ZA200209151B - Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production. - Google Patents
Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production. Download PDFInfo
- Publication number
- ZA200209151B ZA200209151B ZA200209151A ZA200209151A ZA200209151B ZA 200209151 B ZA200209151 B ZA 200209151B ZA 200209151 A ZA200209151 A ZA 200209151A ZA 200209151 A ZA200209151 A ZA 200209151A ZA 200209151 B ZA200209151 B ZA 200209151B
- Authority
- ZA
- South Africa
- Prior art keywords
- slurry
- activity
- synthesis
- gas
- catalyst
- Prior art date
Links
- 239000002002 slurry Substances 0.000 title claims description 236
- 239000003054 catalyst Substances 0.000 title claims description 230
- 230000000694 effects Effects 0.000 title claims description 167
- 238000003786 synthesis reaction Methods 0.000 title claims description 165
- 229930195733 hydrocarbon Natural products 0.000 title claims description 156
- 230000015572 biosynthetic process Effects 0.000 title claims description 155
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 155
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 124
- 238000004519 manufacturing process Methods 0.000 title description 4
- 239000007789 gas Substances 0.000 claims description 125
- 229910052739 hydrogen Inorganic materials 0.000 claims description 82
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 74
- 239000001257 hydrogen Substances 0.000 claims description 72
- 239000002245 particle Substances 0.000 claims description 65
- 238000000034 method Methods 0.000 claims description 56
- 239000007788 liquid Substances 0.000 claims description 52
- 230000008569 process Effects 0.000 claims description 51
- 230000003716 rejuvenation Effects 0.000 claims description 41
- 238000006243 chemical reaction Methods 0.000 claims description 37
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 15
- 230000003197 catalytic effect Effects 0.000 claims description 13
- 239000012530 fluid Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 4
- 239000010941 cobalt Substances 0.000 claims description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 238000005194 fractionation Methods 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 238000011065 in-situ storage Methods 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- 230000000977 initiatory effect Effects 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- -1 methane Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000003870 refractory metal Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011959 amorphous silica alumina Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000005555 metalworking Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
- C07C1/0445—Preparation; Activation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
- C07C1/063—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
- C07C1/066—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system used for dissolving, suspending or transporting the catalyst
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/587,148 US6696502B1 (en) | 2000-06-02 | 2000-06-02 | Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200209151B true ZA200209151B (en) | 2003-09-01 |
Family
ID=24348561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200209151A ZA200209151B (en) | 2000-06-02 | 2002-11-11 | Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6696502B1 (fr) |
| EP (1) | EP1292554B1 (fr) |
| JP (1) | JP5097324B2 (fr) |
| AR (1) | AR028932A1 (fr) |
| AT (1) | ATE308492T1 (fr) |
| AU (2) | AU2001259224B2 (fr) |
| BR (1) | BR0111315A (fr) |
| CA (1) | CA2408529C (fr) |
| DE (1) | DE60114619T2 (fr) |
| DK (1) | DK1292554T3 (fr) |
| ES (1) | ES2252229T3 (fr) |
| NO (1) | NO20025787L (fr) |
| WO (1) | WO2001094281A1 (fr) |
| ZA (1) | ZA200209151B (fr) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6753286B2 (en) * | 2002-01-29 | 2004-06-22 | Exxonmobil Research And Engineering Company | Supported catalyst regeneration |
| US7419928B2 (en) * | 2003-04-11 | 2008-09-02 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst production |
| GB2410449B (en) * | 2004-01-28 | 2008-05-21 | Statoil Asa | Fischer-Tropsch catalysts |
| US7230034B2 (en) * | 2004-03-19 | 2007-06-12 | Conocophillips Company | Prevention of and recovering from a catalyst bed slumping in a gas-agitated multiphase reactor |
| JP5100151B2 (ja) * | 2006-02-28 | 2012-12-19 | 新日鐵住金株式会社 | 合成ガスから炭化水素を製造する触媒、触媒の製造方法、合成ガスから炭化水素を製造する方法、及び、触媒の再生方法 |
| GB2446127A (en) * | 2007-01-30 | 2008-08-06 | Gtl F1 Ag | Preparation of Fischer-Tropsch Catalysts |
| DE102008021628A1 (de) | 2008-04-25 | 2009-12-24 | Ibh Engineering Gmbh | Vorrichtung und Verfahren sowie Verwendung eines Reaktors zur Herstellung von Roh,- Brenn- und Kraftstoffen aus organischen Substanzen |
| GB2473071B (en) | 2009-09-01 | 2013-09-11 | Gtl F1 Ag | Fischer-tropsch catalysts |
| GB2475492B (en) | 2009-11-18 | 2014-12-31 | Gtl F1 Ag | Fischer-Tropsch synthesis |
| JP5676120B2 (ja) * | 2010-02-26 | 2015-02-25 | Ｊｘ日鉱日石エネルギー株式会社 | 活性化フィッシャー・トロプシュ合成触媒の製造方法及び炭化水素の製造方法 |
| CN103249481B (zh) | 2010-08-09 | 2015-11-25 | Gtl.F1公司 | 费托催化剂 |
| FR2977809B1 (fr) * | 2011-07-12 | 2016-01-08 | Arkema France | Regeneration de catalyseur en continu dans un reacteur a lit fluidise |
| JP5869397B2 (ja) * | 2012-03-28 | 2016-02-24 | 独立行政法人石油天然ガス・金属鉱物資源機構 | 気泡塔型スラリー床反応器のスタートアップ方法 |
| US9604189B2 (en) * | 2012-12-20 | 2017-03-28 | Shell Oil Company | Methods and systems for promoting hydrogen gas distribution within cellulosic biomass solids during hydrothermal digestion |
| CN115364625B (zh) * | 2022-08-26 | 2025-02-11 | 攀钢集团攀枝花钢铁研究院有限公司 | 四氯化钛生产过程中氯化尾气的处理方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3524330A1 (de) * | 1985-07-08 | 1987-01-08 | Basf Ag | Verfahren zur herstellung von katalysatoren und ihre verwendung bei hydrier- und aminierreaktionen |
| US5292705A (en) | 1992-09-24 | 1994-03-08 | Exxon Research & Engineering Co. | Activation of hydrocarbon synthesis catalyst |
| US5283216A (en) | 1992-09-24 | 1994-02-01 | Exxon Research And Engineering Company | Rejuvenation of hydrocarbon synthesis catalyst |
| PE31698A1 (es) | 1995-11-08 | 1998-06-15 | Shell Int Research | Proceso de activacion y rejuvenecimiento de catalizador |
| US5958986A (en) | 1997-05-02 | 1999-09-28 | Exxon Research And Engineering Co. | Slurry hydrocarbon synthesis process with catalyst rejuvenation in external lift pipe (law544) |
| US5817702A (en) | 1997-05-02 | 1998-10-06 | Exxon Research And Engineering Company | Hydrocarbon synthesis catalyst slurry rejuvenation with gas disengagement |
| US5821270A (en) * | 1997-05-02 | 1998-10-13 | Exxon Research And Engineering Company | Slurry hydrocarbon synthesis process with multistage catalyst rejuvenation |
| US5844005A (en) * | 1997-05-02 | 1998-12-01 | Exxon Research And Engineering Company | Hydrocarbon synthesis using reactor tail gas for catalyst rejuvenation |
| US5811363A (en) | 1997-05-02 | 1998-09-22 | Exxon Research And Engineering Company | Catalyst rejuvenation in hydrocarbon synthesis slurry with reduced slurry recontamination |
| US5811468A (en) * | 1997-05-06 | 1998-09-22 | Exxon Research And Engineering Company | Combination gas disengaging downcomer-rejuvenation tube for in-situ slurry catalyst rejuvenation (LAW541) |
| US6323248B1 (en) * | 2000-06-02 | 2001-11-27 | Exxonmobil Research And Engineering Company | Slurry hydrocarbon synthesis with fresh catalyst activity increase during hydrocarbon production |
-
2000
- 2000-06-02 US US09/587,148 patent/US6696502B1/en not_active Expired - Lifetime
-
2001
- 2001-04-27 CA CA002408529A patent/CA2408529C/fr not_active Expired - Lifetime
- 2001-04-27 WO PCT/US2001/013699 patent/WO2001094281A1/fr not_active Ceased
- 2001-04-27 ES ES01932718T patent/ES2252229T3/es not_active Expired - Lifetime
- 2001-04-27 AU AU2001259224A patent/AU2001259224B2/en not_active Expired
- 2001-04-27 AU AU5922401A patent/AU5922401A/xx active Pending
- 2001-04-27 DE DE60114619T patent/DE60114619T2/de not_active Expired - Lifetime
- 2001-04-27 JP JP2002501799A patent/JP5097324B2/ja not_active Expired - Fee Related
- 2001-04-27 DK DK01932718T patent/DK1292554T3/da active
- 2001-04-27 AT AT01932718T patent/ATE308492T1/de not_active IP Right Cessation
- 2001-04-27 BR BR0111315-1A patent/BR0111315A/pt not_active IP Right Cessation
- 2001-04-27 EP EP01932718A patent/EP1292554B1/fr not_active Expired - Lifetime
- 2001-05-28 AR ARP010102538A patent/AR028932A1/es unknown
-
2002
- 2002-11-11 ZA ZA200209151A patent/ZA200209151B/en unknown
- 2002-12-02 NO NO20025787A patent/NO20025787L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU2001259224B2 (en) | 2005-09-08 |
| BR0111315A (pt) | 2003-12-16 |
| JP5097324B2 (ja) | 2012-12-12 |
| JP2003535677A (ja) | 2003-12-02 |
| DE60114619T2 (de) | 2006-07-27 |
| ES2252229T3 (es) | 2006-05-16 |
| NO20025787D0 (no) | 2002-12-02 |
| ATE308492T1 (de) | 2005-11-15 |
| EP1292554A1 (fr) | 2003-03-19 |
| CA2408529A1 (fr) | 2001-12-13 |
| AU5922401A (en) | 2001-12-17 |
| EP1292554B1 (fr) | 2005-11-02 |
| US6696502B1 (en) | 2004-02-24 |
| CA2408529C (fr) | 2009-12-08 |
| WO2001094281A1 (fr) | 2001-12-13 |
| AR028932A1 (es) | 2003-05-28 |
| DE60114619D1 (de) | 2005-12-08 |
| DK1292554T3 (da) | 2006-03-06 |
| NO20025787L (no) | 2003-01-27 |
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