ES2085900T3 - Catalizador y procedimiento para la polimerizacion de olefinas. - Google Patents

Catalizador y procedimiento para la polimerizacion de olefinas.

Info

Publication number
ES2085900T3
ES2085900T3 ES90314420T ES90314420T ES2085900T3 ES 2085900 T3 ES2085900 T3 ES 2085900T3 ES 90314420 T ES90314420 T ES 90314420T ES 90314420 T ES90314420 T ES 90314420T ES 2085900 T3 ES2085900 T3 ES 2085900T3
Authority
ES
Spain
Prior art keywords
titanium
aluminum compound
oxi
organo
organ
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90314420T
Other languages
English (en)
Inventor
Toshiyuki Tsutsui
Kenji Sugimura
Takashi Ueda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP34091889A external-priority patent/JP2837720B2/ja
Priority claimed from JP34091289A external-priority patent/JP2953522B2/ja
Priority claimed from JP34091589A external-priority patent/JP2953524B2/ja
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Application granted granted Critical
Publication of ES2085900T3 publication Critical patent/ES2085900T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

DE ACUERDO CON LA PRESENTE INVENCION, SE PRESENTAN CATALIZADORES PARA LA POLIMERIZACION DE OLEFINAS COMPRENDIENDO: (A) UN COMPONENTE CATALIZADOR DE TITANIO CONTENIENDO TITANIO, MAGNESIO Y HALOGENO COMO INGREDIENTES PRINCIPALES. (B-1) UN COMPONENTE DE TRANSICION DE METAL CONTENIENDO UN ESQUELETO DE CICLOALCADIENIL, (C) UN OXI-COMPUESTO DE ORGANOALUMINIO Y SI ES NECESARIO (D) UN COMPUESTO DE ORGANOALUMINIO. ADEMAS Y DE ACUERDO CON LA INVENCION SE PROPORCIONAN CATALIZADORES DE POLIMERIZACION DE OLEFINAS CONTENIENDO (A) COMPONENTE CATALIZADOR DE TITANIO MAGNESIO Y HALOGENO COMO INGREDIENTES SUBSTANCIALES, (B-2) UN COMPONENTE DE TRANSICION DE METAL CONTENIENDO UN ESQUELETO DE CICLOALCADIENIL Y UN COMPUESTO DE ANION CONTENIENDO BORO. (C) UN OXI-COMPUESTO DE ORGANOALUMINIO Y/O (D) UN PREPARADO DE ORGANOALUMINIO.
ES90314420T 1989-12-29 1990-12-28 Catalizador y procedimiento para la polimerizacion de olefinas. Expired - Lifetime ES2085900T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP34091889A JP2837720B2 (ja) 1989-12-29 1989-12-29 オレフィン重合用触媒およびオレフィンの重合方法
JP34091289A JP2953522B2 (ja) 1989-12-29 1989-12-29 オレフィン重合用固体触媒およびオレフィンの重合方法
JP34091589A JP2953524B2 (ja) 1989-12-29 1989-12-29 オレフィン重合用触媒およびオレフィンの重合方法

Publications (1)

Publication Number Publication Date
ES2085900T3 true ES2085900T3 (es) 1996-06-16

Family

ID=27340984

Family Applications (2)

Application Number Title Priority Date Filing Date
ES90314420T Expired - Lifetime ES2085900T3 (es) 1989-12-29 1990-12-28 Catalizador y procedimiento para la polimerizacion de olefinas.
ES95102497T Expired - Lifetime ES2120088T3 (es) 1989-12-29 1990-12-28 Catalizador y procedimiento de polimerizacion de olefinas.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES95102497T Expired - Lifetime ES2120088T3 (es) 1989-12-29 1990-12-28 Catalizador y procedimiento de polimerizacion de olefinas.

Country Status (7)

Country Link
US (1) US5145818A (es)
EP (2) EP0656373B1 (es)
KR (1) KR940006217B1 (es)
AT (1) ATE133963T1 (es)
CA (1) CA2033364C (es)
DE (2) DE69025306T2 (es)
ES (2) ES2085900T3 (es)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3049569B2 (ja) * 1990-03-23 2000-06-05 東ソー株式会社 ポリオレフィンの製造方法
JP3463811B2 (ja) * 1991-04-24 2003-11-05 Ｊｓｒ株式会社 ブタジエン系重合体の製造方法
CA2077744C (en) * 1991-09-30 2003-04-15 Edwar Shoukri Shamshoum Homogeneous-heterogeneous catalyst system for polyolefins
DE69220675T2 (de) * 1991-12-13 1997-10-23 Exxon Chemical Patents, Inc., Baytown, Tex. ETHYLEN/HöHERE ALPHA-OLEFINCOPOLYMERE
EP0572034A2 (en) * 1992-05-29 1993-12-01 Idemitsu Kosan Company Limited Ethylenic copolymer and ethylenic copolymer composition
JP3153000B2 (ja) * 1992-06-11 2001-04-03 三菱化学株式会社 α‐オレフィン重合体の製造法
BE1006438A3 (fr) * 1992-12-17 1994-08-30 Solvay Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines.
RU2113443C1 (ru) * 1993-01-29 1998-06-20 Дзе Дау Кемикал Компани Способ получения композиции сополимеров этилена и альфа-олефинов, композиция сополимеров этилена и альфа-олефинов
DE69403928T2 (de) * 1993-04-09 1997-12-18 Tosoh Corp Katalysator und Verfahren zur Olefin-Polymerisation
US5643846A (en) * 1993-04-28 1997-07-01 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
US5804524A (en) * 1993-04-28 1998-09-08 Fina Technology, Inc. Process for a isotactic/syndiotactic polymer blend in a single reactor
CA2129794A1 (en) * 1993-08-10 1995-02-11 Toshiyuki Tsutsui Olefin polymerization catalysts and methods of olefin polymerization
DE4330667A1 (de) * 1993-09-10 1995-03-16 Basf Ag Verfahren zur Herstellung von mehrphasigen Homo- oder Copolymerisaten von C¶2¶-C¶1¶¶0¶-Alk-1-enen in einer Reaktionszone
WO1995011264A1 (en) * 1993-10-21 1995-04-27 Mobil Oil Corporation Polyolefin blends of bimodal molecular weight distribution
DE4344672C1 (de) * 1993-12-27 1995-06-14 Basf Ag Verfahren zur Herstellung von Polymerisaten des Ethylens durch Suspensionspolymerisation
US6214949B1 (en) * 1993-12-29 2001-04-10 Fina Technology, Inc. Polymerization of polyolefins having low melt flow and high molecular weight
RU2156253C2 (ru) * 1994-01-19 2000-09-20 Бп Кемикэлс Лимитед Каталитическая композиция, металлоценовый комплекс и способ полимеризации олефинов
ES2150529T3 (es) * 1994-04-07 2000-12-01 Bp Chem Int Ltd Procedimiento de polimerizacion.
IT1270253B (it) 1994-06-20 1997-04-29 Spherilene Srl Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene
IT1270070B (it) 1994-07-08 1997-04-28 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
KR100388716B1 (ko) 1994-09-08 2003-11-28 엑손모빌 오일 코포레이션 단일반응기내에서의분자량분포가넓거나또는이중모드인수지의촉매적조절방법
US5622906A (en) * 1994-09-16 1997-04-22 Phillips Petroleum Company Compositions useful for olefin polymerization and processes therefor and therewith
US5525678A (en) * 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
US5792534A (en) 1994-10-21 1998-08-11 The Dow Chemical Company Polyolefin film exhibiting heat resistivity, low hexane extractives and controlled modulus
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5869575A (en) * 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
US5916982A (en) * 1995-09-29 1999-06-29 Nippon Oil Co., Ltd. Process for the production of polyolefins
CN1105730C (zh) * 1996-04-09 2003-04-16 三井化学株式会社 烯烃聚合催化剂及烯烃聚合方法,以及烯烃聚合物组合物和热模塑产品
US6660816B2 (en) 1996-12-20 2003-12-09 Sumitomo Chemical Company, Limited Process for preparing olefin polymers
ES2226362T3 (es) * 1998-05-06 2005-03-16 Huntsman Polymers Corporation Polimerizaciones usando catalizador adyuvante.
US6136747A (en) * 1998-06-19 2000-10-24 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst composition for the production of olefin polymers
US6376416B1 (en) * 1998-07-21 2002-04-23 Japan Polychem Corporation Olefin polymerization catalyst and process for producing olefin polymer
CA2245375C (en) 1998-08-19 2006-08-15 Nova Chemicals Ltd. Dual reactor polyethylene process using a phosphinimine catalyst
CN1091451C (zh) * 1998-10-06 2002-09-25 中国石油化工集团公司 合成宽或双峰分子量分布的聚烯烃的催化剂及制备方法
CN1107082C (zh) * 1998-12-25 2003-04-30 中国石油化工集团公司 一种合成宽或双分子量分布的聚烯烃的催化剂及制备方法
US6265037B1 (en) 1999-04-16 2001-07-24 Andersen Corporation Polyolefin wood fiber composite
WO2000068276A1 (en) * 1999-05-10 2000-11-16 Japan As Represented By Director General Of The Agency Of Industrial Science And Technology Process for producing olefin living polymer
US6288182B1 (en) 1999-10-12 2001-09-11 Saudi Basic Industries Corporation Supported metallocene catalyst system for olefin polymerization
EP1101777A1 (en) 1999-11-22 2001-05-23 UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION (a Delaware corporation) Mixed metal catalysts
RU2270192C2 (ru) * 2001-04-19 2006-02-20 Эйсай Ко., Лтд. Производные 2-иминопирролидина
CA2347410C (en) 2001-05-11 2009-09-08 Nova Chemicals Corporation Solution polymerization process catalyzed by a phosphinimine catalyst
US7172987B2 (en) 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
DE102004008313B4 (de) * 2004-02-20 2014-01-16 Wankel Super Tec Gmbh Kreiskolbenbrennkraftmaschine mit einer verbesserten Innendichtung
US20060205898A1 (en) * 2005-03-08 2006-09-14 Goyal Shivendra K Dual reactor polyethylene resins with balanced physical properties
US20060235147A1 (en) * 2005-04-14 2006-10-19 Nova Chemicals (International) S.A. Dual reactor polyethylene resins for food packaging - films, bags and pouches
JP6108894B2 (ja) * 2013-03-19 2017-04-05 三井化学株式会社 オレフィン重合用触媒、それを用いたオレフィン系重合体の製造方法
BR112019005532B1 (pt) 2016-09-29 2023-04-11 Dow Global Technologies Llc Sistema e (pró)catalisador de ziegler-natta modificado
SG11202009998SA (en) 2018-04-11 2020-11-27 Mitsui Chemicals Inc 4-methyl-1-pentene polymer particle and method for producing 4-methyl-1-pentene resin

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4295991A (en) * 1978-09-26 1981-10-20 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds

Also Published As

Publication number Publication date
ES2120088T3 (es) 1998-10-16
DE69025306T2 (de) 1996-08-29
CA2033364C (en) 1998-04-07
KR940006217B1 (ko) 1994-07-13
EP0656373A2 (en) 1995-06-07
ATE133963T1 (de) 1996-02-15
CA2033364A1 (en) 1991-06-30
KR910011915A (ko) 1991-08-07
DE69032530T2 (de) 1999-01-21
EP0656373A3 (es) 1995-07-05
DE69032530D1 (de) 1998-09-03
EP0436399A3 (en) 1992-11-25
EP0436399B1 (en) 1996-02-07
US5145818A (en) 1992-09-08
EP0436399A2 (en) 1991-07-10
DE69025306D1 (de) 1996-03-21
EP0656373B1 (en) 1998-07-29

Similar Documents

Publication Publication Date Title
ES2120088T3 (es) Catalizador y procedimiento de polimerizacion de olefinas.
EP0439964A3 (en) Olefin polymerization catalyst and process for the polymerization of olefins
ES2052004T5 (es) Procedimiento de preparacion de poliolefinas y catalizador de polimerizacion.
AR013018A1 (es) Procedimiento para la preparacion de un componente de catalizador de polimerizacion de olefina que contiene magnesio, titanio, halogeno y un donante de electrones; componente de catalizador realizado mediante el mismo y uso del mismo.
ES2137266T3 (es) Catalizadores de polimerizacion de olefinas a base de metales de transicion.
ES2153136T3 (es) Composicion mejorada de catalizador de polimerizacion de adicion de olefinas.
BR9712535A (pt) Complexo metálico e catalisador e processo para a polimerização de olefinas
AU629434B2 (en) Components and catalysts for the polymerization of olefins
MY105224A (en) Catalysts for the polymerization of olefins.
ES2118551T3 (es) Catalizador de epoxidacion y su procedimiento de preparacion.
ES2152653T3 (es) Cocatalizador de metaloceno.
BR0015237B1 (pt) mÉtodos para a preparaÇço e para a fabricaÇço de um sistema de catalisador suportado, e processo para a polimerizaÇço de olefinas.
DE3764281D1 (de) Katalytische zusammensetzungen zur isomerisierung und disproportionierung von olefinen.
MX9100493A (es) Catalizadores de portadores y procedimiento para su preparacion
HU911057D0 (en) Olefin polymerization catalysts and components
IT8048894A0 (it) Perfezionamento nei catalizzatori abase di titanio per la polimerizza zione e copolimerizzazione di olefine e procedimento di preparazione
ES2040051T3 (es) Catalizador de niquel/silice y la preparacion y uso del mismo.
EA199600031A2 (ru) Мезопористый алюмогель и способ его получения
BR0012220A (pt) Complexos de alcóxidos de magnésio/titânio catalisadores de polimerização feitos destes, e seu uso
BR0115358A (pt) Sistema catalìtico e seu uso em polimerização de olefinas
NO971377L (no) Katalysatorbestanddel, samt anvendelse av denne ved olefinpolymerisering
ES8106915A1 (es) Procedimiento para la preparacion de un catalizador de poli-merizacion
GB1518034A (en) Hydrocarbon isomerization catalysts and procedures for the preparation and use thereof
EP0425702A4 (en) Catalyst component for olefin polymerization
GB1345363A (en) Process for the preparation of zeolites

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 436399

Country of ref document: ES