ATE133963T1 - Katalysator und verfahren für die olefinpolymerisation - Google Patents

Katalysator und verfahren für die olefinpolymerisation

Info

Publication number: ATE133963T1
Authority: AT; Austria
Prior art keywords: compound; olefin polymerization; organoaluminum; catalyst component; titanium
Prior art date: 1989-12-29

Application number

AT90314420T

Other languages

English (en)

Inventor

Toshiyuki C O Mitsui P Tsutsui

Waki-Cho

Kenji C O Mitsui Petr Sugimura

Cho

Takashi C O Mitsui Petroc Ueda

Original Assignee

Mitsui Petrochemical Ind

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-12-29

Filing date

1990-12-28

Publication date

1996-02-15

1989-12-29 Priority claimed from JP34091289A external-priority patent/JP2953522B2/ja

1989-12-29 Priority claimed from JP34091889A external-priority patent/JP2837720B2/ja

1989-12-29 Priority claimed from JP34091589A external-priority patent/JP2953524B2/ja

1990-12-28 Application filed by Mitsui Petrochemical Ind filed Critical Mitsui Petrochemical Ind

1996-02-15 Application granted granted Critical

1996-02-15 Publication of ATE133963T1 publication Critical patent/ATE133963T1/de

Links

150000001336 alkenes Chemical class 0.000 title abstract 4
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 4
239000003054 catalyst Substances 0.000 title abstract 3
238000000034 method Methods 0.000 title 1
238000006116 polymerization reaction Methods 0.000 title 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 3
229910052719 titanium Inorganic materials 0.000 abstract 3
239000010936 titanium Substances 0.000 abstract 3
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 2
-1 anion compound Chemical class 0.000 abstract 2
229910052796 boron Inorganic materials 0.000 abstract 2
150000001875 compounds Chemical class 0.000 abstract 2
125000001485 cycloalkadienyl group Chemical group 0.000 abstract 2
239000003446 ligand Substances 0.000 abstract 2
239000002685 polymerization catalyst Substances 0.000 abstract 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
229910052736 halogen Inorganic materials 0.000 abstract 1
150000002367 halogens Chemical class 0.000 abstract 1
239000004615 ingredient Substances 0.000 abstract 1
229910052749 magnesium Inorganic materials 0.000 abstract 1
239000011777 magnesium Substances 0.000 abstract 1
230000000379 polymerizing effect Effects 0.000 abstract 1
239000011949 solid catalyst Substances 0.000 abstract 1
239000000725 suspension Substances 0.000 abstract 1
150000003623 transition metal compounds Chemical class 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

AT90314420T 1989-12-29 1990-12-28 Katalysator und verfahren für die olefinpolymerisation ATE133963T1 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
JP34091289A JP2953522B2 (ja)	1989-12-29	1989-12-29	オレフィン重合用固体触媒およびオレフィンの重合方法
JP34091889A JP2837720B2 (ja)	1989-12-29	1989-12-29	オレフィン重合用触媒およびオレフィンの重合方法
JP34091589A JP2953524B2 (ja)	1989-12-29	1989-12-29	オレフィン重合用触媒およびオレフィンの重合方法

Publications (1)

Publication Number	Publication Date
ATE133963T1 true ATE133963T1 (de)	1996-02-15

Family

ID=27340984

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AT90314420T ATE133963T1 (de)	1989-12-29	1990-12-28	Katalysator und verfahren für die olefinpolymerisation

Country Status (7)

