WO2026068360A1 - Procédé de fabrication d'hydrogène et de carbone solide à partir de déchets - Google Patents
Procédé de fabrication d'hydrogène et de carbone solide à partir de déchetsInfo
- Publication number
- WO2026068360A1 WO2026068360A1 PCT/EP2025/076825 EP2025076825W WO2026068360A1 WO 2026068360 A1 WO2026068360 A1 WO 2026068360A1 EP 2025076825 W EP2025076825 W EP 2025076825W WO 2026068360 A1 WO2026068360 A1 WO 2026068360A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pyrolysis
- reactor
- feedstock
- gas stream
- process according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/22—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/28—Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using moving solid particles, e.g. fluidised bed technique
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/05—Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/085—Methods of heating the process for making hydrogen or synthesis gas by electric heating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
La présente invention concerne un procédé de fabrication d'hydrogène à partir de déchets, le procédé comprenant les étapes consistant à (a) fournir une charge d'alimentation F, ladite charge d'alimentation F comprenant des déchets, (b) convertir ladite charge d'alimentation F par une première réaction de pyrolyse dans un premier réacteur de pyrolyse PR1 en un produit de réaction RP1, ledit produit de réaction RP1 comprenant un courant de gaz GS, (c) séparer ledit courant de gaz GS dudit produit de réaction RP1 dans une unité de séparation de gaz SU, (d) facultativement fournir une co-charge d'alimentation gazeuse COF, et (e) convertir ledit courant de gaz GS et la co-charge d'alimentation gazeuse COF facultativement fournie à l'étape d) par une seconde réaction de pyrolyse dans un second réacteur de pyrolyse PR2 en hydrogène H et en carbone pyrolytique granulaire GPC, la seconde réaction de pyrolyse étant conduite dans un réacteur à lit mobile, un réacteur à lit fluidisé ou un réacteur à lit fixe. L'invention concerne également une installation chimique appropriée pour conduire ledit procédé.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP24203074.0 | 2024-09-27 | ||
| EP24203074 | 2024-09-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2026068360A1 true WO2026068360A1 (fr) | 2026-04-02 |
Family
ID=92926388
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2025/076825 Pending WO2026068360A1 (fr) | 2024-09-27 | 2025-09-19 | Procédé de fabrication d'hydrogène et de carbone solide à partir de déchets |
Country Status (1)
| Country | Link |
|---|---|
| WO (1) | WO2026068360A1 (fr) |
Citations (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2982622A (en) | 1958-09-02 | 1961-05-02 | Exxon Research Engineering Co | Hydrocarbon conversion process |
| WO1995003375A1 (fr) | 1993-07-20 | 1995-02-02 | Basf Aktiengesellschaft | Procede de recyclage de matieres plastiques dans un vapocraqueur |
| EP0713906A1 (fr) | 1994-11-24 | 1996-05-29 | Basf Aktiengesellschaft | Procédé de recyclage de matériaux plastiques dans une unité de vapocraquage |
| US20040118047A1 (en) | 2002-12-18 | 2004-06-24 | Choudhary Vasant Ramchandra | Process for the continuous production of carbon monoxide-free hydrogen from methane or methane-rich hydrocarbons |
| US20060112639A1 (en) | 2003-11-29 | 2006-06-01 | Nick Peter A | Process for pyrolytic heat recovery enhanced with gasification of organic material |
| WO2013004398A2 (fr) | 2011-07-05 | 2013-01-10 | Linde Aktiengesellschaft | Procédé de production parallèle d'hydrogène et de produits à base de carbone |
| WO2019145279A1 (fr) | 2018-01-26 | 2019-08-01 | Basf Se | Dispositif garni d'une substance solide pour la mise en œuvre de réactions endothermiques, à chauffage électrique direct |
| WO2020016186A1 (fr) | 2018-07-19 | 2020-01-23 | Basf Se | Composition de mélange comprenant du coke de pétrole et du carbone pyrolytique pour électrodes |
| WO2020118417A1 (fr) | 2018-12-10 | 2020-06-18 | Ekona Power Inc. | Procédé et réacteur destinés à produire au moins un produit |
| WO2020200522A1 (fr) | 2019-04-05 | 2020-10-08 | Linde Gmbh | Réacteur pour réactions endothermiques à hautes températures |
| WO2021069394A1 (fr) | 2019-10-09 | 2021-04-15 | Reissner Markus | Procédé et système de production d'un mélange gazeux contenant des hydrocarbures et contenant de l'hydrogène à partir de plastique |
| US20210331918A1 (en) | 2020-04-23 | 2021-10-28 | Exxonmobil Research And Engineering Company | Methane pyrolysis using stacked fluidized beds |
| WO2022043773A1 (fr) | 2020-08-26 | 2022-03-03 | Hindustan Petroleum Corporation Limited | Composition de catalyseurs pour la production d'hydrogène |
| US20220185664A1 (en) | 2020-12-15 | 2022-06-16 | Ekona Power Inc. | Methods of producing one or more products using a feedstock gas reactor |
| WO2023057242A1 (fr) | 2021-10-06 | 2023-04-13 | Basf Se | Utilisation d'un matériau vecteur carboné dans des réacteurs à lit |
| CN116426308A (zh) | 2023-03-29 | 2023-07-14 | 上海菲利科思新材料有限公司 | 一种废塑料生产乙烯装置蒸汽裂解原料油和纳米炭材料的方法及装置系统 |
| WO2023222695A1 (fr) * | 2022-05-19 | 2023-11-23 | Quantafuel Asa | Procédé de préparation d'hydrogène et de combustible liquide à partir d'une charge d'alimentation de plastique |
| WO2024115488A1 (fr) | 2022-11-28 | 2024-06-06 | Basf Se | Procédé de fonctionnement d'un processus de craquage |
-
2025
- 2025-09-19 WO PCT/EP2025/076825 patent/WO2026068360A1/fr active Pending
Patent Citations (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2982622A (en) | 1958-09-02 | 1961-05-02 | Exxon Research Engineering Co | Hydrocarbon conversion process |
| WO1995003375A1 (fr) | 1993-07-20 | 1995-02-02 | Basf Aktiengesellschaft | Procede de recyclage de matieres plastiques dans un vapocraqueur |
| EP0713906A1 (fr) | 1994-11-24 | 1996-05-29 | Basf Aktiengesellschaft | Procédé de recyclage de matériaux plastiques dans une unité de vapocraquage |
| US20040118047A1 (en) | 2002-12-18 | 2004-06-24 | Choudhary Vasant Ramchandra | Process for the continuous production of carbon monoxide-free hydrogen from methane or methane-rich hydrocarbons |
| US20060112639A1 (en) | 2003-11-29 | 2006-06-01 | Nick Peter A | Process for pyrolytic heat recovery enhanced with gasification of organic material |
| WO2013004398A2 (fr) | 2011-07-05 | 2013-01-10 | Linde Aktiengesellschaft | Procédé de production parallèle d'hydrogène et de produits à base de carbone |
| WO2019145279A1 (fr) | 2018-01-26 | 2019-08-01 | Basf Se | Dispositif garni d'une substance solide pour la mise en œuvre de réactions endothermiques, à chauffage électrique direct |
| WO2020016186A1 (fr) | 2018-07-19 | 2020-01-23 | Basf Se | Composition de mélange comprenant du coke de pétrole et du carbone pyrolytique pour électrodes |
| WO2020118417A1 (fr) | 2018-12-10 | 2020-06-18 | Ekona Power Inc. | Procédé et réacteur destinés à produire au moins un produit |
| WO2020200522A1 (fr) | 2019-04-05 | 2020-10-08 | Linde Gmbh | Réacteur pour réactions endothermiques à hautes températures |
| US20220152568A1 (en) | 2019-04-05 | 2022-05-19 | Linde Gmbh | Reactor for endothermic high-temperature reactions |
| WO2021069394A1 (fr) | 2019-10-09 | 2021-04-15 | Reissner Markus | Procédé et système de production d'un mélange gazeux contenant des hydrocarbures et contenant de l'hydrogène à partir de plastique |
| US20210331918A1 (en) | 2020-04-23 | 2021-10-28 | Exxonmobil Research And Engineering Company | Methane pyrolysis using stacked fluidized beds |
| WO2022043773A1 (fr) | 2020-08-26 | 2022-03-03 | Hindustan Petroleum Corporation Limited | Composition de catalyseurs pour la production d'hydrogène |
| US20220185664A1 (en) | 2020-12-15 | 2022-06-16 | Ekona Power Inc. | Methods of producing one or more products using a feedstock gas reactor |
| WO2023057242A1 (fr) | 2021-10-06 | 2023-04-13 | Basf Se | Utilisation d'un matériau vecteur carboné dans des réacteurs à lit |
| WO2023222695A1 (fr) * | 2022-05-19 | 2023-11-23 | Quantafuel Asa | Procédé de préparation d'hydrogène et de combustible liquide à partir d'une charge d'alimentation de plastique |
| WO2024115488A1 (fr) | 2022-11-28 | 2024-06-06 | Basf Se | Procédé de fonctionnement d'un processus de craquage |
| CN116426308A (zh) | 2023-03-29 | 2023-07-14 | 上海菲利科思新材料有限公司 | 一种废塑料生产乙烯装置蒸汽裂解原料油和纳米炭材料的方法及装置系统 |
Non-Patent Citations (4)
| Title |
|---|
| ANDREI VEKSHA ET AL.: "Defossilization and decarbonization of hydrogen production using plastic waste", JOURNAL OF HAZARDOUS MATERIALS, vol. 452, 2023, pages 131270, XP087303344, Retrieved from the Internet <URL:https://doi.org/10.1016/j.jhazmat.2023.131270> DOI: 10.1016/j.jhazmat.2023.131270 |
| JÖRG WOIDASKY: "Ullmanns Encyclopedia of Industrial Chemistry", 2020, WILEY-VCH VERLAG GMBH & CO. KGAA, article "Pyrolysis", pages: 15 - 17 |
| LAURENT FULCHERIVANDADJULIEN ROHANIELLIOTT WYSENED HARDMANENOCH DAMES, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, vol. 48, 2023, pages 2920 - 2928 |
| VEKSHA ANDREI ET AL: "Defossilization and decarbonization of hydrogen production using plastic waste: Temperature and feedstock effects during thermolysis stage", JOURNAL OF HAZARDOUS MATERIALS, ELSEVIER, AMSTERDAM, NL, vol. 452, 22 March 2023 (2023-03-22), XP087303344, ISSN: 0304-3894, [retrieved on 20230322], DOI: 10.1016/J.JHAZMAT.2023.131270 * |
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