WO2025006750A2 - Filtre et appareil de fabrication et procédé associé - Google Patents

Filtre et appareil de fabrication et procédé associé Download PDF

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Publication number
WO2025006750A2
WO2025006750A2 PCT/US2024/035822 US2024035822W WO2025006750A2 WO 2025006750 A2 WO2025006750 A2 WO 2025006750A2 US 2024035822 W US2024035822 W US 2024035822W WO 2025006750 A2 WO2025006750 A2 WO 2025006750A2
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WO
WIPO (PCT)
Prior art keywords
slurry
liquid
filter body
filter
cylindrical structure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2024/035822
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English (en)
Other versions
WO2025006750A3 (fr
Inventor
Hai-Feng Zhang
Devin GAREIS
Yilda TORRES
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AO Smith Corp
Original Assignee
AO Smith Corp
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Filing date
Publication date
Application filed by AO Smith Corp filed Critical AO Smith Corp
Priority to CN202480033966.7A priority Critical patent/CN121263247A/zh
Publication of WO2025006750A2 publication Critical patent/WO2025006750A2/fr
Publication of WO2025006750A3 publication Critical patent/WO2025006750A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/14—Other self-supporting filtering material ; Other filtering material
    • B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
    • B01D39/2055—Carbonaceous material
    • B01D39/2058—Carbonaceous material the material being particulate
    • B01D39/2062—Bonded, e.g. activated carbon blocks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04—Additives and treatments of the filtering material
    • B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/0604—Arrangement of the fibres in the filtering material
    • B01D2239/0636—Two or more types of fibres present in the filter material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/0604—Arrangement of the fibres in the filtering material
    • B01D2239/064—The fibres being mixed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/0645—Arrangement of the particles in the filtering material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/08—Special characteristics of binders
    • B01D2239/086—Binders between particles or fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10—Filtering material manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/12—Special parameters characterising the filtering material
    • B01D2239/1233—Fibre diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/12—Special parameters characterising the filtering material
    • B01D2239/1241—Particle diameter

Definitions

  • Water filters constructed using activated carbon are capable of removing undesirable chemicals, disinfection byproducts for example, from drinking water.
  • One common type of such filters is made by housing granular activated carbon (GAC) within a container. While cost- effective, such filter have generally low performance, and must be of a large size or must be replaced frequently.
  • Another type of such filter is a carbon block filter, made by extruding or compression molding carbon powder with a binder. Such carbon block filters have somewhat better performance, but can suffer from increased cost and undesirably high pressure drop, and are difficult to make in larger sizes.
  • Carbon block filters have the benefit of being formed via a one-step process (molding or extrusion). Additives can be added into the carbon block filter to increase the functionality of the filter. However, forming a carbon block filter having both a low pressure-drop and high performance is limited by the brittleness of the carbon block filter. The brittleness of the carbon block filter also makes it difficult to produce larger filters. In contrast to carbon block filters, composite paper type filters can have multiple functions with a low pressure drop, increased performance and the potential for a longer lifetime. However, a drawback of the composite paper type filters is that the manufacturing process is a two-step process: first making the composite filter papers, and then rolling the filter papers into filters. Furthermore, there are limitations in improving the performance of composite paper type filters, as the amount of carbon that can be added to such filter is limited by the need to maintain flexibility in the paper material for rolling.
  • the present disclosure relates to a method of making a water filter.
  • the method of making a water filter includes creating a slurry mixture comprising a liquid, at least one fiber material, and powder.
  • a filter body is built from the slurry while simultaneously removing at least a portion of the liquid from the slurry.
  • the filter body is cured using heat to form a filter block.
  • the powder includes activated carbon, and in some such embodiments at least 90% by weight of the activated carbon has a particle size that is in the range of 45pm to 180pm.
  • the powder includes at least one additive.
  • the at least one additive includes a Heavy Metal Removal Power (HMRP).
  • the at least one additive includes Activated Teff Straw (ATF).
  • the at least one additive includes Kinetic Degradation Fluxion (KDF) material.
  • combinations of two or more of the above are provided as additives.
  • at least 50% by weight of an additive has a particle size between 20pm to 50pm.
  • the fiber material includes activated carbon fiber (ACF).
  • the fiber material includes glass fiber.
  • the fiber material includes Polyethylene Terephthalate (PET).
  • PET Polyethylene Terephthalate
  • the fiber material includes cellulose.
  • the fiber material includes acrylic.
  • the fiber material includes two or more of the above.
  • the fiber includes at least two fiber materials.
  • the fibers of a first fiber material have lengths in a range of 1-10pm and the fibers of the second fiber material have lengths in a range of 3-5mm. Some particular embodiments have 2-10% by weight of the fiber consisting of PET fibers having lengths of 3-5mm.
  • the slurry is at least 90% liquid by weight after the slurry mixture is created.
  • the portion of the liquid removed while building the filter body is removed by a centrifugal force or a compressive force or both.
  • the filter body is dried to remove a remaining portion of the liquid prior to curing the filter body.
  • Some embodiments include building the filter body by rotating a liquid-permeable hollow cylindrical structure about a central axis, dispensing the slurry mixture within an internal volume of the hollow cylindrical structure, and building from the slurry a filter body upon the hollow cylindrical structure in a radially inward direction.
  • the portion of the liquid can be removed from the filter body through the liquid-permeable hollow cylindrical structure by way of centrifugal force caused by rotating the structure about the central axis.
  • dispensing the slurry mixture can include delivering the slurry mixture into a hollow tube arranged approximately along the central axis and translating the hollow tube parallel to the central axis such that an opening of the hollow tube repeatedly traverses between a first and a second end of the hollow cylindrical structure.
  • the opening can, in some embodiments, traverse between the first end and the second end at a rate of 1-20 cycles per minute.
  • the liquid-permeable hollow cylindrical structure can, ins some embodiments, rotate at a rate of 1000-2500 revolutions per minute.
  • a first portion of liquid is removed from the slurry prior to the step of building the filter body, and a second portion of liquid is removed from the slurry while building the filter body.
  • the slurry can have a first liquid content after the slurry mixture is created and a second liquid content after removing the first portion of the liquid from the slurry.
  • the second liquid content is between 10% and 30% of the first liquid content.
  • the first portion of liquid is removed from the slurry by placing the slurry in contact with a liquid-permeable membrane, applying a negative pressure gradient across the liquid-permeable membrane, and driving the first portion of liquid through the liquid-permeable membrane using the negative pressure gradient.
  • building the filter body includes placing the slurry into a mold having one or more orifices arranged at at least one end of the mold, and applying a compressive load to the slurry in order to drive the second portion of the liquid from the slurry through the one or more orifices.
  • Fig. 1 is a flowchart detailing a method of making a water filter according to one embodiment.
  • Fig. 2 is a schematic front view of an apparatus used in some embodiments of the method of Fig. 1.
  • Fig. 3 is an enlarged front view of a liquid-permeable hollow cylindrical structure of the apparatus of Fig. 2.
  • Fig. 4 is a schematic side view of the apparatus of Fig. 2.
  • FIG. 5 an enlarged front view of a hollow tube that provides a slurry mixture to the hollow cylindrical structure of Fig. 3.
  • Fig. 6 is a schematic side view of the hollow tube providing the slurry mixture to the hollow cylindrical structure.
  • Fig. 7 is a flowchart detailing a method of making a water filter according to another embodiment.
  • Fig. 8 is a schematic front view of an apparatus used in some embodiments of the method of Fig. 7.
  • Fig. 9 is a bottom view of an apparatus used in some embodiments of the method of Fig. 7.
  • Fig. 10 is a cross-sectional side view of the apparatus of Fig. 9, as viewed along the lines X-X of Fig. 9.
  • Fig. 1 illustrates a method of making a water filter with Figs. 2-6 illustrating one embodiment of an apparatus for carrying out the method illustrated in Fig. 1.
  • the method of making a water filter according to Fig. l is a wet process for filter making that includes forming a slurry, radially building a filter from the slurry, drying the filter, and curing the filter.
  • a slurry is formed.
  • the slurry includes one or more powders, one or more fibers, and a liquid material.
  • the powder can include activated carbon and, in different embodiments, includes additional additives to provide various different functions, as desired.
  • HMRP heavy metal removal powder
  • ATF activated teff straw
  • KDF kinetic degradation fluxion
  • Other additives may be further included to reduce contaminants such as heavy metals, chlorine, and bacteria.
  • the particle size of the activated carbon powder is less than 200pm and in some embodiments is as small as 20pm (e.g., between 20pm-200pm, at least 20pm). In one embodiment, at least 90% of the activated carbon powder has a particle size between 44pm and 177pm.
  • the particle size of the additives is dependent upon the particular additive and may be similar to the particle size of the activated carbon. In some embodiments, the particle size of the additives is between 20pm and 50pm.
  • the fibers incorporated into the slurry include inorganic fibers such as activated carbon fiber (ACF) and/or glass fiber.
  • the fibers include organic fibers such as polyethylene terephthalate (PET), cellulose, and/or acrylic.
  • PET polyethylene terephthalate
  • the fibers can have varying diameters and lengths.
  • glass fiber can have a diameter between 100nm-200nm and an average length of 1 -1 Opm.
  • Activated carbon fiber can have a diameter between 3-5pm (or larger) with an average length between 0. lmm-3.0mm.
  • PET can have a diameter between 1-5 gm and an average length between 3mm-5mm.
  • PET is a binding fiber having a core-sheath structure with a core and a sheath having different melting temperatures to bind the structure without damaging the structure.
  • Cellulose can have a diameter as small as 0. 1 gm and a length between 2gm-100gm.
  • Other fibers not listed herein can have sizes ranging the size of cellulose to the size of PET.
  • Multiple fiber materials may be used simultaneously within the mixture for the slurry. For example, long fibers (e.g., 3mm-6mm PET) may be mixed with short fibers at a ratio of 5-25: 1 (e.g., 5: 1, 10: 1, 15: 1, 20: 1) by weight.
  • the powder(s) and fiber(s) are added to the liquid, which, in some embodiments, is water.
  • the weight ratio of powder to fiber can, in some exemplary embodiments, be between 2: 1 and 10: 1.
  • the ratio of solids to liquids is between 1 : 100 and 10: 100 by weight (i.e., 10-100 times more liquid than solid) to facilitate sufficient flow during the filter building process.
  • the ratio of solids to liquids is in the range of 1 : 10 to 1 : 50 by weight (e.g., 1 :10, 1 :20, 1:50, etc.).
  • the materials are mixed together and homogenized via a mixer (e.g., a high shear rotary mixer) to form the slurry.
  • the solids are mixed with the liquids via rotation of rotor blades of the mixer at speeds between 1000RPM- 6000RPM.
  • a filter is built from the slurry.
  • Figs. 2-6 illustrate an apparatus 200 for forming the filter from the slurry.
  • the apparatus 200 includes a base 204 that rests upon a flat surface (e.g., a ground surface, a tabletop surface).
  • the base 204 supports a liquid-permeable hollow cylindrical structure 208 within which the filter is formed.
  • the hollow cylindrical structure 208 is rotatably mounted to the base 200 such that the hollow cylindrical structure 208 is configured to rotate about a rotational axis 212.
  • the hollow cylindrical structure 208 is generally cylindrical and has a central axis that is coaxial with the rotational axis 212.
  • the hollow cylindrical structure 208 is mounted to the base 204 such that the rotational axis 212 extends generally parallel with the flat surface upon which the apparatus 200 rests.
  • the hollow cylindrical structure 208 is shown in greater detail in Fig. 3.
  • the hollow cylindrical structure 208 includes a first end plate 216 at a first axial extent 220 of the hollow cylindrical structure 208, a second end plate 224 at a second axial extent 228 (opposite the first axial extent 220), and a liquid permeable cylinder 232 extending between the two end plates 216, 224.
  • the liquid permeable cylinder 232 is a mesh tube and may be formed as a porous polymer tubing or as stainless-steel mesh.
  • a woven sheet or a non-woven porous paper or mat may be positioned within the liquid permeable cylinder 232 to prevent solid material loss through the openings 236 of the liquid permeable cylinder 232.
  • the openings 236 in the mesh tube 232 are between 0.5mm and 2.0mm in diameter (or width if non-circular) with the openings 236 covering between 20% and 70% of the surface of the liquid permeable cylinder 232.
  • the inner diameter of the liquid permeable cylinder 232 corresponds to the desired outer diameter of the finished filter formed therein. Accordingly, filters having different outer diameters can be formed by utilizing cylinders 232 of different inner diameters.
  • the inner diameter of the cylinder 232 may be as small as 10mm. In other embodiments, the inner diameter of the cylinder 232 may be 25mm-100mm. Still other embodiments may utilize a cylinder 232 having an inner diameter larger than those, including a diameter of 250mm or greater.
  • a plurality of support rods 237 extend between the two end plates 224 to secure the second end plate 224 to the first end plate 220.
  • the support rods 237 are located radially outward of the liquid permeable cylinder 232 so as to not interfere with the filter forming process within the cylinder 232.
  • the support rods 237 are formed as threaded rods held in place via nuts threaded thereon.
  • the support rods 237 are preferably arranged at a constant angular spacing around the rotational axis 212, such as (for example) at 90°, 60°, 45°, etc.
  • Each end plate 216, 224 (or in some embodiments, only the second end plate 224) includes a central opening 240 centered on the rotational axis 212. With the exception of the central openings 240, the end plates 216, 224 are substantially liquid impermeable to prevent liquids and solids from passing therethrough during the fdter making process.
  • a delivery tube 244 extends through the central openings 240 to deliver the slurry into the hollow cylindrical structure 208. As shown in Fig. 2, the delivery tube 244 is mounted to the base 204 and includes an inlet 248 at a first end, and an opening or outlet 252 (Fig. 5) within the hollow cylindrical structure 208.
  • the outlet 252 is located between the ends of the delivery tube 244. As shown in greater detail in Fig. 5, the outlet 252 is preferably located on a lower side (underside) of the delivery tube 244 such that gravity assists in delivering the slurry from the tube 244 into the liquid permeable cylinder 232. In other embodiments where only the second plate 224 includes a central opening, the second end of the delivery tube 244 may terminate within the hollow cylindrical structure 208 with the outlet formed at the second end.
  • the delivery tube 244 is hollow at least between the inlet 248 and the outlet 252, such that the slurry is configured to enter the inlet 248 of the delivery tube 244 and exit the delivery tube 244 via the outlet 252.
  • the inner diameter of the delivery tube 244 may be between 0.5” and 3” (and may be larger, for producing larger filter sizes). In some embodiments, such as larger-scale apparatuses 200, multiple delivery tubes 244 may be utilized simultaneously.
  • the inlet 248 is coupled to a slurry tank 256 that holds the slurry, with the slurry fed from the slurry tank 256 to the delivery tube 244 via a pump or via a gravity feed (i.e., the outlet of the slurry tank 256 being positioned above the outlet 252 of the delivery tube 244).
  • a gravity feed i.e., the outlet of the slurry tank 256 being positioned above the outlet 252 of the delivery tube 244.
  • other methods may be utilized to move the slurry out of the slurry tank, such as a hydraulic cylinder.
  • a mixer may be positioned within the slurry tank 256 to continually mix the slurry within the slurry tank 256, even during operation of the apparatus 100.
  • a valve 260 can be positioned between the slurry tank 256 and the outlet 252 of the delivery tube 244 (i.e., between the slurry tank 256 and the inlet 248 of the delivery tube 244 or between the inlet 248 of the delivery tube 244 and the outlet 252 of the delivery tube 244) to control the flow from the slurry tank 256.
  • the valve 260 is manually actuated.
  • the valve 260 is actuated electronically, hydraulically, or a combination of the same, based on a signal (e.g., from a controller).
  • the delivery tube 244 is mounted to a support 254 (and optionally a further support, such as within the output shaft 272) that permits axial translation of the delivery tube 244 relative to the base 204 and relative to the hollow cylindrical structure 208.
  • the outlet 252 is configured to translate along the length of the mesh tube 232 between the two end plates 216, 224 to facilitate delivery of the slurry along the entire length of the mesh tube 232.
  • the delivery tube is configured to travel such that the outlet 252 translates between the two axial extents at a rate of 1-20 cycles per minute (a cycle being defined as translating from a first end to a second end and then back to the first end).
  • the delivery tube 244 is moved manually by an operator.
  • the delivery tube is moved electrically or hydraulically (e.g., by a motor, linear actuator, lead screw, etc.) and is controlled via a controller to move at a predetermined rate.
  • the base 204 of the apparatus 200 includes a motor 262 for imparting rotation to the hollow cylindrical structure 208.
  • the motor 262 includes a motor shaft 264 that rotates the hollow cylindrical structure 208, either directly or indirectly (e.g., through a belt and pully or gear arrangement 268).
  • the motor shaft 264 can indirectly drive the hollow cylindrical structure 208 through a separate output shaft 272 that is coupled to the hollow cylindrical structure 208 for rotating with the hollow cylindrical structure 208.
  • the output shaft 272 and hollow cylindrical structure 208 rotate at 1000-2500 revolutions per minute. In other embodiments, the speeds may be still greater than 2500 revolutions per minute.
  • the end plate 224 includes a mounting structure 276 for securing the hollow cylindrical structure 208 to the base 204 while still allowing relative rotation therebetween.
  • the mounting structure 276 includes fasteners (such as threaded fasteners) for coupling the hollow cylindrical structure 208 to the output shaft 272 (or motor shaft 264, in the case where the motor 262 directly drives the rotation).
  • the mounting structure 276 may be formed as a chuck on the output shaft 272 that is moved radially to grasp the hollow cylindrical structure 208.
  • the output shaft 272 is hollow such that the second end 250 of the delivery tube 244 extends into the output shaft 272.
  • the apparatus 200 can include a splash guard 278 that extends substantially around the hollow cylindrical structure 208 to limit the flow of liquid outside the confines of the apparatus 200. Additionally, the apparatus 200 includes a liquid catch basin 280 positioned below the hollow cylindrical structure 208 to catch liquid that flows out through the openings 236 in the mesh tube 232 and to catch liquid that drops downward off of the splash guard 278. [0034]
  • the motor 262 is actuated, thereby rotating the motor shaft 264 and further rotating the output shaft 272 via the belt and pully or gear arrangement 268. As the output shaft 272 rotates, the hollow cylindrical structure 208 likewise rotates about the rotational axis 212.
  • the delivery tube 244 is positioned within the central opening 240 of the end plates 216, 224 so that the outlet 252 of the delivery tube 244 is positioned within the liquid permeable cylinder 232 of the hollow cylindrical structure 208.
  • the delivery tube 244 is actuated, either manually or via electronic or hydraulic control, to translate between first and second extremes, corresponding to the outlet 252 extending to the two axial extents of the liquid permeable cylinder 232. With the hollow cylindrical structure 208 rotating and the delivery tube 244 translating, the slurry is provided from the slurry tank 256 to the delivery tube.
  • Providing the slurry from the slurry tank 256 can include opening the valve 260 and can further include operating a pump (or otherwise allowing the flow to exit the tank 256, e.g. via gravity) to deliver the slurry to the delivery tube 244.
  • the slurry enters the inlet 248 of the delivery tube 244 and exits through the outlet 252 into the liquid permeable cylinder 232 of the hollow cylindrical structure.
  • the slurry builds up on the cylinder 232 with centrifugal forces pushing the liquid portion (e.g., water) of the slurry through the openings 236 (as shown by arrows 284 on Fig. 6).
  • the powder and fiber of the slurry build up on the cylinder 232, progressively building further inward (as shown by arrows 288 on Fig. 6) as the slurry continues to pour in from the outlet 252.
  • the valve 260 is closed and (if used) the pump is deactivated to prevent providing further slurry to the delivery tube 244.
  • the actuation of the delivery tube 244 and operation of the motor 262 are likewise deactivated to halt translation of the delivery tube 244 and rotation of the hollow cylindrical structure.
  • the slurry (with much of the liquid removed via operation of the apparatus 100) within the cylinder 232 represents a built filter with post processing steps of drying (step 103) and curing (step 104) resulting in a finished filter.
  • at least 90% of the original liquid content of the slurry has been removed in step 102, and up to 95% of the original liquid content has been removed in step 102 in particularly preferable embodiments.
  • the filter is dried at step 103.
  • the built filter and cylinder 232 are removed together.
  • the built filter may be removed from the cylinder prior to drying.
  • the drying process removes any remaining water that was not removed during the formation of the fdter.
  • the filter is cured at step 104. Curing includes further heating to fuse the fibers of the filter body together, resulting in a finished filter.
  • the curing can include heating the filter to a temperature that is near, but below, a melting temperature of the binder material, so that individual strands of the binder material fuse together at the conclusion of the curing step 104 (e.g. during a cool-down).
  • the drying step 103 and the curing step 104 can be performed in a single combined operation.
  • Fig. 7 illustrates another method of making a water filter, with Figs. 8-10 illustrating apparatus for carrying out the method of Fig. 7 in one embodiment.
  • the method of making a water filter according to Fig. 7 is a wet process for filter making that includes forming a slurry, removing a first portion of liquid from the slurry, forming slurry into a filter shape and removing a second portion of liquid, drying the filter, and curing the filter.
  • step 301 The mixing of the slurry (step 301) can be performed in a like manner to that described previously with reference to step 101 of Fig. 1. Proceeding to step 302, a first portion of the liquid content of the slurry is removed therefrom, resulting in a slurry that is still fluid but is substantially higher in viscosity than the initial slurry.
  • the slurry has a first liquid content after step 301, and a second liquid content that is less than the first liquid content after step 302.
  • the slurry has a paste-like consistency after the first portion of liquid has been removed in step 302.
  • the first portion of the liquid is in the range of 70-90% of the original liquid content of the slurry, for example 80%, so that the second liquid content is between 10% and 30% of the first liquid content, for example 20%.
  • Fig. 2 depicts an apparatus 402 for performing step 302 according to one embodiment.
  • the apparatus 402 includes a troth 404 into which the slurry can be poured or otherwise dispensed.
  • the troth 404 includes a horizontally arranged plate 406 at a bottom end of the troth, with a series of openings 410 arranged thereon.
  • the plate 406 can, for example, be formed of a sheet of perforated plate material, expanded metal plate, etc., and the openings 410 can cover a substantial portion of the total surface of the plate 406.
  • the openings 410 can comprise a total open area that is equal to 50% or more, 60% or more, 70% or more, or 80% or more of the total surface area of the plate 406.
  • a suction device such as a vacuum 416 is in fluid communication with a plenum 412 of the troth 402, the plenum 412 being arranged below the horizontally arranged plate 406.
  • the slurry is poured or otherwise dispensed into the troth 402 onto the membrane 408, such that the surface of the plate 406 is covered with slurry.
  • the suction device 416 is then engaged to reduce the pressure within the plenum 412 to be below the pressure above the slurry (which can be atmospheric pressure), thereby creating a negative pressure gradient across the liquid-permeable membrane.
  • the negative pressure gradient drives at least a portion of the liquid within the slurry through the liquid-permeable membrane 408 and the openings 410, as indicated by the arrows 414.
  • the solids of the slurry such as the fiber material, powder, and additives, are not able to pass through the membrane 408 and remain within the slurry.
  • step 302 the slurry is substantially drier but remains in a fluid state and the fiber, powder, and other additives remain well-mixed within the slurry.
  • step 303 the slurry is placed into a mold in order to both remove a second portion of water from the slurry and form the slurry into a filter body having the desired filter shape.
  • Figs. 9-10 depict a mold 420 that, in some embodiments, can serve as an apparatus for performing step 303.
  • the mold 410 includes an outer sleeve 422 which has an inner surface that corresponds to the desired outer profile of the completed water filter body.
  • the outer sleeve 422 has a cylindrical shape, but it should be understood that other geometries can be used to form filter bodies having different shapes.
  • a bottom pressure plate 428 is arranged at a bottom end 426 of the outer sleeve 422.
  • Orifices 432 are arranged over the surface of the bottom pressure plate 428 and extend through the bottom pressure plate 428.
  • a central rod 430 extends upwardly into an inner volume of the sleeve 422 from the bottom pressure plate 428, and is shaped and sized to define an inner surface of the filter body.
  • a liquid-permeable membrane 434 such as a woven sheet or a non-woven porous paper or mat, is placed into the inner cavity of the sleeve 422 and rests upon the bottom pressure plate 428.
  • a central opening is provided in the membrane 434 to accommodate the central rod 430.
  • the membrane 434 covers the apertures 432, so that at least the solid portions of the slurry placed within the mold 420 are prevented from passing through the orifices 432.
  • a desired amount of the slurry is subsequently introduced into the inner cavity of the sleeve 422 from a top end 424 of the sleeve to form the water filter.
  • a top pressure plate 438 is placed on top of the slurry and at least partially within the inner cavity, and a compressive force (indicated by the arrows 440) is applied to the top pressure plate 438 in order to compress the slurry between the plates 438 and 428.
  • a second portion of liquid is driven from the slurry through the liquid-permeable membrane 434 and the orifices 432.
  • the slurry can be compressed such that the overall height of the slurry within the mold 420 (i.e. the distance between the inwardly facing surfaces of the pressure plates 428, 438) corresponds to a desired height of the water filter body.
  • the position of the top pressure plate 438 can then be locked, relative to the outer sleeve 422 and the bottom pressure plate 428, in order to maintain that spacing.
  • the mold 420 is placed within an oven to dry out any remaining portion of the liquid from the filter body (step 304). After drying, the filter body is cured (step 305) in a similar fashion to that described with respect to step 104.
  • the curing step can be performed while the filter body is still within the mold 420.
  • the filter body may be sufficiently solid after the drying step 304 that it can be removed from the mold 420 for the curing step.
  • the drying step 304 and the curing step 305 can be performed in a single combined operation.
  • a filter formed by the processes described above can result in a decreased pressure drop with 50%-100% greater capacity than a conventional carbon block filter of the same size. Additionally, the processes allow for increased flexibility in including additives to address specific contaminants. Mixing the additives into a liquid slurry results in a more even distribution of the additives as compared to a dry mixture. Additionally, the processes described above can allow for larger filters to be produced than in a traditional sintered carbon block filter process.
  • a filter constructed according to the method of Fig. 1 was made using short fibers (having nanometer-range diameters and 5- 100pm lengths), long fibers (2 denier diameter and 3-6mm lengths), and 80x325 mesh size activated carbon, with a weight ratio of 15: 1 : 135 (short fibers:long fibers:carbon), or a powderfiber weight ratio of approximately 8.4:1.
  • the filter was constructed to an outer diameter of 106mm, an internal diameter of 84mm, and a length of 223mm. This filter was tested to NSF53 testing standards for volatile organic chemical (VOC) removal, using chloroform as the test contaminant, and showed a test capacity of 8300 liters of water treated, with an end-of-test pressure drop of 2-3psi.
  • VOC volatile organic chemical
  • a filter constructed according to the method of Fig. 7 was made using the same short fibers, long fibers, and activated carbon, and with HRMP material added for lead removal, with a weight ratio of 17:2:37:28 (short fibers:long fibers:carbon:HRMP), or a powderfiber weight ratio of approximately 3.4: 1.
  • the filter was constructed to an outer diameter of 50mm, an internal diameter of 10mm, and a length of 125mm. This filter was tested for lead removal at an elevated flow rate of 2L/minute, and showed a test capacity of 3300 liters of water treated, with an end-of-test pressure drop of 30psi.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Filtering Materials (AREA)

Abstract

La présente invention concerne un procédé de fabrication d'un filtre à eau consistant à préparer un mélange de matières en suspension comportant un liquide, au moins un matériau fibreux et de la poudre. Un corps de filtre est construit à partir de la suspension tout en retirant simultanément au moins une partie du liquide de la suspension. Le corps de filtre est durci à l'aide de chaleur pour former un bloc de filtre. La poudre peut comprendre du charbon actif dont la taille des particules est comprise entre 45 μm et 180 μm, et peut comprendre au moins un additif pour éliminer un contaminant.
PCT/US2024/035822 2023-06-28 2024-06-27 Filtre et appareil de fabrication et procédé associé Ceased WO2025006750A2 (fr)

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CN202480033966.7A CN121263247A (zh) 2023-06-28 2024-06-27 过滤器及其制造装置和方法

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WO2000064578A1 (fr) * 1999-04-23 2000-11-02 University Of Kentucky Research Foundation Filtres alliant une magnetite et du charbon actif pour purifier un ecoulement fluide
US6830685B2 (en) * 2001-12-05 2004-12-14 Fresenius Usa, Inc. Filtering device with associated sealing design and method
US10828587B2 (en) * 2015-04-17 2020-11-10 Hollingsworth & Vose Company Stable filter media including nanofibers
US20190194039A1 (en) * 2016-06-02 2019-06-27 Honeywell International Inc. Water purification system
US11370705B2 (en) * 2018-09-26 2022-06-28 NOVOREACH Technologies LLC Composition and method for making geopolymer tubes
US11377369B2 (en) * 2019-03-24 2022-07-05 Mind Body (Asia) Limited Multi-stage water filtration system

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