WO2024251832A1 - Vitrage et son procédé de fabrication - Google Patents

Vitrage et son procédé de fabrication Download PDF

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Publication number
WO2024251832A1
WO2024251832A1 PCT/EP2024/065495 EP2024065495W WO2024251832A1 WO 2024251832 A1 WO2024251832 A1 WO 2024251832A1 EP 2024065495 W EP2024065495 W EP 2024065495W WO 2024251832 A1 WO2024251832 A1 WO 2024251832A1
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WO
WIPO (PCT)
Prior art keywords
dielectric layer
glazing
substrate
layer
uppermost dielectric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/EP2024/065495
Other languages
English (en)
Inventor
Thomas TROST
Yahya MOTEMANI SHARABIANI
Jan Hagen
Marie GUIN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Original Assignee
Saint Gobain Glass France SAS
Compagnie de Saint Gobain SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saint Gobain Glass France SAS, Compagnie de Saint Gobain SA filed Critical Saint Gobain Glass France SAS
Publication of WO2024251832A1 publication Critical patent/WO2024251832A1/fr
Anticipated expiration legal-status Critical
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001—General methods for coating; Devices therefor
    • C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23—Oxides
    • C03C17/245—Oxides by deposition from the vapour phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
    • C03C17/366—Low-emissivity or solar control coatings
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/15—Deposition methods from the vapour phase
    • C03C2218/154—Deposition methods from the vapour phase by sputtering
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/06—Coating with compositions not containing macromolecular substances

Definitions

  • the present invention relates to a glazing comprising a protective layer for imparting scratch and/or wear resistance and a method for producing such glazing.
  • Glazing substrate such as soda-lime glass or polymer substrates
  • Coatings that are provided on glazing substrates for imparting specific functionalities may also be sensitive to mechanical abrasion.
  • Such protective layer also called “overcoat”, is usually very thin.
  • Such protective layer can be deposited using conventional thin layer deposition processes, such as sputtering process, in particular enhanced by a magnetic field, referred to in this case as the "magnetron" process.
  • Diamond like carbon (DLC) overcoats are well-known for increasing the scratch resistance of glazing systems.
  • the main drawback of DLC is their intrinsic thermal instability. For this reason, DLC coatings are not suitable per se for application requiring exposure to high temperature such as tempering. Additional sacrificial layers must be provided for protecting the DLC coating during heat treatments (WO 2005/021454, WO 2019/020485). This solution however, in addition to complicating the manufacturing process, cannot completely avoid the degradation of the anti-scratch properties of the DLC coating.
  • Transition-metal oxides based overcoats such as zirconium oxide based layers or titanium and zirconium oxide based layers, have also been used as protective layers (WO 2016/097557). Such overcoats can withstand thermal treatments and moderately improve the scratch resistance of glazing systems but they generally do not reach the anti-scratch performances of DLC coatings.
  • oxide layer comprising hafnium and zirconium, and optionally vanadium, in top of fulfilling those requirements, also provide good transparency in the visible range, which is particularly advantageous for glazing applications.
  • the present invention relates to a glazing comprising a substrate coated with a coating comprising an uppermost dielectric layer, wherein said uppermost dielectric layer is an oxide layer comprising from 55 to 85 at.% of hafnium, from 5 to 28 at.% of zirconium and from 2 to 35 at.% of niobium based on the total of metallic atoms.
  • the uppermost dielectric layer of the invention provides good scratch resistance properties. It can also tolerate heat treatments, which appears, contrary to DLC layers, to improve its scratch resistance properties. Accordingly, the coating of the invention is advantageously submitted to heat treatment, such as tempering, bending or annealing using laser radiation, flash lamp or infrared lamps.
  • the substrate is preferably a glass substrate or polymeric substrate, such as polycarbonate. It is preferably transparent, colorless or colored, for example blue, green, gray or bronze.
  • the thickness of the substrate generally varies between 0.7 mm and 19 mm, preferably between 1 and 10 mm, in particular between 2 and 68 mm, and even between 2 and 4 mm.
  • the substrate can be flat or bent.
  • the substrate has typically a light transmission of at least 30%.
  • the glass is preferably of soda-lime-silica type but it can also be a glass of borosilicate or alumino-borosilicate type.
  • the glass substrate is preferably of the float glass type, that is to say capable of having been obtained by a process which consists in pouring the molten glass onto a bath of molten tin ("float" bath).
  • the glass substrate can also be obtained by rolling between two rolls, a technique which makes it possible in particular to print patterns at the surface of the glass.
  • the glass substrate may be tempered glass.
  • the glass substrate can be a colored glass.
  • the glass substrate preferably comprises coloring agents, with the following weight contents: Fe20s (total iron) from 1.2 to 2.3%, in particular from 1.5 to 2.2%, CoO from 50 to 400 ppm, in particular from 200 to 350 ppm, Se from 0 to 35 ppm, in particular from 10 to 30 ppm.
  • the redox is preferably from 0.1 to 0.4, more preferably from 0,2 to 0,3.
  • the redox is defined by the weight ratio of ferrous iron (expressed as FeO) to total iron (expressed as Fe20s).
  • the glass comprises only iron oxide as coloring agent in a weight content as follows: Fe20s (total iron) from 0.1 to 1.1%, in particular from 0.5 to 1.0%.
  • the redox is preferably from 0.1 to 0.4.
  • the glass substrate can be a clear or extra-clear glass.
  • the term "clear glass” is understood to mean a soda-lime-silica glass obtained by floating which is not coated with layers and which exhibits a light transmission of the order of 90%, a light reflection of the order of 8% and an energy transmission of the order of 87%, for a thickness of 4 mm.
  • the light and energy transmissions and reflections are as defined by the standard NF EN 410.
  • Typical clear glasses are, for example, sold under the name SGG PlaniClear by Saint-Gobain Glass France or under the name Planibel Clair by AGC Flat Glass Europe. These substrates are conventionally employed in the manufacture of vehicle glazings.
  • the uppermost dielectric layer is provided on the substrate. It has typically a thickness from 2 to 100 nm, preferably from 5 to 60 nm, or to 40nm, or even to 20 nm.
  • the uppermost dielectric layer may be in direct contact with the substrate.
  • an adhesion layer or a barrier layer may be provided between the substrate and the uppermost dielectric layer.
  • a functional stack may be provided between the substrate and the uppermost dielectric layer.
  • the uppermost dielectric layer is the last layer of the coating and in direct contact with the atmosphere.
  • the terms “below” and “above” associated with the position of two elements A and B do not rule out the presence of other elements between said elements A and B.
  • the first layer is closer to, respectively further from, the substrate than the other.
  • an element A "in direct contact” with an element B means that no other element is positioned between these. It is the same for the expressions “directly on” and “directly under”. Thus, it is understood that, unless it is indicated otherwise, other elements may be inserted between each of the elements.
  • dielectric layer within the meaning of the present invention refers to a nonmetallic layer, in other words a layer which does not consist of metal.
  • the uppermost dielectric layer comprises from 55 to 85 at.%, preferably 60 to 85 at.%, more preferably 62 to 83 at.%, of hafnium, from 5 to 28 at.%, preferably 7 to 22 at.%, more preferably 9 to 20 at.%, of zirconium, and from 2 to 35 at.%, preferably 5 to 32 at.%, more preferably 8 to 30 at.%, of niobium, the percentages being based on the total of metallic atoms in the uppermost dielectric layer.
  • the uppermost dielectric layer can comprises from 60 to 85 at.% of hafnium, from 5 to 22 at.% of zirconium, and from 2 to 35 at.% of niobium.
  • the uppermost dielectric layer can comprises from 62 to 83 at.%, of hafnium, from 7 to 22 at.% of zirconium, and from 5 to 32 at.% of niobium.
  • Hafnium, zirconium and niobium represent typically more than 80 at.%, preferably more than 90 at.%, more preferably more than 95 at.% of the total metallic atoms in the uppermost dielectric layer.
  • the coating of the invention may comprise an adhesion layer or barrier layer between the substrate and the uppermost dielectric layer.
  • the adhesion layer or barrier layer is preferably in direct contact with the substrate and the uppermost dielectric layer. It may be based on silicon oxide, silicon nitride or silicon oxynitride. Its thickness is typically from 5 to 80 nm, preferably from 10 to 50 nm.
  • the coating of the invention may comprise a functional stack between the substrate and the uppermost dielectric layer.
  • the functional stack may provide specific properties to the article of the invention such as solar control, low-emissivity, electromagnetic shielding, heating, anti-condensation, anti -reflection or privacy properties.
  • the functional stack may be a solar-control or low-emissivity coating. It may comprise a functional layer selected from infrared reflecting metal layers, such as a silver layer, or a transparent conductive oxide, such as indium tin oxide (ITO).
  • ITO indium tin oxide
  • the functional layer is preferably provided between at least two dielectric layers.
  • the dielectric layers are typically based on silicon oxide, nitride or oxynitride, titanium oxide, zinc oxide, zirconium oxide or mixtures thereof.
  • composition of a layer means that said layer comprises at least 80% by weight of the specified material, preferably more than 90%, such as more than 95% by weight of said material. Said layer may essentially consist of said material, i.e. comprising more than 99% of said material.
  • composition of a layer means that said layer comprises only said material and inevitable impurities.
  • the glazing of the present invention can be a building glazing or a vehicle glazing, e.g. for cars, trucks, trains...
  • the glazing may be a single (monolithic) glazing, a multiple (in particular double or triple) glazing or a laminated glazing. It may be tempered or bent.
  • the coating according to the present invention is generally positioned on the external faces of the glazing (either toward indoor and/or toward outdoor).
  • the glazing is preferably a vehicle glazing, such as a windshield, a sidelite or a sunroof of a vehicle, wherein the coating is on the side exposed to external environment.
  • the glazing of the present invention has typically a light transmission of at least 30%, preferably at least 50% or even at least 70%.
  • the glazing of the present invention is a laminated glazing comprising a first glass substrate, in particular intended to be on positioned on the external side of a vehicle, having an external surface Fl and a connecting surface F2, a second glass substrate, in particular intended to be positioned at the inner side of a vehicle, having a connecting surface F3 and an internal surface F4, and a laminating layer between the first and second glass substrates, wherein the first glass substrate is coated with the coating of the invention on its external surface Fl .
  • the second glass substrate may be similar to or different from the first glass substrate.
  • the second glass substrate is preferably of soda-lime-silica type but it can also be a glass of borosilicate or alumino-borosilicate type. It can be clear or colored. It has typically a thickness from 0,5 to 4 mm, preferably from 1 to 3 mm.
  • the laminating layer is in contact, preferably in direct contact, with the connecting surface of the first glass substrate F2 and of the second glass substrate F3.
  • the laminating layer is typically a polymeric layer comprising at least one layer, such as a polyvinylacetal layer, in particular polyvinylbutyral (PVB). It preferably consists of such PVB layers. It can be colorless or colored, in particular for adapting the optical and/or thermal properties of the glazing if needed.
  • the laminating layer can advantageously have sound absorption properties for absorbing air-borne and/or structure-borne sounds. It can for instance comprise three polymeric layers including two external polymeric layers, preferably PVB layers, and one internal polymeric layer, optionally also a PVB layer, between the two external layers, wherein the internal layer has a lower hardness than the external layers.
  • the laminating layer can also have heat insulation properties, in particular by reflecting infrared radiations.
  • it may comprise a low emissivity (low-e) coating, e.g. a coating comprising a silver layer or a coating comprising a succession of alternating dielectric layers having low refractive index and high refractive index.
  • low-e coting can be deposited on a polyethylene terephtalate (PET) layer sandwiched between two PVB layers.
  • the laminating layer has typically a thickness from 0,3 to 1,5 mm, preferably from 0,5 to
  • the laminating layer can have a lower thickness on one side of the glazing compared to the center of the glazing in order to avoid ghost image when using a head-up display (HUD) system.
  • HUD head-up display
  • the glazing of the present invention preferably comprises at least one sensor, typically positioned on the internal side of the glazing, i.e. the internal surface F4 of a laminated glazing s defined above.
  • Said at least one sensor can be a camera system (e.g. in the visible wavelength and/or infrared wavelength range, in particular near infrared or thermal infrared) or a Lidar.
  • the present invention also relates to a process for manufacturing a glazing as defined above, comprising providing a glazing substrate and depositing a coating comprising an uppermost dielectric layer on said substrate resulting in a coated substrate, wherein said uppermost dielectric layer is an oxide layer comprising from 55 to 85 at.%, preferably 60 to 85 at.%, more preferably 62 to 83 at.%, of hafnium, from 5 to 28 at.%, preferably 7 to 22 at.%, more preferably 9 to 20 at.%, of zirconium, and from 2 to 35 at.%, preferably 5 to 32 at.%, more preferably 8 to 30 at.%, of niobium, the percentages being based on the total of metallic atoms in the uppermost dielectric layer.
  • the present invention also relates to a process for protecting (i.e. improving its scratch resistance) an article, in particular comprising a glass or polymeric substrate, comprising depositing a coating comprising an uppermost dielectric layer on said substrate, wherein said uppermost dielectric layer is an oxide layer comprising from 55 to 85 at.%, preferably 60 to 85 at.%, more preferably 62 to 83 at.%, of hafnium, from 5 to 28 at.%, preferably 7 to 22 at.%, more preferably 9 to 20 at.%, of zirconium, and from 2 to 35 at.%, preferably 5 to 32 at.%, more preferably 8 to 30 at.%, of niobium, the percentages being based on the total of metallic atoms in the uppermost dielectric layer.
  • the present invention also relates to the use of an uppermost dielectric layer for improving the scratch resistance of an article, in particular comprising a glass or polymeric substrate, wherein said uppermost dielectric layer ins an oxide layer comprising from 55 to 85 at.%, preferably 60 to 85 at.%, more preferably 62 to 83 at.%, of hafnium, from 5 to 28 at.%, preferably 7 to 22 at.%, more preferably 9 to 20 at.%, of zirconium, and from 2 to 35 at.%, preferably 5 to 32 at.%, more preferably 8 to 30 at.%, of niobium, the percentages being based on the total of metallic atoms in the uppermost dielectric layer.
  • the uppermost dielectric layer may be deposited on the substrate by sputtering method, in particular using magnetic-field-assisted cathode sputtering process ("magnetron" process).
  • the coating comprises other layers, such as a barrier or adhesion layer, or a functional stack, the whole coating is advantageously deposited by sputtering method.
  • the sputtering may be a reactive sputtering using metallic target in oxidative atmosphere.
  • oxide targets having the same composition as the uppermost dielectric layer can be used for depositing the uppermost dielectric layer.
  • the uppermost dielectric layer of the present invention can withstand heat treatment. Its scratch resistance properties even appear to be improved by heat treatments.
  • the process of the present invention thus advantageously includes a heat treatment step subsequent to the deposition of the coating.
  • the heat treatment can be selected from tempering, bending or annealing.
  • the heat treatment step may be a tempering step, particularly in the case of a glass substrate. Tempering is typically performed at temperatures from 550 to 750°C for few minutes such as 3 to 30 minutes.
  • the heat treatment may be a bending step, particularly in the case of a glass substrate. Bending can be performed by gravity (the glass substrate deforming under its own weight) or by pressing, at temperatures typically from 550 to 650°C.
  • the glazing comprises at least two glass substrates, such as for laminated glazings
  • the glass substrates can be bend separately.
  • the two glass substrates are bend together.
  • a separating powder such as calcium and/or magnesium carbonate, can be introduced between the two glass substrates during the bending in order to keep the two substrates separated from each other by creating a space, typically from 20 to 50 pm wide.
  • the second glass substrate generally intended to be positioned at the inner side of a vehicle, is typically placed on the first glass substrate.
  • the heat treatment step may be an annealing step, in particular rapid annealing methods using laser, flash lamps or infrared lamps.
  • annealing step in particular rapid annealing methods using laser, flash lamps or infrared lamps.
  • Such methods are particularly adapted for improving the properties of functional coatings, e.g. crystallizing infrared reflective layers, by heating the functional coating typically at temperatures from 200 to 600°C for few seconds, or even less than 1 second, without heating the substrate. It is thus adapted to glass substrates as well as polymeric substrates.
  • Oxide layers comprising different proportions of hafnium, zirconium and niobium are deposited on Planiclear® glass substrates by magnetron sputtering using co-sputtering of three metallic targets in an oxidative Ar-O? atmosphere under a pressure from 3.0el0' 3 to 5.0el0‘ 3 mbar.
  • the scratch resistance of the oxide layers is measured after tempering at 640°C for 8 minutes and few days of exposure to ambient atmosphere.
  • Scratch resistance test a side of borosilicate bead piece is slid on the surface of the sample. One single run is performed for a distance of about 10 mm with a constant load of 10 N. The scratch test is repeated similarly with a steel bead under a load of 5 N and 10 N. All the scratch tests are performed and evaluated by a single trained technician in order to ensure repeatability. The scratch resistance is rated based on the resulting scratch marks observed by microscope: ® extremely visible scratch marks; Q moderately visible scratch marks; O very slightly visible scratch marks; ⁇ no visible scratch marks. For comparison, similar scratch test is performed on uncoated Planiclear® substrate (CO), and Planiclear® substrate coated with DLC layer (Cl) and hafnium oxide layer (C2). The results of the scratch tests are summarized in table 1 .
  • all examples II to 17 according to the invention have better scratch resistance than the uncoated substrate CO and example Cl comprising a DLC layer, and at least similar scratch resistance as example C2 comprising a HfOx layer. 14 to 17 have even better scratch resistance than the example C2 comprising a HfOx layer.
  • the oxide layers of examples II to 17 have excellent transparency and neutral color which remain very similar after tempering.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

La présente invention concerne un vitrage comprenant un substrat revêtu d'un revêtement comprenant une couche diélectrique supérieure, ladite couche diélectrique supérieure étant une couche d'oxyde comprenant de 55 à 85 at. % d'hafnium, de 5 à 28 at. % de zirconium, et de 2 à 35 at. % de niobium, ainsi qu'un procédé de fabrication dudit vitrage.
PCT/EP2024/065495 2023-06-06 2024-06-05 Vitrage et son procédé de fabrication Pending WO2024251832A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP23305895.7 2023-06-06
EP23305895 2023-06-06

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Publication Number Publication Date
WO2024251832A1 true WO2024251832A1 (fr) 2024-12-12

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005021454A2 (fr) 2003-09-02 2005-03-10 Guardian Indusries Corp. Article revetu thermotraitable avec revetement a base de carbone sous forme de diamant amorphe (depot cda)
WO2016097557A1 (fr) 2014-12-19 2016-06-23 Saint-Gobain Glass France Vitrage contrôle solaire ou bas émissif comprenant une couche de protection supérieure
US20170369367A1 (en) * 2014-12-23 2017-12-28 Saint-Gobain Glass France Glazing comprising a carbon-based upper protective layer
US20180029930A1 (en) * 2015-02-24 2018-02-01 Saint-Gobain Glass France Glazing comprising a protective coating
WO2019020485A1 (fr) 2017-07-26 2019-01-31 Saint-Gobain Glass France Revêtements thermiquement conditionnables présentant du carbone similaire au diamant
US20220009826A1 (en) * 2018-11-16 2022-01-13 Saint-Gobain Glass France Heat-treated material having improved mechanical properties
US20220363036A1 (en) * 2019-09-30 2022-11-17 Saint-Gobain Glass France Laminated glazing having low light transmission and high selectivity

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005021454A2 (fr) 2003-09-02 2005-03-10 Guardian Indusries Corp. Article revetu thermotraitable avec revetement a base de carbone sous forme de diamant amorphe (depot cda)
WO2016097557A1 (fr) 2014-12-19 2016-06-23 Saint-Gobain Glass France Vitrage contrôle solaire ou bas émissif comprenant une couche de protection supérieure
US20170369367A1 (en) * 2014-12-23 2017-12-28 Saint-Gobain Glass France Glazing comprising a carbon-based upper protective layer
US20180029930A1 (en) * 2015-02-24 2018-02-01 Saint-Gobain Glass France Glazing comprising a protective coating
WO2019020485A1 (fr) 2017-07-26 2019-01-31 Saint-Gobain Glass France Revêtements thermiquement conditionnables présentant du carbone similaire au diamant
US20220009826A1 (en) * 2018-11-16 2022-01-13 Saint-Gobain Glass France Heat-treated material having improved mechanical properties
US20220363036A1 (en) * 2019-09-30 2022-11-17 Saint-Gobain Glass France Laminated glazing having low light transmission and high selectivity

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