ATE167706T1 - Elektrokatalytische asymmetrische dihydroxylierung von olefinen - Google Patents
Elektrokatalytische asymmetrische dihydroxylierung von olefinenInfo
- Publication number
- ATE167706T1 ATE167706T1 AT93906081T AT93906081T ATE167706T1 AT E167706 T1 ATE167706 T1 AT E167706T1 AT 93906081 T AT93906081 T AT 93906081T AT 93906081 T AT93906081 T AT 93906081T AT E167706 T1 ATE167706 T1 AT E167706T1
- Authority
- AT
- Austria
- Prior art keywords
- adh
- osmium
- olefins
- reaction
- asymmetric dihydroxylation
- Prior art date
Links
- 238000006256 asymmetric dihydroxylation reaction Methods 0.000 title abstract 5
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 3
- 229910052762 osmium Inorganic materials 0.000 abstract 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 150000002334 glycols Chemical class 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 230000001404 mediated effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000012285 osmium tetroxide Substances 0.000 abstract 1
- 229910000489 osmium tetroxide Inorganic materials 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4061—Regeneration or reactivation of catalysts containing metals involving membrane separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4076—Regeneration or reactivation of catalysts containing metals involving electrochemical processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
- B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/839,601 US5302257A (en) | 1992-02-21 | 1992-02-21 | Electrocatalytic asymmetric dihydroxylation of olefinic compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE167706T1 true ATE167706T1 (de) | 1998-07-15 |
Family
ID=25280180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT93906081T ATE167706T1 (de) | 1992-02-21 | 1993-02-19 | Elektrokatalytische asymmetrische dihydroxylierung von olefinen |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5302257A (de) |
| EP (1) | EP0643781B1 (de) |
| JP (1) | JP3623960B2 (de) |
| AT (1) | ATE167706T1 (de) |
| AU (1) | AU670266B2 (de) |
| CA (1) | CA2130564C (de) |
| DE (1) | DE69319342T2 (de) |
| ES (1) | ES2117705T3 (de) |
| WO (1) | WO1993017150A1 (de) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5302257A (en) * | 1992-02-21 | 1994-04-12 | Sepracor, Inc. | Electrocatalytic asymmetric dihydroxylation of olefinic compounds |
| US6126795A (en) * | 1996-11-27 | 2000-10-03 | The United States Of America As Represented By The Secretary Of Commerce | Electroenzymatic reactor and method for enzymatic catalysis |
| US6800744B1 (en) * | 1997-07-02 | 2004-10-05 | Genome Therapeutics Corporation | Nucleic acid and amino acid sequences relating to Streptococcus pneumoniae for diagnostics and therapeutics |
| DE69902833T2 (de) * | 1998-03-02 | 2003-05-28 | Kobayshi Shu | Mikroverkapselte Osmiumoxidzusammensetzung |
| US6342496B1 (en) * | 1999-03-01 | 2002-01-29 | Sepracor Inc. | Bupropion metabolites and methods of use |
| DE19920039A1 (de) | 1999-04-25 | 2000-10-26 | Bayer Ag | Verfahren zur asymmetrischen Dihydroxylierung von Olefinen mittels Osmium-Katalysatoren |
| DE19920038A1 (de) | 1999-04-25 | 2000-10-26 | Bayer Ag | Verfahren zur Dihydroxylierung von Olefinen mittels Übergangsmetall-Katalysatoren |
| WO2003035253A1 (en) * | 2001-10-23 | 2003-05-01 | Council Of Scientific And Industrial Research | Process for the preparation of supported osmates |
| US6552234B1 (en) | 2001-10-23 | 2003-04-22 | Council Of Scientific And Industrial Research | Process for the preparation of supported osmates |
| US6646168B2 (en) * | 2001-10-23 | 2003-11-11 | Council Of Scientific And Industrial Research | Supported osmates, process for preparation thereof, and a process for the preparation of chiral vicinal diols using supported osmate catalyst |
| DE10213981A1 (de) * | 2002-03-28 | 2003-10-16 | Bayer Ag | Verfahren zur Herstellung von vicinalen Diolen |
| AU2002351836A1 (en) * | 2002-11-04 | 2004-06-07 | Janssen Pharmaceutica N.V. | Process for electrochemical oxidation of ferrocyanide to ferricyanide |
| CN113416977B (zh) * | 2021-06-22 | 2022-12-30 | 中国科学技术大学 | 一种KRu4O8纳米棒材料、其制备方法及其应用 |
| CN114990591B (zh) * | 2022-07-21 | 2024-02-20 | 河南师范大学 | 电化学不对称双羟化反应合成手性非环核苷类化合物的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3488394A (en) * | 1966-05-11 | 1970-01-06 | Fmc Corp | Oxidation of olefinic compounds to glycols |
| US3650918A (en) * | 1969-08-27 | 1972-03-21 | Continental Oil Co | Electrochemical oxidation of olefinic compounds |
| US3953305A (en) * | 1975-01-17 | 1976-04-27 | Standard Oil Company | Catalyst regeneration |
| US4217291A (en) * | 1978-12-26 | 1980-08-12 | Gulf Research & Development Company | Method of oxidizing osmium (III) and osmium (IV) to a higher valency state |
| US4278517A (en) * | 1980-06-26 | 1981-07-14 | Union Carbide Corporation | Osmium catalyzed hydroxylation of olefins with selenoxide cooxidants |
| KR890701536A (ko) * | 1987-09-18 | 1989-12-20 | 존 알 데이비 | 좌우상 선택적 제조방법 |
| US5126494A (en) * | 1988-01-11 | 1992-06-30 | Massachusetts Institute Of Technology | Methods for catalytic asymmetric dihydroxylation of olefins |
| US5302257A (en) * | 1992-02-21 | 1994-04-12 | Sepracor, Inc. | Electrocatalytic asymmetric dihydroxylation of olefinic compounds |
-
1992
- 1992-02-21 US US07/839,601 patent/US5302257A/en not_active Expired - Lifetime
-
1993
- 1993-02-19 AU AU37255/93A patent/AU670266B2/en not_active Expired
- 1993-02-19 AT AT93906081T patent/ATE167706T1/de not_active IP Right Cessation
- 1993-02-19 ES ES93906081T patent/ES2117705T3/es not_active Expired - Lifetime
- 1993-02-19 WO PCT/US1993/001483 patent/WO1993017150A1/en not_active Ceased
- 1993-02-19 CA CA002130564A patent/CA2130564C/en not_active Expired - Lifetime
- 1993-02-19 JP JP51496593A patent/JP3623960B2/ja not_active Expired - Lifetime
- 1993-02-19 DE DE69319342T patent/DE69319342T2/de not_active Expired - Lifetime
- 1993-02-19 EP EP93906081A patent/EP0643781B1/de not_active Expired - Lifetime
-
1994
- 1994-01-18 US US08/182,919 patent/US5419817A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5419817A (en) | 1995-05-30 |
| ES2117705T3 (es) | 1998-08-16 |
| EP0643781B1 (de) | 1998-06-24 |
| DE69319342D1 (de) | 1998-07-30 |
| US5302257A (en) | 1994-04-12 |
| AU670266B2 (en) | 1996-07-11 |
| DE69319342T2 (de) | 1998-11-19 |
| CA2130564A1 (en) | 1993-09-02 |
| EP0643781A1 (de) | 1995-03-22 |
| JPH07507101A (ja) | 1995-08-03 |
| JP3623960B2 (ja) | 2005-02-23 |
| EP0643781A4 (en) | 1995-04-26 |
| AU3725593A (en) | 1993-09-13 |
| WO1993017150A1 (en) | 1993-09-02 |
| CA2130564C (en) | 2005-11-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |