ZA200209733B - Fischer tropsch process. - Google Patents
Fischer tropsch process. Download PDFInfo
- Publication number
- ZA200209733B ZA200209733B ZA200209733A ZA200209733A ZA200209733B ZA 200209733 B ZA200209733 B ZA 200209733B ZA 200209733 A ZA200209733 A ZA 200209733A ZA 200209733 A ZA200209733 A ZA 200209733A ZA 200209733 B ZA200209733 B ZA 200209733B
- Authority
- ZA
- South Africa
- Prior art keywords
- catalyst
- liquid
- free
- reaction zone
- stream
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 58
- 239000007788 liquid Substances 0.000 claims description 190
- 238000006243 chemical reaction Methods 0.000 claims description 77
- 239000003054 catalyst Substances 0.000 claims description 65
- 229930195733 hydrocarbon Natural products 0.000 claims description 49
- 150000002430 hydrocarbons Chemical class 0.000 claims description 49
- 239000004215 Carbon black (E152) Substances 0.000 claims description 40
- 239000007789 gas Substances 0.000 claims description 39
- 239000002245 particle Substances 0.000 claims description 37
- 238000009835 boiling Methods 0.000 claims description 28
- 230000015572 biosynthetic process Effects 0.000 claims description 24
- 239000002904 solvent Substances 0.000 claims description 23
- 238000003786 synthesis reaction Methods 0.000 claims description 23
- 230000003197 catalytic effect Effects 0.000 claims description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 229910017052 cobalt Inorganic materials 0.000 claims description 9
- 239000010941 cobalt Substances 0.000 claims description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000002002 slurry Substances 0.000 claims description 8
- 239000007792 gaseous phase Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 238000004891 communication Methods 0.000 claims description 3
- 239000000047 product Substances 0.000 description 38
- 239000006227 byproduct Substances 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 229910001868 water Inorganic materials 0.000 description 17
- 239000007787 solid Substances 0.000 description 13
- 238000005243 fluidization Methods 0.000 description 12
- 238000000926 separation method Methods 0.000 description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- 238000000746 purification Methods 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 239000013067 intermediate product Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- 238000004517 catalytic hydrocracking Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 229910052702 rhenium Inorganic materials 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 244000187656 Eucalyptus cornuta Species 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical class CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000006148 magnetic separator Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 235000013849 propane Nutrition 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0405—Apparatus
- C07C1/042—Temperature controlling devices; Heat exchangers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0425—Catalysts; their physical properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0013793.5A GB0013793D0 (en) | 2000-06-06 | 2000-06-06 | Process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200209733B true ZA200209733B (en) | 2003-10-15 |
Family
ID=9893111
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200209733A ZA200209733B (en) | 2000-06-06 | 2002-11-29 | Fischer tropsch process. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6716887B2 (de) |
| EP (1) | EP1290109B1 (de) |
| AR (1) | AR028681A1 (de) |
| AT (1) | ATE275183T1 (de) |
| AU (2) | AU2001264047B2 (de) |
| CA (1) | CA2411840A1 (de) |
| DE (1) | DE60105293T2 (de) |
| GB (1) | GB0013793D0 (de) |
| WO (1) | WO2001094499A1 (de) |
| ZA (1) | ZA200209733B (de) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004511619A (ja) * | 2000-10-13 | 2004-04-15 | ビーピー エクスプロレーション オペレーティング カンパニー リミテッド | フィッシャートロプシュ合成法 |
| US7183327B2 (en) * | 2004-03-18 | 2007-02-27 | Conocophillips Company | Optimized particle distribution for slurry bubble column reactors |
| WO2007009987A1 (en) * | 2005-07-20 | 2007-01-25 | Shell Internationale Research Maatschappij B.V. | Hydrocarbon synthesis process |
| GB2444055B (en) * | 2006-11-23 | 2011-11-23 | Gtl F1 Ag | Gas to liquids plant with consecutive Fischer-Tropsch reactors and hydrogen make-up |
| US20080260631A1 (en) | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| GB2465554B (en) | 2008-11-18 | 2013-03-13 | Gtl F1 Ag | Slurry bubble column reactor |
| US8114915B2 (en) * | 2008-12-05 | 2012-02-14 | Exxonmobil Research And Engineering Company | Method and system for handling slurries of varying liquid rates and solids content |
| GB2466315B (en) | 2008-12-22 | 2013-01-09 | Gtl F1 Ag | Apparatus and method for conducting a Fischer-Tropsch synthesis reaction |
| US8119014B2 (en) * | 2008-12-23 | 2012-02-21 | Exxonmobil Research And Engineering Company | Systems and methods to remove liquid product and fines from a slurry reactor |
| US8278363B2 (en) | 2009-03-23 | 2012-10-02 | Thomas Charles Holcombe | Fischer-tropsch reactions using heat transfer tubes with a catalyst layer on the outside surfaces |
| GB2471338B (en) * | 2009-06-26 | 2014-12-24 | Gtl F1 Ag | Apparatus and process for three-phase reacton |
| SA111320792B1 (ar) * | 2010-09-29 | 2014-11-13 | Univ Zhejiang | مفاعل بلمرة للطبقة المميعة وطريقة لتحضير البوليمر |
| JP6145348B2 (ja) | 2013-07-30 | 2017-06-07 | 新日鉄住金エンジニアリング株式会社 | 炭化水素合成用の反応器 |
| US10710043B2 (en) | 2014-09-24 | 2020-07-14 | Raven Sr, Llc | Compact and maintainable waste reformation apparatus |
| EP4598669A1 (de) * | 2022-10-04 | 2025-08-13 | Oberon Fuels, Inc. | Reaktor zur umwandlung von dimethylether in wasserstoff |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2646442A (en) * | 1948-06-04 | 1953-07-21 | Texas Co | Hydrocarbon synthesis |
| US5348982A (en) * | 1990-04-04 | 1994-09-20 | Exxon Research & Engineering Co. | Slurry bubble column (C-2391) |
-
2000
- 2000-06-06 GB GBGB0013793.5A patent/GB0013793D0/en not_active Ceased
-
2001
- 2001-05-23 EP EP01938366A patent/EP1290109B1/de not_active Expired - Lifetime
- 2001-05-23 WO PCT/GB2001/002329 patent/WO2001094499A1/en not_active Ceased
- 2001-05-23 AT AT01938366T patent/ATE275183T1/de not_active IP Right Cessation
- 2001-05-23 DE DE60105293T patent/DE60105293T2/de not_active Expired - Fee Related
- 2001-05-23 US US10/297,253 patent/US6716887B2/en not_active Expired - Fee Related
- 2001-05-23 CA CA002411840A patent/CA2411840A1/en not_active Abandoned
- 2001-05-23 AU AU2001264047A patent/AU2001264047B2/en not_active Expired - Fee Related
- 2001-05-23 AU AU6404701A patent/AU6404701A/xx active Pending
- 2001-06-05 AR ARP010102683A patent/AR028681A1/es not_active Application Discontinuation
-
2002
- 2002-11-29 ZA ZA200209733A patent/ZA200209733B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001094499A1 (en) | 2001-12-13 |
| ATE275183T1 (de) | 2004-09-15 |
| CA2411840A1 (en) | 2001-12-13 |
| DE60105293T2 (de) | 2005-03-24 |
| EP1290109A1 (de) | 2003-03-12 |
| EP1290109B1 (de) | 2004-09-01 |
| GB0013793D0 (en) | 2000-07-26 |
| US6716887B2 (en) | 2004-04-06 |
| AU2001264047B2 (en) | 2005-02-03 |
| AU6404701A (en) | 2001-12-17 |
| US20030195264A1 (en) | 2003-10-16 |
| DE60105293D1 (de) | 2004-10-07 |
| AR028681A1 (es) | 2003-05-21 |
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