WO2026034026A1 - Élément de membrane de séparation et dispositif de séparation - Google Patents

Élément de membrane de séparation et dispositif de séparation

Info

Publication number
WO2026034026A1
WO2026034026A1 PCT/JP2025/022457 JP2025022457W WO2026034026A1 WO 2026034026 A1 WO2026034026 A1 WO 2026034026A1 JP 2025022457 W JP2025022457 W JP 2025022457W WO 2026034026 A1 WO2026034026 A1 WO 2026034026A1
Authority
WO
WIPO (PCT)
Prior art keywords
separation membrane
permeate
supply
fluid
separation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/JP2025/022457
Other languages
English (en)
Japanese (ja)
Inventor
エイ キョウ
努 田▲崎▼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of WO2026034026A1 publication Critical patent/WO2026034026A1/fr
Pending legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/08—Flat membrane modules
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Definitions

  • the present invention relates to a separation membrane element and a separation device.
  • Plate-and-frame separation membrane elements which are made up of stacked flat membranes, are known as separation membranes for separating specific fluid components from a liquid or gaseous raw fluid (see, for example, Patent Document 1).
  • separation membranes for separating specific fluid components from a liquid or gaseous raw fluid
  • Patent Document 1 the performance of separation membranes has improved, making it possible to realize thinner separation membranes.
  • Such thin separation membranes can be used to remove carbon dioxide and other substances contained in gases such as exhaust gases.
  • the plate-and-frame type separation membrane element can use a thin separation membrane that is difficult to use in a spiral type separation membrane element.
  • One aspect of the present invention aims to realize a plate-and-frame type separation membrane element with excellent pressure resistance.
  • one embodiment of the present invention provides a plate-and-frame separation membrane element comprising a container and a separation membrane having a region arranged in the shape of a flat membrane within the container, the container including a container body having a bottom surface and a side wall, and a lid joined to the container body and positioned opposite the bottom surface across the side wall of the container body, the lid having a protrusion that protrudes along the outer side of the side wall of the container body toward the bottom surface of the container body.
  • a plate-and-frame type separation membrane element with excellent pressure resistance can be provided.
  • FIG. 1 is a perspective view schematically showing a separation membrane element according to one embodiment of the present invention.
  • FIG. 1 is a cross-sectional view schematically showing a separation membrane element equipped with a flat plate-shaped cover.
  • FIG. 1 is a cross-sectional view schematically showing a state in which a separation membrane element equipped with a flat plate-shaped cover is pressurized.
  • FIG. 2 is a cross-sectional view schematically showing a state in which a separation membrane element according to one embodiment of the present invention is pressurized.
  • 1 is a cross-sectional view schematically showing a separation membrane element according to one embodiment of the present invention.
  • FIG. 1 is a cross-sectional view schematically showing a separation membrane element according to one embodiment of the present invention.
  • 1 is an exploded perspective view showing a stack of a separation membrane element according to one embodiment of the present invention.
  • 1 is a cross-sectional view of a laminate included in a separation membrane element according to one embodiment of the present invention.
  • 1 is a cross-sectional view of a laminate included in a separation membrane element according to one embodiment of the present invention.
  • FIG. 2 is a perspective view illustrating a manufacturing process of a separation membrane element according to one embodiment of the present invention.
  • FIG. 12 is a perspective view illustrating a continuation of the manufacturing process shown in FIG. 11 .
  • FIG. 13 is a perspective view illustrating a continuation of the manufacturing process shown in FIG. 12 .
  • FIG. 2 is a schematic diagram illustrating a test device for an airtightness test performed in the examples.
  • a to B representing a numerical range means “greater than or equal to A and less than or equal to B.”
  • a plate-and-frame type separation membrane element comprises a container and a separation membrane having a region arranged in the form of a flat membrane within the container, the container including a container body having a bottom surface and a side wall, and a lid joined to the container body and arranged opposite the bottom surface across the side wall of the container body, the lid having a protrusion that protrudes toward the bottom surface of the container body along the outer side of the side wall of the container body.
  • FIG. 1 is a perspective view schematically showing a separation membrane element according to one embodiment of the present invention, in which L represents the length direction of the container, W represents the width direction of the container, and H represents the height direction of the container.
  • Separation membrane element 1 is a plate-and-frame type separation membrane element. Separation membrane element 1 includes a container 50.
  • the container 50 includes a container body 40 and a lid 60.
  • the container body 40 has a bottom surface 48 and a side wall 49.
  • the lid 60 is joined to the container body 40 and is positioned opposite the bottom surface 48 with the side wall 49 of the container body 40 in between.
  • the side wall 49 can also be considered a member that connects the bottom surface 48 and the lid 60.
  • the lid 60 and the bottom surface 48 extend in a direction perpendicular to the stacking direction of the laminate 10 described below, and the side wall 49 extends in the stacking direction of the laminate 10.
  • the side wall portion 49 has an upper end 47.
  • the upper end 47 of the side wall portion 49 is located on the opposite side of the container body 40 from the bottom surface portion 48.
  • An opening is formed on the side of the container body 40 opposite the bottom surface portion 48.
  • the upper end 47 of the side wall portion 49 can also be said to be the part that surrounds the opening.
  • the upper end 47 abuts against the lid 60.
  • the lid 60 is positioned so as to close the opening.
  • the storage space can be defined by the lid 60, the bottom surface portion 48, and the side wall portion 49.
  • the shape of the container 50 is not particularly limited, and the lid 60 and bottom portion 48 may be polygonal, such as rectangular, or circular.
  • the side wall portion 49 may be prismatic or cylindrical.
  • the container body 40 may have guide portions 41 for positioning the components that make up the stack 10. If the side wall portion 49 of the container body 40 is prismatic, the guide portions 41 are preferably provided at the corners of the side wall portion 49.
  • FIG. 2 is a cross-sectional view schematically showing a separation membrane element equipped with a flat lid.
  • a conventional separation membrane element 201 as shown in FIG. 2, has a flat lid 260 without protrusions.
  • the vessel body 240 and the lid 260 are bonded via a sealing material such as an adhesive.
  • FIG. 3 is a cross-sectional view schematically showing a separation membrane element equipped with a flat lid under pressure.
  • Figure 4 is a cross-sectional view schematically showing a separation membrane element according to one embodiment of the present invention.
  • Figure 5 is a cross-sectional view schematically showing a separation membrane element according to one embodiment of the present invention in a pressurized state.
  • the inventors have discovered that the pressure resistance of the separation membrane element 1 can be improved by providing the lid 60 with a protrusion 61 that protrudes toward the bottom surface 48 of the container body 40 along the outside of the side wall 49 of the container body 40.
  • the protrusion 61 can suppress or prevent the side wall 49 of the container body 40 from deforming outward. This prevents the sealing material between the container body 40 and the lid 60 (for example, both on the outside of the side wall 49 and at the upper end 47 of the container body 40) from peeling off. This prevents fluid leakage.
  • CO2 and the like can be removed from harmful gases such as exhaust gases.
  • Such effects also contribute to the achievement of, for example, Goal 7 “Affordable and clean energy,” Goal 12 “Ensure sustainable consumption and production patterns,” and Goal 13 “Take urgent action to combat climate change” of the Sustainable Development Goals (SDGs) advocated by the United Nations.
  • SDGs Sustainable Development Goals
  • the protrusion protrudes toward the bottom surface of the container body along the outside of the side wall of the container body means that the protrusion protrudes downward parallel to the height direction H of the container.
  • “downward” means vertically downward.
  • the shape of the lid 60 is not particularly limited as long as it has a shape that includes the protrusions 61.
  • the protrusions 61 may be provided on the peripheral edge of a flat lid 60.
  • the flat portion of the lid 60a may extend outward from the protrusions 61a. That is, as shown in Figure 6, the cross section of the portion where the protrusions 61a protrude from the flat portion of the lid 60a may be T-shaped.
  • the center of the lid 60b is lower than the peripheral edge, so that the lid 60b fits onto the container body 40 (known as a latching lid in Japanese).
  • the protrusions 61 are present along the entire peripheral edge of the lid 60 in a planar view. In other words, it is preferable that the protrusions 61 are present so as to surround the entire side wall 49 of the container body 40. For example, if the container body 40 is rectangular in a planar view, it is preferable that the protrusions 61 are present so as to surround all four sides of the rectangle.
  • the lid 60 is adhered to the container body 40 via a sealing material.
  • the lid 60 is adhered to at least one of the outer side of the side wall portion 49 and the upper end 47 of the container body 40 via a sealing material.
  • the components constituting the container 50 can be made of resin, glass, metal, ceramics, etc.
  • Resins include polycarbonate, acrylic resin, fluororesin, polybutylene succinate (PBS), polyethylene terephthalate (PET), polyvinyl chloride (PVC), polystyrene (PS), acrylonitrile butadiene styrene copolymer (ABS), polyphenylene sulfide (PPS), polyethersulfone (PES), polysulfone (PSF), polyacrylonitrile (PAN), polyphenylene oxide (PPO), polyamide (PA), polyimide (PI), polyetherimide (PEI), polyetheretherketone (PEEK), polypropylene (PP), and fiber-reinforced resins made by mixing these resins with glass or other fibers.
  • Metals include stainless steel such as SUS, aluminum, and copper.
  • the components constituting the container 50 can be made of the same material or different materials.
  • Double-sided tape, adhesives, etc. can be used as sealing materials.
  • resins contained in the adhesives include epoxy resins, urethane resins, silicone resins, vinyl chloride copolymer resins, vinyl chloride-vinyl acetate copolymer resins, vinyl chloride-vinylidene chloride copolymer resins, vinyl chloride-acrylonitrile copolymer resins, butadiene-acrylonitrile copolymer resins, polyamide resins, polyvinyl butyral resins, polyester resins, cellulose derivative (nitrocellulose, etc.) resins, styrene-butadiene copolymer resins, various synthetic rubber (elastomer) resins, phenolic resins, urea resins, melamine resins, phenoxy resins, and urea-formamide resins.
  • epoxy resin (resin for epoxy adhesives) adhesives are preferred as sealing materials, and two-component mixed epoxy adhesives are even more preferred.
  • structural bonding tape consisting of acrylic foam coated with an acrylic adhesive can be used.
  • the vessel 50 can have a first supply port 43 communicating with the supply-side flow path member 23 of the laminate 10 (described below) for supplying a raw material fluid, a first discharge port 44 communicating with the supply-side flow path member 23 of the laminate 10 for discharging a non-permeate fluid, and a second discharge port 46 communicating with the permeate-side flow path member 22 of the laminate 10 for discharging a permeate fluid.
  • the vessel 50 may further have a supply and discharge port 45 communicating with the permeate-side flow path member 22 of the laminate 10.
  • the supply and discharge port 45 can be used as a second supply port for supplying a sweep fluid or as a third discharge port for discharging a permeate fluid.
  • the first supply port 43, supply and discharge port 45, first discharge port 44, and second discharge port 46 of the container 50 may all be provided on the side wall portion 49 of the container body 40, or on the lid 60 or bottom portion 48.
  • the separation membrane element preferably has an effective membrane area of 0.1 m 2 or more, more preferably 12.0 m 2 or more, and even more preferably 36.0 m 2 or more.
  • the effective membrane area is preferably 500.0 m2 or less, more preferably 100.0 m2 or less, and even more preferably 50.0 m2 or less.
  • the effective membrane area means the membrane area that can be used for gas separation. It is preferable that the effective membrane area is within these ranges from the viewpoint that a separation device with sufficient performance can be easily manufactured using the separation membrane element.
  • the separation membrane element 1 includes a separation membrane 21 having a region arranged in a flat membrane shape within a container 50.
  • the term "separation membrane having a region arranged in a flat membrane shape within a container 50" means that the separation membrane 21 is contained within the container 50 so as to include a region where it is arranged in a flat state without being wound into a roll or a cylindrical shape.
  • the separation membrane 21 contained within the container 50 may have a folded portion as long as it has a region arranged in a flat membrane shape within the container 50, and as described below, it may be contained within the container 50 in a folded state so as to form a flat membrane region.
  • the separation membrane 21 is not particularly limited, and any known membrane capable of selectively allowing a specific fluid component to permeate from the raw fluid can be used.
  • the separation membrane 21 can be, for example, an ultrafiltration membrane, a nanofiltration membrane, a reverse osmosis membrane, a dialysis membrane, a forward osmosis membrane, a solution-diffusion membrane, a facilitated transport membrane, etc.
  • a solution-diffusion membrane is a membrane that selectively allows molecules to permeate by utilizing the difference in solubility and diffusibility of fluid molecules.
  • Facilitated transport membranes are membranes that contain substances that promote the solubility and/or diffusivity of fluid molecules.
  • the separation membrane 21 is preferably a solution-diffusion membrane.
  • the separation membrane 21 can have a porous membrane and a separation functional layer.
  • the separation membrane 21 may have one or more porous membrane layers, or may have two or more porous membrane layers, or may have three or more porous membrane layers.
  • the porous membrane can be provided on one or both sides of the separation functional layer.
  • the porous membrane provided on one or both sides of the separation functional layer may have one layer, or may have two or more porous membrane layers.
  • the separation membrane 21 may have a support layer for reinforcement, if necessary.
  • the thickness of the separation membrane is preferably 10 to 600 ⁇ m, more preferably 10 to 550 ⁇ m, and even more preferably 10 to 510 ⁇ m.
  • a separation membrane thickness within this range results in a thin membrane that can adequately separate specific fluid components, such as carbon dioxide, from the raw fluid.
  • a separation membrane thickness within this range makes it difficult to use in a spiral-type separation membrane element, but it can be used in a plate-and-frame type separation membrane element.
  • the separation membrane 21 may have a separation functional layer that selectively separates specific fluid components contained in the raw fluid.
  • the separation functional layer can be selected depending on the type of membrane.
  • the separation functional layer is preferably a layer formed using a composition containing a resin.
  • resins include polyacrylic acid, polyamide, cellulose acetate, polysulfone, polyethersulfone, vinylidene fluoride, polyacrylonitrile, polyvinyl chloride-polyacrylonitrile copolymer, epoxy resin, polyimide, polyvinyl alcohol, polysiloxane, polyether block amide copolymer, and polyethylene oxide.
  • the polyacrylic acid may be crosslinked polyacrylic acid, or may be uncrosslinked polyacrylic acid.
  • the separation functional layer may be a gel layer.
  • the gel layer contains a hydrophilic resin such as polyacrylic acid, and may further contain amino acids, aminosulfonic acids, and/or aminophosphonic acids.
  • the gel layer may also contain a surfactant to adjust the wettability of the porous membrane.
  • the gel layer may further contain an alkali metal compound and/or a hydration reaction catalyst to improve the reaction rate between the specific gas component and the alkali metal compound.
  • the thickness of the separation functional layer is preferably 1 to 1000 nm, more preferably 10 to 500 nm, and even more preferably 100 to 400 nm. If the thickness of the separation functional layer is within the above range, specific fluid components such as carbon dioxide can be sufficiently separated from the raw material fluid.
  • the separation functional layer can be produced, for example, by applying a coating liquid containing the resin and medium described above onto a porous membrane.
  • Methods for applying the coating liquid onto a porous membrane include slot die coating, spin coating, bar coating, die coating, blade coating, air knife coating, gravure coating, roll coating, spray coating, dip coating, comma roll coating, kiss coating, screen printing, and inkjet printing.
  • the separation membrane 21 may be composed of only a separation functional layer, or may have a laminated structure in which a separation functional layer and a porous membrane are laminated.
  • the porous membrane can be provided on one or both sides of the separation functional layer and can support or protect the separation functional layer.
  • the porous membrane can be a support layer for supporting the separation functional layer, or a protective layer for protecting the separation functional layer.
  • the porous membrane can be in direct contact with the separation functional layer. It is preferable that the porous membrane has high porosity for fluid permeability so as not to act as a diffusion resistance for the raw fluid supplied to the separation functional layer or for specific fluid components contained in the raw fluid.
  • the porous membrane is preferably formed from a resin material or an inorganic material.
  • resin materials that can be used to form the porous membrane include polyolefin resins such as polyethylene (PE) and polypropylene (PP); fluorine-containing resins such as polytetrafluoroethylene (PTFE), polyvinyl fluoride (PVF), and polyvinylidene fluoride (PVDF); polyester resins such as polyethylene terephthalate (PET) and polyethylene naphthalate; polystyrene (PS), polyethersulfone (PES), polyphenylene sulfide (PPS), polysulfone (PSF), polyacrylonitrile (PAN), polyphenylene oxide (PPO), polyamide (PA), polyimide (PI), polyetherimide (PEI), polyetheretherketone (PEEK), high-molecular-weight polyester, heat-resistant polyamide, aramid, polycarbonate, and mixtures of two or more of these resin materials.
  • polyolefin resins and fluorine-containing resins it is preferable to include at least one of polyolefin resins and fluorine-containing resins, and it is more preferable to include one or more of polyethylene, polypropylene, and polytetrafluoroethylene.
  • Inorganic materials that constitute the porous membrane include metals, glass, ceramics, etc.
  • the porous membrane is not particularly limited as long as it is a porous body, and may be a porous body in the form of a sheet such as a porous resin film, nonwoven fabric, woven fabric, foam, mesh, or net. These porous bodies can also be used as a supporting layer for reinforcement.
  • the porous membrane of the separation membrane may be, for example, one or more layers of porous resin film laminated on one side of the separation functional layer, and one or more layers of nonwoven fabric laminated on the other side of the separation functional layer.
  • (Laminate) 8 is an exploded perspective view of a stack included in a separation membrane element according to one embodiment of the present invention.
  • a container 50 accommodates a stack 10 including two permeate-side channel members 22 and a separation membrane 21 and a feed-side channel member 23 disposed between the two permeate-side channel members 22.
  • a raw fluid flows through the feed-side channel member 23.
  • a permeated fluid that has permeated the separation membrane 21 flows through the permeate-side channel member 22.
  • the height direction H of the container 50 coincides with the stacking direction of the stack 10.
  • the separation membranes 21 included in the stack 10 are stacked so as to have a region in which they are arranged in a flat membrane shape within the container 50.
  • the permeate-side channel member 22 and the feed-side channel member 23 included in the stack 10 are also typically stacked so as to have a region in which they are arranged in a flat membrane shape within the container 50.
  • the laminate 10 may have at least a portion where a permeate-side channel member 22, a separation membrane 21, a supply-side channel member 23, and a permeate-side channel member 22 are stacked in this order.
  • the laminate 10 may have a membrane stack section 20 where a separation membrane 21, a supply-side channel member 23, and a separation membrane 21 are stacked in this order.
  • the laminate 10 preferably has a structure in which the membrane stack section 20 is disposed between two permeate-side channel members 22.
  • the separation membrane has a porous membrane on only one side, it is preferable that the separation membrane 21 and the supply-side channel member 23 are stacked in the membrane stack section 20 so that the separation function layer side of the separation membrane 21 faces the supply-side channel member 23.
  • the separation membrane 21 and the supply-side flow path member 23 may be bonded together with a supply-side sealing material. Also, the permeate-side flow path member 22 and the separation membrane 21 may be bonded together with a permeate-side sealing material.
  • the supply-side sealing material forms the supply-side sealing portion 31, and the permeate-side sealing material forms the permeate-side sealing portion 32. These will be described later.
  • the membrane stack 20 and the permeate-side channel member 22 stacked on the membrane stack 20 may form a membrane leaf.
  • the membrane leaf is a laminate having a layered structure in which the permeate-side channel member 22, separation membrane 21, feed-side channel member 23, and separation membrane 21 are stacked in this order.
  • the laminate 10 may include only one membrane leaf, but preferably has a structure in which multiple membrane leaves are stacked. When the laminate 10 has a structure in which multiple membrane leaves are stacked, as shown in Figure 8, each component and separation membrane may be repeatedly stacked on top of the membrane stack 20, such as the permeate-side channel member 22, separation membrane 21, etc.
  • the number of membrane leaves included in the laminate 10 is not particularly limited, but may be, for example, 2 to 100, 5 to 50, or 10 to 30. It is preferable that the top and bottom surfaces of the laminate 10 are permeate-side channel members 22. In this case, the top permeate-side channel member 22 forms a membrane leaf.
  • the feed-side channel member 23 and the permeate-side channel member 22 preferably have the functions of promoting turbulence (surface renewal of the membrane surface) of the feed fluid and the permeated fluid that has permeated the separation membrane 21, thereby increasing the membrane permeation rate of the permeated fluid in the feed fluid, and minimizing the pressure loss of the feed fluid supplied and the permeated fluid that has permeated the separation membrane 21.
  • the feed-side channel member 23 and the permeate-side channel member 22 preferably have the functions of a spacer that forms a channel for the feed fluid and the permeated fluid, and the functions of generating turbulence in the feed fluid and the permeated fluid, mesh-like (net-like, mesh-like, etc.) ones are preferably used.
  • the shape of the unit lattice of the network is preferably selected from, for example, a square, a rectangle, a rhombus, a parallelogram, etc. depending on the purpose, since the channel for the fluid changes depending on the shape of the network.
  • the materials for the supply-side channel member 23 and the permeate-side channel member 22 are not particularly limited, but are preferably heat-resistant enough to withstand the operating temperature conditions of the separation apparatus in which the separation membrane element 1 is installed.
  • the supply-side channel member 23 and the permeate-side channel member 22 may each independently have a single-layer structure or a multi-layer structure.
  • the supply-side channel member 23 and the permeate-side channel member 22 having a multi-layer structure preferably have a structure in which one or more types of mesh layers are stacked, and the stacked mesh layers may have different mesh structures.
  • the permeate-side channel member 22 has a single-layer structure.
  • the permeate side flow path member 22 has a single layer structure
  • the permeate side flow path member 22 does not have multiple layers. In other words, this means that the permeate side flow path member 22 is made of a single mesh or net, and does not mean that the permeate side flow path member 22, separation membrane 21, and feed side flow path member 23 are not stacked in the separation membrane element 1.
  • the permeate side flow path member 22 has a multi-layer structure means that the permeate side flow path member 22 is made of multiple meshes or nets.
  • the permeate side flow path member is preferably mesh-like.
  • the permeate side flow path member is mesh-like and has a multilayer structure having two or more layers, it is preferable that the number of meshes in each layer of the permeate side flow path member is the same. If the number of meshes in each layer is the same, deformation of the permeate side flow path member due to one layer penetrating into another layer is less likely to occur, thereby improving the compressive strength of the permeate side flow path member.
  • the number of meshes in the permeate side flow path member is preferably 18 meshes or more. There is no particular upper limit on the number of meshes, but it may be, for example, 150 meshes or less.
  • the number of meshes in each layer of the permeate-side channel member may be different.
  • the mesh number of the permeate-side channel member is preferably 50 mesh or more.
  • the upper limit of the mesh number is not particularly limited, but may be, for example, 150 mesh or less.
  • the laminate 10 can have permeate-side plugs 32 arranged to include positions corresponding to the stacking positions of the permeate-side flow path members 22 in the stacking direction of the laminate 10 ( FIG. 8 ).
  • the "positions corresponding to the stacking positions of the permeate-side flow path members 22" refers to the positions occupied by the permeate-side flow path members 22, as well as the positions occupied by the extended portions of the permeate-side flow path members 22 when they are extended in the direction along the plane of the laminate 10 (the direction in which the permeate-side plugs 32 in FIG. 8 exist).
  • the permeate-side plugs 32 may be formed so as to include the permeated portions, with the permeate-side plugging material for forming the permeate-side plugs 32 shown in FIG. 8 permeating into the permeate-side flow path members 22.
  • each layer of the laminate 10 shown in Figure 8 has an edge on its surface.
  • the term "edge” refers to the area on the surface of each layer that is a certain distance from the outer periphery of the layer.
  • the certain distance is not particularly limited as long as it does not interfere with the effectiveness of the separation membrane element, and may be, for example, 1% or less, 5% or less, or 10% or less of the distance between the opposing sides.
  • the area that becomes the edge may be 0.5% or more of the distance between the opposing sides.
  • the edge may exist not only on the upper surface of the laminate 10 (i.e., the direction in which the lid 60 in Figure 1 exists) but also on the lower surface (i.e., the direction in which the bottom surface portion 48 in Figure 1 exists). It is preferable that the certain distance between the upper edge and the lower edge of the same layer is the same.
  • a tape can be provided at the end of the supply-side channel member 23 to prevent seepage of a permeate-side plugging material for forming the permeate-side plugging sections 32, which will be described later.
  • the tape is preferably provided on the end of the supply-side channel member 23 on the side facing the separation membrane 21, and when the separation membranes 21 are disposed on both sides of the supply-side channel member 23, the tape may be provided on both sides of the end of the supply-side channel member 23.
  • a tape can be provided at the end of the permeate-side channel member 22 to prevent seepage of a supply-side plugging material for forming the supply-side plugging sections 31. If the sealing material is a double-sided tape, there is no need to use tape to prevent seepage.
  • each layer included in the laminate 10 has two first ends 11 and two second ends 12 on at least one surface.
  • first ends 11 of the laminate 10 we mean the first ends 11 of all layers included in the laminate 10. The same applies to the second ends 12.
  • the permeate side plugging section 32 may be provided at the first end 11 in addition to the second end 12 of the laminate 10.
  • the permeate side plugging section 32 is provided at the first end 11, it is preferable that the permeate side plugging section 32 be provided along the entire side of the laminate 10 constituting the first end 11 in a plan view.
  • the permeate side plugging section 32 provided at the first end 11 is preferably provided along the first end 11 of the laminate 10.
  • the permeate side plugging section 32 provided at the first end 11 may also be provided at a position corresponding to the stacking position of the permeate side flow path member 22 in the stacking direction of the laminate 10, and may be formed so that the plugging material permeates into the permeate side flow path member 22 and includes this permeated portion.
  • the permeate-side plugging parts 32 may be provided at the two second end parts 12 and at one end part of the first end part 11 shown in FIG.
  • the permeate-side plugging parts 32 at the second end part 12 and the first end part 11 may be formed in a connected state (e.g., U-shaped) in plan view.
  • the supply-side sealing portion 31 and the permeation-side sealing portion 32 are preferably bonded at a position where the respective sealing portions intersect in a planar view (hereinafter sometimes referred to as the "intersection position").
  • the intersection position can be located at a corner of the laminate 10 in a planar view.
  • Figure 9 is a cross-sectional view of the laminate 10 of this separation membrane element, cut in a direction parallel to the second end 12.
  • the separation function layer 53 together with the porous substrate 52, forms the separation membrane 21.
  • the laminate 10 has a supply-side sealing portion 31 between the separation function layer 53 included in the separation membrane 21 and the supply-side flow path member 23 (e.g., adhesive portion 51).
  • Figure 9 shows a state in which the supply-side sealing material forming the supply-side sealing portion 31 has permeated not only the adhesive portion 51 but also the end of the supply-side flow path member 23 (hatched portion).
  • the separation function layer 53 and the supply-side flow path member 23 are bonded at the adhesive portion 51 by the supply-side sealing material.
  • pressure is generated in the direction of the separation membrane 21 (i.e., the direction of the block arrow shown in Figure 9).
  • the supply-side sealing portion 31 also functions to prevent mixing of the fluid flowing through the supply-side channel member 23 and the fluid flowing through the permeate-side channel member 22.
  • Fluids flowing through the supply-side channel member 23 include, for example, the feed fluid and the non-permeated fluid that has not permeated the separation membrane 21.
  • Fluids flowing through the permeate-side channel member 22 include, for example, the permeated fluid that has permeated the separation membrane 21, and a sweep fluid that is supplied to the permeate-side channel member 22 and discharged together with the permeated fluid.
  • the sweep fluid is a fluid that is inactive with respect to the separation functional layer 53 of the separation membrane 21.
  • the laminate 10 is positioned so that the second end 12 of the laminate 10 faces the side wall 49 of the container 50, on which the first supply port 43 and the first discharge port 44 are formed, and the first end 11 of the laminate 10 faces the side wall 49 of the container 50, on which the second discharge port 46 is formed ( FIG. 1 ). If the supply and discharge port 45 of the container 50 is not used or does not have a supply and discharge port 45, a permeate-side plug 32 is formed on the side of the first end 11 of the laminate 10, on which the supply and discharge port 45 in FIG. 1 is located.
  • the container 50 has a supply and discharge port 45 and this supply and discharge port 45 is used, not forming a permeate-side plug 32 at the first end 11 of the laminate 10 allows a sweep fluid to be supplied to the permeate-side flow path member 22 or a permeate fluid to be discharged from the supply and discharge port 45.
  • a separation membrane element 1 having the above-described structure can separate specific fluid components as follows. First, the raw fluid is supplied from the first supply port 43 of the container 50 to the second end 12 side of the laminate 10, thereby supplying the raw fluid into the supply-side channel member 23.
  • the separation functional layer of the separation membrane 21 can selectively permeate specific fluid components contained in the raw fluid flowing through the supply-side channel member 23. As a result, the permeated fluid that has permeated the separation membrane 21 contains a higher content of the specific fluid component than the raw fluid.
  • the separation membrane element 1 is provided with a supply-side plug 31, which prevents the raw fluid supplied to the supply-side channel member 23 and the non-permeated fluid that has not permeated the separation membrane 21 from mixing with the permeated fluid flowing through the permeate-side channel member 22.
  • the separation membrane element 1 is also provided with a permeate-side plug 32, which prevents the permeated fluid that has permeated the separation membrane 21 and flowed through the permeate-side channel member 22 from mixing with the raw fluid and non-permeated fluid flowing through the supply-side channel member 23.
  • the non-permeated fluid that does not permeate the separation membrane 21 flows through the supply-side channel member 23 and is discharged from the second end 12 of the stack 10, which is located on the first outlet 44 side of the container 50, to the outside of the separation membrane element 1 via the first outlet 44.
  • the permeated fluid that permeates the separation membrane 21 flows through the permeate-side channel member 22 and is discharged from the first end 11 of the stack 10, which is located on the second outlet 46 side of the container 50, to the outside of the separation membrane element 1 via the second outlet 46.
  • the permeated fluid flowing through the permeate-side channel member 22 may be discharged from the first end 11 of the stack 10, which is located on the supply and outlet 45 side of the container 50, to the outside of the separation membrane element 1 via the supply and outlet 45, in addition to the second outlet 46. This allows the feed fluid to be separated into a permeated fluid and a non-permeated fluid.
  • the sweep fluid When supplying a sweep fluid to the separation membrane element 1, the sweep fluid is supplied to the first end 11 side of the stack 10 from the supply and discharge outlet 45 of the container 50, thereby supplying the sweep fluid to the permeate side flow path member 22.
  • the sweep fluid flows through the permeate side flow path member 22 and is discharged from the first end 11 side of the stack 10, which is on the second discharge outlet 46 side of the container 50, via the second discharge outlet 46 to the outside of the separation membrane element 1.
  • the supply-side sealing portion 31 and the permeation-side sealing portion 32 are bonded at the intersections of the first end portion 11 and second end portion 12 (i.e., the four corners of the laminate 10), the adhesion of the supply-side sealing portion 31 can be improved at the intersections, making it easier to further improve the airtightness of the supply-side sealing portion 31.
  • the supply-side sealing portion 31 and the permeation-side sealing portion 32 can be formed using a sealing material.
  • the supply-side sealing portion 31 and the permeation-side sealing portion 32 may each independently use an adhesive or double-sided tape as the sealing material. If an adhesive is used, the adhesive may be a dried or hardened adhesive layer.
  • each layer constituting the laminate 10 is depicted as having the same size, but the edges of each layer do not have to be aligned.
  • the membrane stack 20 may be smaller than the permeate-side flow path member 22 in a plan view.
  • the supply-side plugging section 31 can be formed, for example, by applying a plugging material to fill the space formed between two permeate-side flow path members 22 arranged on both sides of the membrane stack 20 outside the first end 11 of the membrane stack 20, and then drying or curing the applied plugging material.
  • the plugging material When applying the plugging material, the plugging material may be applied to the first end 11 of the membrane stack 20, or the plugging material may be allowed to penetrate the separation membrane 21 located at the first end 11 of the membrane stack 20 or the porous membrane of the separation membrane 21 and the supply-side flow path member 23, and the plugging material may then be dried or cured in this state to form the supply-side plugging section 31.
  • the sealing material can be the same as the sealing material used to attach the lid, such as double-sided tape or adhesive.
  • double-sided tape can be attached to one of the separation membranes, the release paper can be peeled off, and the other separation membrane can then be attached.
  • the supply-side sealing section 31 and the permeate-side sealing section 32 may be formed of the same sealing material, or they may be formed of different sealing materials. That is, for example, the sealing material of the supply-side sealing section 31 may be double-sided tape and the sealing material of the permeate-side sealing section 32 may be adhesive, or the sealing material of the supply-side sealing section 31 may be adhesive and the sealing material of the permeate-side sealing section 32 may be double-sided tape. Furthermore, both the sealing material of the supply-side sealing section 31 and the sealing material of the permeate-side sealing section 32 may be double-sided tape or adhesive.
  • the second ends 12 of the two permeate side flow path members 22 arranged on both sides of the membrane stack 20 may be located outside the second end 12 of the membrane stack 20, but the laminate according to one embodiment of the present invention is not limited to this.
  • the first ends 11 of the two permeate side flow path members 22 may be located outside the first end 11 of the separation functional layer.
  • the first ends 11 of the two permeate side flow path members 22 may be located outside the first end 11 of the separation membrane 21 (separation functional layer and porous membrane) and may be located at the same position as the end of the supply side flow path member 23 arranged between the two permeate side flow path members 22.
  • the first ends 11 of the two permeate-side channel members 22 may be located outside the first end 11 of the supply-side channel member 23 disposed between the two permeate-side channel members 22, and may be located at the same position as the first end 11 of the porous membrane included in the separation membrane 21.
  • the supply-side plug 31 may include a portion of the separation membrane 21 and/or a portion of the supply-side channel member 23 (e.g., the first end 11).
  • the laminate 10 may have the structure shown in FIG. 10.
  • FIG. 10 is a cross-sectional view of the laminate 10 cut in a direction parallel to the second end 12.
  • two separation membranes 21 are arranged to sandwich one supply-side channel member 23, and two permeate-side channel members 22 are arranged to sandwich the supply-side channel member 23 and the two separation membranes 21.
  • the first ends 11 of the two separation membranes 21 and the two permeate-side channel members 22 are located outside the first end 11 of the supply-side channel member 23.
  • a supply-side plug 31 is provided outside the first end 11 of the supply-side channel member 23 to fill the space formed between the two separation membranes 21.
  • double-sided tape may be used as a sealing material to form the supply-side plug 31, and the two separation membranes 21 may be bonded together.
  • a permeate-side plug 32 is provided at the first ends 11 of the two permeate-side channel members 22.
  • an adhesive may be used as the sealing material for forming the permeate-side plugging portion 32, and the permeate-side plugging portion 32 may be formed by allowing the adhesive to penetrate into the first end portion 11 of the permeate-side flow path member 22.
  • Separation membrane element 1 is capable of separating a specific fluid component from a feed fluid containing at least that specific fluid component.
  • the feed fluid, the specific fluid component, the permeating fluid, the non-permeating fluid, and the sweep fluid may each independently be a gas or a liquid.
  • Separation membrane element 1 is preferably a gas separation membrane element, and is preferably one that selectively allows specific gas components to permeate from the feed gas.
  • the specific fluid component is preferably an acidic gas.
  • acidic gases include carbon dioxide (CO 2 ), hydrogen sulfide (H 2 S), sulfur oxides (SO x ), and nitrogen oxides (NO x ).
  • the specific gas component is preferably carbon dioxide or hydrogen sulfide, and more preferably carbon dioxide.
  • raw material gases include gases containing acidic gases, and specific examples include residual exhaust gas from synthesis gas synthesized in plants that produce hydrogen or urea, etc.; natural gas; biogas; and combustion exhaust gases emitted from power plants, waste treatment plants, cement factories, etc.
  • the upper limit of GPU is not particularly limited, but may be, for example, 100 GPU or less at 150 kPaG.
  • the airtightness test is the test described in the examples below.
  • Method for manufacturing separation membrane element 11 to 13 are perspective views illustrating a manufacturing process for a separation membrane element according to one embodiment of the present invention, in which L represents the length direction of the container, W represents the width direction of the container, and H represents the height direction of the container.
  • the separation membrane element 1 can be manufactured by using a container 50, a separation membrane 21, a permeate-side flow path member 22, and a feed-side flow path member 23, and stacking the permeate-side flow path member 22, the separation membrane 21, and the feed-side flow path member 23 within the storage space of the container 50 to form a stack 10.
  • a stack 10 that is rectangular in plan view is housed in a prismatic container 50.
  • a membrane stack 20 is first fabricated using a first separation membrane 21a and a second separation membrane 21b as separation membranes 21 and a supply-side flow path member 23.
  • the supply-side flow path member 23 is placed on top of the first separation membrane 21a.
  • the first end 11 of the first separation membrane 21a is located outside the first end 11 of the supply-side flow path member 23.
  • double-sided tape 25 (corresponding to the supply-side sealing portion 31) is laminated on the first separation membrane 21a at a portion outside the first end 11 of the supply-side flow path member 23.
  • the second separation membrane 21b is laminated on top of the supply-side flow path member 23 and double-sided tape 25.
  • the first end 11 of the second separation membrane 21b is located outside the first end 11 of the supply-side flow path member 23. Therefore, the first separation membrane 21a and the second separation membrane 21b are bonded together at their first ends 11 via the double-sided tape 25. This results in a membrane stack 20 having a supply-side channel member 23 between the first separation membrane 21a and the second separation membrane 21b.
  • a container body 40 is prepared.
  • the container body 40 has a storage space for storing each component that makes up the laminate 10, and is shown with its top open.
  • the container body 40 can have guide portions 41 for positioning the components stored within the storage space. If the storage space of the container body 40 is prismatic, the guide portions 41 are preferably provided at the corners of the container body 40.
  • the permeate side flow path member 22 is placed inside the container body 40.
  • a sealing material 33 (corresponding to the permeate side sealing portion 32) is applied to the second end portion 12 of this permeate side flow path member 22 (the end portion extending parallel to the length direction L of the container body 40).
  • the membrane laminate portion 20 is laminated on this permeate side flow path member 22.
  • the membrane laminate portion 20 is positioned so that the portion to which the double-sided tape 25 is attached overlaps an end portion (the first end portion 11, the end portion extending parallel to the width direction W of the container body 40) different from the second end portion 12 to which the sealing material 33 is applied.
  • a permeate-side flow path member 22 is placed on top of the membrane stack 20, and a sealing material 33 is applied.
  • the membrane stack 20 first separation membrane 21a, feed-side flow path member 23, and second separation membrane 21b
  • the permeate-side flow path member 22 stacked on the membrane stack 20 form a membrane leaf.
  • the membrane stack 20 is stacked on the permeate-side flow path member 22.
  • the process of applying the sealing material 33, placing the membrane stack 20, and placing the permeate-side flow path member 22 is then repeated to form a stack 10 within the container body 40, as shown by reference numeral 1005 in FIG. 13. After the stack 10 is formed within the container body 40, the gap between the guide portion 41 of the container body 40 and the stack 10 is sealed with a sealing material.
  • a sealing material 33 is applied to the second end 12 of the permeate-side flow path member 22 included in the uppermost membrane leaf of the stack 10 and to the upper end 47 of the side wall portion 49. Then, a lid 60 is placed on the top surface of the vessel body 40. The sealing material is then dried or cured to obtain the separation membrane element 1 shown in Figure 1.
  • first separation membrane 21a and second separation membrane 21b are used to form the membrane stack 20, but the membrane stack 20 may also be formed by folding a single separation membrane in half and sandwiching the supply-side flow path member 23 between the folded separation membranes.
  • the fold should be located at the first end 11 of the stack 10. It is preferable that the fold be located so that it communicates with the second outlet 46 for discharging the permeated fluid from the container 50. In this case, there is no need to provide a supply-side sealing portion at the first end 11 where the fold of the separation membrane is located.
  • a separation apparatus can have one or more separation membrane elements of the present invention.
  • the arrangement and number of separation membrane elements to be provided in a separation apparatus can be selected depending on the required throughput, the recovery rate of specific fluid components, the size of the space where the separation apparatus is to be installed, etc.
  • the separation device can include a first supply section and a first discharge section that communicate with the supply-side flow path member 23 of the separation membrane element 1, and a second discharge section that communicates with the permeate-side flow path member 22 of the separation membrane element 1.
  • the separation device may further include a supply and discharge section that communicates with the permeate-side flow path member 22 of the separation membrane element 1.
  • the first supply section is an inlet for supplying the raw material fluid to the supply-side channel member 23 and can communicate with a first supply port 43 of the separation membrane element 1.
  • the first discharge section is an outlet for discharging the non-permeating fluid flowing through the supply-side channel member 23 and can communicate with a first discharge port 44 of the separation membrane element 1.
  • the second discharge section is an outlet for discharging the permeating fluid flowing through the permeate-side channel member 22 and can communicate with a second discharge port 46 of the separation membrane element 1.
  • the supply/discharge section can be used as a second supply section, which is an inlet for supplying a sweep fluid to the permeate-side channel member 22, or as a third discharge section for discharging the permeated fluid.
  • the supply/discharge part can be communicated with the supply/discharge port 45 of the separation membrane element 1 .
  • An embodiment of the present invention may include the following features.
  • a plate-and-frame separation membrane element comprising a container and a separation membrane having a region arranged in the shape of a flat membrane within the container, the container including a container body having a bottom surface and a side wall, and a lid joined to the container body and arranged opposite the bottom surface across the side wall of the container body, the lid having a protrusion that protrudes along the outer side of the side wall of the container body toward the bottom surface of the container body.
  • ⁇ 3> The plate-and-frame separation membrane element according to ⁇ 1> or ⁇ 2>, wherein the separation membrane has a separation functional layer that selectively separates a specific fluid component contained in a raw fluid.
  • the separation membrane has a separation functional layer that selectively separates a specific fluid component contained in a raw fluid.
  • ⁇ 4> The plate-and-frame separation membrane element according to ⁇ 3>, wherein the raw material fluid is a gas.
  • ⁇ 5> The plate-and-frame separation membrane element according to ⁇ 3> or ⁇ 4>, wherein the specific fluid component is an acidic gas.
  • ⁇ 6> The plate-and-frame separation membrane element according to any one of ⁇ 3> to ⁇ 5>, wherein the container houses a stack including two permeation-side channel members through which a permeated fluid that has permeated the separation membrane flows, and a feed-side channel member through which the raw material fluid flows, the separation membrane, and the feed-side channel member disposed between the two permeation-side channel members.
  • a separation device comprising the plate-and-frame separation membrane element according to ⁇ 6>, a first supply section and a first discharge section communicating with the supply-side channel member, and a second discharge section communicating with the permeation-side channel member.
  • Example 1 (Preparation of separation membrane)
  • the separation membrane used was a composite membrane, and was constructed by laminating a separation functional layer (Pebax (registered trademark) polyether block amide copolymer), a porous substrate (polyacrylonitrile), and a PET nonwoven fabric as a reinforcing support layer in this order.
  • a separation functional layer Pebax (registered trademark) polyether block amide copolymer
  • a porous substrate polyacrylonitrile
  • PET nonwoven fabric as a reinforcing support layer
  • a PP mesh manufactured by Innovex Co., Ltd.; product name 50-150PPN measuring 319 mm in length and 319 mm in width was used as the permeate-side flow path member.
  • a polycarbonate storage vessel was used as the vessel body.
  • the outer dimensions of the vessel body were 350 mm in length, 350 mm in width, and 85 mm in height, and the inner dimensions of the four corner guides were 320 mm in length and 320 mm in width.
  • a separation membrane measuring 319 mm long x 319 mm wide was used as the separation membrane.
  • a PP diamond net measuring 319 mm long x 296 mm wide (manufactured by SWM Co., Ltd.; product name No.
  • a two-component mixed epoxy adhesive (manufactured by Nagase ChemteX Corporation; product name Denatite 3324) was used as the sealing material for forming the permeate-side plugging parts.
  • This two-component mixed epoxy adhesive was used hereinafter when referring to adhesive, not only for the permeate-side plugging parts but also for other parts.
  • Double-sided tape (manufactured by 3M; product name Y4930) was used as the sealing material for forming the feed-side plugging parts.
  • a membrane stack 20 Prior to fabricating the separation membrane element, a membrane stack 20 was fabricated by the method shown in Fig. 11.
  • the membrane stack 20 had a three-layer structure, with one separation membrane (first separation membrane 21a) and one second separation membrane 21b) used as the upper and lower layers, and one supply-side flow path member 23 used as the middle layer.
  • the upper and lower separation membranes (first separation membrane 21a and second separation membrane 21b) were sealed with a supply-side sealing unit 31.
  • a supply-side flow path member 23 was placed on top of the first separation membrane 21a, and double-sided tape 25 was placed as a sealing material to form supply-side sealing portions 31 on the outside of both end portions of the supply-side flow path member 23 in a plan view.
  • the double-sided tape 25 was placed only on the outside of the end portion (first end portion 11) that will later be arranged parallel to the width direction W of the container body 40.
  • a second separation membrane 21b was placed on top of the supply-side flow path member 23 and double-sided tape 25.
  • both the first separation membrane 21a and the second separation membrane 21b were placed so that their separation functional layers were in contact with the supply-side flow path member 23.
  • a separation membrane element 1 was produced by the method shown in FIGS. 12 and 13 in the following procedure.
  • the permeate-side flow path member 22 was placed inside the container body 40, and an adhesive was applied as a sealing material 33 to both ends of the permeate-side flow path member 22 (ends extending parallel to the longitudinal direction L of the container body 40, second ends 12).
  • the membrane stacking unit 20 was placed inside the container body 40.
  • the double-sided tape 25 of the membrane stacking unit 20 was placed so that it overlapped an end (the end extending parallel to the width direction W of the container body 40, the first end 11) different from the end where the adhesive was applied to the permeate side flow path member 22.
  • a permeate-side flow path member 22 was installed on top of the membrane stacking unit 20.
  • the process of applying adhesive (sealing material 33), installing the membrane stacking unit 20, and installing the permeate-side flow path member 22 was then repeated until 30 membrane leaves were installed (reference numerals 1003, 1004, and 1005 in Figure 13).
  • the four corners of the membrane leaves and the guide section inside the vessel body were sealed with adhesive.
  • Example 1 a cover lid was used as the lid 60.
  • the cross-sectional shape of the cover lid was as shown in Figure 4.
  • the protrusion 61 of the cover lid protruded toward the bottom surface 48 of the container body 40 along the outside of the side wall portion 49 of the container body 40.
  • Example 2 In Example 2, a separation membrane element was obtained by the same manufacturing method as in Example 1, except that a hook lid was used as the lid 60.
  • the cross-sectional shape of the hook lid was as shown in Figure 7.
  • the protrusion 61b of the hook lid protruded toward the bottom surface 48 of the container body 40 along the outside of the side wall 49 of the container body 40.
  • Comparative Example 1 In Comparative Example 1, a separation membrane element was obtained by the same manufacturing method as in Example 1, except that a flat lid was used. The cross-sectional shape of the flat lid was as shown in Figure 2. The flat lid 260 did not have any protrusions.
  • FIG. 14 is a schematic diagram illustrating the testing equipment used in the airtightness tests.
  • a supply section 83 communicating with the first supply port and a discharge section 84 communicating with the first discharge port were provided at two ends of the separation membrane element 1 extending parallel to the longitudinal direction L.
  • a supply section 85 communicating with the supply and discharge port and a discharge section 86 communicating with the second discharge port were provided at two ends of the separation membrane element 1 extending parallel to the width direction W.
  • Valves were provided in the supply section 83, the discharge section 84, the supply section 85, and the discharge section 86.
  • a cylinder was connected to the supply section 83 to supply N2 gas to the first supply port.
  • N2 gas at room temperature (20°C) was supplied into the separation membrane element 1, and a pressure of 150 kPaG (G indicates gauge pressure) was applied to the supply part 83 of the separation membrane element. The pressure was confirmed with the pressure gauge 81, and the valves of the discharge parts 84 and 86 were closed. 2.
  • the valve of the supply part 85 was closed, the valve of the discharge part 86 was opened, and the flow rate of the permeated gas was measured with a membrane flow meter 82 (high-precision precision membrane flow meter, "VP-U series" manufactured by Horiba, Ltd.) and evaluated according to the following criteria.
  • B N2 permeation rate indicated by membrane flow meter is greater than 40 GPU.
  • Table 1 shows the test results for the separation membrane elements of the examples and comparative examples.
  • One aspect of the present invention can be widely used in processes for separating acid gases such as CO2 from mixed gases containing at least acid gases and water vapor, such as synthesis gas synthesized in large-scale plants that produce hydrogen or urea , combustion exhaust gases emitted from power plants, waste disposal sites, cement factories, etc., natural gas, and other exhaust gases.
  • acid gases such as CO2
  • water vapor such as synthesis gas synthesized in large-scale plants that produce hydrogen or urea , combustion exhaust gases emitted from power plants, waste disposal sites, cement factories, etc., natural gas, and other exhaust gases.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

L'invention concerne un élément de membrane de séparation de type à plaques et cadres ayant une excellente résistance à la pression.　Un élément de membrane de séparation de type à plaques et cadres selon la présente divulgation comprend : un récipient ; et une membrane disposée dans le récipient. Le récipient comprend : un corps de récipient ayant une partie de surface inférieure et une partie de paroi latérale ; et un couvercle relié au corps de récipient et disposé de façon à faire face à la partie de surface inférieure avec la partie de paroi latérale entre eux. Le couvercle a une partie de projection faisant saillie vers la partie de surface inférieure le long de l'extérieur de la partie de paroi latérale.
PCT/JP2025/022457 2024-08-05 2025-06-23 Élément de membrane de séparation et dispositif de séparation Pending WO2026034026A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2024-128993 2024-08-05
JP2024128993A JP2026026702A (ja) 2024-08-05 2024-08-05 分離膜エレメントおよび分離装置

Publications (1)

Publication Number Publication Date
WO2026034026A1 true WO2026034026A1 (fr) 2026-02-12

Family

ID=98735026

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2025/022457 Pending WO2026034026A1 (fr) 2024-08-05 2025-06-23 Élément de membrane de séparation et dispositif de séparation

Country Status (2)

Country Link
JP (1) JP2026026702A (fr)
WO (1) WO2026034026A1 (fr)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018051494A (ja) * 2016-09-29 2018-04-05 宇部興産株式会社 貯蔵用ガス製造システム及びその製造方法並びに、貯蔵システム及び貯蔵方法
JP2021531166A (ja) * 2018-07-12 2021-11-18 ハイドロゲン・メム−テック・アーエス ガス分離デバイス
WO2023210275A1 (fr) * 2022-04-26 2023-11-02 住友化学株式会社 Élément de membrane de séparation et dispositif de séparation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018051494A (ja) * 2016-09-29 2018-04-05 宇部興産株式会社 貯蔵用ガス製造システム及びその製造方法並びに、貯蔵システム及び貯蔵方法
JP2021531166A (ja) * 2018-07-12 2021-11-18 ハイドロゲン・メム−テック・アーエス ガス分離デバイス
WO2023210275A1 (fr) * 2022-04-26 2023-11-02 住友化学株式会社 Élément de membrane de séparation et dispositif de séparation

Also Published As

Publication number Publication date
JP2026026702A (ja) 2026-02-18

Similar Documents

Publication Publication Date Title
US20250281882A1 (en) Separation membrane element and separation device
CN101310838B (zh) 用于物质和热量传递的装置
CN110636896B (zh) 螺旋型气体分离膜元件、气体分离膜模块以及气体分离装置
US8673148B2 (en) Multifiltration cartridge filtration apparatus
CN110545896B (zh) 螺旋型气体分离膜元件、气体分离膜模块及气体分离装置
KR102475635B1 (ko) 가스 분리막 엘리먼트, 가스 분리막 모듈 및 가스 분리 장치
EP0296881A2 (fr) Module à membrane perméable sous forme de multiples feuilles
CN102574065B (zh) 膜元件、气体分离装置和内燃机
WO2026034026A1 (fr) Élément de membrane de séparation et dispositif de séparation
JP7713997B2 (ja) 分離膜エレメントおよび分離装置
WO2026034027A1 (fr) Module à membrane de séparation et procédé de séparation de fluides
JPS5962326A (ja) ガス分離モジユ−ル
JP7397697B2 (ja) ガス分離膜エレメント、ガス分離膜モジュール、及びガス分離装置
JP7544558B2 (ja) 分離膜エレメントの製造方法
WO2026034025A1 (fr) Élément de membrane de séparation de type à plaque et cadre et dispositif de séparation
JP5356882B2 (ja) プリーツ成形体の製造方法及びプリーツ成形体
JP5101553B2 (ja) プリーツ成形体の製造方法及びプリーツ成形体
US20260054225A1 (en) Spiral membrane element and membrane separation device
JPH01288303A (ja) 流体分離素子
JP2015112530A (ja) 分離膜モジュール
WO2023176272A1 (fr) Élément de membrane en spirale, séparateur de transmission et procédé de séparation de membrane
JP2013031852A (ja) プリーツ成形体
JPS6353848B2 (fr)
WO2017081784A1 (fr) Module de membrane de séparation, son procédé de production et dispositif de séparation à membrane

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 25851076

Country of ref document: EP

Kind code of ref document: A1