AR117923A2 - Compuestos 4-amino-6-(4-fenilo sustituido)-picolinatos y 6-amino-2-(4-fenilo sustituido)-pirimidin-4-carboxilatos y composición que los comprende - Google Patents
Compuestos 4-amino-6-(4-fenilo sustituido)-picolinatos y 6-amino-2-(4-fenilo sustituido)-pirimidin-4-carboxilatos y composición que los comprendeInfo
- Publication number
- AR117923A2 AR117923A2 ARP200100245A ARP200100245A AR117923A2 AR 117923 A2 AR117923 A2 AR 117923A2 AR P200100245 A ARP200100245 A AR P200100245A AR P200100245 A ARP200100245 A AR P200100245A AR 117923 A2 AR117923 A2 AR 117923A2
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- amino
- substituted phenyl
- alkoxy
- haloalkyl
- Prior art date
Links
- -1 4-SUBSTITUTED PHENYL Chemical class 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 3
- 229910052731 fluorine Inorganic materials 0.000 abstract 3
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000000304 alkynyl group Chemical group 0.000 abstract 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 2
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 2
- 150000002431 hydrogen Chemical group 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052740 iodine Inorganic materials 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 abstract 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 abstract 1
- 125000006583 (C1-C3) haloalkyl group Chemical group 0.000 abstract 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 1
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 1
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
- 125000004890 (C1-C6) alkylamino group Chemical group 0.000 abstract 1
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 abstract 1
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 1
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 1
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 abstract 1
- 125000006519 CCH3 Chemical group 0.000 abstract 1
- 150000001204 N-oxides Chemical class 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 150000001721 carbon Chemical group 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 abstract 1
- 125000005499 phosphonyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/04—Oxygen or sulfur attached to an aliphatic side-chain of a carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/73—Unsubstituted amino or imino radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/42—One nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
- C07D239/47—One nitrogen atom and one oxygen or sulfur atom, e.g. cytosine
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pyridine Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Reivindicación 1: Compuestos de 4-amino-6-(4-fenilo sustituido)-picolinatos y 6-amino-2-(4-fenilo sustituido)-pirimidin-4-carboxilatos caracterizados por tener la fórmula (1), en donde X es CH, CF, CCl, o CCH₃; R¹ es OR¹, en donde R¹ es H, alquilo C₁₋₈, o arilaquilo C₇₋₁₀; R² es halógeno, alquilo C₁₋₄, haloalquilo C₁₋₄, alquenilo C₂₋₄, haloalquenilo C₂₋₄, alcoxi C₁₋₄, o haloalcoxi C₁₋₄; R³ y R⁴ son cada uno, de manera independiente, hidrógeno, alquilo C₁₋₆, haloalquilo C₁₋₆, alquenilo C₃₋₆, haloalquenilo C₃₋₆, alquinilo C₃₋₆, hidroxi, alcoxi C₁₋₆, haloalcoxi C₁₋₆, formilo, (alquilo C₁₋₃)carbonilo, (haloalquilo C₁₋₃)carbonilo, (alcoxi C₁₋₆)carbonilo, (alquilo C₁₋₆)carbamilo, alquilsulfonilo C₁₋₆, tri(alquilo C₁₋₆)sililo, di(alquilo C₁₋₆)fosfonilo, o R³ y R⁴ junto con el átomo de nitrógeno al que se encuentran unidos forman un anillo saturado de 5 ó 6 miembros, o R³ y R⁴ tomados juntos representan =CR³R⁴, en donde R³ y R⁴ son cada uno, de manera independiente, hidrógeno, alquilo C₁₋₆, alquenilo C₃₋₆, alquinilo C₃₋₆, alcoxi C₁₋₆, o alquilamino C₁₋₆, o R³ y R⁴ junto con el átomo de carbono al que se encuentran unidos forman un anillo saturado de 5 ó 6 miembros; y Ar es Ar¹ de fórmula (2), en donde X¹ es H, F, Br, I, etinilo, haloetinilo, CF₂H, OCF₂H, OCF₃, CN, CONH₂, CO₂H, CO₂CH₃, o NO₂; con la salvedad que: i) X¹ no es H, F, OCF₃, o CN, cuando R² es Cl y X es CH; ii) X¹ no es F, I, CN, o etinilo, cuando R² es OCH₃ y X es CF; y iii) X¹ no es H, cuando X es CCl; o una sal de N-óxido de los mismos aceptables en agricultura.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/840,233 US9113629B2 (en) | 2013-03-15 | 2013-03-15 | 4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR117923A2 true AR117923A2 (es) | 2021-09-01 |
Family
ID=51529778
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP140100999A AR095449A1 (es) | 2013-03-15 | 2014-03-14 | 4-amino-6-(4-fenilo sustituido)-picolinatos y 6-amino-2-(4-fenilo sustituido)-pirimidin-4-carboxilatos y su uso como herbicidas |
| ARP200100245A AR117923A2 (es) | 2013-03-15 | 2020-01-30 | Compuestos 4-amino-6-(4-fenilo sustituido)-picolinatos y 6-amino-2-(4-fenilo sustituido)-pirimidin-4-carboxilatos y composición que los comprende |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP140100999A AR095449A1 (es) | 2013-03-15 | 2014-03-14 | 4-amino-6-(4-fenilo sustituido)-picolinatos y 6-amino-2-(4-fenilo sustituido)-pirimidin-4-carboxilatos y su uso como herbicidas |
Country Status (29)
| Country | Link |
|---|---|
| US (1) | US9113629B2 (es) |
| EP (2) | EP2967069B1 (es) |
| JP (4) | JP6527502B2 (es) |
| KR (2) | KR102414529B1 (es) |
| CN (2) | CN105163588B (es) |
| AP (1) | AP2015008772A0 (es) |
| AR (2) | AR095449A1 (es) |
| AU (3) | AU2014235571C1 (es) |
| BR (2) | BR122019021766B8 (es) |
| CA (2) | CA3124191A1 (es) |
| CL (1) | CL2015002665A1 (es) |
| CR (1) | CR20150521A (es) |
| DK (1) | DK2967069T3 (es) |
| ES (2) | ES2959334T3 (es) |
| HR (1) | HRP20182056T1 (es) |
| HU (1) | HUE063201T2 (es) |
| IL (1) | IL240854A (es) |
| LT (1) | LT2967069T (es) |
| MX (1) | MX367303B (es) |
| PH (1) | PH12015502146B1 (es) |
| PL (2) | PL3440938T3 (es) |
| PT (1) | PT2967069T (es) |
| RS (1) | RS58151B1 (es) |
| RU (2) | RU2652132C2 (es) |
| SI (1) | SI2967069T1 (es) |
| UA (2) | UA125174C2 (es) |
| UY (1) | UY35477A (es) |
| WO (1) | WO2014150850A1 (es) |
| ZA (1) | ZA201507330B (es) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2967057B1 (en) * | 2013-03-15 | 2018-11-21 | Dow AgroSciences LLC | Novel 4-aminopyridine and 6-aminopyrimidine carboxylates as herbicides |
| TWI689252B (zh) | 2014-09-15 | 2020-04-01 | 美商陶氏農業科學公司 | 源自於施用吡啶羧酸除草劑與乙醯乳酸合成酶(als)抑制劑的協同性雜草控制 |
| TWI689251B (zh) | 2014-09-15 | 2020-04-01 | 美商陶氏農業科學公司 | 源自於施用吡啶羧酸除草劑與合成生長素除草劑及/或生長素轉運抑制劑的協同性雜草控制 |
| EP3193607A4 (en) | 2014-09-15 | 2018-05-02 | Dow AgroSciences LLC | Synergistic weed control from applications of pyridine carboxylic acid herbicides and photosystem ii inhibitors |
| US10087164B2 (en) * | 2016-05-19 | 2018-10-02 | Dow Agrosciences Llc | Synthesis of 6-aryl-4-aminopicolinates and 2-aryl-6-aminopyrimidine-4-carboxylates by direct Suzuki coupling |
| EP3479696B1 (en) | 2016-06-27 | 2021-06-09 | Moghu Research Center Ltd. | Pyridine-based compound including isoxazoline ring, and use thereof as herbicide |
| CN109400526B (zh) * | 2018-12-27 | 2020-10-16 | 青岛清原化合物有限公司 | 吡啶氧基硫酯衍生物及其制备方法、除草组合物和应用 |
| WO2020133090A1 (zh) | 2018-12-27 | 2020-07-02 | 青岛清原化合物有限公司 | 吡啶氧基硫酯衍生物及其制备方法、除草组合物和应用 |
| WO2020253696A1 (zh) * | 2019-06-20 | 2020-12-24 | 青岛清原化合物有限公司 | 取代的吡啶甲酸吡啶亚甲基酯衍生物及其制备方法、除草组合物和应用 |
| CN113603637B (zh) * | 2021-08-27 | 2023-05-30 | 浙江埃森化学有限公司 | 氟氯吡啶酯的制备方法 |
| CN113548982B (zh) * | 2021-09-03 | 2022-05-06 | 上海三牧化工技术有限公司 | 一种4-氰基-2-氟苄醇的制备方法 |
| CN115692672B (zh) * | 2022-11-23 | 2025-06-03 | 凯盛石墨碳材料有限公司 | 一种脲基嘧啶酮分子修饰纳米硅的制备方法 |
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| JP6000264B2 (ja) | 2010-10-22 | 2016-09-28 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングBayer Intellectual Property GmbH | 新規置換ピコリン酸、その塩及び酸誘導体、並びに、除草剤としてのその使用 |
| JP2014502600A (ja) | 2010-12-16 | 2014-02-03 | バイエル・インテレクチユアル・プロパテイー・ゲー・エム・ベー・ハー | 6−(2−アミノフェニル)ピコリン酸化合物およびそれらの除草剤としての使用 |
| TWI592401B (zh) | 2011-01-25 | 2017-07-21 | 陶氏農業科學公司 | 用於製備4-胺基-3-氯-5-氟-6-(經取代的)吡啶甲酸酯的方法(一) |
| US8835409B2 (en) | 2011-01-25 | 2014-09-16 | Dow Agrosciences, Llc. | 3-alkenyl-6-halo-4-aminopicolinates and their use as herbicides |
| CA2825392C (en) * | 2011-01-25 | 2016-10-25 | Dow Agrosciences Llc | 6-amino-2-substituted-5-vinylsilylpyrimidine-4-carboxylic acids and esters and 4-amino-6-substituted-3-vinylsilylpyridine-2-carboxylic acids and esters as herbicides |
| TWI596088B (zh) | 2011-01-25 | 2017-08-21 | 陶氏農業科學公司 | 4-胺基-6-(經取代的苯基)吡啶甲酸酯及6-胺基-2-(經取代的苯基)-4-嘧啶羧酸酯之芳烷酯以及其等作為除草劑之用途 |
| BR102012016297A8 (pt) * | 2011-06-30 | 2018-07-31 | Dow Agrosciences Llc | 3-alcóxi, tioalquila e amino-4-amino-6-(substituídos)picolinatos e sua aplicação como herbicidas |
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