ATE164860T1 - Ternäres katalysatorsystem und verfahren zur herstellung von polymeren von diolefinen - Google Patents
Ternäres katalysatorsystem und verfahren zur herstellung von polymeren von diolefinenInfo
- Publication number
- ATE164860T1 ATE164860T1 AT95100542T AT95100542T ATE164860T1 AT E164860 T1 ATE164860 T1 AT E164860T1 AT 95100542 T AT95100542 T AT 95100542T AT 95100542 T AT95100542 T AT 95100542T AT E164860 T1 ATE164860 T1 AT E164860T1
- Authority
- AT
- Austria
- Prior art keywords
- diolefins
- catalyst system
- producing polymers
- ternary catalyst
- organometallic compound
- Prior art date
Links
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title 1
- 150000001993 dienes Chemical class 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- -1 lanthanide salt Chemical class 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI940241A IT1273753B (it) | 1994-02-11 | 1994-02-11 | Sistema catalitico e processo per la produzione di polidiolefine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE164860T1 true ATE164860T1 (de) | 1998-04-15 |
Family
ID=11367825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT95100542T ATE164860T1 (de) | 1994-02-11 | 1995-01-17 | Ternäres katalysatorsystem und verfahren zur herstellung von polymeren von diolefinen |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US5627119A (de) |
| EP (1) | EP0667357B1 (de) |
| JP (1) | JP3534874B2 (de) |
| KR (1) | KR100356384B1 (de) |
| CN (1) | CN1064971C (de) |
| AT (1) | ATE164860T1 (de) |
| CA (1) | CA2142229C (de) |
| DE (1) | DE69501971T2 (de) |
| IT (1) | IT1273753B (de) |
| RU (1) | RU2141486C1 (de) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100339524B1 (ko) * | 1994-11-15 | 2002-11-23 | 엘지전자주식회사 | 펄세이터세탁기의포꼬임방지장치 |
| US6117571A (en) * | 1997-03-28 | 2000-09-12 | Advanced Technology Materials, Inc. | Compositions and method for forming doped A-site deficient thin-film manganate layers on a substrate |
| TW420693B (en) | 1997-04-25 | 2001-02-01 | Mitsui Chemicals Inc | Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers |
| US6018007A (en) * | 1997-09-22 | 2000-01-25 | Bridgestone Corporation | Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst |
| DE19746266A1 (de) | 1997-10-20 | 1999-04-22 | Bayer Ag | Katalysator auf Basis von Verbindungen der seltenen Erdmetalle für die Polymerisation von ungesättigten organischen Verbindungen |
| IT1296572B1 (it) * | 1997-11-27 | 1999-07-14 | Enichem Spa | Complessi catalitici a base di lantanidi per la (co)polimerizzazione di dieni coniugati |
| JPH11228634A (ja) * | 1997-12-08 | 1999-08-24 | Agency Of Ind Science & Technol | ブタジエン系重合体、その製造法、および触媒 |
| EP1054026B1 (de) * | 1998-02-04 | 2004-12-08 | JAPAN as Represented by DIRECTOR GENERAL OF AGENCY OF INDUSTRIAL SCIENCE AND TECHNOLOGY | Butadienpolymere und verfahren zur herstellung konjugierter dienpolymere |
| JP4085476B2 (ja) * | 1998-06-15 | 2008-05-14 | 日本ゼオン株式会社 | タイヤ用共役ジエン系ゴム組成物およびタイヤ |
| TW576843B (en) | 1998-12-25 | 2004-02-21 | Mitsui Chemicals Inc | Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst |
| KR100365581B1 (ko) * | 1999-02-25 | 2003-01-15 | 금호석유화학 주식회사 | 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법 |
| KR100674760B1 (ko) | 1999-03-04 | 2007-01-25 | 리가가쿠 겐큐쇼 | 촉매 조성물 |
| KR100298571B1 (ko) | 1999-06-17 | 2001-09-13 | 박찬구 | 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법 |
| FR2795976B1 (fr) * | 1999-07-05 | 2001-10-05 | Rhodia Terres Rares | Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures |
| DE10115106A1 (de) * | 2001-03-27 | 2002-10-10 | Bayer Ag | Blockcopolymerisat auf Basis von konjugierten Diolefinen und polaren Monomeren |
| US9226876B2 (en) * | 2001-10-19 | 2016-01-05 | The Goodyear Tire & Rubber Company | Rubber for baby bottle nipples, pacifiers, and syringe plungers |
| US6780948B2 (en) | 2002-03-28 | 2004-08-24 | The Goodyear Tire & Rubber Company | Synthesis of polyisoprene with neodymium catalyst |
| CN101045770A (zh) * | 2002-10-16 | 2007-10-03 | 米其林技术公司 | 用于合成乙烯和丁二烯共聚物的催化体系 |
| ES2437197T3 (es) * | 2003-06-09 | 2014-01-09 | Bridgestone Corporation | Composiciones elastoméricas de histéresis mejorada que comprenden polímeros terminados con isocianato-alcoxisilanos |
| FR2858817B1 (fr) * | 2003-08-13 | 2006-02-03 | Michelin Soc Tech | Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres |
| US7091150B2 (en) * | 2003-12-19 | 2006-08-15 | The Goodyear Tire & Rubber Company | Synthetic polyisoprene rubber |
| ITMI20040076A1 (it) * | 2004-01-22 | 2004-04-22 | Polimeri Europa Spa | Procedimento per la preparazione di polibutadiene a basso grado di ranificazione |
| EP1816145B1 (de) | 2004-11-01 | 2014-01-15 | Ube Industries, Ltd. | Polymerisationskatalysator für polymer auf basis von konjugierten dienen, verfahren zur herstellung von polymer auf basis von konjugierten dienen damit, kautschukzusammensetzung für reifen und kautschukzusammensetzung für golfball |
| JP4736772B2 (ja) * | 2005-12-12 | 2011-07-27 | 宇部興産株式会社 | ポリブタジエンの製造方法 |
| JP2007161918A (ja) * | 2005-12-15 | 2007-06-28 | Ube Ind Ltd | 共役ジエン重合体の製造方法 |
| JP4983015B2 (ja) * | 2005-12-15 | 2012-07-25 | 宇部興産株式会社 | 共役ジエン重合体の製造方法 |
| FR2906534B1 (fr) * | 2006-09-29 | 2009-01-09 | Rhodia Recherches & Tech | Systeme catalytique de polymerisation a base de borohydrure active. |
| TWI458747B (zh) | 2008-12-25 | 2014-11-01 | Ube Industries | Preparation of conjugated diene polymers |
| EP2363303A1 (de) * | 2010-02-19 | 2011-09-07 | LANXESS Deutschland GmbH | Bimodales NdBR |
| JP5557710B2 (ja) * | 2010-11-30 | 2014-07-23 | 株式会社ブリヂストン | 共重合体 |
| RU2523799C1 (ru) | 2011-12-20 | 2014-07-27 | Чайна Петролеум Энд Кемикал Корпорейшн | Добавка и способ для обрыва полимеризации и/или снижения вязкости раствора полимера |
| FR2984890B1 (fr) * | 2011-12-22 | 2014-06-13 | Michelin Soc Tech | Activation de systemes catalytiques pour la polymerisation stereospecifique des dienes |
| JP6055824B2 (ja) * | 2012-05-30 | 2016-12-27 | 株式会社ブリヂストン | 重合触媒組成物、合成ポリイソプレンの製造方法、及び合成ポリイソプレン |
| JP6031374B2 (ja) | 2013-02-14 | 2016-11-24 | 株式会社ブリヂストン | イソプレン重合触媒組成物、合成ポリイソプレンの製造方法及び合成ポリイソプレン |
| JP6031375B2 (ja) | 2013-02-14 | 2016-11-24 | 株式会社ブリヂストン | 重合触媒組成物、合成ポリイソプレンの製造方法、及び合成ポリイソプレン |
| TWI639502B (zh) * | 2013-03-13 | 2018-11-01 | 日商宇部興產股份有限公司 | 共軛二烯聚合用觸媒及使用該觸媒之共軛二烯聚合物、改質共軛二烯聚合物、其等之製造方法、輪胎用橡膠組成物、及橡膠皮帶用橡膠組成物 |
| US10053526B2 (en) | 2014-07-09 | 2018-08-21 | Ube Industries, Ltd. | Catalyst for conjugated diene polymerization, conjugated diene polymer, modified conjugated diene polymer, polybutadiene, and compositions comprising foregoing |
| TWI671323B (zh) * | 2014-09-12 | 2019-09-11 | 日商宇部興產股份有限公司 | 聚丁二烯及橡膠組成物 |
| CN106046227B (zh) * | 2016-03-01 | 2019-01-04 | 盘锦和运新材料有限公司 | 一种调节低顺式聚异戊二烯橡胶分子量分布的方法 |
