SHIBATA MASAHITO ET AL: "A Study of Engine Oil Composition Effects on Zeolite-type SCR Catalyst Durability", SAE TECHNICAL PAPERS, vol. 1, 23 July 2007 (2007-07-23), US, pages 2042 - 2051, XP093175462, ISSN: 0148-7191, Retrieved from the Internet <URL:https://dx.doi.org/10.4271/2007-01-1924> DOI: 10.4271/2007-01-1924 *
VIGNESH R ET AL: "Critical interpretative review on current outlook and prospects of selective catalytic reduction system for De-NOx strategy in compression ignition engine", FUEL, IPC SIENCE AND TECHNOLOGY PRESS , GUILDFORD, GB, vol. 276, 11 May 2020 (2020-05-11), XP086160070, ISSN: 0016-2361, [retrieved on 20200511], DOI: 10.1016/J.FUEL.2020.117996 *

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EP4680703A1 (fr) 2026-01-21
JP2026508618A (ja) 2026-03-11
CN120981554A (zh) 2025-11-18
KR20250161009A (ko) 2025-11-14

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