AT73353B - Process for the production of gasoline by synthetic means. - Google Patents
Process for the production of gasoline by synthetic means.Info
- Publication number
- AT73353B AT73353B AT73353DA AT73353B AT 73353 B AT73353 B AT 73353B AT 73353D A AT73353D A AT 73353DA AT 73353 B AT73353 B AT 73353B
- Authority
- AT
- Austria
- Prior art keywords
- gasoline
- production
- synthetic means
- gases
- gas
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/68—Aromatisation of hydrocarbon oil fractions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
- C07C1/0495—Non-catalytic processes; Catalytic processes in which there is also another way of activation, e.g. radiation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/35—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of another activation, e.g. radiation, vibration, electrical or electromagnetic means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
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Die höchste Ausbeee-wird bei Benutzung von elektrischen Funkenentladungen, durch das zu behandelnde Gas erreicht, also bei einer Temperatur von 4000 bis 4600, OC ; ein solches Verfahren eignet sich aber weniger zur Ausübung in grossem Massstabe. Das wirtschaftliche Optimum wird bei einer Temperatur, die nur ein wenig über 20000 C, erreicht.
Die Strömungsgeschwindigkeit des Gases durch den elektrischen Ofen hängt von der im Lichtbogen zum Ausgleich gebrachten Energiemenge ab und wird derart geregelt, dass die Reaktionstemperatur von mindestens 20000 C erreicht wird.
In der Zeichnung ist ein zur Ausführung des Verfahrens geeigneter Apparat beispielsweise gezeigt.
1 ist ein aus geeignetem, feuerfestem Material hergestellter Ofen, der durch einen zwischen den Elektroden 3 und 4 erzeugten Lichtbogen 2 derart erhitzt wird, dass die Spannung und die Stromstärke vorzugsweise ungefähr unverändert beibehalten werden. Die zu behandelnden Gase (z. B. Leuchtgas) werden bei gewöhnlichem Atmosphärendruck in einem gleichförmigen Strom durch eine Düse 5 in den Ofen 1 eingeleitet.
Die durch den Lichtbogen, 2 bis auf wenigstens 20000 C erhitzten Gase werden hiedurch zur gegenseitigen Reaktion gebracht, wobei Kohle (graphitierter Koks) abgeschieden wird und dann durch ein Rohr 6 nach einer Kühlvorrichtung geleitet, in weicher eine Kühlflüssigkeit bei 8 ein- geleitet und bei 9 abgeleitet wird, wodurch die Gase in der Rohrschlange 10 zu einer flüchtigen Flüssigkeit verdichtet werden.
Diese Flüssigkeit wird in einem geeigneten Behälter 11 gesammelt. Die unverdichtet gebliebenen Gase können von dem Behälter ll durch ein Rohr 12 mittels eines Ventilators 13 und eines Rohres 14 in den Ofen 1 zurückgeführt werden oder auch werden sie abgeleitet und für andere Zwecke, z. B. als Kraftgas benutzt.
PATENT-ANSPRÜCHE : 1. Verfahren zur Herstellung von Benzin auf syntetischem Wege, dadurch gekenn- zeichnet, dass ein oder mehrere reine oder mit anderen Gasen gemischte, bei gewöhnlicher
Temperatur gasförmige Kohlenwasserstoffe der Methan-, Äthylen-oder Acetylenreihe, z. B. gasförmige Trockendestillationsprodukte von Steinkohle, Braunkohle, Torf usw., gegebenenfalls mit einem Zusatz von Wasserstoff, auf eine Temperatur von mindestens 20000 C erhitzt werden, wobei eine chemische Umsetzung unter Kohlenabscheidung statt- findet. so dass kondensierbare Kohlenwasserstoffe gebildet werden, die im wesentlichen
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The highest output is achieved when using electrical spark discharges through the gas to be treated, i.e. at a temperature of 4000 to 4600, OC; however, such a process is less suitable for practicing on a large scale. The economic optimum is achieved at a temperature just a little over 20,000 C.
The flow rate of the gas through the electric furnace depends on the amount of energy brought to balance in the arc and is regulated in such a way that the reaction temperature of at least 20,000 C is reached.
In the drawing, an apparatus suitable for carrying out the method is shown, for example.
1 is a furnace made of suitable refractory material, which is heated by an arc 2 generated between the electrodes 3 and 4 in such a way that the voltage and the current strength are preferably maintained approximately unchanged. The gases to be treated (for example luminous gas) are introduced into the furnace 1 through a nozzle 5 in a uniform flow at normal atmospheric pressure.
The gases heated by the arc, 2 up to at least 20,000 C are brought to mutual reaction, whereby carbon (graphitized coke) is deposited and then passed through a pipe 6 to a cooling device, into which a cooling liquid is introduced at 8 and at 9 is diverted, whereby the gases in the coil 10 are compressed into a volatile liquid.
This liquid is collected in a suitable container 11. The gases remaining uncompressed can be returned from the container 11 through a pipe 12 by means of a fan 13 and a pipe 14 to the furnace 1 or they are diverted and used for other purposes, e.g. B. used as a fuel gas.
PATENT CLAIMS: 1. Process for the production of gasoline by synthetic means, characterized in that one or more gases are pure or mixed with other gases, in the case of ordinary
Temperature gaseous hydrocarbons of the methane, ethylene or acetylene series, e.g. B. gaseous dry distillation products of hard coal, lignite, peat, etc., optionally with the addition of hydrogen, are heated to a temperature of at least 20,000 C, with a chemical reaction with coal deposition takes place. so that condensable hydrocarbons are formed, which are essentially
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Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE1260X | 1912-08-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AT73353B true AT73353B (en) | 1917-05-10 |
Family
ID=88792698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT73353D AT73353B (en) | 1912-08-07 | 1913-07-12 | Process for the production of gasoline by synthetic means. |
Country Status (5)
| Country | Link |
|---|---|
| AT (1) | AT73353B (en) |
| DE (1) | DE287992C (en) |
| FR (1) | FR457174A (en) |
| GB (1) | GB191317919A (en) |
| NL (1) | NL1260C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2941942B1 (en) * | 2009-02-12 | 2012-08-24 | Armines | PROCESS FOR THE MANUFACTURE OF SYNTHETIC FUELS BY ACTION OF HIGH PRESSURE ELECTRIC DISCHARGES ON GASEOUS MIXTURES |
-
1912
- 1912-12-25 DE DE1912287992 patent/DE287992C/de active Active
-
1913
- 1913-04-26 FR FR457174A patent/FR457174A/en not_active Expired
- 1913-07-12 AT AT73353D patent/AT73353B/en active
- 1913-07-19 NL NL2995A patent/NL1260C/en active
- 1913-08-06 GB GB191317919D patent/GB191317919A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL1260C (en) | 1916-05-01 |
| DE287992C (en) | 1915-10-13 |
| GB191317919A (en) | 1913-10-16 |
| FR457174A (en) | 1913-09-13 |
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