ATE146T1 - PROCESS FOR OBTAINING ANHYDROUS OR SUBSTANTIALLY ANHYDROUS FORMIC ACID. - Google Patents
PROCESS FOR OBTAINING ANHYDROUS OR SUBSTANTIALLY ANHYDROUS FORMIC ACID.Info
- Publication number
- ATE146T1 ATE146T1 AT79104857T AT79104857T ATE146T1 AT E146 T1 ATE146 T1 AT E146T1 AT 79104857 T AT79104857 T AT 79104857T AT 79104857 T AT79104857 T AT 79104857T AT E146 T1 ATE146 T1 AT E146T1
- Authority
- AT
- Austria
- Prior art keywords
- formic acid
- section
- column
- anhydrous
- hydrolysis
- Prior art date
Links
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title abstract 13
- 235000019253 formic acid Nutrition 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 abstract 6
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 3
- 230000007062 hydrolysis Effects 0.000 abstract 3
- 238000006460 hydrolysis reaction Methods 0.000 abstract 3
- 238000000605 extraction Methods 0.000 abstract 1
- 238000004508 fractional distillation Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
A process for the production of anhydrous or substantially anhydrous formic acid by hydrolysis of methyl formate which is carried out in a column having an upper fractionating section, a middle hydrolysis section and a lower extraction section and in which (a) the hydrolysis is carried out in the middle section of the columm, with water and methyl formate in countercurrent, (b) the resulting formic acid is extracted, in the lower section of the column, by means of a carboxylic acid amide which is fed into the lower end of the middle section of the column, (c) the extract phase, consisting in the main of formic acid and the carboxylic acid amide, is distillatively dehydrated, or substantially dehydrated, in the lower section of the column, (d) the methanol and uncovered methyl formate are removed by fractional distillation in the upper section of the column and (e) the pure formic acid or concentrated aqueous formic acid is distilled from the anhydrous or substantially anhydrous extract phase in a second column, leaving the carboxylic acid amide.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19782853991 DE2853991A1 (en) | 1978-12-14 | 1978-12-14 | METHOD FOR DETERMINING WATER-FREE OR MOSTLY WATER-FREE FORMIC ACID |
| EP79104857A EP0012321B1 (en) | 1978-12-14 | 1979-12-04 | Process for the obtention of water-free or substantially water-free formic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE146T1 true ATE146T1 (en) | 1981-09-15 |
Family
ID=6057174
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT79104857T ATE146T1 (en) | 1978-12-14 | 1979-12-04 | PROCESS FOR OBTAINING ANHYDROUS OR SUBSTANTIALLY ANHYDROUS FORMIC ACID. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4262140A (en) |
| EP (1) | EP0012321B1 (en) |
| JP (1) | JPS5583730A (en) |
| AT (1) | ATE146T1 (en) |
| CA (1) | CA1135281A (en) |
| DE (2) | DE2853991A1 (en) |
| NO (1) | NO149470C (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2914671A1 (en) * | 1979-04-11 | 1980-10-23 | Basf Ag | METHOD FOR DETERMINING WATER-FREE OR MOSTLY WATER-FREE FORMIC ACID |
| NL8103517A (en) * | 1981-07-24 | 1983-02-16 | Badger Bv | METHOD FOR SEPARATING CARBONIC ACIDS FROM MIXTURES WITH NON-ACIDS BY AN ABSORPTION STRIP TREATMENT. |
| DE3319651A1 (en) * | 1983-05-31 | 1984-12-06 | Basf Ag, 6700 Ludwigshafen | METHOD FOR THE DISTILLATIVE PRODUCTION OF FORMIC ACID |
| DE3411384A1 (en) * | 1984-03-28 | 1985-10-10 | Basf Ag, 6700 Ludwigshafen | METHOD FOR THE EXTRACTION OF WATER-FREE OR MOSTLY WATER-FREE FORMIC ACID BY HYDROLYSIS OF METHYLFORMIAT |
| DE3417790A1 (en) * | 1984-05-14 | 1985-11-14 | Basf Ag, 6700 Ludwigshafen | METHOD FOR PRODUCING FORMIC ACID |
| US4735690A (en) * | 1986-03-10 | 1988-04-05 | Lloyd Berg | Dehydration of impure formic acid by extractive distillation |
| US4670105A (en) * | 1986-04-07 | 1987-06-02 | Lloyd Berg | Dehydration of propanoic acid by extractive distillation |
| DE4211141A1 (en) * | 1992-04-03 | 1993-10-07 | Basf Ag | Process for the preparation of formic acid by thermal cleavage of quaternary ammonium formates |
| DE19934411C1 (en) | 1999-07-22 | 2001-03-22 | Consortium Elektrochem Ind | Process for the separation and purification of an aqueous mixture of the main components acetic acid and formic acid |
| DE19934410C1 (en) | 1999-07-22 | 2000-12-14 | Consortium Elektrochem Ind | Separation and purification of aqueous mixtures of acetic acid, formic acid and high boiling fractions uses apparatus with separation and distillation columns containing organic solvent |
| DE10002791A1 (en) * | 2000-01-24 | 2001-07-26 | Basf Ag | Production of anhydrous formic acid by hydrolyzing methyl formate comprises introducing methanol-containing methyl formate into distillation column used to distil hydrolysis mixture |
| DE10002794A1 (en) * | 2000-01-24 | 2001-07-26 | Basf Ag | Production of anhydrous formic acid involves hydrolysis of methyl formate, steam distillation, extraction with amide and further distillations, with prior use of steam for stripping aqueous extraction residue |
| US7618725B2 (en) * | 2004-09-21 | 2009-11-17 | The Board Of Trustees Of The University Of Illinois | Low contaminant formic acid fuel for direct liquid fuel cell |
| WO2010030617A1 (en) * | 2008-09-09 | 2010-03-18 | Meadwestvaco Corporation | A method of recovering levulinic acid |
| DE102009035387B4 (en) * | 2009-07-30 | 2012-08-09 | Siemens Aktiengesellschaft | A method and apparatus for converting carbon monoxide and water to carbon dioxide and hydrogen with the separation of at least one product gas |
| WO2013030162A1 (en) * | 2011-08-27 | 2013-03-07 | Taminco | Process of formic acid production by hydrolysis of methyl formate |
| CN108707062A (en) * | 2018-06-08 | 2018-10-26 | 聊城市鲁西化工工程设计有限责任公司 | A kind of technique for sylvite recovery processing |
| MY202430A (en) * | 2018-08-30 | 2024-04-29 | Nextchem Tech S P A | Method and apparatus to produce fatty acids from methyl esters throughout non-catalytic process |
| CN114644549A (en) * | 2022-04-24 | 2022-06-21 | 聊城市鲁西化工工程设计有限责任公司 | Production system and production process of formic acid |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2545730A1 (en) * | 1975-10-11 | 1977-04-21 | Basf Ag | METHOD FOR REPRESENTING ANTIC ACID |
| DE2545658C2 (en) * | 1975-10-11 | 1985-12-19 | Basf Ag, 6700 Ludwigshafen | Process for the production of carboxylic acids from their aqueous solutions |
| US4143066A (en) * | 1976-12-16 | 1979-03-06 | The Dow Chemical Company | Separation and recovery of carboxylic acids from water |
| NO138803C (en) * | 1977-03-30 | 1978-11-15 | Norsk Hydro As | PROCEDURE FOR PREPARATION OF ACTIC ACID |
| DE2744313A1 (en) * | 1977-10-01 | 1979-04-12 | Basf Ag | PROCESS FOR THE PRODUCTION OF FORM ACID |
-
1978
- 1978-12-14 DE DE19782853991 patent/DE2853991A1/en not_active Withdrawn
-
1979
- 1979-12-03 US US06/099,760 patent/US4262140A/en not_active Expired - Lifetime
- 1979-12-04 EP EP79104857A patent/EP0012321B1/en not_active Expired
- 1979-12-04 AT AT79104857T patent/ATE146T1/en not_active IP Right Cessation
- 1979-12-04 DE DE7979104857T patent/DE2960646D1/en not_active Expired
- 1979-12-11 CA CA000341669A patent/CA1135281A/en not_active Expired
- 1979-12-13 JP JP16091479A patent/JPS5583730A/en active Granted
- 1979-12-13 NO NO794080A patent/NO149470C/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6230973B2 (en) | 1987-07-06 |
| NO149470B (en) | 1984-01-16 |
| NO794080L (en) | 1980-06-17 |
| DE2853991A1 (en) | 1980-07-03 |
| EP0012321B1 (en) | 1981-08-12 |
| EP0012321A1 (en) | 1980-06-25 |
| US4262140A (en) | 1981-04-14 |
| CA1135281A (en) | 1982-11-09 |
| JPS5583730A (en) | 1980-06-24 |
| DE2960646D1 (en) | 1981-11-12 |
| NO149470C (en) | 1984-04-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EELA | Cancelled due to lapse of time |