| JP6751207B2 (ja) | 2016-10-31 | 2020-09-02 | 株式会社ブリヂストン | インラインバルク重合のための触媒を調製する方法 |
| ES2748248T3 (es) * | 2017-01-16 | 2020-03-16 | Evonik Operations Gmbh | Polibutadienos, su producción y empleo |
| US11767388B1 (en) | 2019-09-18 | 2023-09-26 | The Goodyear Tire & Rubber Company | Silicon-functionalized rubber |
| EP3838932B1 (de) | 2019-12-20 | 2022-08-10 | The Goodyear Tire & Rubber Company | Synthese von isopren-butadien-copolymerkautschuken |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2921060A (en) * | 1956-07-12 | 1960-01-12 | Sun Oil Co | Polymerization of ethylene with a cerium acetylacetonate-metal alkyl catalyst |
| US3803053A (en) * | 1968-05-08 | 1974-04-09 | Atlantic Richfield Co | Lanthanide oligomerization catalyst |
| DE2830080A1 (de) * | 1978-07-08 | 1980-01-17 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
| IT1140452B (it) * | 1981-09-25 | 1986-09-24 | Anic Spa | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
| CA1212932A (en) * | 1982-04-01 | 1986-10-21 | Derek K. Jenkins | Polymerisation of conjugated dienes |
| US4663405A (en) * | 1986-04-16 | 1987-05-05 | The Goodyear Tire & Rubber Company | Molecular weight modifier for use with lanthanide and actinide catalysts |
| KR910008275B1 (ko) * | 1987-08-19 | 1991-10-12 | 아사히가세이고오교 가부시끼가이샤 | 공역 디엔 화화물 예비중합체 용액 제조를 위한 예비중합방법 |
| US5272236A (en) * | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| GB9119234D0 (en) * | 1991-09-09 | 1991-10-23 | Enichem Elastomers Ltd | Conjugated diene polymerisation |
| US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
| JP3318999B2 (ja) * | 1992-04-09 | 2002-08-26 | 株式会社デンソー | コンプレッサ液圧縮検出装置およびコンプレッサ制御装置 |
| US5347024A (en) * | 1993-03-19 | 1994-09-13 | The Dow Chemical Company | Preparation of addition polymerization catalysts via Lewis acid mitigated metal center oxidation |
-
1994
- 1994-02-11 IT ITMI940241A patent/IT1273753B/it active IP Right Grant
-
1995
- 1995-01-17 AT AT95100542T patent/ATE164860T1/de not_active IP Right Cessation
- 1995-01-17 DE DE69501971T patent/DE69501971T2/de not_active Expired - Lifetime
- 1995-01-17 EP EP95100542A patent/EP0667357B1/de not_active Expired - Lifetime
- 1995-02-03 US US08/383,234 patent/US5627119A/en not_active Expired - Lifetime
- 1995-02-08 KR KR1019950002190A patent/KR100356384B1/ko not_active Expired - Lifetime
- 1995-02-10 CN CN951019430A patent/CN1064971C/zh not_active Expired - Lifetime
- 1995-02-10 CA CA002142229A patent/CA2142229C/en not_active Expired - Lifetime
- 1995-02-10 RU RU95101835A patent/RU2141486C1/ru active
- 1995-02-13 JP JP02437895A patent/JP3534874B2/ja not_active Expired - Lifetime
- 1995-08-17 US US08/516,285 patent/US5659101A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR100356384B1 (ko) | 2003-02-11 |
| US5627119A (en) | 1997-05-06 |
| EP0667357B1 (de) | 1998-04-08 |
| DE69501971T2 (de) | 1998-07-30 |
| JP3534874B2 (ja) | 2004-06-07 |
| RU2141486C1 (ru) | 1999-11-20 |
| ITMI940241A1 (it) | 1995-08-12 |
| JPH07268013A (ja) | 1995-10-17 |
| EP0667357A1 (de) | 1995-08-16 |
| DE69501971D1 (de) | 1998-05-14 |
| CA2142229A1 (en) | 1995-08-12 |
| RU95101835A (ru) | 1997-03-20 |
| US5659101A (en) | 1997-08-19 |
| CA2142229C (en) | 2006-01-17 |
| IT1273753B (it) | 1997-07-10 |
| CN1111646A (zh) | 1995-11-15 |
| ITMI940241A0 (it) | 1994-02-11 |
| KR950032299A (ko) | 1995-12-20 |
| CN1064971C (zh) | 2001-04-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |