ATE133690T1 - Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke. - Google Patents
Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke.Info
- Publication number
- ATE133690T1 ATE133690T1 AT87870132T AT87870132T ATE133690T1 AT E133690 T1 ATE133690 T1 AT E133690T1 AT 87870132 T AT87870132 T AT 87870132T AT 87870132 T AT87870132 T AT 87870132T AT E133690 T1 ATE133690 T1 AT E133690T1
- Authority
- AT
- Austria
- Prior art keywords
- melting points
- molecular weights
- present
- catalysts
- varying
- Prior art date
Links
- 239000012968 metallocene catalyst Substances 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000002844 melting Methods 0.000 abstract 5
- 230000008018 melting Effects 0.000 abstract 5
- 239000003054 catalyst Substances 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 4
- 229920000642 polymer Polymers 0.000 abstract 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3447287A | 1987-04-03 | 1987-04-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE133690T1 true ATE133690T1 (de) | 1996-02-15 |
Family
ID=21876646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT87870132T ATE133690T1 (de) | 1987-04-03 | 1987-09-21 | Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke. |
Country Status (9)
| Country | Link |
|---|---|
| US (5) | US5846896A (de) |
| EP (1) | EP0284708B1 (de) |
| JP (2) | JP2669832B2 (de) |
| KR (1) | KR950008155B1 (de) |
| CN (2) | CN87107013A (de) |
| AT (1) | ATE133690T1 (de) |
| CA (1) | CA1341344C (de) |
| DE (1) | DE3751694T2 (de) |
| ES (1) | ES2082745T3 (de) |
Families Citing this family (113)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0284708B1 (de) * | 1987-04-03 | 1996-01-31 | Fina Technology, Inc. | Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke. |
| GB8716950D0 (en) * | 1987-07-17 | 1987-08-26 | Ici Plc | Polymers & catalyst components |
| DE3726067A1 (de) * | 1987-08-06 | 1989-02-16 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
| US4931417A (en) * | 1987-11-09 | 1990-06-05 | Chisso Corporation | Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure |
| DE3808267A1 (de) * | 1988-03-12 | 1989-09-21 | Hoechst Ag | Verfahren zur herstellung von 1-olefinpolymeren |
| DE3808268A1 (de) * | 1988-03-12 | 1989-09-21 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
| US5155080A (en) * | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| DE3836059A1 (de) * | 1988-10-22 | 1990-05-03 | Hoechst Ag | Verfahren zur herstellung eines ethylen-propylen-copolymers |
| WO1990007526A1 (fr) * | 1988-12-26 | 1990-07-12 | Mitsui Petrochemical Industries, Ltd. | Copolymeres olefines et leur production |
| DE3844282A1 (de) * | 1988-12-30 | 1990-07-05 | Hoechst Ag | Bisindenyl-derivat und verfahren zu seiner herstellung |
| US5004820A (en) * | 1989-08-07 | 1991-04-02 | Massachusetts Institute Of Technology | Preparation of chiral metallocene dihalides |
| JP2768521B2 (ja) * | 1989-09-08 | 1998-06-25 | フイナ・リサーチ・ソシエテ・アノニム | オレフイン用重合触媒および方法 |
| DE4005947A1 (de) * | 1990-02-26 | 1991-08-29 | Basf Ag | Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| DE4030399A1 (de) * | 1990-09-26 | 1992-04-02 | Basf Ag | Makromolekuele des propylens mit einem funktionellen kettenende |
| DE4120009A1 (de) * | 1991-06-18 | 1992-12-24 | Basf Ag | Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen |
| US5359015A (en) * | 1991-11-07 | 1994-10-25 | Exxon Chemical Patents Inc. | Metallocene catalysts and their production and use |
| EP0544308B1 (de) * | 1991-11-28 | 1998-02-18 | Showa Denko Kabushikikaisha | Neues Metallocen und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben |
| US5932669A (en) * | 1991-11-30 | 1999-08-03 | Targor Gmbh | Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts |
| TW309523B (de) * | 1991-11-30 | 1997-07-01 | Hoechst Ag | |
| DE4436113A1 (de) | 1994-10-10 | 1996-04-11 | Hoechst Ag | Metallocenverbindung |
| KR0151873B1 (ko) * | 1994-10-13 | 1998-10-15 | 김영욱 | 메탈로센 화합물, 이의 제조방법 및 이를 촉매로 이용한 고분자의 제조방법 |
| IT1272923B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
| DE59601827D1 (de) * | 1995-02-24 | 1999-06-10 | Basf Ag | Verfahren zur herstellung von polymerisaten von vinylaromatischen verbindungen unter verwendung von polymere enthaltenden katalysatorsystemen |
| DE59606391D1 (de) | 1995-08-22 | 2001-03-01 | Basf Ag | Polymerisate des ethylens mit hoher spannungsrissbeständigkeit und katalysatorsystem für deren herstellung |
| DE19542356A1 (de) | 1995-11-14 | 1997-05-15 | Basf Ag | Verfahren zur Herstellung von Copolymerisaten aus vinylaromatischen und olefinischen Verbindungen durch Dispersionspolymerisation in Gegenwart von Metallocenkatalysatorsystemen |
| DE19546095A1 (de) * | 1995-12-11 | 1997-06-12 | Basf Ag | Verfahren zur Herstellung von Copolymerisaten von vinylaromatischen Verbindungen in einer Stufe unter Verwendung von Doppelschneckenextrudern |
| US5908903A (en) | 1995-12-27 | 1999-06-01 | Basf Aktiengesellschaft | Metallocene catalyst systems containing lewis bases |
| DE19602543A1 (de) | 1996-01-25 | 1997-07-31 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alkenen in Gegenwart von Metallocenkomplexen mit kationisch funktionalisierten Cyclopentadienylliganden |
| DE69710838T2 (de) * | 1996-04-22 | 2002-10-31 | Japan Polyolefins Co. Ltd., Tokio/Tokyo | Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren |
| DE19615953A1 (de) * | 1996-04-22 | 1997-10-23 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums |
| DE19616523A1 (de) * | 1996-04-25 | 1997-11-06 | Basf Ag | Polymerisationskatalysatoren mit beta-Diketiminat-Liganden |
| DE19617230A1 (de) | 1996-04-30 | 1997-11-06 | Basf Ag | Oxidierte Metallocen-Polyolefin-Wachse |
| DE19618007A1 (de) * | 1996-05-04 | 1997-11-06 | Basf Ag | Verfahren zur Wiedergewinnung von Metallocenkomplexen |
| DE19621969A1 (de) * | 1996-05-31 | 1997-12-04 | Basf Ag | Verfahren zur Herstellung von kristallinen Polymerisaten durch Dispersionspolymerisation in Gegenwart von Metallocenkatalysatorsystemen |
| DE19621838A1 (de) * | 1996-05-31 | 1997-12-04 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶2¶-Alkenen unter Zusatz eines Reaktionsverzögerers |
| DE19622272A1 (de) * | 1996-06-03 | 1997-12-04 | Basf Ag | Copolymere von Alk-1-enen und a,beta-Dienen mit erhöhtem Viskositätsindex |
| US6265339B1 (en) | 1996-07-04 | 2001-07-24 | Basf Aktiengesellschaft | Process for preparing carrier-borne transition metal catalysts |
| TR199900388T2 (xx) | 1996-08-26 | 1999-04-21 | Basf Aktiengesellschaft | Yıldız polimerleri ve elde edilmelerine yönelik usul. |
| DE19635503A1 (de) | 1996-09-02 | 1998-03-05 | Basf Ag | Weißbrucharme, zähmodifizierte Propylenpolymerisate |
| DE19642353A1 (de) * | 1996-10-14 | 1998-04-16 | Basf Ag | Katalysatorsysteme, enthaltend Metallkomplexe mit adamantanähnlicher Struktur |
| DE19653079A1 (de) * | 1996-12-19 | 1998-06-25 | Basf Ag | Verfahren zur Gasphasenpolymerisation von C¶2¶-C¶8¶-Alk-1-enen mittels Ziegler -Natta- oder Metallocen-Katalysatorsystemen |
| DE19709866A1 (de) | 1997-03-11 | 1998-09-17 | Basf Ag | Geträgertes Katalysatorsystem zur Polymerisation von Alk-1-enen |
| DE19716239A1 (de) | 1997-04-18 | 1998-10-22 | Basf Ag | Verfahren zur Polymerisation von alpha-Olefinen in der Gasphase |
| DE19723003A1 (de) | 1997-06-02 | 1998-12-03 | Basf Ag | Polymermischung |
| DE19741497A1 (de) * | 1997-09-19 | 1999-03-25 | Basf Ag | Pfropfcopolymere |
| DE19745047A1 (de) | 1997-10-11 | 1999-04-15 | Basf Ag | Polymermischung mit guter Verarbeitbarkeit |
| ATE293132T1 (de) | 1998-03-04 | 2005-04-15 | Exxonmobil Chem Patents Inc | Nicht koordinierende anionen für die polymerisation von olefinen |
| DE19826743A1 (de) | 1998-06-16 | 1999-12-23 | Bayer Ag | Verfahren zur Herstellung von geträgerten Polymerisationskatalysatorsystemen und Verwendung dieser zur Homo- und Copolymerisation ungesättigter Monomere |
| DE19927766A1 (de) | 1999-06-17 | 2000-12-21 | Basf Ag | Trägerkatalysator zur Olefinpolymerisation |
| DE19957384A1 (de) | 1999-11-29 | 2001-05-31 | Targor Gmbh | Hochmolekulares Polypropylen mit breiter Molekulargewichtsverteilung und geringer isotaktischer Sequenzlänge |
| PL355712A1 (en) | 1999-12-21 | 2004-05-17 | Basell Polyolefine Gmbh | Partly crystalline propylene polymerisate composition for production of biaxial-stretched polypropylene films |
| DE19962129A1 (de) | 1999-12-21 | 2001-06-28 | Targor Gmbh | Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation |
| CA2398529A1 (en) | 2000-02-08 | 2001-08-16 | Exxonmobil Chemical Patents Inc. | Method of preparing group 14 bridged biscyclopentadienyl ligands |
| JP4031656B2 (ja) | 2002-03-14 | 2008-01-09 | バセル ポリオレフィン イタリア エス．アール．エル． | ポリプロピレン系樹脂組成物およびそのフィルム |
| AU2003255279A1 (en) | 2002-08-16 | 2004-03-03 | Johnson & Johnson Vision Care, Inc. | Molds for producing contact lenses |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| ES2394304T3 (es) | 2002-10-15 | 2013-01-30 | Exxonmobil Chemical Patents, Inc. | Sistema de múltiples catalizadores para la polimerización de olefinas y polímeros producidos a partir de éstos |
| US7195806B2 (en) * | 2003-01-17 | 2007-03-27 | Fina Technology, Inc. | High gloss polyethylene articles |
| JP3949064B2 (ja) * | 2003-02-06 | 2007-07-25 | ヒロセ電機株式会社 | 電気コネクタ |
| EP1615961A1 (de) | 2003-04-15 | 2006-01-18 | ExxonMobil Chemical Patents Inc. | Katalysatoren für propylencopolymere, polymerisationsverfahren und propylencopolymer |
| US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| US7285608B2 (en) * | 2004-04-21 | 2007-10-23 | Novolen Technology Holdings C.V. | Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| US7169864B2 (en) | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
| US7413812B2 (en) | 2005-04-26 | 2008-08-19 | Fina Technology, Inc. | Polypropylene article and method of preparing polypropylene article |
| US20060247394A1 (en) * | 2005-04-29 | 2006-11-02 | Fina Technology, Inc. | Process for increasing ethylene incorporation into random copolymers |
| US7232869B2 (en) | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
| WO2007011459A1 (en) | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Polyalpha-olefin compositions and processes to produce the same |
| US7989670B2 (en) | 2005-07-19 | 2011-08-02 | Exxonmobil Chemical Patents Inc. | Process to produce high viscosity fluids |
| WO2007011462A1 (en) | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Lubricants from mixed alpha-olefin feeds |
| US8921290B2 (en) | 2006-06-06 | 2014-12-30 | Exxonmobil Research And Engineering Company | Gear oil compositions |
| US8299007B2 (en) | 2006-06-06 | 2012-10-30 | Exxonmobil Research And Engineering Company | Base stock lubricant blends |
| US8834705B2 (en) | 2006-06-06 | 2014-09-16 | Exxonmobil Research And Engineering Company | Gear oil compositions |
| US8501675B2 (en) | 2006-06-06 | 2013-08-06 | Exxonmobil Research And Engineering Company | High viscosity novel base stock lubricant viscosity blends |
| US8535514B2 (en) | 2006-06-06 | 2013-09-17 | Exxonmobil Research And Engineering Company | High viscosity metallocene catalyst PAO novel base stock lubricant blends |
| CN101490105B (zh) | 2006-07-19 | 2013-10-02 | 埃克森美孚化学专利公司 | 采用茂金属催化剂制备聚烯烃的方法 |
| JP5863157B2 (ja) | 2006-12-18 | 2016-02-16 | 日東電工株式会社 | 粘着シート |
| US8513478B2 (en) | 2007-08-01 | 2013-08-20 | Exxonmobil Chemical Patents Inc. | Process to produce polyalphaolefins |
| JP5266335B2 (ja) | 2008-01-31 | 2013-08-21 | エクソンモービル・ケミカル・パテンツ・インク | メタロセン触媒によるポリ−アルファオレフィン類の生産におけるリニアアルファオレフィン類の改良された利用 |
| US8865959B2 (en) | 2008-03-18 | 2014-10-21 | Exxonmobil Chemical Patents Inc. | Process for synthetic lubricant production |
| CA2718894C (en) | 2008-03-31 | 2013-01-15 | Exxonmobil Chemical Patents Inc. | Production of shear-stable high viscosity pao |
| US8394746B2 (en) | 2008-08-22 | 2013-03-12 | Exxonmobil Research And Engineering Company | Low sulfur and low metal additive formulations for high performance industrial oils |
| US8247358B2 (en) | 2008-10-03 | 2012-08-21 | Exxonmobil Research And Engineering Company | HVI-PAO bi-modal lubricant compositions |
| EP2373701B1 (de) | 2008-12-31 | 2016-03-09 | W.R. Grace & Co.-Conn. | Verbesserte prokatalysatorzusammensetzung und verfahren |
| WO2010078494A2 (en) | 2008-12-31 | 2010-07-08 | Dow Global Technologies Inc. | Procatalyst composition with substituted 1,2-phenylene aromatic diester internal donor and method |
| JP5525847B2 (ja) | 2009-03-17 | 2014-06-18 | 日本ポリプロ株式会社 | プロピレン系多層シートおよびそれを用いた加圧処理用包装袋 |
| US9017593B2 (en) | 2009-06-16 | 2015-04-28 | Exxonmobil Chemical Patents Inc. | Composite materials comprising propylene-based polymer blend coatings |
| US9005739B2 (en) | 2009-07-23 | 2015-04-14 | Exxonmobil Chemical Patents Inc. | Laminated articles and their production |
| WO2011011124A1 (en) | 2009-07-23 | 2011-01-27 | Exxonmobil Chemical Patents Inc. | Polypropylene-based elastomer coating compositions |
| US8716201B2 (en) | 2009-10-02 | 2014-05-06 | Exxonmobil Research And Engineering Company | Alkylated naphtylene base stock lubricant formulations |
| WO2011053406A1 (en) | 2009-10-29 | 2011-05-05 | Exxonmobil Chemical Patents Inc. | Pressure-sensitive hot melt adhesive compositions |
| US8263520B2 (en) * | 2009-12-02 | 2012-09-11 | Dow Global Technologies Llc | Two atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture |
| JP5575267B2 (ja) | 2009-12-24 | 2014-08-20 | エクソンモービル・ケミカル・パテンツ・インク | 新規合成ベースストックの製造方法 |
| US8759267B2 (en) | 2010-02-01 | 2014-06-24 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
| US8642523B2 (en) | 2010-02-01 | 2014-02-04 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
| US8728999B2 (en) | 2010-02-01 | 2014-05-20 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient |
| US8598103B2 (en) | 2010-02-01 | 2013-12-03 | Exxonmobil Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low, medium and high speed engines by reducing the traction coefficient |
| US8748362B2 (en) | 2010-02-01 | 2014-06-10 | Exxonmobile Research And Engineering Company | Method for improving the fuel efficiency of engine oil compositions for large low and medium speed gas engines by reducing the traction coefficient |
| US9815915B2 (en) | 2010-09-03 | 2017-11-14 | Exxonmobil Chemical Patents Inc. | Production of liquid polyolefins |
| US8609793B2 (en) | 2010-10-07 | 2013-12-17 | Chevron Phillips Chemical Company Lp | Catalyst systems containing a bridged metallocene |
| US8637616B2 (en) | 2010-10-07 | 2014-01-28 | Chevron Philips Chemical Company Lp | Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects |
| US8629292B2 (en) | 2010-10-07 | 2014-01-14 | Chevron Phillips Chemical Company Lp | Stereoselective synthesis of bridged metallocene complexes |
| CN103154123B (zh) | 2010-10-15 | 2016-01-27 | 埃克森美孚化学专利公司 | 聚丙烯-基粘合剂组合物 |
| EP2573091A1 (de) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen |
| CN103890151B (zh) | 2011-10-10 | 2016-01-20 | 埃克森美孚化学专利公司 | 聚α-烯烃组合物和制备聚α-烯烃组合物的方法 |
| JP6201853B2 (ja) * | 2014-03-25 | 2017-09-27 | 日本ポリプロ株式会社 | メタロセン錯体及びオレフィン重合体の製造方法 |
| CN104017117B (zh) * | 2014-06-19 | 2017-01-25 | 中国科学院长春应用化学研究所 | 茂金属催化剂及其制备方法、聚乙烯纳米纤维的制备方法 |
| JP6613987B2 (ja) * | 2016-03-28 | 2019-12-04 | 日本ポリプロ株式会社 | メタロセン錯体、オレフィン重合用触媒、およびオレフィン重合体の製造方法 |
| CN113574105B (zh) * | 2019-03-19 | 2023-04-25 | 三井化学株式会社 | 丙烯系树脂组合物、成型体和丙烯聚合物 |
| EP4159439A4 (de) | 2020-06-02 | 2023-12-06 | Japan Polypropylene Corporation | Harzzusammensetzung auf polypropylenbasis, laminat und verfahren zur herstellung davon |
| US11827734B1 (en) | 2022-09-09 | 2023-11-28 | King Fahd University Of Petroleum And Minerals | Method of making a polyolefin |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3135809A (en) * | 1960-07-21 | 1964-06-02 | Southern Res Inst | Isomerization process |
| DE2608863A1 (de) | 1976-03-04 | 1977-09-08 | Basf Ag | Verfahren zum herstellen von polyaethylen |
| DE2608933A1 (de) | 1976-03-04 | 1977-09-08 | Basf Ag | Verfahren zum herstellen von polyaethylen |
| DE3007725A1 (de) | 1980-02-29 | 1981-09-17 | Hansjörg Prof. Dr. 2000 Hamburg Sinn | Verfahren zur herstellung von polyethylen, polypropylen und copolymeren |
| DE3127133A1 (de) | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
| US5324800A (en) * | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4937299A (en) * | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| US4522982A (en) | 1983-06-06 | 1985-06-11 | Exxon Research & Engineering Co. | Isotactic-stereoblock polymers of alpha-olefins and process for producing the same |
| US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| ES8604994A1 (es) * | 1983-06-06 | 1986-02-16 | Exxon Research Engineering Co | Un procedimiento para preparar una mezcla de reactor de un polimero de etileno y al menos una alfa-olefina. |
| ZA844157B (en) * | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| DE3443087A1 (de) | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
| DE3508887A1 (de) * | 1985-03-13 | 1986-09-25 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von optisch aktiven polyolefinen |
| US4808561A (en) * | 1985-06-21 | 1989-02-28 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4752597A (en) * | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| US5077255A (en) * | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| US4767735A (en) * | 1987-02-02 | 1988-08-30 | Cosden Technology, Inc. | Catalyst pretreatment process |
| EP0284708B1 (de) * | 1987-04-03 | 1996-01-31 | Fina Technology, Inc. | Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke. |
| US4794096A (en) * | 1987-04-03 | 1988-12-27 | Fina Technology, Inc. | Hafnium metallocene catalyst for the polymerization of olefins |
| US4892851A (en) * | 1988-07-15 | 1990-01-09 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| JP3402473B2 (ja) | 1991-08-20 | 2003-05-06 | 日本ポリケム株式会社 | オレフィン重合用触媒 |
| EP0581754A1 (de) * | 1992-07-10 | 1994-02-02 | Fina Technology, Inc. | Verfahren und Katalysator für Herstellung isotaktischen Polyolefinen |
-
1987
- 1987-09-21 EP EP87870132A patent/EP0284708B1/de not_active Expired - Lifetime
- 1987-09-21 AT AT87870132T patent/ATE133690T1/de not_active IP Right Cessation
- 1987-09-21 DE DE3751694T patent/DE3751694T2/de not_active Expired - Lifetime
- 1987-09-21 ES ES87870132T patent/ES2082745T3/es not_active Expired - Lifetime
- 1987-09-25 CA CA000547879A patent/CA1341344C/en not_active Expired - Fee Related
- 1987-10-12 KR KR1019870011263A patent/KR950008155B1/ko not_active Expired - Lifetime
- 1987-10-13 CN CN87107013A patent/CN87107013A/zh active Pending
- 1987-10-16 JP JP62259835A patent/JP2669832B2/ja not_active Expired - Lifetime
-
1991
- 1991-05-06 US US07/696,408 patent/US5846896A/en not_active Expired - Lifetime
-
1995
- 1995-06-26 CN CN95106885A patent/CN1077897C/zh not_active Expired - Lifetime
-
1996
- 1996-07-23 JP JP8211975A patent/JPH09157322A/ja active Pending
-
1997
- 1997-03-05 US US08/812,364 patent/US6117957A/en not_active Expired - Fee Related
-
2000
- 2000-05-20 US US09/574,339 patent/US6344577B1/en not_active Expired - Fee Related
-
2001
- 2001-11-07 US US10/045,875 patent/US6649712B2/en not_active Expired - Fee Related
- 2001-11-07 US US10/045,462 patent/US6872790B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2082745T3 (es) | 1996-04-01 |
| US6649712B2 (en) | 2003-11-18 |
| EP0284708A1 (de) | 1988-10-05 |
| DE3751694T2 (de) | 1996-08-01 |
| US20020111444A1 (en) | 2002-08-15 |
| DE3751694D1 (de) | 1996-03-14 |
| CA1341344C (en) | 2002-03-05 |
| JPS63295607A (ja) | 1988-12-02 |
| CN1118353A (zh) | 1996-03-13 |
| JPH09157322A (ja) | 1997-06-17 |
| US6117957A (en) | 2000-09-12 |
| US20020193537A1 (en) | 2002-12-19 |
| KR950008155B1 (ko) | 1995-07-25 |
| EP0284708B1 (de) | 1996-01-31 |
| CN1077897C (zh) | 2002-01-16 |
| KR880012653A (ko) | 1988-11-28 |
| US6344577B1 (en) | 2002-02-05 |
| JP2669832B2 (ja) | 1997-10-29 |
| US6872790B2 (en) | 2005-03-29 |
| CN87107013A (zh) | 1988-10-19 |
| US5846896A (en) | 1998-12-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3751694D1 (de) | Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke. | |
| ATE199018T1 (de) | Verfahren zur herstellung von äthylenpolymeren | |
| ATE11295T1 (de) | Verfahren zur polymerisation von olefinen. | |
| ES2076934T3 (es) | Catalizador metaloceno de hafnio para la polimerizacion de olefinas. | |
| DE59409990D1 (de) | Verfahren zur Herstellung von Polyolefinen | |
| DE69414667D1 (de) | Verfahren zur herstellung von olefinpolymeren und mittels dieses verfahrens gefertigte produkte | |
| DE69501971D1 (de) | Ternäres Katalysatorsystem und Verfahren zur Herstellung von Polymeren von Diolefinen | |
| ATE58383T1 (de) | Einsatz von antistatika zur vermeidung von belagbildung bei der herstellung von ethylenpolymerisaten in gasphasenreakatoren. | |
| ATE81518T1 (de) | Herstellung von polyarylenetherketonen. | |
| DE3671749D1 (de) | Verfahren zur polymerisierung von olefinen mit einem ziegler-natta-katalysator und zwei organometallverbindungen. | |
| DE68911812D1 (de) | Katalysatorbestandteil für Olefinpolymerisation, Verfahren zur Herstellung davon, Olefinpolymerisationskatalysator und Verfahren zur Polymerisation von Olefinen. | |
| DE59204800D1 (de) | Verfahren zur Herstellung von syndiotaktischen Polyolefinen mit breiter Molmassenverteilung | |
| DE69033719D1 (de) | Verfahren zur Herstellung von syndiotaktischen Polymeren | |
| DE3674227D1 (de) | Verfahren zur herstellung von oligomeren und polymeren von alpha-olefinen. | |
| EP0355446A3 (de) | 1-Olefin Isoblockpolymer und Verfahren zu seiner Herstellung | |
| DE69014625D1 (de) | Längliche objekte aus copolymeren von kohlenstoffmonoxid und einem olefinischen ungesättigten monomer und verfahren zu deren herstellung. | |
| DE3785721D1 (de) | Wasserloesliche quartaere polyammoniumsalze, verfahren zu ihrer herstellung und ihre verwendung. | |
| FI873649A7 (fi) | Etylenpolymerblandningar, foerfarande foer deras framstaellning och deras anvaendning foer framstaellning av industriella produkter. | |
| ATE166077T1 (de) | Metallocen(co)polymere, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren; metallocene hierfür. | |
| BR8800716A (pt) | Processo de preparacao de polimeros com grupamentos imidas e polimeros | |
| ATE168384T1 (de) | Katalysator und verfahren zur (co)polymerisation von alpha-olefinen | |
| DE59209759D1 (de) | Katalysator und Verfahren zur Herstellung von hochmolekularen Polyolefinen | |
| BR9005748A (pt) | Processo para preparacao de polimeros lineares de monoxido de carbono com um ou mais compostos olefinicamente insaturados | |
| ATE183754T1 (de) | Niedermolekulare funktionelle copolymerisate, verfahren zu ihrer herstellung und ihre verwendung | |
| ATE149537T1 (de) | Verfahren zur herstellung von polyketonpolymeren |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EELA | Cancelled due to lapse of time |