Country	Link
US (1)	US5145818A (de)
EP (2)	EP0656373B1 (de)
KR (1)	KR940006217B1 (de)
AT (1)	ATE133963T1 (de)
CA (1)	CA2033364C (de)
DE (2)	DE69025306T2 (de)
ES (2)	ES2085900T3 (de)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP3049569B2 (ja) *	1990-03-23	2000-06-05	東ソー株式会社	ポリオレフィンの製造方法
JP3463811B2 (ja) *	1991-04-24	2003-11-05	Ｊｓｒ株式会社	ブタジエン系重合体の製造方法
CA2077744C (en) *	1991-09-30	2003-04-15	Edwar Shoukri Shamshoum	Homogeneous-heterogeneous catalyst system for polyolefins
ES2109473T3 (es) *	1991-12-13	1998-01-16	Exxon Chemical Patents Inc	Copolimeros de etileno/alfa-olefinas superiores.
EP0572034A2 (de) *	1992-05-29	1993-12-01	Idemitsu Kosan Company Limited	Ethylencopolymere und Ethylencopolymerzusammensetzung
JP3153000B2 (ja) *	1992-06-11	2001-04-03	三菱化学株式会社	α‐オレフィン重合体の製造法
BE1006438A3 (fr) *	1992-12-17	1994-08-30	Solvay	Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines.
BR9405715A (pt) *	1993-01-29	1995-11-28	Dow Chemical Co	Processo para preparar um composição de interpolímero de etileno/a-olefina e composição de interpolímero de etileno/a-olefina
DE69403928T2 (de) *	1993-04-09	1997-12-18	Tosoh Corp	Katalysator und Verfahren zur Olefin-Polymerisation
US5643846A (en) *	1993-04-28	1997-07-01	Fina Technology, Inc.	Process for a isotactic/syndiotactic polymer blend in a single reactor
US5804524A (en) *	1993-04-28	1998-09-08	Fina Technology, Inc.	Process for a isotactic/syndiotactic polymer blend in a single reactor
CA2129794A1 (en) *	1993-08-10	1995-02-11	Toshiyuki Tsutsui	Olefin polymerization catalysts and methods of olefin polymerization
DE4330667A1 (de) *	1993-09-10	1995-03-16	Basf Ag	Verfahren zur Herstellung von mehrphasigen Homo- oder Copolymerisaten von C¶2¶-C¶1¶¶0¶-Alk-1-enen in einer Reaktionszone
JP3390446B2 (ja) *	1993-10-21	2003-03-24	モービル・オイル・コーポレーション	高分子量成分及び低分子量成分を含む樹脂組成物
DE4344672C1 (de) *	1993-12-27	1995-06-14	Basf Ag	Verfahren zur Herstellung von Polymerisaten des Ethylens durch Suspensionspolymerisation
US6214949B1 (en) *	1993-12-29	2001-04-10	Fina Technology, Inc.	Polymerization of polyolefins having low melt flow and high molecular weight
RU2156253C2 (ru) *	1994-01-19	2000-09-20	Бп Кемикэлс Лимитед	Каталитическая композиция, металлоценовый комплекс и способ полимеризации олефинов
ATE194993T1 (de) *	1994-04-07	2000-08-15	Bp Chem Int Ltd	Polymerisationsverfahren
IT1270253B (it)	1994-06-20	1997-04-29	Spherilene Srl	Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
IT1270070B (it)	1994-07-08	1997-04-28	Spherilene Srl	Componenti e catalizzatori per la polimerizzazione di olefine
CN1078596C (zh)	1994-09-08	2002-01-30	美孚石油公司	用于单反应器中控制宽/双态树脂的mwd的混合催化剂
US5622906A (en) *	1994-09-16	1997-04-22	Phillips Petroleum Company	Compositions useful for olefin polymerization and processes therefor and therewith
US5525678A (en) *	1994-09-22	1996-06-11	Mobil Oil Corporation	Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
US5792534A (en)	1994-10-21	1998-08-11	The Dow Chemical Company	Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus
US5529965A (en) *	1994-10-28	1996-06-25	Exxon Chemical Patents Inc.	Polymerization catalyst systems, their production and use
US5869575A (en) *	1995-08-02	1999-02-09	The Dow Chemical Company	Ethylene interpolymerizations
EP0768319A1 (de) *	1995-09-29	1997-04-16	Nippon Oil Co. Ltd.	Verfahren zur Herstellung von Polyolefinen
WO1997038024A1 (en) *	1996-04-09	1997-10-16	Mitsui Chemicals, Inc.	Olefin polymerization catalyst, olefin polymerization method, olefin polymer compositions, and thermoformed articles
US6660816B2 (en)	1996-12-20	2003-12-09	Sumitomo Chemical Company, Limited	Process for preparing olefin polymers
EP1090047B1 (de) *	1998-05-06	2004-08-04	Huntsman Polymers Corporation	Polymerisation unter verwendung mehrerer katalysatoren
US6136747A (en) *	1998-06-19	2000-10-24	Union Carbide Chemicals & Plastics Technology Corporation	Mixed catalyst composition for the production of olefin polymers
DE69911128T2 (de) *	1998-07-21	2004-07-08	Japan Polychem Corp.	Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren
CA2245375C (en)	1998-08-19	2006-08-15	Nova Chemicals Ltd.	Dual reactor polyethylene process using a phosphinimine catalyst
CN1091451C (zh) *	1998-10-06	2002-09-25	中国石油化工集团公司	合成宽或双峰分子量分布的聚烯烃的催化剂及制备方法
CN1107082C (zh) *	1998-12-25	2003-04-30	中国石油化工集团公司	一种合成宽或双分子量分布的聚烯烃的催化剂及制备方法
US6265037B1 (en)	1999-04-16	2001-07-24	Andersen Corporation	Polyolefin wood fiber composite
EP1209171A4 (de) *	1999-05-10	2004-04-21	Jp Agency Of Industrialscience	Verfahren zur herstellung lebender polyolefine
US6288182B1 (en) *	1999-10-12	2001-09-11	Saudi Basic Industries Corporation	Supported metallocene catalyst system for olefin polymerization
EP1101777A1 (de)	1999-11-22	2001-05-23	UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION (a Delaware corporation)	Metallmischkatalysatoren
US7476688B2 (en) *	2001-04-19	2009-01-13	Eisai R&D Management Co., Ltd.	Cyclic amidine derivatives
CA2347410C (en)	2001-05-11	2009-09-08	Nova Chemicals Corporation	Solution polymerization process catalyzed by a phosphinimine catalyst
US7172987B2 (en)	2002-12-31	2007-02-06	Univation Technologies, Llc	Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
DE102004008313B4 (de) *	2004-02-20	2014-01-16	Wankel Super Tec Gmbh	Kreiskolbenbrennkraftmaschine mit einer verbesserten Innendichtung
US20060205898A1 (en) *	2005-03-08	2006-09-14	Goyal Shivendra K	Dual reactor polyethylene resins with balanced physical properties
US20060235147A1 (en) *	2005-04-14	2006-10-19	Nova Chemicals (International) S.A.	Dual reactor polyethylene resins for food packaging - films, bags and pouches
JP6108894B2 (ja) *	2013-03-19	2017-04-05	三井化学株式会社	オレフィン重合用触媒、それを用いたオレフィン系重合体の製造方法
KR102449456B1 (ko)	2016-09-29	2022-10-11	다우 글로벌 테크놀로지스 엘엘씨	개질된 지글러-나타 (전)촉매 및 시스템
WO2019198694A1 (ja)	2018-04-11	2019-10-17	三井化学株式会社	４－メチル－１－ペンテン系重合体粒子および４－メチル－１－ペンテン系樹脂の製造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4295991A (en) *	1978-09-26	1981-10-20	Exxon Research & Engineering Co.	Titanium trichloride catalyst component and the process for the production thereof
US4701432A (en) *	1985-11-15	1987-10-20	Exxon Chemical Patents Inc.	Supported polymerization catalyst
US4659685A (en) *	1986-03-17	1987-04-21	The Dow Chemical Company	Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
IL85097A (en) *	1987-01-30	1992-02-16	Exxon Chemical Patents Inc	Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) *	1987-01-30	1989-07-24	Exxon Chemical Patents Inc	Method for polymerization of olefines,diolefins and acetylene unsaturated compounds

1990
- 1990-12-21 US US07/631,428 patent/US5145818A/en not_active Expired - Lifetime
- 1990-12-27 KR KR1019900021918A patent/KR940006217B1/ko not_active Expired - Lifetime
- 1990-12-28 ES ES90314420T patent/ES2085900T3/es not_active Expired - Lifetime
- 1990-12-28 ES ES95102497T patent/ES2120088T3/es not_active Expired - Lifetime
- 1990-12-28 EP EP95102497A patent/EP0656373B1/de not_active Expired - Lifetime
- 1990-12-28 DE DE69025306T patent/DE69025306T2/de not_active Expired - Lifetime
- 1990-12-28 AT AT90314420T patent/ATE133963T1/de not_active IP Right Cessation
- 1990-12-28 CA CA002033364A patent/CA2033364C/en not_active Expired - Fee Related
- 1990-12-28 DE DE69032530T patent/DE69032530T2/de not_active Expired - Lifetime
- 1990-12-28 EP EP90314420A patent/EP0436399B1/de not_active Expired - Lifetime

Also Published As

Publication number	Publication date
ES2120088T3 (es)	1998-10-16
EP0436399A3 (en)	1992-11-25
DE69025306D1 (de)	1996-03-21
CA2033364A1 (en)	1991-06-30
CA2033364C (en)	1998-04-07
EP0656373A3 (de)	1995-07-05
ES2085900T3 (es)	1996-06-16
KR940006217B1 (ko)	1994-07-13
EP0436399B1 (de)	1996-02-07
DE69032530D1 (de)	1998-09-03
EP0436399A2 (de)	1991-07-10
EP0656373B1 (de)	1998-07-29
US5145818A (en)	1992-09-08
EP0656373A2 (de)	1995-06-07
KR910011915A (ko)	1991-08-07
DE69032530T2 (de)	1999-01-21
DE69025306T2 (de)	1996-08-29

Legal Events

Date	Code	Title	Description
1996-08-15	RER	Ceased as to paragraph 5 lit. 3 law introducing patent treaties

Publication	Publication Date	Title
DE69032530D1 (de)	1998-09-03	Katalysator und Verfahren für die Olefinpolymerisation
DE69028979D1 (de)	1996-11-28	Katalysator und Verfahren für die Olefinpolymerisation
DE69113489D1 (de)	1995-11-09	Feste Katalysatoren und Verfahren für die Olefinpolymerisation.
BR9714571A (pt)	2000-03-28	Complexos metálicos contendo indenila substituìdo com 3-arila, catalisador e processo de polimerização
ATE109487T1 (de)	1994-08-15	Bestandteil eines olefinpolymerisationskatalysators, katalysator und verfahren für die olefinpolymerisation.
CA2139356A1 (en)	1994-01-20	Transition Metal Olefin Polymerization Catalysts
ATE166891T1 (de)	1998-06-15	Komponente und katalysator für die olefinpolymerisation
DE69315471D1 (de)	1998-01-15	Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung
BR9509457A (pt)	1998-01-06	Composição catalítica e processo para a polimerização de uma olefina
NO165915C (no)	1991-05-02	Hydroformyleringsprosess, diorganofosfitt-ligand og rhodium-komplekskatalysator til bruk ved fremgangsmaaten samt etkatalysatorforloeperpreparat.
DE69127220D1 (de)	1997-09-18	Festes Titan enthaltendes Katalysatorbestandteil und Katalysator für Olefinpolymerisation, vorpolymerisierte Olefinpolymerisationskatalysator und Verfahren für Olefinpolymerisation
BR0208642A (pt)	2004-03-09	Processo de preparação de um componente catalisador e componente catalisador
BR0313087A (pt)	2005-06-28	Derivados de indenila tricìclico substituìdo com 4-arila contendo complexos de metais do grupo 4 e seu uso
CA2103301A1 (en)	1994-05-19	Catalyst for Olefin Polymerization and Process for Olefin Polymerization Using the Same
BR9203545A (pt)	1993-04-13	Catalisadores e processos para a preparacao de um polimero de olefina ou copolimero amorfo bem como polimero e copolimero
RO67844B (ro)	1983-07-30	Procedeu de obtinere a unui catalizator pentru polimerizarea olefinelor
MY103812A (en)	1993-09-30	Olefin polymerization catalyst and process for the polymerization of olefins.
WO2000058370A8 (de)	2002-05-30	Verfahren zur polymerisation von olefinen
EP0970963A3 (de)	2001-07-04	Übergangsmetallverbindung, Olefinpolymerisationskatalysatorkomponente, Olefinpolymerisationskatalysator, und Verfahren zur Polymerisierung von Olefinen
CA2101965A1 (en)	1994-02-07	Olefin Polymerization Catalyst and Method for the Polymerization of Olefin Using Said Olefin Polymerization Catalyst
ES458282A1 (es)	1978-02-16	Un procedimiento para la preparacion de un catalizador de polimerizacion de olefinas.