ATE164860T1 - Ternäres katalysatorsystem und verfahren zur herstellung von polymeren von diolefinen - Google Patents
Ternäres katalysatorsystem und verfahren zur herstellung von polymeren von diolefinenInfo
- Publication number
- ATE164860T1 ATE164860T1 AT95100542T AT95100542T ATE164860T1 AT E164860 T1 ATE164860 T1 AT E164860T1 AT 95100542 T AT95100542 T AT 95100542T AT 95100542 T AT95100542 T AT 95100542T AT E164860 T1 ATE164860 T1 AT E164860T1
- Authority
- AT
- Austria
- Prior art keywords
- diolefins
- catalyst system
- producing polymers
- ternary catalyst
- organometallic compound
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 150000001993 dienes Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- -1 lanthanide salt Chemical class 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI940241A IT1273753B (it) | 1994-02-11 | 1994-02-11 | Sistema catalitico e processo per la produzione di polidiolefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE164860T1 true ATE164860T1 (de) | 1998-04-15 |
Family
ID=11367825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT95100542T ATE164860T1 (de) | 1994-02-11 | 1995-01-17 | Ternäres katalysatorsystem und verfahren zur herstellung von polymeren von diolefinen |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US5627119A (de) |
| EP (1) | EP0667357B1 (de) |
| JP (1) | JP3534874B2 (de) |
| KR (1) | KR100356384B1 (de) |
| CN (1) | CN1064971C (de) |
| AT (1) | ATE164860T1 (de) |
| CA (1) | CA2142229C (de) |
| DE (1) | DE69501971T2 (de) |
| IT (1) | IT1273753B (de) |
| RU (1) | RU2141486C1 (de) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100339524B1 (ko) * | 1994-11-15 | 2002-11-23 | 엘지전자주식회사 | 펄세이터세탁기의포꼬임방지장치 |
| US6117571A (en) * | 1997-03-28 | 2000-09-12 | Advanced Technology Materials, Inc. | Compositions and method for forming doped A-site deficient thin-film manganate layers on a substrate |
| TW420693B (en) | 1997-04-25 | 2001-02-01 | Mitsui Chemicals Inc | Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers |
| US6018007A (en) * | 1997-09-22 | 2000-01-25 | Bridgestone Corporation | Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst |
| DE19746266A1 (de) | 1997-10-20 | 1999-04-22 | Bayer Ag | Katalysator auf Basis von Verbindungen der seltenen Erdmetalle für die Polymerisation von ungesättigten organischen Verbindungen |
| IT1296572B1 (it) * | 1997-11-27 | 1999-07-14 | Enichem Spa | Complessi catalitici a base di lantanidi per la (co)polimerizzazione di dieni coniugati |
| JPH11228634A (ja) * | 1997-12-08 | 1999-08-24 | Agency Of Ind Science & Technol | ブタジエン系重合体、その製造法、および触媒 |
| DE69938848D1 (de) * | 1998-02-04 | 2008-07-10 | Agency Ind Science Techn | Butadienpolymer und Verfahren zur Herstellung von konjugiertem Dienpolymer |
| JP4085476B2 (ja) * | 1998-06-15 | 2008-05-14 | 日本ゼオン株式会社 | タイヤ用共役ジエン系ゴム組成物およびタイヤ |
| TW576843B (en) | 1998-12-25 | 2004-02-21 | Mitsui Chemicals Inc | Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst |
| KR100365581B1 (ko) * | 1999-02-25 | 2003-01-15 | 금호석유화학 주식회사 | 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법 |
| WO2000052062A1 (fr) * | 1999-03-04 | 2000-09-08 | Riken | Composition de catalyseur |
| KR100298571B1 (ko) | 1999-06-17 | 2001-09-13 | 박찬구 | 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법 |
| FR2795976B1 (fr) * | 1999-07-05 | 2001-10-05 | Rhodia Terres Rares | Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures |
| DE10115106A1 (de) * | 2001-03-27 | 2002-10-10 | Bayer Ag | Blockcopolymerisat auf Basis von konjugierten Diolefinen und polaren Monomeren |
| US9226876B2 (en) * | 2001-10-19 | 2016-01-05 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, and syringe plungers |
| US6780948B2 (en) | 2002-03-28 | 2004-08-24 | The Goodyear Tire & Rubber Company | Synthesis of polyisoprene with neodymium catalyst |
| CA2502345A1 (fr) * | 2002-10-16 | 2004-04-29 | Michelin Recherche Et Technique S.A. | Copolymeres ethylene/ butadiene, system catalytique et les produires et production desdits polymers |
| ES2437197T3 (es) * | 2003-06-09 | 2014-01-09 | Bridgestone Corporation | Composiciones elastoméricas de histéresis mejorada que comprenden polímeros terminados con isocianato-alcoxisilanos |
| FR2858817B1 (fr) * | 2003-08-13 | 2006-02-03 | Michelin Soc Tech | Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres |
| US7091150B2 (en) * | 2003-12-19 | 2006-08-15 | The Goodyear Tire & Rubber Company | Synthetic polyisoprene rubber |
| ITMI20040076A1 (it) * | 2004-01-22 | 2004-04-22 | Polimeri Europa Spa | Procedimento per la preparazione di polibutadiene a basso grado di ranificazione |
| KR101185562B1 (ko) * | 2004-11-01 | 2012-09-24 | 우베 고산 가부시키가이샤 | 공액 디엔 중합체의 중합용 촉매 및 그를 이용한 공액 디엔중합체의 제조 방법, 타이어용 고무 조성물 및 골프공용고무 조성물 |
| JP4736772B2 (ja) * | 2005-12-12 | 2011-07-27 | 宇部興産株式会社 | ポリブタジエンの製造方法 |
| JP2007161918A (ja) * | 2005-12-15 | 2007-06-28 | Ube Ind Ltd | 共役ジエン重合体の製造方法 |
| JP4983015B2 (ja) * | 2005-12-15 | 2012-07-25 | 宇部興産株式会社 | 共役ジエン重合体の製造方法 |
| FR2906534B1 (fr) * | 2006-09-29 | 2009-01-09 | Rhodia Recherches & Tech | Systeme catalytique de polymerisation a base de borohydrure active. |
| TWI458747B (zh) | 2008-12-25 | 2014-11-01 | Ube Industries | Preparation of conjugated diene polymers |
| EP2363303A1 (de) * | 2010-02-19 | 2011-09-07 | LANXESS Deutschland GmbH | Bimodales NdBR |
| JP5557710B2 (ja) * | 2010-11-30 | 2014-07-23 | 株式会社ブリヂストン | 共重合体 |
| RU2523799C1 (ru) | 2011-12-20 | 2014-07-27 | Чайна Петролеум Энд Кемикал Корпорейшн | Добавка и способ для обрыва полимеризации и/или снижения вязкости раствора полимера |
| FR2984890B1 (fr) * | 2011-12-22 | 2014-06-13 | Michelin Soc Tech | Activation de systemes catalytiques pour la polymerisation stereospecifique des dienes |
| US9365666B2 (en) | 2012-05-30 | 2016-06-14 | Bridgestone Corporation | Polymerization catalyst composition, method for producing synthetic polyisoprene, and synthetic polyisoprene |
| JP6031375B2 (ja) | 2013-02-14 | 2016-11-24 | 株式会社ブリヂストン | 重合触媒組成物、合成ポリイソプレンの製造方法、及び合成ポリイソプレン |
| JP6031374B2 (ja) | 2013-02-14 | 2016-11-24 | 株式会社ブリヂストン | イソプレン重合触媒組成物、合成ポリイソプレンの製造方法及び合成ポリイソプレン |
| EP2975067B1 (de) * | 2013-03-13 | 2017-10-04 | UBE Industries, Ltd. | Katalysator zur verwendung für die polymerisation von konjugiertem dien, konjugiertes dienpolymer und modifiziertes konjugiertes dienpolymer jeweils hergestellt unter verwendung dieses katalysators, zugehörige verfahren zur herstellung dieser polymere, kautschukzusammensetzung für reifen und kautschukzusammensetzung für gummiriemen |
| JP6665779B2 (ja) * | 2014-07-09 | 2020-03-13 | 宇部興産株式会社 | 共役ジエン重合用触媒、共役ジエン重合体、変性共役ジエン重合体、及びポリブタジエン、並びに、それらを含む組成物 |
| JPWO2016039004A1 (ja) * | 2014-09-12 | 2017-06-22 | 宇部興産株式会社 | ポリブタジエン、及びゴム組成物 |
| CN106046227B (zh) * | 2016-03-01 | 2019-01-04 | 盘锦和运新材料有限公司 | 一种调节低顺式聚异戊二烯橡胶分子量分布的方法 |
| CN109863181B (zh) | 2016-10-31 | 2021-07-16 | 株式会社普利司通 | 制备用于在线本体聚合的催化剂的方法 |
| PT3348589T (pt) * | 2017-01-16 | 2019-10-18 | Evonik Degussa Gmbh | Polibutadienos, preparação e utilização dos mesmos |
| US11767388B1 (en) | 2019-09-18 | 2023-09-26 | The Goodyear Tire & Rubber Company | Silicon-functionalized rubber |
| EP3838932B1 (de) | 2019-12-20 | 2022-08-10 | The Goodyear Tire & Rubber Company | Synthese von isopren-butadien-copolymerkautschuken |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2921060A (en) * | 1956-07-12 | 1960-01-12 | Sun Oil Co | Polymerization of ethylene with a cerium acetylacetonate-metal alkyl catalyst |
| US3803053A (en) * | 1968-05-08 | 1974-04-09 | Atlantic Richfield Co | Lanthanide oligomerization catalyst |
| DE2830080A1 (de) * | 1978-07-08 | 1980-01-17 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| IT1140452B (it) * | 1981-09-25 | 1986-09-24 | Anic Spa | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
| CA1212932A (en) * | 1982-04-01 | 1986-10-21 | Derek K. Jenkins | Polymerisation of conjugated dienes |
| US4663405A (en) * | 1986-04-16 | 1987-05-05 | The Goodyear Tire & Rubber Company | Molecular weight modifier for use with lanthanide and actinide catalysts |
| EP0304088B1 (de) * | 1987-08-19 | 1993-01-27 | Asahi Kasei Kogyo Kabushiki Kaisha | Präpolymerisationsverfahren zur Herstellung einer Lösung einer konjugierten Dienverbindung |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| GB9119234D0 (en) * | 1991-09-09 | 1991-10-23 | Enichem Elastomers Ltd | Conjugated diene polymerisation |
| US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
| JP3318999B2 (ja) * | 1992-04-09 | 2002-08-26 | 株式会社デンソー | コンプレッサ液圧縮検出装置およびコンプレッサ制御装置 |
| US5347024A (en) * | 1993-03-19 | 1994-09-13 | The Dow Chemical Company | Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation |
-
1994
- 1994-02-11 IT ITMI940241A patent/IT1273753B/it active IP Right Grant
-
1995
- 1995-01-17 AT AT95100542T patent/ATE164860T1/de not_active IP Right Cessation
- 1995-01-17 DE DE69501971T patent/DE69501971T2/de not_active Expired - Lifetime
- 1995-01-17 EP EP95100542A patent/EP0667357B1/de not_active Expired - Lifetime
- 1995-02-03 US US08/383,234 patent/US5627119A/en not_active Expired - Lifetime
- 1995-02-08 KR KR1019950002190A patent/KR100356384B1/ko not_active Expired - Lifetime
- 1995-02-10 CA CA002142229A patent/CA2142229C/en not_active Expired - Lifetime
- 1995-02-10 CN CN951019430A patent/CN1064971C/zh not_active Expired - Lifetime
- 1995-02-10 RU RU95101835A patent/RU2141486C1/ru active
- 1995-02-13 JP JP02437895A patent/JP3534874B2/ja not_active Expired - Lifetime
- 1995-08-17 US US08/516,285 patent/US5659101A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ITMI940241A1 (it) | 1995-08-12 |
| IT1273753B (it) | 1997-07-10 |
| RU2141486C1 (ru) | 1999-11-20 |
| CA2142229A1 (en) | 1995-08-12 |
| US5627119A (en) | 1997-05-06 |
| EP0667357A1 (de) | 1995-08-16 |
| DE69501971D1 (de) | 1998-05-14 |
| KR100356384B1 (ko) | 2003-02-11 |
| ITMI940241A0 (it) | 1994-02-11 |
| RU95101835A (ru) | 1997-03-20 |
| KR950032299A (ko) | 1995-12-20 |
| JP3534874B2 (ja) | 2004-06-07 |
| JPH07268013A (ja) | 1995-10-17 |
| CA2142229C (en) | 2006-01-17 |
| DE69501971T2 (de) | 1998-07-30 |
| US5659101A (en) | 1997-08-19 |
| CN1064971C (zh) | 2001-04-25 |
| EP0667357B1 (de) | 1998-04-08 |
| CN1111646A (zh) | 1995-11-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |