WO2024250143A1 - Article en dose unitaire soluble dans l'eau comprenant une composition de détergent à lessive liquide qui comprend du polyéthylène glycol et un agent anti-acarien - Google Patents

Article en dose unitaire soluble dans l'eau comprenant une composition de détergent à lessive liquide qui comprend du polyéthylène glycol et un agent anti-acarien Download PDF

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Publication number
WO2024250143A1
WO2024250143A1 PCT/CN2023/098297 CN2023098297W WO2024250143A1 WO 2024250143 A1 WO2024250143 A1 WO 2024250143A1 CN 2023098297 W CN2023098297 W CN 2023098297W WO 2024250143 A1 WO2024250143 A1 WO 2024250143A1
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WO
WIPO (PCT)
Prior art keywords
water
weight
unit dose
composition
dose article
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2023/098297
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English (en)
Inventor
Yajie DING
Zhaoqi FAN
Ming Tang
Kejing DU
Shiqing Wu
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Procter and Gamble Co
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Procter and Gamble Co
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Publication date
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Priority to PCT/CN2023/098297 priority Critical patent/WO2024250143A1/fr
Publication of WO2024250143A1 publication Critical patent/WO2024250143A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043—Liquid or thixotropic (gel) compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides

Definitions

  • the present invention relates to water-soluble unit dose articles comprising a liquid laundry detergent composition which comprises polyethylene glycol having a weight average molecular weight of from about 150 to about 2000 Daltons and an anti-mite agent.
  • the water-soluble unit dose article comprises the water-soluble film shaped such that the unit dose article comprises at least one internal compartment surrounded by the water-soluble film.
  • Preferred film materials are preferably polymeric materials.
  • the film material can, for example, be obtained by casting, blow-moulding, extrusion or blown extrusion of the polymeric material, as known in the art.
  • requirements for detergent unit dose articles include stability, physical properties for films and “weeping” performance.
  • the liquid contained in the detergent unit dose articles needs to be stable during the shelf life, i.e., no phase separation or flocculation.
  • “weeping” phenomenon occurs during the storage of the unit dose articles, i.e., some minor liquid composition comes out of the unit dose articles through the film.
  • High level of “weeping” is not acceptable for consumers.
  • the film material needs to have appropriate physical properties. Particularly, swelling performance of film materials may be important.
  • the film material may swell or de-swell after it contacts the liquid contained in the unit dose articles due to the interaction between the film material and some ingredients in the liquid. Too much swelling gives floppy unit dose articles which are not desirable for consumers and too much de-swelling renders unit dose articles sensitive to breakage. All these aspects need to be considered in the design of unit dose articles in order to achieve an overall good performance in all these aspects, e.g., an improved balance among these aspects.
  • P&G has reported a water-soluble unit dose article is formed by using a liquid detergent composition comprising polyethylene glycol having a weight average molecular weight of from about 150 to about 300 Daltons in combination with the non-aqueous solvent that can meet need as mentioned above.
  • Dust mites may be one of the most prevalent indoor allergens. They are potentially responsible for from 50 to 80 percent of all asthma cases, and countless cases of eczema, hay fever and other allergic reactions. Dust mites can burrow and cling to fabrics, mostly in carpet, household upholstery, mattress, beddings, and sometimes clothing.
  • water-soluble unit dose articles with anti-mite benefits.
  • anti-mite agents including certain plant extracts, certain natural essential oils, phenol derivatives, antibiotic natamycin, zirconium phosphate, gamma-hexachlorocyclohexane, pirimiphos methyl, diethyl-m-toluamide, dibutyl phthalate, benzyl benzoate, thiabendazole, p-menthane-3, 8-diol, tannic acid, N-lower alkyl neoalkanamides, propylene glycol monooleate, propylene glycol mono-linoleate, propylene glycol linolenate, and the like.
  • anti-mite agents into the liquid laundry detergent composition in the water-soluble unit dose articles is challenging.
  • the presence of such anti-mite agents may change the rheological properties of the liquid laundry detergent composition and result in more incidents of film sealing failure caused by liquid stringing during the manufacturing process.
  • addition of such anti-mite agents into the liquid laundry detergent composition may also result in greater impact on the film plasticization properties. Therefore, it would be good to co-formulate anti-mite agents with agents that improve their weight efficiency, such that their overall level can be kept minimal.
  • liquid laundry detergent composition containing the anti-mite agent (such as benzyl benzoate) will provide an improved anti-mite benefit, in comparison with a similar liquid laundry detergent composition that is substantially free of such polyethylene glycol.
  • the anti-mite agent such as benzyl benzoate
  • Such liquid laundry detergent composition is particularly suitable for making the anti-mite unit dose articles of the present invention.
  • the present invention in one aspect relates to a water-soluble unit dose article comprising a water-soluble film and a liquid laundry detergent composition wrapped with the water-soluble film, wherein the liquid laundry detergent composition comprises from 1%to 25%, by weight of the composition, of polyethylene glycol having a weight average molecular weight of from about 150 to about 2000 Daltons, and from 0.01%to 10%by weight of the composition of an anti-mite agent.
  • the polyethylene glycol is present at a level of from 2%to 22%, preferably from 2.5%to 20%, more preferably from 3%to 18%, even more preferably from 4%to 16%by weight of the composition.
  • the polyethylene glycol has a weight average molecular weight of from 150 to 1000 Daltons, preferably from 150 to 800 Daltons.
  • the anti-mite agent is present in the amount of from 0.1%to 10%, preferably from 0.2%to 9%, and more preferably from 0.5%to 8%, by weight of the composition.
  • the anti-mite agent is benzyl benzoate.
  • the weight ratio of the polyethylene glycol to the anti-mite agent is from 100: 1 to 1: 10, preferably from 20: 1 to 1: 5, and more preferably from 10: 1 to 1: 2, even more preferably from 5 : 1 to 1: 1.
  • the liquid laundry detergent composition comprises less than 15%, preferably less than 12%, by weight of the composition, of water.
  • the anti-mite unit dose articles of the present invention comprising liquid laundry detergent composition containing the polyethylene glycol having a weight average molecular weight of from about 150 to about 2000 Daltons surprisingly and unexpectedly provide an improved anti-mite benefit, in comparison with a similar anti-mite unit dose articles that is substantially free of such polyethylene glycol.
  • the terms “comprise” , “comprises” , “comprising” , “include” , “includes” , “including” , “contain” , “contains” , and “containing” are meant to be non-limiting, i.e., other steps and other ingredients which do not affect the end of result can be added.
  • the above terms encompass the terms “consisting of” and “consisting essentially of” .
  • composition is “substantially free” of a specific ingredient, it is meant that the composition comprises less than a trace amount, alternatively less than 0.1%, alternatively less than 0.01%, alternatively less than 0.001%, by weight of the composition, of the specific ingredient.
  • laundry detergent composition means a composition for cleaning soiled materials, including fabrics. Such compositions may be used as a pre-laundering treatment, a post-laundering treatment, or may be added during the rinse or wash cycle of the laundering operation.
  • unit dose laundry detergent composition herein refers to a water-soluble pouch containing a certain volume of liquid wrapped with a water-soluble film.
  • non-aqueous solvent means any non-aqueous solvent except the polyethylene glycol contained in the water-soluble unit dose article according to the present disclosure (e.g., the polyethylene glycol having a weight average molecular weight of from about 150 to about 2000 Daltons) .
  • alkyl means a hydrocarbyl moiety which is branched or unbranched, substituted or unsubstituted. Included in the term “alkyl” is the alkyl portion of acyl groups.
  • washing solution refers to the typical amount of aqueous solution used for one cycle of laundry washing, preferably from 1 L to 50 L, alternatively from 1 L to 20 L for hand washing and from 10 L to 50 L for machine washing.
  • oiled fabric is used non-specifically and may refer to any type of natural or artificial fibers, including natural, artificial, and synthetic fibers, such as, but not limited to, cotton, linen, wool, polyester, nylon, silk, acrylic, and the like, as well as various blends and combinations.
  • the present invention discloses a water-soluble unit dose article comprising a water-soluble film and a liquid laundry detergent composition, where the liquid laundry detergent composition comprises polyethylene glycol having a weight average molecular weight of from about 150 to about 2000 Daltons, and an anti-mite agent such as benzyl benzoate. Particularly, the liquid laundry detergent composition is wrapped with the water-soluble film.
  • the water-soluble film and the liquid detergent composition are described in more detail below.
  • the water-soluble unit dose article comprises the water-soluble film shaped such that the unit-dose article comprises at least one internal compartment surrounded by the water-soluble film.
  • the unit dose article may comprise a first water-soluble film and a second water-soluble film sealed to one another such to define the internal compartment.
  • the water-soluble unit dose article is constructed such that the detergent composition does not leak out of the compartment during storage. However, upon addition of the water-soluble unit dose article to water, the water-soluble film dissolves and releases the contents of the internal compartment into the wash liquor.
  • the compartment should be understood as meaning a closed internal space within the unit dose article, which holds the detergent composition.
  • a first water-soluble film may be shaped to comprise an open compartment into which the detergent composition is added.
  • a second water-soluble film is then laid over the first film in such an orientation as to close the opening of the compartment. The first and second films are then sealed together along a seal region.
  • the unit dose article may comprise more than one compartment, even at least two compartments, or even at least three compartments.
  • the compartments may be arranged in superposed orientation, i.e., one positioned on top of the other. In such an orientation the unit dose article will comprise three films, top, middle and bottom.
  • the compartments may be positioned in a side-by-side orientation, i.e., one orientated next to the other.
  • the compartments may even be orientated in a ‘tyre and rim’ arrangement, i.e., a first compartment is positioned next to a second compartment, but the first compartment at least partially surrounds the second compartment but does not completely enclose the second compartment.
  • one compartment may be completely enclosed within another compartment.
  • the unit dose article comprises at least two compartments, one of the compartments may be smaller than the other compartment.
  • the unit dose article comprises at least three compartments, two of the compartments may be smaller than the third compartment, and preferably the smaller compartments are superposed on the larger compartment.
  • the superposed compartments preferably are orientated side-by-side.
  • the detergent composition according to the present invention may be comprised in at least one of the compartments. It may for example be comprised in just one compartment, or may be comprised in two compartments, or even in three compartments.
  • Each compartment may comprise the same or different compositions.
  • the different compositions could all be in the same form, or they may be in different forms.
  • the water-soluble unit dose article may comprise at least two internal compartments, wherein the liquid laundry detergent composition is comprised in at least one of the compartments, preferably wherein the unit dose article comprises at least three compartments, wherein the detergent composition is comprised in at least one of the compartments.
  • the water-soluble unit dose article comprises a liquid laundry detergent composition.
  • liquid laundry detergent composition refers to any laundry detergent composition comprising a liquid capable of wetting and treating a fabric, and includes, but is not limited to, liquids, gels, pastes, dispersions and the like.
  • the liquid composition can include solids or gases in suitably subdivided form, but the liquid composition excludes forms which are non-fluid overall, such as tablets or granules.
  • the liquid detergent composition can be used in a fabric hand wash operation or may be used in an automatic machine fabric wash operation.
  • the liquid laundry detergent composition may comprise polyethylene glycol having a weight average molecular weight of from about 150 to about 2000 Daltons and an anti-mite agent.
  • the weight ratio of the polyethylene glycol to the anti-mite agent is from about 100: 1 to about 1: 10, preferably from about 20: 1 to about 1: 5, and more preferably from about 10: 1 to about 1: 2, even more preferably from about 5 : 1 to about 1: 1.25.
  • the polyethylene glycol and the anti-mite agent are described in more detail below.
  • the liquid laundry detergent composition comprises from 1%to 25%, by weight of the composition, of polyethylene glycol having a weight average molecular weight of from about 150 to about 2000 Daltons.
  • the polyethylene glycol may be present at a level of from 2%to 22%, preferably from 2.5%to 20%, more preferably from 3%to 18%, even more preferably from 4%to 16%, for example 1.5%, or 2%, or 2.5%, or 3%, or 3.5%, or 4%, or 4.5%, or 5%, or 6%, or 7%, or 9%, or 10%, or 11%, or 12%, or 15%, or 17%, or 20%, or any ranges therebetween, by weight of the composition.
  • the polyethylene glycol may have a weight average molecular weight of from about 150 to about 1000 Daltons, preferably from about 150 to about 800 Daltons, e.g., 150 Daltons, or 200 Daltons, or 250 Daltons, or 300 Daltons, or 350 Daltons, or 400 Daltons, or 600 Daltons, and any ranges therebetween.
  • the liquid laundry detergent composition comprises, as an anti-mite agent, from about 0.1%to about 20%, preferably from about 1%to about 20%, of benzyl benzoate by total weight of said liquid laundry detergent composition.
  • Benzyl benzoate has been known to have anti-mite benefit when used at a relatively high concentration, e.g., at least about 1%. Although benzyl benzoate has also been used at lower concentrations (i.e., below 1%) as a back filler or solvent for perfume raw materials, such usage of benzyl benzoate does not provide satisfactory anti-mite benefit. Further, at such lower concentrations, the impact of benzyl benzoate on the rheological properties, more particularly liquid stringing properties, of the liquid laundry detergent composition are not significant.
  • Incorporation of benzyl benzoate into the water-soluble unit dose article of the present invention preferably at an amount ranging from about 1%to about 20%, more preferably from about 2%to about 15%, still more preferably from about 3%to about 12%, most preferably from about 4%to about 10%, by total weight of the liquid detergent composition enclosed in such unit dose article, not only provides anti-mite benefit, but also reduces liquid stringing during manufacturing of such unit dose article and controls the negative impact on film plasticization properties over time after such unit dose article is made.
  • the liquid laundry detergent composition is characterized by a high shear viscosity ranging from about 100 to about 900 mPa ⁇ s, preferably from about 150 to about 800 mPa ⁇ s, more preferably from about 200 to about 600 mPa ⁇ smeasured at a shear rate of about 1000 s -1 and at a temperature of about 20°C, measured following the test method described herein.
  • the fluid is preferably a non-Newtonian fluid with shear-thinning properties, hence is further characterized by a low shear viscosity ranging from about 1000 mPa. sto about 10000 mPa. s, preferably from about 1500 mPa. sto about 7500 mPa.
  • non-Newtonian fluids with shear thinning properties are believed to have enhanced physical stability properties, especially enhanced phase separation prevention properties, as well as ability to suspend particles. Viscosity is measured using a rotational rheometer.
  • the high shear viscosity is measured at about 20°C at a shear rate of about 1000s -1 and the low shear viscosity is measured at about 20°C at a shear rate of about 0.5s -1 using a TA instruments AR-G2 Rheometer (spindle: 40mm 2° steel cone geometry) .
  • the measurement method includes a conditioning step (10s -1 for 10 seconds) , a peak hold step (0.05s -1 for 180 seconds) and a shear ramp (180 seconds) from 0.1 to 1200s -1 , all at 20°C.
  • Suitable fluids may include, but are not limited to, detergent compositions, such as those sold under the tradenames TIDE, GAIN, ARIEL, TIDE PODS, GAIN FLINGS, FAIRY and CASCADE manufactured by The Procter &Gamble Company, Cincinnati, Ohio, USA.
  • a sufficient high amount of benzyl benzoate e.g., from about 1 wt%to about 20 wt%, can be used in a liquid laundry detergent composition with a high shear viscosity of about 100-900 mPa ⁇ s (measured at a shear rate of about 1000 s -1 and at a temperature of about 20°C) to not only provide anti-mite benefit, but also to reduce liquid stringing, which in turn helps to prevent or minimize film sealing failure when such liquid laundry detergent composition is enclosed into a pouch formed by a water-soluble film for making an anti-mite unit dose article.
  • the liquid laundry detergent composition further comprises from about 0.1%to about 30%, for example 1%, 2%, 3%, 5%, 7%, 12%, 15%, 17%, 20%, 25%or any ranges therebetween, preferably from about 1%to about 25%, more preferably from about 2%to about 20%, still more preferably from about 3%to 15%, by weight of the composition, of a non-aqueous solvent.
  • Non-aqueous solvent hereinwith means any non-aqueous solvent except the polyethylene glycol contained in the water-soluble unit dose article according to the present disclosure (e.g., the polyethylene glycol having a weight average molecular weight of from about 150 to about 2000 Daltons) .
  • the non-aqueous solvent may be selected from the group consisting of monoalcohols, diols, polyols, glycol ethers and any combinations thereof. More preferably, the non-aqueous solvent may be selected from the group consisting of ethanol, propanol, isopropanol, terpineol, ethylene glycol, 1, 2-propanediol, 1, 3-propanediol, 1, 2-butanediol; 1, 3-butanediol; 1, 4-butanediol; 2, 3-butanediol, glycerin, butanetriol, pentaerythritol, dipropylene glycol (DPG) , tripropylene glycol (TPG) , polypropylene glycol (PPG) , n-butoxy propoxy propanol (nBPP) , diethylene glycol, 2-ethoxyethanol, 2-butoxyethanol, and any combinations thereof.
  • DPG dipropylene glyco
  • diol solvent as used herein means alcohol compounds having two hydroxyl groups.
  • polyol solvent as used herein means alcohol compounds having three or more hydroxyl groups.
  • hydroxyl ether solvent as used herein means ether compounds having at least one hydroxyl group.
  • 1, 2-propanediol may be present in an amount ranging from 0.1%to 15%, preferably from 1%to 14%, more preferably from 3%to 13%, by weight of the composition.
  • glycerin may be present in an amount ranging from 0.1%to 10%, preferably from 1%to 9%, more preferably from 3%to 8%, by weight of the composition.
  • liquid laundry detergent composition may comprise 1, 2-propanediol, glycerin and polyethylene glycol having a weight average molecular weight of from about 150 to about 600 Daltons in which the total amount of 1, 2-propanediol, glycerin and polyethylene glycol may range from 5%to 50%, preferably from 10%to 45%, more preferably from 15%to 40%, by weight of the composition.
  • liquid laundry detergent composition may comprise 1, 2-propanediol and polyethylene glycol having a weight average molecular weight of from about 150 to about 600 Daltons in which the weight ratio of 1, 2-propanediol and the polyethylene glycol is from 0.1 to 0.6, preferably from 0.15 to 0.5, and more preferably from 0.2 to 0.4.
  • liquid laundry detergent composition may comprise glycerin and polyethylene glycol having a weight average molecular weight of from about 150 to about 300 Daltons in which the weight ratio of glycerin and the polyethylene glycol is from 0.1 to 0.7, preferably from 0.2 to 0.6 and more preferably from 0.3 to 0.5.
  • liquid laundry detergent composition may comprise 1, 2-propanediol and glycerin in which the weight ratio of 1, 2-propanediol and glycerin is from 0.2 to 5, preferably from 0.4 to 3, and more preferably from 0.5 to 1.
  • the liquid laundry detergent composition comprises between about 0.5%and about 20%, more preferably between about 1%and about 15%, most preferably between about 5%and about 12%by weight of the liquid laundry detergent composition of water.
  • the liquid laundry detergent composition may comprise an alkanolamine, preferably the alkanolamine comprises monoethanolamine, triethanolamine or a mixture thereof, most preferably the alkonolamine comprises monoethanolamine.
  • the liquid laundry detergent composition comprises between about 5%and about 15%, more preferably between about 6%and about 10%by weight of the liquid laundry detergent composition of the alkanolamine, preferably of monoethanolamine, triethanolamine or a mixture thereof, most preferably of monoethanolamine.
  • the water-soluble unit dose article may comprise an adjunct ingredient selected from hueing dyes, polymers, builders, dye transfer inhibiting agents, dispersants, enzymes, enzyme stabilizers, catalytic materials, bleach, bleach activators, polymeric dispersing agents, anti-redeposition agents, suds suppressors, aesthetic dyes, opacifiers, perfumes, perfume delivery systems, structurants, hydrotropes, processing aids, pigments and mixtures thereof.
  • an adjunct ingredient selected from hueing dyes, polymers, builders, dye transfer inhibiting agents, dispersants, enzymes, enzyme stabilizers, catalytic materials, bleach, bleach activators, polymeric dispersing agents, anti-redeposition agents, suds suppressors, aesthetic dyes, opacifiers, perfumes, perfume delivery systems, structurants, hydrotropes, processing aids, pigments and mixtures thereof.
  • the liquid laundry detergent composition in the unite dose article has a pH between 6 and 10, between 6.5 and 8.9, or between 7 and 8, wherein the pH of the laundry detergent composition is measured as a 10%product concentration in demineralized water at 20°C.
  • the liquid detergent composition of the present invention may further comprise from 0.1%to 70%, preferably from 1%to 60%, more preferably from 5%to 50%, most preferably from 10%to 45%, by weight of the composition, of a surfactant.
  • the surfactant may be selected from the group consisting of C 6 -C 20 alkyldimethyl amine oxides, C 6-20 amido alkyl dimethyl amine oxides, C 6 -C 20 linear alkylbenzene sulfonates (LAS) , C 6 -C 20 alkyl sulfates (AS) , C 6 -C 20 alkyl alkoxy sulfates (AAS) , C 6 -C 20 methyl ester sulfonates (MES) , C 6 -C 20 alkyl ether carboxylates (AEC) , fatty acids, alkyl alkoxylated alcohols, alkyl alkoxylated phenols, alkyl polysaccharides, alkyl polygly
  • the surfactant may comprise a C 6 -C 20 alkyldimethyl amine oxide, a C 6 -C 20 LAS, and a C 6 -C 20 alkoxylated alcohol having a weight average degree of alkoxylation ranging from 1 to 20 preferably a C 6 -C 20 ethoxylated alcohol having a weight average degree of ethoxylation ranging from 1 to 20.
  • the anionic surfactant may be selected from the group consisting of C 6 -C 20 linear alkylbenzene sulfonates (LAS) , C 6 -C 20 alkyl sulfates (AS) , C 6 -C 20 alkyl alkoxy sulfates (AAS) , C 6 -C 20 methyl ester sulfonates (MES) , C 6 -C 20 alkyl ether carboxylates (AEC) , fatty acids and any combinations thereof.
  • LAS linear alkylbenzene sulfonates
  • AS alkyl sulfates
  • AAS alkyl alkoxy sulfates
  • MES C 6 -C 20 methyl ester sulfonates
  • AEC alkyl ether carboxylates
  • the anionic surfactant system may comprise a C 6 -C 20 LAS and optionally an additional anionic surfactant such as a C 6 -C 20 AS and/or a C 6 -C 20 AAS preferably a C 6 -C 20 alkyl ethoxylated sulfate having a weight average degree of ethoxylation ranging from 1 to 7.
  • LAS is C 10 -C 16 LAS, preferably C 12 -C 14 LAS.
  • the non-ionic surfactant may be selected from the group consisting of alkyl alkoxylated alcohols, alkyl alkoxylated phenols, alkyl polysaccharides, alkyl polyglycosides, methyl ester ethoxylates, polyhydroxy fatty acid amides, alkoxylated fatty acid esters, sucrose esters, sorbitan esters and alkoxylated derivatives of sorbitan esters, and any combinations thereof. More preferably, the nonionic surfactant may comprise a C 8 -C 18 ethoxylated alcohol having a weight average degree of ethoxylation ranging from 1 to 20, preferably from 5 to 15, more preferably from 5 to 10.
  • the surfactant may comprise an anionic surfactant and a non-ionic surfactant in which the anionic surfactant comprises a C 6 -C 20 LAS and optionally a C 6 -C 20 AS and/or a C 6 -C 20 AAS and the non-ionic surfactant comprises a C 6 -C 20 alkoxylated alcohol having a weight average degree of alkoxylation ranging from 1 to 20, preferably from 5 to 15, more preferably from 5 to 10.
  • the weight ratio of LAS to AA x S is at least 0.6, preferably at least 0.8, more preferably at least 0.9, most preferably at least 1, for example 0.6, 0.7, 0.8, 0.9, 1, 1.2, 1.5, 2, 2.5, 3, 4, 5, 8, 10 or any ranges therebetween.
  • the C 6 -C 20 LAS is present in an amount ranging from 1%to 30%, preferably from 2%to 25%, more preferably from 3%to 20%, by weight of the composition.
  • the C 6 -C 20 AAS is present in an amount ranging from 1%to 20%, preferably from 2%to 15%, more preferably from 3%to 10%, by weight of the composition.
  • the C 6 -C 20 alkoxylated alcohol is present in an amount ranging from 1%to 60%, preferably from 2%to 45%, more preferably from 3%to 30%, most preferably from 3%to 20%, by weight of the composition.
  • the liquid laundry detergent composition may further comprise from 1%to 30%, preferably from 2%to 25%, more preferably from 3%to 20%, by weight of the composition, of an amine oxide.
  • the liquid laundry detergent composition may further comprise from 0.1%to 10%, preferably from 0.5%to 8%, more preferably from 0.7%to 6%, most preferably from 1%to 3, by weight of the composition, of a fatty acid.
  • liquid laundry detergent composition may comprise:
  • a surfactant selected from the group consisting of a C 6 -C 20 LAS, a C 6 -C 20 AAS, a C 6 -C 20 alkoxylated alcohol having a weight average degree of alkoxylation ranging from 5 to 10, and the combinations thereof.
  • the water-soluble film of the present invention is soluble or dispersible in water.
  • the water-soluble film preferably has a thickness of from 20 to 150 micron, preferably 35 to 125 microns, even more preferably 50 to 110 microns, most preferably about 76 microns.
  • the film has a water-solubility of at least 50%, preferably at least 75%or even at least 95%, as measured by the method set out here after using a glass-filter with a maximum pore size of 20 microns: 5 grams ⁇ 0.1 gram of film material is added in a pre-weighed 3L beaker and 2L ⁇ 5ml of distilled water is added. This is stirred vigorously on a magnetic stirrer, Labline model No. 1250 or equivalent and 5 cm magnetic stirrer, set at 600 rpm, for 30 minutes at 30 o C. Then, the mixture is filtered through a folded qualitative sintered-glass filter with a pore size as defined above (max. 20 micron) . The water is dried off from the collected filtrate by any conventional method, and the weight of the remaining material is determined (which is the dissolved or dispersed fraction) . Then, the percentage solubility or dispersibility can be calculated.
  • the water-soluble film material may be obtained by casting, blow-moulding, extrusion or blown extrusion of the polymeric material, as known in the art.
  • the water-soluble film comprises polyvinylalcohol.
  • the polyvinylalcohol may be present between 50%and 95%, preferably between 55%and 90%, more preferably between 60%and 80%by weight of the water-soluble film.
  • the polyvinylalcohol preferably comprises polyvinyl alcohol homopolymer, polyvinylalcohol copolymer, or a mixture thereof.
  • the water-soluble film comprises a blend of polyvinylalcohol homopolymers and/or anionic polyvinylalcohol copolymers, preferably wherein the polyvinylalcohol copolymers are selected from sulphonated and carboxylated anionic polyvinylalcohol copolymers especially carboxylated anionic polyvinylalcohol copolymers, most preferably the water-soluble film comprises a blend of a polyvinylalcohol homopolymer and a carboxylated anionic polyvinylalcohol copolymer, or a blend of polyvinylalcohol homopolymers.
  • the polyvinylalcohol comprises an anionic polyvinyl alcohol copolymer, most preferably a carboxylated anionic polyvinylalcohol copolymer.
  • the polyvinylalcohol in the water-soluble film is a blend of a polyvinylalcohol homopolymer and a carboxylated anionic polyvinylalcohol copolymer, the homopolymer and the anionic copolymer are present in a relative weight ratio of 90/10 to 10/90, preferably 80/20 to 20/80, more preferably 70/30 to 50/50.
  • the term “homopolymer” generally includes polymers having a single type of monomeric repeating unit (e.g., a polymeric chain comprising or consisting of a single monomeric repeating unit) .
  • the term “homopolymer” further includes copolymers having a distribution of vinyl alcohol monomer units and optionally vinyl acetate monomer units, depending on the degree of hydrolysis (e.g., a polymeric chain comprising or consisting of vinyl alcohol and vinyl acetate monomer units) .
  • a polyvinylalcohol homopolymer can include only vinyl alcohol units.
  • copolymer generally includes polymers having two or more types of monomeric repeating units (e.g., a polymeric chain comprising or consisting of two or more different monomeric repeating units, whether as random copolymers, block copolymers, etc. ) .
  • copolymer (or “polyvinylalcohol copolymer” ) further includes copolymers having a distribution of vinyl alcohol monomer units and vinyl acetate monomer units, depending on the degree of hydrolysis, as well as at least one other type of monomeric repeating unit (e.g., a ter- (or higher) polymeric chain comprising or consisting of vinyl alcohol monomer units, vinyl acetate monomer units, and one or more other monomer units, for example anionic monomer units) .
  • monomeric repeating unit e.g., a ter- (or higher) polymeric chain comprising or consisting of vinyl alcohol monomer units, vinyl acetate monomer units, and one or more other monomer units, for example anionic monomer units
  • a polyvinylalcohol copolymer can include a copolymer having vinyl alcohol units and one or more other monomer units, but no vinyl acetate units.
  • anionic copolymer includes copolymers having an anionic monomer unit comprising an anionic moiety.
  • anionic monomer units which can be used for the anionic polyvinyl alcohol co-polymer include the vinyl polymerization units corresponding to monocarboxylic acid vinyl monomers, their esters and anhydrides, dicarboxylic monomers having a polymerizable double bond, their esters and anhydrides, vinyl sulfonic acid monomers, and alkali metal salts of any of the foregoing.
  • suitable anionic monomer units include the vinyl polymerization units corresponding to vinyl anionic monomers including vinyl acetic acid, maleic acid, monoalkyl maleate, dialkyl maleate, monomethyl maleate, dimethyl maleate, maleic anyhydride, fumaric acid, monoalkyl fumarate, dialkyl fumarate, monomethyl fumarate, dimethyl fumarate, fumaric anyhydride, itaconic acid, monomethyl itaconate, dimethyl itaconate, itaconic anhydride, vinyl sulfonic acid, allyl sulfonic acid, ethylene sulfonic acid, 2-acrylamido-1-methylpropanesulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, 2-methylacrylamido-2-methylpropanesulfonic acid, 2-sufoethyl acrylate, alkali metal salts of the foregoing (e.g., sodium, potassium, or other alkali metal salts) , esters of the for
  • the anionic monomer may be one or more acrylamido methylpropanesulfonic acids (e.g., 2-acrylamido-1-methylpropanesulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, 2-methylacrylamido-2-methylpropanesulfonic acid) , alkali metal salts thereof (e.g., sodium salts) , and combinations thereof.
  • the anionic moiety of the first anionic monomer unit is selected from a sulphonate, a carboxylate, or a mixture thereof, more preferably a carboxylate, most preferably an acrylate, a methacrylate, a maleate, or a mixture thereof.
  • the anionic monomer unit is present in the anionic polyvinyl alcohol copolymer in an average amount in a range of between 1 mol. %and 10 mol. %, preferably between 2 mol. %and 5 mol. %.
  • the polyvinyl alcohol, and/or in case of polyvinylalcohol blends the individual polyvinylalcohol polymers have an average viscosity ( ⁇ 1) in a range of between 4 mPa. sand 30 mPa. s, preferably between 10mPa. sand 25 mPa. s, measured as a 4%polyvinyl alcohol copolymer solution in demineralized water at 20 degrees C.
  • the viscosity of a polyvinyl alcohol polymer is determined by measuring a freshly made solution using a Brookfield LV type viscometer with UL adapter as described in British Standard EN ISO 15023-2: 2006 Annex E Brookfield Test method. It is international practice to state the viscosity of 4%aqueous polyvinyl alcohol solutions at 20 °C. It is well known in the art that the viscosity of an aqueous water-soluble polymer solution (polyvinylalcohol or otherwise) is correlated with the weight-average molecular weight of the same polymer, and often the viscosity is used as a proxy for weight-average molecular weight.
  • the weight-average molecular weight of the polyvinylalcohol can be in a range of 30,000 to 175,000, or 30,000 to 100,000, or 55,000 to 80,000.
  • the polyvinyl alcohol, and/or in case of polyvinylalcohol blends the individual polyvinylalcohol polymers have an average degree of hydrolysis in a range of between 75%and 99%, preferably between 80%and 95%, most preferably between 85%and 95%.
  • a suitable test method to measure the degree of hydrolysis is as according to standard method JIS K6726.
  • the water-soluble film comprises a non-aqueous plasticizer.
  • the non-aqueous plasticizer is selected from polyols, sugar alcohols, and mixtures thereof.
  • Suitable polyols include polyols selected from the group consisting of glycerol, diglycerin, ethylene glycol, diethylene glycol, triethyleneglycol, tetraethylene glycol, polyethylene glycols up to 400 molecular weight, neopentyl glycol, 1, 2-propylene glycol, 1, 3-propanediol, dipropylene glycol, polypropylene glycol, 2-methyl-1, 3-propanediol, trimethylolpropane and polyether polyols, or a mixture thereof.
  • Suitable sugar alcohols include sugar alcohols selected from the group consisting of isomalt, maltitol, sorbitol, xylitol, erythritol, adonitol, dulcitol, pentaerythritol and mannitol, or a mixture thereof.
  • the non-aqueous plasticizer is selected from glycerol, 1, 2-propanediol, dipropylene glycol, 2-methyl-1, 3-propanediol, trimethylolpropane, triethyleneglycol, polyethyleneglycol, sorbitol, or a mixture thereof, most preferably selected from glycerol, sorbitol, trimethylolpropane, dipropylene glycol, and mixtures thereof.
  • One particularly suitable plasticizer system includes a blend of glycerol, sorbitol and trimethylol propane.
  • Another particularly suitable plasticizer system includes a blend of glycerin, dipropylene glycol, and sorbitol.
  • the film comprises between 5%and 50%, preferably between 10%and 40%, more preferably between 20%and 30%by weight of the film of the non-aqueous plasticizer.
  • the water-soluble film comprises a surfactant.
  • the water-soluble film comprises a surfactant in an amount between 0.1%and 2.5%, preferably between 1%and 2%by weight of the water-soluble film.
  • Suitable surfactants can include the nonionic, cationic, anionic and zwitterionic classes.
  • Suitable surfactants include, but are not limited to, polyoxyethylenated polyoxypropylene glycols, alcohol ethoxylates, alkylphenol ethoxylates, tertiary acetylenic glycols and alkanolamides (nonionics) , polyoxyethylenated amines, quaternary ammonium salts and quaternized polyoxyethylenated amines (cationics) , and amine oxides, N-alkylbetaines and sulfobetaines (zwitterionics) .
  • Suitable surfactants include dioctyl sodium sulfosuccinate, lactylated fatty acid esters of glycerol and propylene glycol, lactylic esters of fatty acids, sodium alkyl sulfates, polysorbate 20, polysorbate 60, polysorbate 65, polysorbate 80, lecithin, acetylated fatty acid esters of glycerol and propylene glycol, and acetylated esters of fatty acids, and combinations thereof.
  • the water-soluble film according to the invention comprises lubricants /release agents.
  • Suitable lubricants/release agents can include, but are not limited to, fatty acids and their salts, fatty alcohols, fatty esters, fatty amines, fatty amine acetates and fatty amides.
  • Preferred lubricants/release agents are fatty acids, fatty acid salts, and fatty amine acetates.
  • the amount of lubricant/release agent in the water-soluble film is in a range of from 0.02%to 1.5%, preferably from 0.1%to 1%by weight of the water-soluble film.
  • the water-soluble film comprises fillers, extenders, antiblocking agents, detackifying agents or a mixture thereof.
  • suitable fillers, extenders, antiblocking agents, detackifying agents or a mixture thereof include, but are not limited to, starches, modified starches, crosslinked polyvinylpyrrolidone, crosslinked cellulose, microcrystalline cellulose, silica, metallic oxides, calcium carbonate, talc and mica.
  • Preferred materials are starches, modified starches and silica.
  • the amount of filler, extender, antiblocking agent, detackifying agent or mixture thereof in the water-soluble film is in a range of from 0.1%to 25%, preferably from 1%to 10%, more preferably from 2%to 8%, most preferably from 3%to 5%by weight of the water-soluble film.
  • one preferred range for a suitable filler, extender, antiblocking agent, detackifying agent or mixture thereof is from 0.1%to 1%, preferably 4%, more preferably 6%, even more preferably from 1%to 4%, most preferably from 1%to 2.5%, by weight of the water-soluble film.
  • the water-soluble film according to the invention has a residual moisture content of at least 4%, more preferably in a range of from 4%to 15%, even more preferably of from 5%to 10%by weight of the water-soluble film as measured by Karl Fischer titration.
  • Preferred films exhibit good dissolution in cold water, meaning unheated distilled water.
  • Preferably such films exhibit good dissolution at temperatures of 24°C, even more preferably at 10°C.
  • good dissolution it is meant that the film exhibits water-solubility of at least 50%, preferably at least 75%or even at least 95%, as measured by the method set out here after using a glass-filter with a maximum pore size of 20 microns, described above.
  • Preferred films include those supplied by Monosol under the trade references M8630, M8900, M8779, M8310.
  • the film may be opaque, transparent or translucent.
  • the film may comprise a printed area.
  • the area of print may be achieved using standard techniques, such as flexographic printing or inkjet printing.
  • the ink used in the printed area comprises between 0ppm and 20ppm, preferably between 0ppm and 15ppm, more preferably between 0ppm and 10ppm, even more preferably between 0ppm and 5ppm, even more preferably between 0ppm and 1ppm, even more preferably between 0ppb and 100ppb, most preferably 0ppb dioxane.
  • Those skilled in the art will be aware of known methods and techniques to determine the dioxane level within the ink formulations.
  • the film may comprise an aversive agent, for example a bittering agent.
  • Suitable bittering agents include, but are not limited to, naringin, sucrose octaacetate, quinine hydrochloride, denatonium benzoate, or mixtures thereof.
  • Any suitable level of aversive agent may be used in the film. Suitable levels include, but are not limited to, 1 to 5000ppm, or even 100 to 2500ppm, or even 250 to 2000rpm.
  • the water-soluble film or water-soluble unit dose article or both are coated in a lubricating agent, preferably, wherein the lubricating agent is selected from talc, zinc oxide, silicas, siloxanes, zeolites, silicic acid, alumina, sodium sulphate, potassium sulphate, calcium carbonate, magnesium carbonate, sodium citrate, sodium tripolyphosphate, potassium citrate, potassium tripolyphosphate, calcium stearate, zinc stearate, magnesium stearate, starch, modified starches, clay, kaolin, gypsum, cyclodextrins or mixtures thereof.
  • the lubricating agent is selected from talc, zinc oxide, silicas, siloxanes, zeolites, silicic acid, alumina, sodium sulphate, potassium sulphate, calcium carbonate, magnesium carbonate, sodium citrate, sodium tripolyphosphate, potassium citrate, potassium tripolyphosphate, calcium stearate, zinc stea
  • the water-soluble film and each individual component thereof, independently comprises between 0ppm and 20ppm, preferably between 0ppm and 15ppm, more preferably between 0ppm and 10ppm, even more preferably between 0ppm and 5ppm, even more preferably between 0ppm and 1ppm, even more preferably between 0ppb and 100ppb, most preferably 0ppb dioxane.
  • 0ppm and 20ppm preferably between 0ppm and 15ppm, more preferably between 0ppm and 10ppm, even more preferably between 0ppm and 5ppm, even more preferably between 0ppm and 1ppm, even more preferably between 0ppb and 100ppb, most preferably 0ppb dioxane.
  • a further aspect of the present invention is a method of washing comprising the steps of adding the water-soluble unit dose article according to the present invention to sufficient water to dilute the liquid detergent composition by a factor of at least 300 fold to create a wash liquor and contacting items to be washed with said wash liquor.
  • a further aspect of the present invention is a packaged product comprising a recloseable container and at least one water-soluble unit dose article according to the present invention comprised therein.
  • the storage receptacle is a flexible, preferably resealable, bag, a rigid, preferably recloseable, tub or a mixture thereof, preferably, wherein the storage receptacle comprises a child resistant closure.
  • suitable child resistant closures Those skilled in the art will be aware of suitable child resistant closures.
  • the package may be made from any suitable material.
  • the container may be made from metallic materials, Aluminium, plastic materials, cardboard materials, laminates, cellulose pulp materials or a mixture thereof.
  • the package may be made from a plastic material, preferably a polyolefin material.
  • the package may be made from polypropylene, polystyrene, polyethylene, polyethylene terephthalate, PVC or a mixture thereof or more durable engineering plastics like Acrylonitrile Butadiene Styrene (ABS) , Polycarbonates, Polyamides and the like
  • ABS Acrylonitrile Butadiene Styrene
  • the material used to make the container may comprise other ingredients, such as colorants, preservatives, plasticisers, UV stabilizers, Oxygen, perfume and moisture barriers recycled materials and the like.
  • Test fabrics are washed together with 1.7kg ballast (cotton to fabric ratio 8: 2) and half piece of soil ballast sheets (SBL2004 available from WfK Testgewebe GmbH, Brüggen, Germany) under cycling below:
  • deposition of the anti-mite agent is determined by using GC-MS measurements.
  • the Anti-Mite agent BB (benzyl benzoate) deposited on fabric via laundry is extracted by using ethanol with the aid of ASE (Accelerated Solvent Extractor) .
  • the extraction is analyzed by GC-MS (Agilent Technologies Gas Chromatograph 7890B-Mass Selective Detector 5977B) equipped with J&W TM DB-5ms Ultra Inert Column (30m length x 0.25mm internal diameter x 0.25 ⁇ m film thickness) .
  • the following settings are used for Front Split/Splitless inlet: carrier: helium, Split ratio 10: 1, Heater on 280°C, Pressure 13.81psi, Flow 1.6mL/min.
  • BB is identified by matching retention time and mass spectra with that of BB raw material standard.
  • Deposition amount (BB/fabric: mg/g) is calibrated by external standard curve (Tetradecane as Internal standard) by spiking different amount of BB onto clean/blank fabrics and then extracted/treated analyzed using same procedures with testing samples.
