ES2117705T3 - Dihidroxilacion asimetrica electrocatalitica de compuestos olefinicos. - Google Patents

Dihidroxilacion asimetrica electrocatalitica de compuestos olefinicos.

Info

Publication number
ES2117705T3
ES2117705T3 ES93906081T ES93906081T ES2117705T3 ES 2117705 T3 ES2117705 T3 ES 2117705T3 ES 93906081 T ES93906081 T ES 93906081T ES 93906081 T ES93906081 T ES 93906081T ES 2117705 T3 ES2117705 T3 ES 2117705T3
Authority
ES
Spain
Prior art keywords
adh
asymmetric dihydroxylation
osmium
olephine
electro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93906081T
Other languages
English (en)
Inventor
Yun Gao
Charles M Zepp
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Pharma America Inc
Original Assignee
Sepracor Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sepracor Inc filed Critical Sepracor Inc
Application granted granted Critical
Publication of ES2117705T3 publication Critical patent/ES2117705T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4061—Regeneration or reactivation of catalysts containing metals involving membrane separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4076—Regeneration or reactivation of catalysts containing metals involving electrochemical processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

SE DESCRIBE UN PROCESO EN EL QUE GLICOLES OPTICAMENTE ACTIVOS SE PRODUCEN A TRAVES DE UNA REACCION DE DIHIDROXILACION ASIMETRICA ELECTROLITICA (ADH) QUE IMPLICA OLEFINAS COMO SUBSTRATOS. LA REACCION ADH ESTA FAVORECIDA POR UNA CANTIDAD CATALITICAMENTE ACTIVA DE TRETOXIDO DE OSMIO O UN PRECURSOR QUE CONTIENE OSMIO EN UN MEDIO PROTICO EN PRESENCIA DE UN LIGANDO QUIRAL. CUALQUIER ESPECIE DE OSMIO DE VALENCIA INFERIOR PRODUCIDO EN EL CURSO DE LA REACCION ADH SE REGENERA ELECTROLITICAMENTE BIEN DIRECTAMENTE EN AUSENCIA DE UN OXIDANTE SECUNDARIO O INDIRECTAMENTE EN PRESENCIA DE UN OXIDANTE SECUNDARIO QUE EXPERIMENTA POR SI MISMO LA REGENERACION ELECTROLITICA.
ES93906081T 1992-02-21 1993-02-19 Dihidroxilacion asimetrica electrocatalitica de compuestos olefinicos. Expired - Lifetime ES2117705T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/839,601 US5302257A (en) 1992-02-21 1992-02-21 Electrocatalytic asymmetric dihydroxylation of olefinic compounds

Publications (1)

Publication Number Publication Date
ES2117705T3 true ES2117705T3 (es) 1998-08-16

Family

ID=25280180

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93906081T Expired - Lifetime ES2117705T3 (es) 1992-02-21 1993-02-19 Dihidroxilacion asimetrica electrocatalitica de compuestos olefinicos.

Country Status (9)

Country Link
US (2) US5302257A (es)
EP (1) EP0643781B1 (es)
JP (1) JP3623960B2 (es)
AT (1) ATE167706T1 (es)
AU (1) AU670266B2 (es)
CA (1) CA2130564C (es)
DE (1) DE69319342T2 (es)
ES (1) ES2117705T3 (es)
WO (1) WO1993017150A1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5302257A (en) * 1992-02-21 1994-04-12 Sepracor, Inc. Electrocatalytic asymmetric dihydroxylation of olefinic compounds
US6126795A (en) * 1996-11-27 2000-10-03 The United States Of America As Represented By The Secretary Of Commerce Electroenzymatic reactor and method for enzymatic catalysis
US6800744B1 (en) * 1997-07-02 2004-10-05 Genome Therapeutics Corporation Nucleic acid and amino acid sequences relating to Streptococcus pneumoniae for diagnostics and therapeutics
DE69902833T2 (de) * 1998-03-02 2003-05-28 Kobayshi Shu Mikroverkapselte Osmiumoxidzusammensetzung
US6342496B1 (en) * 1999-03-01 2002-01-29 Sepracor Inc. Bupropion metabolites and methods of use
DE19920039A1 (de) 1999-04-25 2000-10-26 Bayer Ag Verfahren zur asymmetrischen Dihydroxylierung von Olefinen mittels Osmium-Katalysatoren
DE19920038A1 (de) 1999-04-25 2000-10-26 Bayer Ag Verfahren zur Dihydroxylierung von Olefinen mittels Übergangsmetall-Katalysatoren
WO2003035253A1 (en) * 2001-10-23 2003-05-01 Council Of Scientific And Industrial Research Process for the preparation of supported osmates
US6552234B1 (en) 2001-10-23 2003-04-22 Council Of Scientific And Industrial Research Process for the preparation of supported osmates
US6646168B2 (en) * 2001-10-23 2003-11-11 Council Of Scientific And Industrial Research Supported osmates, process for preparation thereof, and a process for the preparation of chiral vicinal diols using supported osmate catalyst
DE10213981A1 (de) * 2002-03-28 2003-10-16 Bayer Ag Verfahren zur Herstellung von vicinalen Diolen
AU2002351836A1 (en) * 2002-11-04 2004-06-07 Janssen Pharmaceutica N.V. Process for electrochemical oxidation of ferrocyanide to ferricyanide
CN113416977B (zh) * 2021-06-22 2022-12-30 中国科学技术大学 一种KRu4O8纳米棒材料、其制备方法及其应用
CN114990591B (zh) * 2022-07-21 2024-02-20 河南师范大学 电化学不对称双羟化反应合成手性非环核苷类化合物的方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3488394A (en) * 1966-05-11 1970-01-06 Fmc Corp Oxidation of olefinic compounds to glycols
US3650918A (en) * 1969-08-27 1972-03-21 Continental Oil Co Electrochemical oxidation of olefinic compounds
US3953305A (en) * 1975-01-17 1976-04-27 Standard Oil Company Catalyst regeneration
US4217291A (en) * 1978-12-26 1980-08-12 Gulf Research & Development Company Method of oxidizing osmium (III) and osmium (IV) to a higher valency state
US4278517A (en) * 1980-06-26 1981-07-14 Union Carbide Corporation Osmium catalyzed hydroxylation of olefins with selenoxide cooxidants
KR890701536A (ko) * 1987-09-18 1989-12-20 존 알 데이비 좌우상 선택적 제조방법
US5126494A (en) * 1988-01-11 1992-06-30 Massachusetts Institute Of Technology Methods for catalytic asymmetric dihydroxylation of olefins
US5302257A (en) * 1992-02-21 1994-04-12 Sepracor, Inc. Electrocatalytic asymmetric dihydroxylation of olefinic compounds

