AR007730A1 - Disposición de compresor de refrigeración multietapa que tiene múltiples intercambiadores de calor de núcleo acorazado para enfriar una corriente de alimentación normalmente gaseosa y método para ser llevada a cabo en dicha disposición - Google Patents

Disposición de compresor de refrigeración multietapa que tiene múltiples intercambiadores de calor de núcleo acorazado para enfriar una corriente de alimentación normalmente gaseosa y método para ser llevada a cabo en dicha disposición

Info

Publication number
AR007730A1
AR007730A1 ARP970103039A ARP970103039A AR007730A1 AR 007730 A1 AR007730 A1 AR 007730A1 AR P970103039 A ARP970103039 A AR P970103039A AR P970103039 A ARP970103039 A AR P970103039A AR 007730 A1 AR007730 A1 AR 007730A1
Authority
AR
Argentina
Prior art keywords
stage
shell
compression
liquid
shells
Prior art date
Application number
ARP970103039A
Other languages
English (en)
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of AR007730A1 publication Critical patent/AR007730A1/es

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00—Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/22—Arrangements for directing heat-exchange media into successive compartments, e.g. arrangements of guide plates
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/008—Hydrocarbons
    • F25J1/0082—Methane
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/008—Hydrocarbons
    • F25J1/0085—Ethane; Ethylene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/008—Hydrocarbons
    • F25J1/0087—Propane; Propylene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0203—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
    • F25J1/0207—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle as at least a three level SCR refrigeration cascade
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0203—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
    • F25J1/0208—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop
    • F25J1/0209—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop as at least a three level refrigeration cascade
    • F25J1/021—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop as at least a three level refrigeration cascade using a deep flash recycle loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244—Operation; Control and regulation; Instrumentation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0262—Details of the cold heat exchange system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J5/00—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
    • F25J5/002—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger
    • F25J5/005—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger in a reboiler-condenser, e.g. within a column
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00—Details related to the use of reboiler-condensers
    • F25J2250/02—Bath type boiler-condenser using thermo-siphon effect, e.g. with natural or forced circulation or pool boiling, i.e. core-in-kettle heat exchanger

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)

Abstract

En compresión de refrigeración multi-etapa, donde el refrigerante líquido retirado de un intercambiador de calor de tipo núcleo acorazado conectado auna etapa de alta compresión es pasado a un intercambiador similar conectado a una etapa decomp resión más baja, se mejora la estabilidad de nivel delíquido en el intercambiador de etapa de compresión más alta, proveyendo un volumen de oleada aumentado. Una placa reductora de circulación que atraviesauna porción inferior de la corazadivide en una zona de enfriamiento que contiene los núcleos, y una zona de descarga que es parte del volumen deoleada. La altura del reductor de circulación se selecciona para facilitar el mantenimiento de por lo menos un nivel de líquidofunciona l mínimo en lacoraza. El líquido refrigerante retirado desde la zona de descarga de la coraza de etapa alta es suministrado a la zona de enfriamiento de una corazaconectada a una etapa de compresión más baja. El nivel de líquido enla coraza es mantenido manipulando flujo hacia el refrigerante líquido que es vaporizadohacia adentro de la zona de enfriamiento de la coraza de etapa de compresión más alta. Un compresor refrigerante puede emplear dos o más etapas decompresión,donde las c orazas de etapa más alta son típicamente mucho más chicas que las corazas de etapa más baja, y el esquema descripto evita que sevuelque gran nivel de líquido en el averno de una etapa más alta que resulta de menor nivel delíquido que se vue lca en las corazas de etapa inferior.
ARP970103039A 1996-07-17 1997-07-08 Disposición de compresor de refrigeración multietapa que tiene múltiples intercambiadores de calor de núcleo acorazado para enfriar una corriente de alimentación normalmente gaseosa y método para ser llevada a cabo en dicha disposición AR007730A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/682,463 US5651270A (en) 1996-07-17 1996-07-17 Core-in-shell heat exchangers for multistage compressors

Publications (1)

Publication Number Publication Date
AR007730A1 true AR007730A1 (es) 1999-11-10

Family

ID=24739825

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP970103039A AR007730A1 (es) 1996-07-17 1997-07-08 Disposición de compresor de refrigeración multietapa que tiene múltiples intercambiadores de calor de núcleo acorazado para enfriar una corriente de alimentación normalmente gaseosa y método para ser llevada a cabo en dicha disposición

Country Status (8)

Country Link
US (1) US5651270A (es)
AR (1) AR007730A1 (es)
AU (1) AU717627B2 (es)
CA (1) CA2258944C (es)
CO (1) CO4700571A1 (es)
ID (1) ID17616A (es)
MY (1) MY132936A (es)
WO (1) WO1998002698A1 (es)

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DZ2671A1 (fr) * 1997-12-12 2003-03-22 Shell Int Research Processus de liquéfaction d'un produit alimenté gazeux riche en méthane pour obtenir un gaz natural liquéfié.
MY125082A (en) 1999-12-15 2006-07-31 Shell Int Research Compression apparatus for gaseous refrigerant
TWI314637B (en) * 2003-01-31 2009-09-11 Shell Int Research Process of liquefying a gaseous, methane-rich feed to obtain liquefied natural gas
US6962060B2 (en) * 2003-12-10 2005-11-08 Air Products And Chemicals, Inc. Refrigeration compression system with multiple inlet streams
GB0400986D0 (en) * 2004-01-16 2004-02-18 Cryostar France Sa Compressor
US20070245770A1 (en) * 2006-04-19 2007-10-25 Saudi Arabian Oil Company Optimization of a dual refrigeration system natural gas liquid plant via empirical experimental method
US8591199B2 (en) * 2007-01-11 2013-11-26 Conocophillips Company Multi-stage compressor/driver system and method of operation
JP5259727B2 (ja) * 2007-12-04 2013-08-07 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 炭化水素流の冷却及び/又は液化の方法及び装置
BRPI0918587B1 (pt) * 2008-09-08 2020-10-13 Conocophillips Company processo e instalação para liquefazer um fluxo de gás natural
US20100319877A1 (en) * 2009-06-23 2010-12-23 Conocophillips Company Removable Flow Diversion Baffles for Liquefied Natural Gas Heat Exchangers
LT2603760T (lt) * 2010-03-31 2019-09-10 Linde Aktiengesellschaft Pagrindinis šilumokaitis ir vamzdžio šoninio srauto aušinimo būdas
DE102011013340A1 (de) 2010-12-30 2012-07-05 Linde Aktiengesellschaft Verteileinrichtung und Wärmetauschervorrichtung
US20130153172A1 (en) * 2011-12-20 2013-06-20 Conocophillips Company Method and apparatus for reducing the impact of motion in a core-in-shell heat exchanger
CN104024783B (zh) * 2011-12-20 2016-08-31 科诺科菲利浦公司 用于抑制芯壳式热交换器中的晃动的内部挡板
DE102012021637A1 (de) * 2012-11-02 2014-05-08 Linde Aktiengesellschaft Verfahren zum Abkühlen einer Kohlenwasserstoff-reichen Fraktion
EP3077750B1 (de) * 2013-12-05 2018-02-21 Linde Aktiengesellschaft Wärmeübertrager mit sammelkanal für den abzug einer flüssigen phase
AU2015225534B2 (en) * 2014-03-04 2019-03-14 Conocophillips Company Heat exchanger for a liquefied natural gas facility
WO2015134188A1 (en) * 2014-03-07 2015-09-11 Conocophillips Company Heat exchanger system with mono-cyclone inline separator
WO2015168509A1 (en) * 2014-05-01 2015-11-05 Conocophillips Company Liquid drains in core-in-shell heat exchanger
EP2944909A1 (de) * 2014-05-13 2015-11-18 Linde Aktiengesellschaft Wärmeübertrager mit Kanälen zur Dämpfung von Flüssigkeitsbewegungen
US11162732B2 (en) * 2015-04-07 2021-11-02 Conocophillips Company Quench system for a refrigeration cycle of a liquefied natural gas facility and method of quenching
US12491464B2 (en) 2017-05-21 2025-12-09 EnFlex, Inc. Process for separating hydrogen from an olefin hydrocarbon effluent vapor stream
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US11668523B2 (en) * 2017-05-21 2023-06-06 EnFlex, Inc. Process for separating hydrogen from an olefin hydrocarbon effluent vapor stream
US12111104B2 (en) 2017-05-21 2024-10-08 EnFlex, Inc. Process for separating hydrogen from an olefin hydrocarbon effluent vapor stream
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Also Published As

Publication number Publication date
WO1998002698A1 (en) 1998-01-22
CA2258944A1 (en) 1998-01-22
CO4700571A1 (es) 1998-12-29
CA2258944C (en) 2004-02-24
AU3305797A (en) 1998-02-09
ID17616A (id) 1998-01-15
AU717627B2 (en) 2000-03-30
MY132936A (en) 2007-10-31
US5651270A (en) 1997-07-29

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