  • Step 2 3) Visually inspect the samples to determine if they are still homogeneous systems after Step 2) . If there is any phase separation such as the formation of separated layers or flocculation, it is determined as “fail” . If there is no phase separation, it is determined as “pass” .
  • Corneometer (available from BMM&DI Clinical Sciences company) is used to measure weeping level of unit dose articles.
  • the Measurement Principle is based on capacitance measurement of a dielectric medium. For Liquitabs it measures the dielectric constant of water and other substances which penetrate the PVA-Film.
  • the unit dose articles need to be pre-conditioned in room condition 25°C or 32°C, 80%RH CTCH for 48hrs.
  • the sensor of the Corneometer To measure the weeping level, put the sensor of the Corneometer on the surface of unit dose articles and press it down slowly until a measurement is registered. For a multi compartment unit dose article, the bottom layer is measured 5 times and each top layer 2 times.
  • Weeping level can then be defined by correlating average, lower and upper limit of the range with the Weeping Scale being reflected below.
  • a 76 ⁇ m thick polyvinylalcohol based water soluble film is used to assess film physical properties.
  • Film physical properties is defined through measuring film thickness increase%, area increase%, volume increase%, maximum tensile stress, and tensile strain%after having subjected the water-soluble film to an ageing experiment through immersing in liquid detergent composition samples as above.
  • a film sample of 12.5 cm by 2.5 cm is immersed within 150 ml of test liquid by 1) selecting a flat clean inert glass recipient, 2) covering the bottom of the recipient with a thin layer of the example formulation to be tested, 3) carefully spreading the film to be tested on the liquid, 4) gently pushing air bubbles trapped under the film towards the sides, 5) gently pouring the remaining example formulation on top of the film, in such a way that the film is fully immersed into the liquid, ensuring that the film is free of wrinkles and that no air bubbles are in contact with the film, and 6) closing the glass container and 7) storing the closed container for 5 days at 50°C, 80%RH CTCH.
  • the film After ageing, the film is removed from the formulation example and gently wiped dry with a soft dry liquid absorbing paper, followed immediately by measuring the post film immersion and stress-strain profile.
  • Comparative Sample 1 is a unit dose article comprising liquid detergent compositions containing the anti-mite agent (i.e., benzyl benzoate) but in absent of any polyethylene glycol.
  • the Inventive Sample 1 contains both benzyl benzoate and Polyethylene glycol having a weight average molecular weight of 200 Daltons 200 (PEG200) .
  • Brightener 49 Premix comprises 8.4%active brightener 49, 39.5%nonionic surfactant and 39.5%propylene glycol 2 Graft copolymer of PVP/PVAc-g-PEG at a weight ratio of 20: 30: 50 ratio with a weight average molecular weight 16,800 Dalton. 3 DTI polymer, poly (1-vinylpyrrolidone-co-1-vinylimidazole) , commercially available as HP 56K from BASF
  • Test 1 Deposition Test as described hereinabove, the deposition of the anti-mite agent for Comparative Sample 1 and Inventive Sample 1 are measured.
  • the results indicate that the introduction of the polyethylene glycol having a weight average molecular weight of from 150 to 2000 Daltons (e.g., polyethylene glycol 200) can significantly improve the deposition of anti-mite agent (1.093 vs. 0.980) .
  • the combination of the anti-mite agent and polyethylene glycol having a weight average molecular weight of from 150 to 2000 Daltons can provide a significant improvement on anti-mite efficacy of the anti-mite agent compared to a detergent formulation containing the anti-mite agent only.
  • Example 2 Exemplary Formulations of Unit Dose Laundry Detergent Compositions
  • the unit dose article comprises one single chamber or multiple compartments.
  • the compartments may be arranged in superposed orientation, i.e., one positioned on top of the other, alternatively, the compartments may be positioned in a side-by-side orientation.
  • Table 3 shows exemplary water-soluble unit dose formulations containing polyethylene glycol having a weight average molecular weight of from 150 to 2000 Daltons and anti-mite agent. These compositions are encapsulated into compartment (s) of the unit dose by using a polyvinyl-alcohol-based film.
  • the composition can be part of a single chamber water soluble unit dose article or can be split over multiple compartments resulting in below “averaged across compartments” full article composition.
  • Nonionic surfactant C 12 -C 14 ethoxylated alcohol 2: Anionic surfactant A: C 12 -C 14 alkyl ethoxylated sulfate 3: Anionic surfactant B: C 11 -C 13 linear alkylbenzene sulfonates 4: SRP polymer: ethoxylated polyethyleneimine commercially available from BASF (PEI600EO20) .

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Abstract

La présente invention concerne des articles en dose unitaire solubles dans l'eau comprenant une composition de détergent à lessive liquide qui comprend du polyéthylène glycol ayant un poids moléculaire moyen en poids d'environ 150 à environ 2000 Daltons et un agent anti-acarien.
PCT/CN2023/098297 2023-06-05 2023-06-05 Article en dose unitaire soluble dans l'eau comprenant une composition de détergent à lessive liquide qui comprend du polyéthylène glycol et un agent anti-acarien Ceased WO2024250143A1 (fr)

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PCT/CN2023/098297 WO2024250143A1 (fr) 2023-06-05 2023-06-05 Article en dose unitaire soluble dans l'eau comprenant une composition de détergent à lessive liquide qui comprend du polyéthylène glycol et un agent anti-acarien

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180334641A1 (en) * 2017-05-17 2018-11-22 Henkel IP & Holding GmbH Stable unit dose compositions
EP3741836A1 (fr) * 2019-05-24 2020-11-25 The Procter & Gamble Company Article de dose unitaire anti-mite
CA3096644A1 (en) * 2020-10-21 2020-12-31 The Procter & Gamble Company Laundry detergent composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20180334641A1 (en) * 2017-05-17 2018-11-22 Henkel IP & Holding GmbH Stable unit dose compositions
EP3741836A1 (fr) * 2019-05-24 2020-11-25 The Procter & Gamble Company Article de dose unitaire anti-mite
CA3096644A1 (en) * 2020-10-21 2020-12-31 The Procter & Gamble Company Laundry detergent composition

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