ATE199018T1 - Verfahren zur herstellung von äthylenpolymeren - Google Patents
Verfahren zur herstellung von äthylenpolymerenInfo
- Publication number
- ATE199018T1 ATE199018T1 AT97118519T AT97118519T ATE199018T1 AT E199018 T1 ATE199018 T1 AT E199018T1 AT 97118519 T AT97118519 T AT 97118519T AT 97118519 T AT97118519 T AT 97118519T AT E199018 T1 ATE199018 T1 AT E199018T1
- Authority
- AT
- Austria
- Prior art keywords
- ethylene
- metallocene compound
- ethylene polymers
- racemic
- meso
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI941279A IT1270253B (it) | 1994-06-20 | 1994-06-20 | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE199018T1 true ATE199018T1 (de) | 2001-02-15 |
Family
ID=11369136
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT97118519T ATE199018T1 (de) | 1994-06-20 | 1995-06-19 | Verfahren zur herstellung von äthylenpolymeren |
| AT95924286T ATE169939T1 (de) | 1994-06-20 | 1995-06-19 | Ethylen copolymere |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT95924286T ATE169939T1 (de) | 1994-06-20 | 1995-06-19 | Ethylen copolymere |
Country Status (25)
| Country | Link |
|---|---|
| US (2) | US6136936A (de) |
| EP (2) | EP0821011B1 (de) |
| JP (2) | JP3698437B2 (de) |
| KR (1) | KR100379138B1 (de) |
| CN (1) | CN1092672C (de) |
| AT (2) | ATE199018T1 (de) |
| AU (1) | AU689915B2 (de) |
| BG (1) | BG100411A (de) |
| BR (1) | BR9506041A (de) |
| CA (1) | CA2169841A1 (de) |
| CZ (1) | CZ290960B6 (de) |
| DE (2) | DE69504178T2 (de) |
| ES (2) | ES2154440T3 (de) |
| FI (1) | FI960741L (de) |
| IL (1) | IL114196A (de) |
| IT (1) | IT1270253B (de) |
| MX (1) | MX9600690A (de) |
| MY (1) | MY117891A (de) |
| NO (1) | NO960650L (de) |
| NZ (1) | NZ289111A (de) |
| PL (1) | PL182374B1 (de) |
| RU (1) | RU2155776C2 (de) |
| SK (1) | SK281515B6 (de) |
| WO (1) | WO1995035333A2 (de) |
| ZA (1) | ZA955102B (de) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1272922B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Procedimento per la preparazione di composti metallocenici |
| BR9602268A (pt) * | 1995-05-16 | 1998-04-07 | Union Carbide Chem Plastic | Processo para a produção de polietileno e polietileno |
| UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
| IT1283630B1 (it) * | 1996-05-09 | 1998-04-23 | Enichem Spa | Procedimento per la preparazione di copolimeri elastomerici ep(d)m |
| DE69720609T2 (de) * | 1996-07-16 | 2003-11-13 | Basell Polyolefine Gmbh | Verfahren zur Modifikation von die Rac/Meso-Verhältnis einer Metallocenverbindung |
| DE69813958T2 (de) * | 1997-07-18 | 2004-03-11 | Mitsui Chemicals, Inc. | Ungesättigte Copolymere, Verfahren zu deren Herstellung und Mischungen, die diese enthalten |
| ES2198098T3 (es) | 1998-03-09 | 2004-01-16 | Basell Poliolefine Italia S.P.A. | Procedimiento multietapas para la polimerizacion de olefinas. |
| US6177527B1 (en) | 1998-09-08 | 2001-01-23 | Union Carbide Chemical & Plastics Technology Corporation | Process for the preparation of polyethylene or polypropylene |
| CA2317485A1 (en) | 1998-11-20 | 2000-06-02 | Montell Technology Company B.V. | Bridged metallocenes, preparation, use in catalytic systems |
| CN1367801A (zh) * | 1999-05-14 | 2002-09-04 | 杜邦唐弹性体公司 | 高度结晶的无规乙烯/α-烯烃/多烯烃共聚体 |
| SG97919A1 (en) † | 1999-08-31 | 2003-08-20 | Sumitomo Chemical Co | Ethylene-alpha-olefin copolymer and polyethylene composition |
| SG96700A1 (en) * | 2001-09-27 | 2003-06-16 | Sumitomo Chemical Co | Catalyst component for addition polymerization, process for producing catalyst for addition polymerization and process for producing addition polymer |
| DE10244212A1 (de) * | 2002-09-23 | 2004-03-25 | Bayer Aktiengesellschaft | Zinkoxiddispersionen in halogen- und wasserfreien Dispersionsmedien |
| AU2003282957A1 (en) * | 2002-11-07 | 2004-06-03 | Dow Global Technologies, Inc. | Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby |
| US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| CN101472964B (zh) * | 2006-06-27 | 2012-09-05 | 尤尼威蒂恩技术有限责任公司 | 使用茂金属催化剂的改进聚合方法、其聚合产物及最终用途 |
| BRPI0713012B1 (pt) * | 2006-06-27 | 2018-05-08 | Univation Tech Llc | copolímero de etileno alfa-olefina, composição, artigo obtido através de moldagem rotativa e processo para a produção de um copolímero de etileno alfa-olefina |
| CN102190743B (zh) * | 2006-07-25 | 2013-03-13 | 三井化学株式会社 | 乙烯聚合物的制造方法 |
| EP2275201A1 (de) * | 2009-06-18 | 2011-01-19 | Total Petrochemicals Research Feluy | Polymerisierungsverfahren mit verbesserter Polymerhomogenität |
| US20110003940A1 (en) * | 2009-07-01 | 2011-01-06 | Dow Global Technologies Inc. | Ethylene-based polymer compositions for use as a blend component in shrinkage film applications |
| JP5767202B2 (ja) * | 2012-12-18 | 2015-08-19 | 旭化成ケミカルズ株式会社 | エチレン重合体並びに延伸成形体、微多孔膜、及び電池用セパレータ |
| JP5767203B2 (ja) * | 2012-12-19 | 2015-08-19 | 旭化成ケミカルズ株式会社 | エチレン重合体並びに延伸成形体、微多孔膜、及び電池用セパレーター |
| KR101689456B1 (ko) * | 2015-01-23 | 2016-12-23 | 한화토탈 주식회사 | 에틸렌계 공중합체 및 이의 제조 |
| FR3045612B1 (fr) * | 2015-12-17 | 2017-12-15 | Michelin & Cie | Copolymere d'ethylene et de butadiene de microstructure homogene |
| FR3045613B1 (fr) * | 2015-12-17 | 2017-12-15 | Michelin & Cie | Copolymere d'ethylene et de butadiene de microstructure homogene |
| US10889663B2 (en) | 2017-11-29 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Asymmetric ANSA-metallocene catalyst compounds for producing polyolefins having a broad molecular weight distribution |
| US10882925B2 (en) | 2017-11-29 | 2021-01-05 | Exxonmobil Chemical Patents Inc. | Catalysts that produce polyethylene with broad, bimodal molecular weight distribution |
| KR102258230B1 (ko) | 2018-10-19 | 2021-05-28 | 한화솔루션 주식회사 | 올레핀계 중합체 |
| US11014997B2 (en) | 2019-05-16 | 2021-05-25 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing high density polyethylenes with long chain branching |
| US11339279B2 (en) | 2020-04-01 | 2022-05-24 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing LLDPE and MDPE copolymers with long chain branching for film applications |
| US11267919B2 (en) | 2020-06-11 | 2022-03-08 | Chevron Phillips Chemical Company Lp | Dual catalyst system for producing polyethylene with long chain branching for blow molding applications |
| CN114591455B (zh) * | 2020-12-03 | 2023-10-31 | 中国石油天然气股份有限公司 | 催化剂及其制备方法、烯烃聚合催化剂体系 |
| US12122857B2 (en) | 2021-12-16 | 2024-10-22 | Chevron Phillips Chemical Company Lp | Controlling long-chain branch content with dual activator-supports |
| CN116789879A (zh) * | 2022-03-14 | 2023-09-22 | 中国石油化工股份有限公司 | 用于乙烯和降冰片烯共聚的体系及其应用、乙烯-降冰片烯共聚物及其制备方法 |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| US4701432A (en) * | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US5084534A (en) | 1987-06-04 | 1992-01-28 | Exxon Chemical Patents, Inc. | High pressure, high temperature polymerization of ethylene |
| US5039766A (en) * | 1988-06-28 | 1991-08-13 | Sumitomo Chemical Company, Limited | Liquid catalyst component, catalyst system containing said component and process for producing ethylene-alpha-olefin copolymer using said catalyst system |
| US5229022A (en) | 1988-08-01 | 1993-07-20 | Exxon Chemical Patents Inc. | Ethylene alpha-olefin polymer substituted mono- and dicarboxylic acid dispersant additives (PT-920) |
| DE3836059A1 (de) * | 1988-10-22 | 1990-05-03 | Hoechst Ag | Verfahren zur herstellung eines ethylen-propylen-copolymers |
| IT1227893B (it) * | 1988-12-14 | 1991-05-14 | Himont Inc Centerville Road Ne | Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto |
| US5218071A (en) * | 1988-12-26 | 1993-06-08 | Mitsui Petrochemical Industries, Ltd. | Ethylene random copolymers |
| DE3916555A1 (de) | 1989-05-20 | 1990-11-22 | Hoechst Ag | Verfahren zur herstellung von ethylenpolymeren |
| JP2769728B2 (ja) * | 1989-10-31 | 1998-06-25 | 日本石油化学株式会社 | ポリマーの分岐分布測定法 |
| US5145818A (en) * | 1989-12-29 | 1992-09-08 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst and process for the polymerization of olefins |
| TW198726B (de) * | 1989-12-29 | 1993-01-21 | Mitsui Petroleum Chemicals Ind | |
| TW206240B (de) * | 1990-02-13 | 1993-05-21 | Mitsui Petroleum Chemicals Ind | |
| CA2085581C (en) * | 1990-06-22 | 2002-07-30 | Joann Marie Canich | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
| ES2071888T3 (es) * | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
| US5631335A (en) | 1991-05-09 | 1997-05-20 | Phillips Petroleum Company | Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes |
| ES2155492T3 (es) * | 1991-05-27 | 2001-05-16 | Basell Polyolefine Gmbh | Procedimiento para la obtencion de poliolefinas con una amplia distribucion de pesos moleculares. |
| CA2069995C (en) * | 1991-05-31 | 1996-04-09 | Mitsui Chemicals, Incorporated | Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization |
| WO1993003093A1 (en) * | 1991-07-18 | 1993-02-18 | Exxon Chemical Patents Inc. | Heat sealed article |
| TW300901B (de) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| JP3394997B2 (ja) * | 1991-10-15 | 2003-04-07 | バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 特異的に置換されたインデニル配位子を持つメタロセンを用いてオレフィンポリマーを製造する方法 |
| WO1993009148A1 (en) * | 1991-11-07 | 1993-05-13 | Exxon Chemical Patents Inc. | Process for producing polyolefin |
| TW318184B (de) * | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
| JPH07501845A (ja) * | 1991-12-13 | 1995-02-23 | エクソン・ケミカル・パテンツ・インク | エチレンとより長いアルファーオレフィンのコポリマー |
| JPH05310847A (ja) * | 1992-05-08 | 1993-11-22 | Nippon Oil Co Ltd | エチレン・α−オレフィン共重合体 |
| US5240894A (en) | 1992-05-18 | 1993-08-31 | Exxon Chemical Patents Inc. | Method for making and using a supported metallocene catalyst system |
| DE4217171A1 (de) * | 1992-05-23 | 1993-11-25 | Basf Ag | Kontinuierliches Gasphasenwirbelschichtverfahren zur Herstellung von Ethylenhomopolymerisaten und -copolymerisaten |
| EP0572034A2 (de) * | 1992-05-29 | 1993-12-01 | Idemitsu Kosan Company Limited | Ethylencopolymere und Ethylencopolymerzusammensetzung |
| IT1255514B (it) * | 1992-09-24 | 1995-11-09 | Luigi Resconi | Copolimeri dell'etilene con monomeri olefinici, processo per la loro preparazione e catalizzatore |
| DE59309424D1 (de) * | 1992-08-15 | 1999-04-15 | Targor Gmbh | Verfahren zur Herstellung von Polyolefinen |
| JP3450855B2 (ja) * | 1992-11-02 | 2003-09-29 | エクソンモービル・ケミカル・パテンツ・インク | ホットメルト接着剤用エチレンコポリマーのブレンド |
| US5464905A (en) * | 1992-11-19 | 1995-11-07 | Mitsui Petrochemical Industries, Ltd. | Ethylene/α-olefin copolymer composition, graft modified ethylene/α-olefin copolymer composition, ethylene copolymer composition, and multi-stage olefin polymerization process |
| EP0601495B1 (de) * | 1992-12-07 | 2002-04-24 | Mitsubishi Chemical Corporation | Harzzusammensetzung für extrudierte Formen |
| IT1264680B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
| JPH09501707A (ja) * | 1993-08-06 | 1997-02-18 | エクソン・ケミカル・パテンツ・インク | 重合触媒、その製造及び使用 |
| IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
| UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
| BR9602268A (pt) * | 1995-05-16 | 1998-04-07 | Union Carbide Chem Plastic | Processo para a produção de polietileno e polietileno |
| FI104826B (fi) | 1996-01-30 | 2000-04-14 | Borealis As | Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi |
| FI971565A7 (fi) | 1997-04-14 | 1998-10-15 | Borealis As | Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä |
-
1994
- 1994-06-20 IT ITMI941279A patent/IT1270253B/it active IP Right Grant
-
1995
- 1995-06-07 US US08/486,602 patent/US6136936A/en not_active Expired - Fee Related
- 1995-06-16 IL IL11419695A patent/IL114196A/xx not_active IP Right Cessation
- 1995-06-19 CA CA002169841A patent/CA2169841A1/en not_active Abandoned
- 1995-06-19 DE DE69504178T patent/DE69504178T2/de not_active Revoked
- 1995-06-19 NZ NZ289111A patent/NZ289111A/en unknown
- 1995-06-19 PL PL95314425A patent/PL182374B1/pl not_active IP Right Cessation
- 1995-06-19 EP EP97118519A patent/EP0821011B1/de not_active Revoked
- 1995-06-19 AT AT97118519T patent/ATE199018T1/de not_active IP Right Cessation
- 1995-06-19 ES ES97118519T patent/ES2154440T3/es not_active Expired - Lifetime
- 1995-06-19 RU RU96105711/04A patent/RU2155776C2/ru not_active IP Right Cessation
- 1995-06-19 AU AU28856/95A patent/AU689915B2/en not_active Ceased
- 1995-06-19 CZ CZ1996767A patent/CZ290960B6/cs not_active IP Right Cessation
- 1995-06-19 MX MX9600690A patent/MX9600690A/es active IP Right Grant
- 1995-06-19 EP EP95924286A patent/EP0742799B1/de not_active Revoked
- 1995-06-19 MY MYPI95001651A patent/MY117891A/en unknown
- 1995-06-19 JP JP50166796A patent/JP3698437B2/ja not_active Expired - Fee Related
- 1995-06-19 SK SK348-96A patent/SK281515B6/sk unknown
- 1995-06-19 KR KR1019960700825A patent/KR100379138B1/ko not_active Expired - Fee Related
- 1995-06-19 BR BR9506041A patent/BR9506041A/pt not_active IP Right Cessation
- 1995-06-19 WO PCT/EP1995/002372 patent/WO1995035333A2/en not_active Ceased
- 1995-06-19 DE DE69520051T patent/DE69520051T2/de not_active Revoked
- 1995-06-19 ES ES95924286T patent/ES2121402T3/es not_active Expired - Lifetime
- 1995-06-19 CN CN95190756A patent/CN1092672C/zh not_active Expired - Fee Related
- 1995-06-19 AT AT95924286T patent/ATE169939T1/de not_active IP Right Cessation
- 1995-06-19 FI FI960741A patent/FI960741L/fi unknown
- 1995-06-20 ZA ZA955102A patent/ZA955102B/xx unknown
-
1996
- 1996-02-19 NO NO960650A patent/NO960650L/no not_active Application Discontinuation
- 1996-03-11 BG BG100411A patent/BG100411A/xx unknown
-
2000
- 2000-06-23 US US09/603,139 patent/US6664351B1/en not_active Expired - Fee Related
-
2004
- 2004-12-27 JP JP2004376687A patent/JP4299775B2/ja not_active Expired - Fee Related
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ATE199018T1 (de) | Verfahren zur herstellung von äthylenpolymeren | |
| DE69501971D1 (de) | Ternäres Katalysatorsystem und Verfahren zur Herstellung von Polymeren von Diolefinen | |
| RU94033101A (ru) | Способ получения полимеров этилена и продукты, полученные из них | |
| PT743324E (pt) | Producao de polietileno usando metalocenos estereoisomericos | |
| ATE229039T1 (de) | Polymerisation verfahren zur herstellung von polyolefin-elastomeren kationenerzeugender co- katalysator für die activierung von metallocen- katalysatorvorläufer, polyolefin-elastomeren mit einer einziger kombination von eigenschaften und daraus hergestellte produkten | |
| DE69033719D1 (de) | Verfahren zur Herstellung von syndiotaktischen Polymeren | |
| EP0818458A4 (de) | Übergangsmetallverbindung, polymerisationskatalysator für olefine und verfahren zur herstellung olefinischer polymere | |
| EP0372414A3 (de) | Verfahren zur Herstellung einer heterogenen Metallocenkatalysatorkomponente | |
| ATE133690T1 (de) | Metallocen-katalysatorsysteme für die polymersation von olefinen, mit einer silizium- hydrocarbyl-brücke. | |
| DE3671749D1 (de) | Verfahren zur polymerisierung von olefinen mit einem ziegler-natta-katalysator und zwei organometallverbindungen. | |
| DE69708683D1 (de) | Polymerisationsverfahren hoher aktivität unter verwendung eines metallocens | |
| ATE33497T1 (de) | Verfahren zur herstellung eines auf vanadiumverbindungen basierten katalysators auf traeger fuer (misch)polymerisierung von aethylen und so erhaltener katalysator. | |
| DE69516258D1 (de) | Verfahren zur Gewinnung von Polyolefinen mit breiter bimodularer oder multimodaler Molekulargewichtsverteilung | |
| ATE200496T1 (de) | Verfahren zur herstellung und anwendung eines geträgerten metallocen-alumoxan katalysators | |
| WO1996000246A1 (en) | Polymerization process and catalyst systems useful therein | |
| ATE528327T1 (de) | Verfahren zur polymerisierung von olefine. | |
| ATE466892T1 (de) | Fester katalysatorbestandteil zur polymerisation und copolymerisation von ethylen, verfahren zu dessen herstellung | |
| ATE299153T1 (de) | Verfahren zur polymerisierung von olefine | |
| ATE136042T1 (de) | Ethylenpolymere und verfahren zur herstellung derselben in der gasphase | |
| DE69024128D1 (de) | Verfahren zur Herstellung eines Katalysatorbestandtteils für Ethylenpolymerisation für die Produktion eines Polymers mit relativ enger Molekulargewichtsverteilung | |
| EP0926166A4 (de) | Katalysatorkomponente für die olefinpolymerisation, katalysator für die olefinpolymerisation und verfahren zur herstellung von polyolefinen | |
| EA199900267A2 (ru) | Способ получения катализатора циглера-натта для полимеризации в растворе смеси, катализатор и способ полимеризации в растворе смеси | |
| FR2596398B1 (fr) | Procede de polymerisation de l'ethylene permettant d'obtenir un polymere de distribution large de masses moleculaires |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification | ||
| REN | Ceased due to non-payment of the annual fee | ||
| RZN | Patent revoked |