Also Published As

Publication number Publication date
US5419817A (en) 1995-05-30
EP0643781B1 (en) 1998-06-24
DE69319342D1 (de) 1998-07-30
US5302257A (en) 1994-04-12
AU670266B2 (en) 1996-07-11
DE69319342T2 (de) 1998-11-19
CA2130564A1 (en) 1993-09-02
EP0643781A1 (en) 1995-03-22
JPH07507101A (ja) 1995-08-03
JP3623960B2 (ja) 2005-02-23
EP0643781A4 (en) 1995-04-26
AU3725593A (en) 1993-09-13
WO1993017150A1 (en) 1993-09-02
ATE167706T1 (de) 1998-07-15
CA2130564C (en) 2005-11-01

Similar Documents

Publication Publication Date Title
ES2117705T3 (es) Dihidroxilacion asimetrica electrocatalitica de compuestos olefinicos.
TR200003584T2 (tr) Vinil asetat katalizörü
DE3574937D1 (de) Reaktor zum durchfuehren von heterogenen, katalysierten chemischen reaktionen.
DE3771686D1 (de) Selektives herstellungsverfahren von alkencarbonsaeurederivaten.
DE3586878D1 (de) Durch uebergangsmetall-komplexverbindungen katalysierte reaktionen.
MX9911269A (en) Method for oxidizing an organic compound containing at least on c-c double bond
IT1165700B (it) Procedimenti enzimatici
CA2021586A1 (en) Method and apparatus for heterogeneous chemiluminescence assay
DE502004011288D1 (de) Auf basis von phosphoramiditliganden
BR9910837A (pt) Catalizador para produção de acetato de vinila por reação de etileno, oxigênio e ácido acético, método para preparar um catalizador , e processo para produção de acetato de vinila
MY117733A (en) Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier
MY117131A (en) Vinyl acetate process utilizing a palladium-gold-copper catalyst
Daikai et al. Asymmetric catalysis with self‐organized chiral lanthanum complexes: Practical and highly enantioselective epoxidation of α, β‐unsaturated ketones
ATE37047T1 (de) Verfahren zum automatischen regenerieren von kupferchlorid-aetzloesungen.
ES8505265A1 (es) Un metodo para regenerar y reutilizar un catalizador de metal precioso-estano para chapado no electrolitico
DE3772847D1 (de) Verfahren zur herstellung von 2-methyl-1,4-naphthochinon.
ES8701770A1 (es) Procedimiento para preparar 1-bencil-3,4-bis-(difenilfosfino)-pirrolidina opticamente activa
Ihara et al. Cyclodextrin-catalyzed hydrolysis of enantiomeric esters showing stereoselectivity.
EP0077202A3 (en) Process for hydroxylating olefins using osmium-halogen compound catalysts
EP0148950A4 (en) Process for preparing bilirubin oxidase.
EP0334966A4 (en) Process for synthesizing optically active compounds
ES2043881T3 (es) Procedimiento para regenerar soluciones de corrosion de permanganato asi como dispositivo para la realizacion del procedimiento.
EP0528498A3 (en) Catalysts used for producing carbonic acid esters and methods of producing carbonic acid esters using the same
DE60021051D1 (de) Katalysator zur Herstellung von Allylacetat
DE69917675D1 (de) Methode zum herstellen von carbonaten in einem kontinuierlichen verfahren

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 643781

Country of ref document: ES