ATE163935T1 - Verfahren und zusammensetzung zur förderung von hydrosilylierungsreaktionen unter verwendung sterisch gehinderter stickstoff- und phosphorhaltiger verbindungen - Google Patents
Verfahren und zusammensetzung zur förderung von hydrosilylierungsreaktionen unter verwendung sterisch gehinderter stickstoff- und phosphorhaltiger verbindungenInfo
- Publication number
- ATE163935T1 ATE163935T1 AT92122115T AT92122115T ATE163935T1 AT E163935 T1 ATE163935 T1 AT E163935T1 AT 92122115 T AT92122115 T AT 92122115T AT 92122115 T AT92122115 T AT 92122115T AT E163935 T1 ATE163935 T1 AT E163935T1
- Authority
- AT
- Austria
- Prior art keywords
- carbon atoms
- arylalkyl
- derivative
- alkyl
- promoter
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000006459 hydrosilylation reaction Methods 0.000 title abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 title abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 title abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 150000001875 compounds Chemical class 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 230000001737 promoting effect Effects 0.000 title 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 6
- 125000003342 alkenyl group Chemical group 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 4
- 229910052697 platinum Inorganic materials 0.000 abstract 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical class P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000002253 acid Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229910000073 phosphorus hydride Chemical class 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0801—General processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/14—Preparation thereof from optionally substituted halogenated silanes and hydrocarbons hydrosilylation reactions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/828—Platinum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Silicon Polymers (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/815,821 US5191103A (en) | 1991-12-30 | 1991-12-30 | Process and composition for promoting hydrosilylation reactions using sterically hindered nitrogen-containing and phosphorus-containing compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE163935T1 true ATE163935T1 (de) | 1998-03-15 |
Family
ID=25218936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT92122115T ATE163935T1 (de) | 1991-12-30 | 1992-12-29 | Verfahren und zusammensetzung zur förderung von hydrosilylierungsreaktionen unter verwendung sterisch gehinderter stickstoff- und phosphorhaltiger verbindungen |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5191103A (de) |
| EP (1) | EP0550064B1 (de) |
| AT (1) | ATE163935T1 (de) |
| DE (1) | DE69224728T2 (de) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9223335D0 (en) * | 1992-11-06 | 1992-12-23 | Dow Corning | Hydrosilylation process |
| JPH08143778A (ja) * | 1994-11-18 | 1996-06-04 | Kanegafuchi Chem Ind Co Ltd | ヒドロシリル化法及びそれを利用した硬化剤の製造方法 |
| US5449802A (en) * | 1994-12-27 | 1995-09-12 | Dow Corning Corporation | Acetylenic alcohols and ethers as accelerators for hydrosilation |
| JP2978435B2 (ja) * | 1996-01-24 | 1999-11-15 | チッソ株式会社 | アクリロキシプロピルシランの製造方法 |
| US5856369A (en) * | 1996-07-30 | 1999-01-05 | Osi Specialties, Inc. | Polyethers and polysiloxane copolymers manufactured with double metal cyanide catalysts |
| US6071977A (en) * | 1996-10-31 | 2000-06-06 | Ck Witco Corporation | Hydrosilation in high boiling natural vegetable oils |
| CA2221389C (en) | 1996-11-18 | 2009-01-27 | Kenrick M. Lewis | Treatment of polyethers prior to hydrosilylation |
| US6103847A (en) * | 1997-05-27 | 2000-08-15 | Witco Corporation | Siloxane-polyether copolymers with unsaturated functionalities, and process for making them |
| US6013711A (en) * | 1997-06-18 | 2000-01-11 | Ck Witco Corporation | Hydrophilic polysiloxane compositions |
| US5986022A (en) * | 1998-04-01 | 1999-11-16 | Witco Corporation | Continuous manufacture of silicone coploymers |
| US5922895A (en) * | 1998-04-17 | 1999-07-13 | Dow Corning Corporation | Amine borane complexes and phosphineborane complexes as catalyst for hydrosilation |
| US6372874B1 (en) | 1998-12-04 | 2002-04-16 | Crompton Corporation | Process for the preparation of siloxane-oxyalkylene copolymers |
| WO2001014458A1 (en) * | 1999-08-25 | 2001-03-01 | General Electric Company | Polar solvent compatible polyethersiloxane elastomers |
| US6346583B1 (en) | 1999-08-25 | 2002-02-12 | General Electric Company | Polar solvent compatible polyethersiloxane elastomers |
| US6797742B2 (en) | 1999-08-25 | 2004-09-28 | General Electric Company | Polar solvent compatible polyethersiloxane elastomers |
| US6590117B1 (en) | 2001-11-15 | 2003-07-08 | Crompton Corporation | Promoted hydrosilation reactions |
| US20040053810A1 (en) * | 2002-08-16 | 2004-03-18 | Tully Jo Anne | Liquid laundry compositions comprising silicone additives |
| US6897280B2 (en) | 2002-09-23 | 2005-05-24 | General Electric Company | Continuous manufacture of silicone copolymers via multi-stage blade-mixed plug flow tubular reactor |
| DE10359589A1 (de) * | 2003-12-18 | 2005-07-28 | Wacker-Chemie Gmbh | Verfahren zur Herstellung von Organosiliciumverbindungen |
| EP2001932B1 (de) | 2006-03-31 | 2009-08-12 | Dow Corning Corporation | Herstellungsverfahren für silikonpolyether |
| US20080033136A1 (en) * | 2006-07-13 | 2008-02-07 | Rinard Chauncey J | Selective hydrosilylation conditions |
| US7259220B1 (en) * | 2006-07-13 | 2007-08-21 | General Electric Company | Selective hydrosilylation method |
| US7569645B2 (en) * | 2007-06-27 | 2009-08-04 | Momentive Performance Materials Inc. | Curable silyl-containing polymer composition containing paint adhesion additive |
| JP5459280B2 (ja) * | 2011-09-12 | 2014-04-02 | 信越化学工業株式会社 | オルガノキシシリル基又はシロキシ基含有エチルノルボルネン化合物の製造方法 |
| KR20140137428A (ko) | 2012-03-22 | 2014-12-02 | 모멘티브 퍼포먼스 머티리얼즈 인크. | 친수성 실리콘 모노머, 이의 제조방법 및 이를 함유하는 박막 |
| JP6250026B2 (ja) | 2012-03-22 | 2017-12-20 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | 重合化可能なアミド含有有機ケイ素化合物、ケイ素含有ポリマーおよびそれらによる生物医学用具 |
| KR20140138926A (ko) | 2012-03-22 | 2014-12-04 | 모멘티브 퍼포먼스 머티리얼즈 인크. | 친수성 매크로머 및 이를 포함하여 구성되는 하이드로겔 |
| JP6257653B2 (ja) | 2013-02-06 | 2018-01-10 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | （メタ）アクリロキシ含有トリシロキサン、シロキサン含有ポリマー、およびそれらによる生物医学用具 |
| EP3415548B1 (de) | 2017-06-13 | 2020-03-25 | Evonik Operations GmbH | Verfahren zur herstellung sic-verknüpfter polyethersiloxane |
| EP3415547B1 (de) | 2017-06-13 | 2020-03-25 | Evonik Operations GmbH | Verfahren zur herstellung sic-verknüpfter polyethersiloxane |
| CN109867790B (zh) * | 2018-12-24 | 2021-07-13 | 南京美思德新材料有限公司 | 一种有机硅聚醚共聚物及其制备方法 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2637738A (en) * | 1949-09-17 | 1953-05-05 | Union Carbide & Carbon Corp | Reaction of silanes with aliphatic unsaturated compounds |
| US3057902A (en) * | 1960-08-31 | 1962-10-09 | Union Carbide Corp | Ester solvents and basic catalysts employed in an addition process |
| US3159601A (en) * | 1962-07-02 | 1964-12-01 | Gen Electric | Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes |
| US3220972A (en) * | 1962-07-02 | 1965-11-30 | Gen Electric | Organosilicon process using a chloroplatinic acid reaction product as the catalyst |
