ZA200308227B - Integrated process for the preparation of alkyl and alkenyl substituted aromatic compounds. - Google Patents
Integrated process for the preparation of alkyl and alkenyl substituted aromatic compounds. Download PDFInfo
- Publication number
- ZA200308227B ZA200308227B ZA200308227A ZA200308227A ZA200308227B ZA 200308227 B ZA200308227 B ZA 200308227B ZA 200308227 A ZA200308227 A ZA 200308227A ZA 200308227 A ZA200308227 A ZA 200308227A ZA 200308227 B ZA200308227 B ZA 200308227B
- Authority
- ZA
- South Africa
- Prior art keywords
- integrated process
- process according
- reactor
- stream
- catalyst
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 59
- 230000008569 process Effects 0.000 title claims description 57
- 150000001491 aromatic compounds Chemical class 0.000 title claims description 20
- 125000003342 alkenyl group Chemical group 0.000 title claims description 12
- 125000000217 alkyl group Chemical group 0.000 title claims description 10
- 238000002360 preparation method Methods 0.000 title description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 82
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 69
- 239000003054 catalyst Substances 0.000 claims description 66
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 60
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 53
- 238000005804 alkylation reaction Methods 0.000 claims description 51
- 230000029936 alkylation Effects 0.000 claims description 44
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 37
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 35
- 239000005977 Ethylene Substances 0.000 claims description 35
- 229940093470 ethylene Drugs 0.000 claims description 35
- -1 alkenyl hydrocarbon Chemical class 0.000 claims description 34
- 229930195733 hydrocarbon Natural products 0.000 claims description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims description 31
- 239000012071 phase Substances 0.000 claims description 24
- 239000012530 fluid Substances 0.000 claims description 21
- 230000008929 regeneration Effects 0.000 claims description 19
- 238000011069 regeneration method Methods 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 239000010457 zeolite Substances 0.000 claims description 18
- 238000004821 distillation Methods 0.000 claims description 16
- 239000007789 gas Substances 0.000 claims description 16
- 238000010555 transalkylation reaction Methods 0.000 claims description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 230000003197 catalytic effect Effects 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 9
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 7
- 230000000295 complement effect Effects 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- 238000004438 BET method Methods 0.000 claims description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 239000007791 liquid phase Substances 0.000 claims description 6
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052733 gallium Inorganic materials 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229910052680 mordenite Inorganic materials 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- VIDOPANCAUPXNH-UHFFFAOYSA-N 1,2,3-triethylbenzene Chemical class CCC1=CC=CC(CC)=C1CC VIDOPANCAUPXNH-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000002485 combustion reaction Methods 0.000 claims description 2
- 150000005195 diethylbenzenes Chemical class 0.000 claims description 2
- 239000002737 fuel gas Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910000311 lanthanide oxide Inorganic materials 0.000 claims description 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 2
- 150000002602 lanthanoids Chemical class 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229940058172 ethylbenzene Drugs 0.000 description 38
- 229940044603 styrene Drugs 0.000 description 25
- 229940076134 benzene Drugs 0.000 description 16
- 239000000047 product Substances 0.000 description 15
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000003153 chemical reaction reagent Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000012159 carrier gas Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 230000000630 rising effect Effects 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 239000007792 gaseous phase Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000007775 late Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- RXXCIBALSKQCAE-UHFFFAOYSA-N 3-methylbutoxymethylbenzene Chemical compound CC(C)CCOCC1=CC=CC=C1 RXXCIBALSKQCAE-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 229910001195 gallium oxide Inorganic materials 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
- C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
- C07C15/46—Styrene; Ring-alkylated styrenes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Electrodes Of Semiconductors (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2001MI001110A ITMI20011110A1 (it) | 2001-05-25 | 2001-05-25 | Procedimento integrato per la preparazione di composti aromatici alchil e alchenil sostituiti |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200308227B true ZA200308227B (en) | 2004-10-22 |
Family
ID=11447757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200308227A ZA200308227B (en) | 2001-05-25 | 2003-10-22 | Integrated process for the preparation of alkyl and alkenyl substituted aromatic compounds. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US7094940B2 (de) |
| EP (1) | EP1390330B1 (de) |
| JP (1) | JP4451131B2 (de) |
| CN (1) | CN1263715C (de) |
| AR (1) | AR033926A1 (de) |
| AT (1) | ATE354557T1 (de) |
| BR (1) | BR0209512B1 (de) |
| CA (1) | CA2446552C (de) |
| DE (1) | DE60218301T2 (de) |
| DK (1) | DK1390330T3 (de) |
| EG (1) | EG23095A (de) |
| ES (1) | ES2282470T3 (de) |
| IT (1) | ITMI20011110A1 (de) |
| MX (1) | MXPA03010606A (de) |
| RU (1) | RU2266886C2 (de) |
| SA (1) | SA02230180B1 (de) |
| WO (1) | WO2002096844A1 (de) |
| ZA (1) | ZA200308227B (de) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE266614T1 (de) | 2000-02-02 | 2004-05-15 | Dow Global Technologies Inc | Integriertes verfahren zur herstellung einer alkenyl-substituierten aromatischen verbindung |
| ITMI20040198A1 (it) * | 2004-02-09 | 2004-05-09 | Snam Progetti | Dispositivo reattore-rigeneratore e suo impiego nella produzione di stirene |
| MXPA06008965A (es) | 2004-02-09 | 2007-02-20 | Down Chemical Company | Proceso para la preparacion de compuestos de hidrocarburos deshidrogenados. |
| WO2006016727A2 (ja) * | 2004-08-13 | 2006-02-16 | Tatsuhiro Nisimura | 重質油改質用触媒、重質油改質方法及びその装置 |
| ITMI20052514A1 (it) * | 2005-12-29 | 2007-06-30 | Polimeri Europa Spa | Procedimento migliorato per la deidrogenazione di idrocarburi alchilaeomatici finalizzata alla produzione di monomeri vinilaromatici |
| US8653317B2 (en) * | 2009-03-19 | 2014-02-18 | Dow Global Technologies Llc | Dehydrogenation process and catalyst |
| IT1397885B1 (it) * | 2009-12-23 | 2013-02-04 | Polimeri Europa Spa | Processo per preparare etilbenzene. |
| MX391707B (es) | 2015-03-30 | 2025-03-21 | Dow Global Technologies Llc | Proceso integrado de deshidrogenacion de hidrocarburos de c3-c4. |
| AR109242A1 (es) * | 2016-05-09 | 2018-11-14 | Dow Global Technologies Llc | Un proceso para la deshidrogenación catalítica |
| RU2655924C1 (ru) * | 2018-02-27 | 2018-05-30 | Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" | Способ получения олефиновых углеводородов |
| US11203559B2 (en) | 2018-07-05 | 2021-12-21 | Dow Global Technologies Llc | Chemical processes and systems that include the combustion of supplemental fuels |
| EP3817849B1 (de) * | 2018-07-05 | 2025-11-19 | Dow Global Technologies LLC | Verfahren zur inbetriebnahme von wirbelschichtreaktorsystemen |
| WO2020009860A1 (en) | 2018-07-05 | 2020-01-09 | Dow Global Technologies Llc | Chemical processing utilizing hydrogen containing supplemental fuel for catalyst processing |
| CN109622002B (zh) * | 2018-12-17 | 2021-12-21 | 西北大学 | 一种用于提高btx产率的催化剂的制备方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2689501B1 (fr) * | 1992-04-01 | 1994-05-20 | Elf Atochem Sa | Procede de fabrication d'ethylbenzene. |
| IT1264626B1 (it) * | 1993-06-16 | 1996-10-04 | Eniricerche Spa | Processo per la preparazione di cumene |
| IT1295072B1 (it) * | 1997-09-26 | 1999-04-27 | Snam Progetti | Procedimento per la produzione di stirene |
-
2001
- 2001-05-25 IT IT2001MI001110A patent/ITMI20011110A1/it unknown
-
2002
- 2002-05-14 RU RU2003133447/04A patent/RU2266886C2/ru not_active IP Right Cessation
- 2002-05-14 EP EP02774017A patent/EP1390330B1/de not_active Expired - Lifetime
- 2002-05-14 WO PCT/EP2002/005311 patent/WO2002096844A1/en not_active Ceased
- 2002-05-14 BR BRPI0209512-2A patent/BR0209512B1/pt not_active IP Right Cessation
- 2002-05-14 DE DE60218301T patent/DE60218301T2/de not_active Expired - Lifetime
- 2002-05-14 AT AT02774017T patent/ATE354557T1/de not_active IP Right Cessation
- 2002-05-14 CN CNB028102223A patent/CN1263715C/zh not_active Expired - Fee Related
- 2002-05-14 DK DK02774017T patent/DK1390330T3/da active
- 2002-05-14 JP JP2003500024A patent/JP4451131B2/ja not_active Expired - Fee Related
- 2002-05-14 ES ES02774017T patent/ES2282470T3/es not_active Expired - Lifetime
- 2002-05-14 US US10/477,516 patent/US7094940B2/en not_active Expired - Lifetime
- 2002-05-14 CA CA2446552A patent/CA2446552C/en not_active Expired - Fee Related
- 2002-05-14 MX MXPA03010606A patent/MXPA03010606A/es active IP Right Grant
- 2002-05-24 AR ARP020101931A patent/AR033926A1/es active IP Right Grant
- 2002-05-25 EG EG20020555A patent/EG23095A/xx active
- 2002-06-30 SA SA02230180A patent/SA02230180B1/ar unknown
-
2003
- 2003-10-22 ZA ZA200308227A patent/ZA200308227B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AR033926A1 (es) | 2004-01-07 |
| BR0209512A (pt) | 2004-07-13 |
| EP1390330B1 (de) | 2007-02-21 |
| ITMI20011110A1 (it) | 2002-11-25 |
| RU2266886C2 (ru) | 2005-12-27 |
| RU2003133447A (ru) | 2005-05-10 |
| DK1390330T3 (da) | 2007-06-04 |
| CA2446552C (en) | 2011-01-04 |
| DE60218301T2 (de) | 2007-11-15 |
| DE60218301D1 (de) | 2007-04-05 |
| SA02230180B1 (ar) | 2007-10-29 |
| CA2446552A1 (en) | 2002-12-05 |
| ES2282470T3 (es) | 2007-10-16 |
| MXPA03010606A (es) | 2004-03-09 |
| JP4451131B2 (ja) | 2010-04-14 |
| ATE354557T1 (de) | 2007-03-15 |
| JP2004527580A (ja) | 2004-09-09 |
| US7094940B2 (en) | 2006-08-22 |
| CN1509263A (zh) | 2004-06-30 |
| ITMI20011110A0 (it) | 2001-05-25 |
| EP1390330A1 (de) | 2004-02-25 |
| CN1263715C (zh) | 2006-07-12 |
| US20040152932A1 (en) | 2004-08-05 |
| WO2002096844A1 (en) | 2002-12-05 |
| BR0209512B1 (pt) | 2012-11-27 |
| EG23095A (en) | 2004-03-31 |
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