ZA200700435B - Polylsulfone-polyether blockcopolymers, process to synthesize it, membranes made therefrom - Google Patents

Polylsulfone-polyether blockcopolymers, process to synthesize it, membranes made therefrom Download PDF

Info

Publication number: ZA200700435B
Authority: ZA; South Africa
Prior art keywords: block; block copolymer; phi; blocks; copolymer according
Prior art date: 2004-07-22

Application number

ZA200700435A

Other languages

English (en)

Inventor

Thomas H Schwab

Original Assignee

Solvay Advanced Polymers Llc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2004-07-22

Filing date

2007-01-15

Publication date

2008-07-30

2007-01-15 Application filed by Solvay Advanced Polymers Llc filed Critical Solvay Advanced Polymers Llc

2008-07-30 Publication of ZA200700435B publication Critical patent/ZA200700435B/en

Links

229920001400 block copolymer Polymers 0.000 title claims description 45
238000000034 method Methods 0.000 title claims description 13
239000012528 membrane Substances 0.000 title description 25
229920000570 polyether Polymers 0.000 title description 4
239000004721 Polyphenylene oxide Substances 0.000 title description 3
229920000642 polymer Polymers 0.000 claims description 23
125000003118 aryl group Chemical group 0.000 claims description 15
229920001577 copolymer Polymers 0.000 claims description 9
-1 aromatic diol Chemical class 0.000 claims description 7
239000002904 solvent Substances 0.000 claims description 6
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
125000002947 alkylene group Chemical group 0.000 claims description 4
239000004615 ingredient Substances 0.000 claims description 4
238000006116 polymerization reaction Methods 0.000 claims description 4
238000006068 polycondensation reaction Methods 0.000 claims description 3
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
238000006073 displacement reaction Methods 0.000 claims description 2
229910052736 halogen Inorganic materials 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
230000000269 nucleophilic effect Effects 0.000 claims description 2
230000002194 synthesizing effect Effects 0.000 claims description 2
150000002009 diols Chemical class 0.000 claims 2
ZYZWCJWINLGQRL-UHFFFAOYSA-N 4-phenylcyclohexa-2,4-diene-1,1-diol Chemical group C1=CC(O)(O)CC=C1C1=CC=CC=C1 ZYZWCJWINLGQRL-UHFFFAOYSA-N 0.000 claims 1
241000767684 Thoe Species 0.000 claims 1
239000007788 liquid Substances 0.000 claims 1
230000000063 preceeding effect Effects 0.000 claims 1
210000004379 membrane Anatomy 0.000 description 25
229920002492 poly(sulfone) Polymers 0.000 description 12
229920001223 polyethylene glycol Polymers 0.000 description 8
239000002202 Polyethylene glycol Substances 0.000 description 7
239000000654 additive Substances 0.000 description 7
229920006393 polyether sulfone Polymers 0.000 description 7
230000003301 hydrolyzing effect Effects 0.000 description 5
230000002209 hydrophobic effect Effects 0.000 description 5
239000011148 porous material Substances 0.000 description 5
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 4
229920001477 hydrophilic polymer Polymers 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
238000000108 ultra-filtration Methods 0.000 description 4
239000007789 gas Substances 0.000 description 3
238000001631 haemodialysis Methods 0.000 description 3
230000000322 hemodialysis Effects 0.000 description 3
238000001471 micro-filtration Methods 0.000 description 3
229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
239000001267 polyvinylpyrrolidone Substances 0.000 description 3
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
239000000126 substance Substances 0.000 description 3
150000003457 sulfones Chemical class 0.000 description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
241000100287 Membras Species 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
235000010290 biphenyl Nutrition 0.000 description 2
239000004305 biphenyl Substances 0.000 description 2
VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical compound C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 2
239000012510 hollow fiber Substances 0.000 description 2
229920001515 polyalkylene glycol Polymers 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
230000001954 sterilising effect Effects 0.000 description 2
238000004659 sterilization and disinfection Methods 0.000 description 2
IBRQUKZZBXZOBA-UHFFFAOYSA-N 1-chloro-3-(3-chlorophenyl)sulfonylbenzene Chemical compound ClC1=CC=CC(S(=O)(=O)C=2C=C(Cl)C=CC=2)=C1 IBRQUKZZBXZOBA-UHFFFAOYSA-N 0.000 description 1
229930185605 Bisphenol Natural products 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
229920012266 Poly(ether sulfone) PES Polymers 0.000 description 1
239000004695 Polyether sulfone Substances 0.000 description 1
229920000491 Polyphenylsulfone Polymers 0.000 description 1
229920003295 Radel® Polymers 0.000 description 1
239000002253 acid Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
239000003513 alkali Substances 0.000 description 1
238000013459 approach Methods 0.000 description 1
229920005601 base polymer Polymers 0.000 description 1
235000013405 beer Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
238000005266 casting Methods 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
238000007385 chemical modification Methods 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000003776 cleavage reaction Methods 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000000576 coating method Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
229920006351 engineering plastic Polymers 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
229920001600 hydrophobic polymer Polymers 0.000 description 1
230000005661 hydrophobic surface Effects 0.000 description 1
229960004337 hydroquinone Drugs 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
230000002427 irreversible effect Effects 0.000 description 1
238000002386 leaching Methods 0.000 description 1
230000007774 longterm Effects 0.000 description 1
APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
230000035699 permeability Effects 0.000 description 1
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
238000009832 plasma treatment Methods 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
230000007017 scission Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000004513 sizing Methods 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
230000001225 therapeutic effect Effects 0.000 description 1
238000005690 transetherification reaction Methods 0.000 description 1
229920000428 triblock copolymer Polymers 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
- B01D71/80—Block polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/46—Post-polymerisation treatment, e.g. recovery, purification, drying
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/52—Polyethers
- B01D71/521—Aliphatic polyethers
- B01D71/5211—Polyethylene glycol or polyethyleneoxide
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/66—Polymers having sulfur in the main chain, with or without nitrogen, oxygen or carbon only
- B01D71/68—Polysulfones; Polyethersulfones
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
- C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
- C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
- C08G65/42—Phenols and polyhydroxy ethers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/20—Polysulfones
- C08G75/23—Polyethersulfones

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Analytical Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Separation Using Semi-Permeable Membranes (AREA)
Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
External Artificial Organs (AREA)
Polyesters Or Polycarbonates (AREA)
Polyethers (AREA)

ZA200700435A 2004-07-22 2007-01-15 Polylsulfone-polyether blockcopolymers, process to synthesize it, membranes made therefrom ZA200700435B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US58984804P	2004-07-22	2004-07-22

Publications (1)

Publication Number	Publication Date
ZA200700435B true ZA200700435B (en)	2008-07-30

Family

ID=35033551

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ZA200700435A ZA200700435B (en)	2004-07-22	2007-01-15	Polylsulfone-polyether blockcopolymers, process to synthesize it, membranes made therefrom

Country Status (9)

Country	Link
EP (1)	EP1773913B1 (de)
JP (1)	JP2008507614A (de)
KR (1)	KR20070036141A (de)
CN (1)	CN1989174A (de)
AT (1)	ATE412686T1 (de)
DE (1)	DE602005010711D1 (de)
SG (1)	SG129009A1 (de)
WO (1)	WO2006012453A1 (de)
ZA (1)	ZA200700435B (de)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US20090275725A1 (en)	2006-06-22	2009-11-05	Basf Se	Polysulphones and polyether sulphones with reduced yellow index and processes for their preparation
ATE537220T1 (de) *	2007-12-18	2011-12-15	Solvay Specialty Polymers Usa	Polyphenylsulfonketon-copolymere
KR100950087B1 (ko) *	2008-04-21	2010-03-29	한국화학연구원	폴리에테르 설폰 수지의 제조방법
AU2012260780B2 (en) *	2011-05-25	2015-12-17	Solvay Specialty Polymers Usa, Llc	Polymers with reduced estrogenic activity
JP6169255B2 (ja)	2013-05-02	2017-07-26	ビーエーエスエフソシエタス・ヨーロピアＢａｓｆＳｅ	ポリアリールエーテルスルホンコポリマー
CA2923657C (en) *	2013-11-01	2022-05-31	Virginia Tech Intellectual Properties, Inc.	Crosslinked polymer compositions for gas separation membranes
CN106659982B (zh) *	2014-08-12	2020-06-26	巴斯夫欧洲公司	制备膜的方法
JP6379995B2 (ja) *	2014-10-24	2018-08-29	Nok株式会社	炭素膜用製膜原液およびこれを用いた中空糸炭素膜の製造方法
CN105504299A (zh) *	2016-02-24	2016-04-20	中国科学院烟台海岸带研究所	一种aba型聚砜家族嵌段共聚物的合成方法
WO2017187279A1 (en)	2016-04-29	2017-11-02	Sabic Global Technologies B.V.	Healable thermoplastic resins
JP7305621B2 (ja)	2017-09-11	2023-07-10	フレセニウスメディカルケアホールディングスインコーポレーテッド	微多孔膜およびその作製方法
WO2021182342A1 (ja) *	2020-03-09	2021-09-16	住友化学株式会社	ブロックコポリマー
EP4400533A4 (de) *	2021-09-06	2025-08-13	Sumitomo Chemical Co	Blockcopolymer
KR20250083510A (ko)	2022-10-11	2025-06-10	솔베이 스페셜티 폴리머즈 유에스에이, 엘.엘.씨.	친수성이 개선된 폴리아릴에테르설폰 공중합체
WO2025210172A1 (en) *	2024-04-05	2025-10-09	Syensqo Specialty Polymers Usa, Llc	Polyarylethersulfone containing phosphorous and made from dihaloarylsulfone and alicyclic diol
WO2025210173A1 (en) *	2024-04-05	2025-10-09	Syensqo Specialty Polymers Usa, Llc	Polyarylethersulfone containing phosphorous and made from dihaloarylsulfone and acyclic diol

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Publication number	Priority date	Publication date	Assignee	Title
JPS6375031A (ja) *	1985-06-12	1988-04-05	アモコ・コ−ポレイション	スルホン化ポリ（アリ−ルエ−テル）樹脂の製造方法
US4625000A (en) *	1985-06-12	1986-11-25	Union Carbide Corporation	Process for preparing sulfonated poly(aryl ether) resins
DE19515689A1 (de) *	1995-04-28	1996-10-31	Bayer Ag	Polysulfon/Polyether-Blockcopolykondensate
US5911880A (en) *	1995-12-15	1999-06-15	Research Corporation Technologies, Inc.	Self-wetting membranes from engineering plastics
JP3983337B2 (ja) *	1996-03-29	2007-09-26	帝人株式会社	ポリアルキルエーテル単位を含むスルホンおよびケトンの医療用材料への適用
DE19907605A1 (de) *	1999-02-23	2000-08-24	Bayer Ag	Verfahren zur Herstellung von Polyetherblockcopolysulfonen

2005
- 2005-07-21 WO PCT/US2005/025944 patent/WO2006012453A1/en not_active Ceased
- 2005-07-21 JP JP2007522771A patent/JP2008507614A/ja active Pending
- 2005-07-21 AT AT05773816T patent/ATE412686T1/de not_active IP Right Cessation
- 2005-07-21 KR KR1020077001371A patent/KR20070036141A/ko not_active Withdrawn
- 2005-07-21 SG SG200700240A patent/SG129009A1/en unknown
- 2005-07-21 CN CNA200580024377XA patent/CN1989174A/zh active Pending
- 2005-07-21 EP EP05773816A patent/EP1773913B1/de not_active Expired - Lifetime
- 2005-07-21 DE DE602005010711T patent/DE602005010711D1/de not_active Expired - Lifetime
2007
- 2007-01-15 ZA ZA200700435A patent/ZA200700435B/en unknown

Also Published As

Publication number	Publication date
EP1773913A1 (de)	2007-04-18
DE602005010711D1 (de)	2008-12-11
WO2006012453A1 (en)	2006-02-02
SG129009A1 (en)	2007-02-26
KR20070036141A (ko)	2007-04-02
ATE412686T1 (de)	2008-11-15
JP2008507614A (ja)	2008-03-13
CN1989174A (zh)	2007-06-27
EP1773913B1 (de)	2008-10-29

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