| US3715334A (en) * | 1970-11-27 | 1973-02-06 | Gen Electric | Platinum-vinylsiloxanes |
| US3795656A (en) * | 1973-01-02 | 1974-03-05 | Stauffer Chemical Co | Organosilicon compositions containing ammonium platinum adducts |
| US3925434A (en) * | 1975-01-22 | 1975-12-09 | Union Carbide Corp | The reaction of chlorosilanes with unsaturated organic compounds |
| US4292433A (en) * | 1980-10-31 | 1981-09-29 | Chisso Corporation | Method for producing 3-chloropropyltrichlorosilane |
| JPS57149290A (en) * | 1981-03-13 | 1982-09-14 | Shin Etsu Chem Co Ltd | Production of glycerol-modified silicone |
| EP0073556B1 (de) * | 1981-08-14 | 1986-01-22 | Imperial Chemical Industries Plc | Katalysator |
| DE3133869C1 (de) * | 1981-08-27 | 1983-05-05 | Th. Goldschmidt Ag, 4300 Essen | Verfahren zur Addition von organischen Siliciumverbindungen mit SiH-Gruppen an Verbindungen mit olefinischen Doppelbindungen |
| US4398010A (en) * | 1981-12-07 | 1983-08-09 | Sws Silicones Corporation | Method for accelerating the activity of a hydrosilation catalyst |
| US4417069A (en) * | 1983-02-22 | 1983-11-22 | General Electric Company | Method of preparing β-phenylethylchlorosilanes |
| US4447633A (en) * | 1983-06-14 | 1984-05-08 | North Dakota State University | Ultrasonically promoted hydrosilations |
| US4510094A (en) * | 1983-12-06 | 1985-04-09 | Minnesota Mining And Manufacturing Company | Platinum complex |
| JPS6114235A (ja) * | 1984-06-29 | 1986-01-22 | Toray Silicone Co Ltd | シリコ−ン硬化物から水素ガスの発生を抑制する方法 |
| US4578497A (en) * | 1984-11-30 | 1986-03-25 | Gulf Research & Development Company | Tetraalkylsilane synthetic fluids |
| FR2575085B1 (fr) * | 1984-12-20 | 1987-02-20 | Rhone Poulenc Spec Chim | Complexe platine-triene comme catalyseur de reaction d'hydrosilylation et son procede de preparation |
| FR2575086B1 (fr) * | 1984-12-20 | 1987-02-20 | Rhone Poulenc Spec Chim | Complexe platine-alcenylcyclohexene comme catalyseur de reaction d'hydrosilylation et son procede de preparation |
| JPS61205287A (ja) * | 1985-03-08 | 1986-09-11 | Toshiba Silicone Co Ltd | アミノ基含有有機ケイ素化合物の製造法 |
| US4705765A (en) * | 1985-12-19 | 1987-11-10 | General Electric Company | Hydrosilylation catalyst, method for making and use |
| US4681963A (en) * | 1985-12-19 | 1987-07-21 | General Electric Company | Hydrosilylation catalyst, method for making and use |
| US4614812A (en) * | 1985-12-31 | 1986-09-30 | Union Carbide Corporation | Novel process for promoting hydrosilation reactions using a second hydrosilane |
| JPH089005B2 (ja) * | 1987-01-29 | 1996-01-31 | 東燃株式会社 | ヒドロシリル化触媒の製造方法 |
| US4847398A (en) * | 1987-09-09 | 1989-07-11 | Union Carbide Corporation | Process for the preparation of siloxane-oxyalkylene copolymers |
| JP2665250B2 (ja) * | 1989-02-10 | 1997-10-22 | 昭和電工株式会社 | アミノプロピルアルコキシシランの製造法 |
| FR2648821A1 (de) * | 1989-06-22 | 1990-12-28 | Rhone Poulenc Chimie | |
| JPH0791307B2 (ja) * | 1990-06-07 | 1995-10-04 | 信越化学工業株式会社 | シクロペンチルトリクロロシランの製造方法 |
-
1991
- 1991-12-30 US US07/815,821 patent/US5191103A/en not_active Expired - Lifetime
-
1992
- 1992-12-29 DE DE69224728T patent/DE69224728T2/de not_active Expired - Lifetime
- 1992-12-29 EP EP92122115A patent/EP0550064B1/de not_active Expired - Lifetime
- 1992-12-29 AT AT92122115T patent/ATE163935T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0550064A2 (de) | 1993-07-07 |
| DE69224728D1 (de) | 1998-04-16 |
| EP0550064B1 (de) | 1998-03-11 |
| US5191103A (en) | 1993-03-02 |
| EP0550064A3 (en) | 1993-09-22 |
| DE69224728T2 (de) | 1998-07-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |